• Title/Summary/Keyword: cement production

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Comparison of Model-simulated Atmospheric Carbon Dioxide with GOSAT Retrievals

  • Shim, Chang-Sub;Nassar, Ray;Kim, Jhoon
    • Asian Journal of Atmospheric Environment
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    • v.5 no.4
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    • pp.263-277
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    • 2011
  • Global atmospheric $CO_2$ distributions were simulated with a chemical transport model (GEOS-Chem) and compared with space-borne observations of $CO_2$ column density by GOSAT from April 2009 to January 2010. The GEOS-Chem model simulated 3-D global atmospheric $CO_2$ at $2^{\circ}{\times}2.5^{\circ}$ horizontal resolution using global $CO_2$ surface sources/sinks as well as 3-D emissions from aviation and the atmospheric oxidation of other carbon species. The seasonal cycle and spatial distribution of GEOS-Chem $CO_2$ columns were generally comparable with GOSAT columns over each continent with a systematic positive bias of ~1.0%. Data from the World Data Center for Greenhouse Gases (WDCGG) from twelve ground stations spanning $90^{\circ}S-82^{\circ}N$ were also compared with the modeled data for the period of 2004-2009 inclusive. The ground-based data show high correlations with the GEOS-Chem simulation ($0.66{\leq}R^2{\leq}0.99$) but the model data have a negative bias of ~1.0%, which is primarily due to the model initial conditions. Together these two comparisons can be used to infer that GOSAT $CO_2$ retrievals underestimate $CO_2$ column concentration by ~2.0%, as demonstrated in recent validation work using other methods. We further estimated individual source/sink contributions to the global atmospheric $CO_2$ budget and trends through 7 tagged $CO_2$ tracers (fossil fuels, ocean exchanges, biomass burning, biofuel burning, net terrestrial exchange, shipping, aviation, and CO oxidation) over 2004-2009. The global $CO_2$ trend over this period (2.1 ppmv/year) has been mainly driven by fossil fuel combustion and cement production (3.2 ppmv/year), reinforcing the fact that rigorous $CO_2$ reductions from human activities are necessary in order to stabilize atmospheric $CO_2$ levels.

Compressive Strength Properties of Geopolymer Using Power Plant Bottom Ash and NaOH Activator (화력발전소 바텀애쉬와 수산화나트륨 활성화제를 이용해 제작한 지오폴리머의 압축강도 특성)

  • An, Eung-Mo;Cho, Sung-Baek;Lee, Su-Jeong;Miyauchi, Hiroyuki;Kim, Gyu-Yong
    • Korean Journal of Materials Research
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    • v.22 no.2
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    • pp.71-77
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    • 2012
  • When a new bonding agent using coal ash is utilized as a substitute for cement, it has the advantages of offering a reduction in the generation of carbon dioxide and securing the initial mechanical strength such that the agent has attracted strong interest from recycling and eco-friendly construction industries. This study aims to establish the production conditions of new hardening materials using clean bottom ash and an alkali activation process to evaluate the characteristics of newly manufactured hardening materials. The alkali activator for the compression process uses a NaOH solution. This study concentrated on strength development according to the concentration of the NaOH solution, the curing temperature, and the curing time. The highest compressive strength of a compressed body appeared at 61.24MPa after curing at $60^{\circ}C$ for 28 days. This result indicates that a higher curing temperature is required to obtain a higher strength body. Also, the degree of geopolymerization was examined using a scanning electron microscope, revealing a micro-structure consisting of a glass-like matrix and crystalized grains. The microstructures generated from the activation reaction of sodium hydroxide were widely distributed in terms of the factors that exercise an effect on the compressive strength of the geopolymer hardening bodies. The Si/Al ratio of the geopolymer having the maximum strength was about 2.41.

Optimization of cost and mechanical properties of concrete with admixtures using MARS and PSO

  • Benemaran, Reza Sarkhani;Esmaeili-Falak, Mahzad
    • Computers and Concrete
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    • v.26 no.4
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    • pp.309-316
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    • 2020
  • The application of multi-variable adaptive regression spline (MARS) in predicting he long-term compressive strength of a concrete with various admixtures has been investigated in this study. The compressive strength of concrete specimens, which were made based on 24 different mix designs using various mineral and chemical admixtures in different curing ages have been obtained. First, The values of fly ash (FA), micro-silica (MS), water-reducing admixture (WRA), coarse and fine aggregates, cement, water, age of samples and compressive strength were defined as inputs to the model, and MARS analysis was used to model the compressive strength of concrete and to evaluate the most important parameters affecting the estimation of compressive strength of the concrete. Next, the proposed equation by the MARS method using particle swarm optimization (PSO) algorithm has been optimized to have more efficient equation from the economical point of view. The proposed model in this study predicted the compressive strength of the concrete with various admixtures with a correlation coefficient of R=0.958 rather than the measured compressive strengths within the laboratory. The final model reduced the production cost and provided compressive strength by reducing the WRA and increasing the FA and curing days, simultaneously. It was also found that due to the use of the liquid membrane-forming compounds (LMFC) for its lower cost than water spraying method (SWM) and also for the longer operating time of the LMFC having positive mechanical effects on the final concrete, the final product had lower cost and better mechanical properties.

Modified Sulfur Distribution and Compressive Strength Characteristics of Modified Sulfur Mortar Based on the Mixing Method and Curing Condition (비빔방법과 양생조건에 따른 개질유황 모르타르의 개질유황 분포도 및 압축강도 특성)

  • Jung, Byeong-Yeol;Lee, Sang-Soo;Song, Ha-Young
    • Journal of the Korea Institute of Building Construction
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    • v.14 no.1
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    • pp.61-67
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    • 2014
  • As industry advances, the production of industrial sulfur is increasing every year. Therefore, this study intended to investigate the modified sulfur distribution and compressive strength characteristics of modified sulfur mortar based on the mixing method and curing conditions by adding modified sulfur with a melting point of approximately $65^{\circ}C$ in order to provide basic data for the application of the modified sulfur to the mortar or concrete. The results of the experiment showed that the mixture of fine aggregate and cement with water, followed by the addition of modified sulfur, would be most advantageous in terms of fluidity and strength. The results of EDS analysis also showed that the distribution of sulfur was the best. In terms of the curing conditions, the highest compressive strength was achieved through water curing and air dry curing at $20^{\circ}C$. However, it was found that the long-term strength was adversely affected by curing at over $40^{\circ}C$.

A Study on Environmentally Friendly Soil Pavement Materials Using Weathered Soil and Inorganic Binder (화강풍화토와 무기질 결합재를 활용한 친환경 흙포장에 관한 연구)

  • Jung, Hyuksang;Jang, Cheolho;An, Byungjae;Chun, Byungsik
    • Journal of the Korean GEO-environmental Society
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    • v.10 no.4
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    • pp.25-31
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    • 2009
  • In this study, the problem of existing soil pavement is a long-term durability lack and crack occurrence. It complements in order to develop the environmental soil pavement material which composites readily blended mineral binder of liquid and decomposed granite soils. It was estimated optimal mixture proportion for unconfined compressive strength, permeability, $Cr^{6+}$detection test, SEM test with age, freezing and thawing test. It resulted mixture proportion of powder types mineral binder for rates of cement : fly ash : plaster was optimal rates of 50 : 33 : 7, and $Cr^{6+}$detection test as a result was a slight production. SEM test with 3days as a result was made Ettringite. It was found that this material was early development of early-strength for chemical. This study indicated that it will execute field appliciability Evaluation test, examination of soil pavement method with decomposed granite soils and mineral binder.

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Effect of Additives on the Compressive Strength of Geopolymerized Fly Ash (각종 첨가제가 지오폴리머 반응된 석탄회의 압축강도에 미치는 영향)

  • Hwang, Yeon
    • Korean Journal of Materials Research
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    • v.22 no.9
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    • pp.494-498
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    • 2012
  • Geopolymer cements and geopolymer resins are newly advanced mineral binders that are used in order to reduce the carbon dioxide generation that accompanies cement production. The effect of additives on the compressive strength of geopolymerized class-F fly ash was investigated. Blast furnace slag, calcium hydroxide($Ca(OH)_2$), and silica fume powders were added to fly ash. A geopolymeric reaction was initiated by adding a solution of water glass and sodium hydroxide(NaOH) to the powder mixtures. The compressive strength of pure fly ash cured at room temperature for 28 days was found to be as low as 291 $kgf/cm^{-2}$, which was not a suitable value for use in engineering materials. On the contrary, addition of 20 wt% and 40 wt% of blast furnace slag powders to fly ash increased the compressive strength to 458 $kgf/cm^{-2}$ and 750 $kgf/cm^{-2}$, respectively. 5 wt% addition of $Ca(OH)_2$ increased the compressive strength up to 640 $kgf/cm^{-2}$; further addition of $Ca(OH)_2$ further increased the compressive strength. When 2 wt% of silica fume was added, the compressive strength increased to 577 $kgf/cm^{-2}$; the maximum strength was obtained at 6 wt% addition of silica fume. It was confirmed that the addition of CaO and $SiO_2$ to the fly ash powders was effective at increasing the compressive strength of geopolymerized fly ash.

Fundamental Study on Estimating Compressive Strength and Physical Characteristic of Heat insulation Lightweight Mortar With Foam Agent (기포제 혼입 단열형 경량모르타르의 물리적 특성 및 압축강도 추정에 관한 기초적 연구)

  • Min, Tae-Beom;Woo, Young-Je;Lee, han-Seung
    • KIEAE Journal
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    • v.10 no.3
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    • pp.89-96
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    • 2010
  • In comparison with ordinary or heavy-weight concrete, light-weight air void concrete has the good aspects in optimizing super tall structure systems for the process of design considering wind load and seismic load by lightening total dead load of buildings and reducing natural resources used. Light-weight air void concrete has excellent properties of heat and sound insulating due to its high amount porosity of air voids. So, it has been used as partition walls and the floor of Ondol which is the traditional Korean floor heating system. Under the condition of which the supply of light-weight aggregates are limited, the development of light-weight concrete using air voids is highly required in the aspects of reduced manufacturing prices and mass production. In this study, we investigated the physical properties and thermal behaviors of specimens that applied different mixing ratios of foaming agent to evaluate the possibility of use in the structural elements. We proposed the estimating equation for compressive strength of each mix having different ratio of foaming agent. We also confirmed that the density of cement matrix is decreased as the mixing amount of foaming agent increase up to 0.6% of foaming agent mixing ratio which was observed by SEM. Based on porosity and compressive strength of control mortar without foaming agent, we built the estimating equations of compressive strength for mortars with foaming agent. The upper limit of use in foaming agent is about 0.6% of the binder amount. Each air void is independent, and size of voids range from 50 to $100{\mu}m$.

International Symposium and Collaborative Study on Deep Cement Mixing, Okinawa 2009 (2009 오키나와 Deep Mixing 심포지엄 및 공동연구)

  • Jeong, Gyeong-Hwan;Shin, Min-Shik;Han, Gyeong-Tae;Lee, Jung-Hwa;Kim, Jae-Hwan
    • Proceedings of the Korean Geotechical Society Conference
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    • 2008.03a
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    • pp.972-978
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    • 2008
  • Quality Assurance of Deep Mixing to fulfill the requirements of geotechnical design cannot be achieved only by the process control During production conducted by the deep mixing contractor but it should involve relevant activities that are carried out prior to, during and after the construction by all the parties involved in a deep mixing project. The requirement is different for different application, and hence, QA/QC method/procedure and verification technique may be different for different application. In order to maintain the high quality of deep mixing work in the global market, it is necessary to conduct a research project, such as investigation of illustrations, the variety of existing QA/QC methods/procedures, the correlation between the outcomes of different QA/QC methods. In these reason, it has been held the international meeting to discuss them, in that kind of activities in 2009 it will be held Symposium. Also Collaborative study for QA/QC is on goin, and conduction by all participated members. The subject for collaborative study are, task 1 : investigation of laboratory tests procedures, task 2 : comparing of different laboratory tests procedures, task 3 : QA/QC method/procedures, task 4 : integrated Task1 ~task 3. The discussion of the results in all task will be held in the Symposium separately. In this paper, it was presented four tasks. Also the results in task 1 and 2 conducting domestically until now, such as investigation of laboratory test procedures, effect on the unconfined compressive strength by aging temperature and by delayed time.

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Growth in the Sultanate of Oman of Small Ruminants Given Date Byproducts-Urea Multinutrient Blocks

  • El Hag, M.G.;Al-Merza, M.A.;Al Salti, B.
    • Asian-Australasian Journal of Animal Sciences
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    • v.15 no.5
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    • pp.671-674
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    • 2002
  • This study investigated the use of multinutrient blocks (MNB) composed of 35% date syrup, 35% date syrup byproducts, 10% date fronds, 7% urea, 7% cement and 6% common salt for growing small ruminants, as partial substitute for the roughage component of the diet (Rhodes grass hay) and its effect on feedlot performance and economics of feeding. Eight growing local Omani goats and 8 sheep (each about one year old) were used in this study. Mean body weights for goats and sheep (kg), respectively were $21.1{\pm}4.5$ and $25.5{\pm}4.1$. The goats and sheep were subdivided into two sub-groups of more or less equal body weights for each species. Each sub-group in both species was either fed on 0.5 kg concentrate+ad libitum Rhodes grass hay or the same diet+restricted hay (about 0.2 kg/head/day) and ad libitum amount of MNB. Sheep significantly (p<0.05) consumed greater amounts of MNB ($36{\pm}17$g/head/day) than goats ($6{\pm}2.5$ g/head/day). Feeding of the MNB was effective in sparing about 40% of the roughage Rhodes grass hay for goats (from 240 to 140 g) and about 42% for sheep (from 252 to 146 g) or approximately 100 g/head/day for both goats and sheep. This reduction (or sparing) in the consumption of Rhodes grass hay was coupled by an improvement in daily liveweight gain (g/head/day) in both goats (from 29 to 46 by 58.6%) and sheep (from 26 to 39 by 50%) and also by an improvement in the feed conversion efficiency (g feed/g gain) of both goats (from 25 to 13.8 by 45%) and sheep (from 28.7 to 17.2 by 40%). Cost of daily consumed feeds as well as cost/kg gain (or cost of meat) were both reduced due to feeding of MNB. They were both respectively reduced by 7.5% (from 53 Baisa/day to 49) and 38% (from 1,828 Baisa/kg to 1,140). It was economically viable to feed MNBs containing date by-products and urea to small ruminants in the Sultanate of Oman.

Studies on Cd, Pb, Hg and Cr Values in Dog Hairs from Urban Korea

  • Park, S.H.;Lee, M.H.;Kim, S.K.
    • Asian-Australasian Journal of Animal Sciences
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    • v.18 no.8
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    • pp.1135-1140
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    • 2005
  • Dogs are a very good indicator of the pollution load on the environment. They share people's environment and are exposed to the action of the same pollutants. This study was to estimate the heavy metal contents in dog hairs in domestic districts, and to assess effects of age, sex, feed habits, living area, breeding environment and smoking habit of owner. The mean concentrations of heavy metals in 204 samples were 0.09${\pm}$0.10 ${\mu}g$/g, 0.21${\pm}$0.09 ${\mu}g$/g, 0.82${\pm}$0.09 ${\mu}g$/g and 0.48${\pm}$0.07 ${\mu}g$/g (Cadmium (Cd), Mercury (Hg), Lead (Pb) and Chromium (Cr)) in dog hairs, respectively. Concentrations of Pb, Cd, Hg and Cr in dog hairs in Yeongnam including Ulsan and Seoul, were higher than in Chungchong and Honam, and concentrations of Pb were significantly different (p<0.01). Concentrations of Cd, Hg, Pb and Cr in dog hairs increased with age (p<0.05). Only dogs fed commercial pet foods had significantly higher Cd and Cr concentrations in hairs than dogs fed dog feed and human diet (p<0.01 in Cd and p<0.05 in Cr). Cr concentrations of dog hairsfrom dogs kept on cement floors were the highest of the other environments (p<0.01). Heavy metal concentrations of dogs owned by smokers, were higher than dogs of non-smokers, but there were no significant differences.