• Title/Summary/Keyword: cement matrix

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Application of ASTM C 1260 for Cement Matrix Mixed with FlyAsh and Lithium Nitrate (플라이애시와 질산리튬을 사용한 시멘트 경화체의 ASTM C 1260 적용성 검토)

  • Kim, Seong-Kwon;Yun, Kyong-Ku;Hong, Seung-Ho;Kang, Moon-Sik
    • International Journal of Highway Engineering
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    • v.14 no.3
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    • pp.1-7
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    • 2012
  • The purpose of this study was to review application of ASTM C 1260 for cement matrix with flyash and lithium nitrate using reactive aggregate. The experimental program included the accelerated mortar bar test (AMBT: ASTM C 1260) for the slate which was evaluated as reactive aggregate by ASTM C 1260 at the previous study. The cement, which was substituted by 10, 20, 30% flyash containing less than 10% CaO, could control ASR expansion. From the experiment applying lithium nitrate to control ASR, the mortar bar containing lithium nitrate showed more than 0.1% expansion at 14 days. This is probably due to dissolution of lithium nitrate in NaOH solution during test periods. Thus, it is necessary to adopt another test method to verify the control effect of lithium nitrate against alkali-silica reaction.

Microstructural Investigation on the Deterioration of Silica Fume Blended Cement Matrix Under Magnesium Sulfate Attack (황산마그네슘 침식을 받은 실리카 퓸 혼합 시멘트 경화체의 성능저하에 대한 미세구조적 관찰)

  • Lee, Seung-Tae
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.12 no.6
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    • pp.55-62
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    • 2008
  • This paper reports the effect of replacement levels of silica fume on the resistance to magnesium sulfate attack. Mortar specimens incorporating silica fume were exposed to 5% magnesium sulfate solution for 360 days at ambient temperature. The main variable was the replacement levels of silica fume(0, 5, 10 and 15% of cement by mass). The resistance of mortar specimens incorporating silica fume against magnesium sulfate attack was regularly monitored by measuring compressive strength and expansion. In addition, in order to investigate the reactants formed by magnesium sulfate attack, various instrumental analyses such as XRD, SEM and DSC were used. Results demonstrated that the formation of gypsum, thaumasite and brucite led to a significant deterioration due to magnesium sulfate attack in cement matrix incorporating silica fume.

Mechanical Properties of Non-cement Matrix Utilizing the Circulating Fluidized Bed Combustion Boiler Fly Ash and Dyeing Sludge Carbide (염색슬러지 탄화물과 순환 유동층 연소 보일러 플라이애시를 활용한 무시멘트 경화체의 역학적 특성)

  • Kim, Tae-Hyun;Lee, Seung-Ho;Lee, Yong;Shin, Jin-Hyun;Lee, Sang-Soo
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.4 no.4
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    • pp.425-430
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    • 2016
  • Both rapid industrial development and society has achieved more comfortable life. But, behind this facts of this industrial development have current pictures that occur global warming and much more by-products by environmental pollution. Therefore, this study used BFS and CFA as by-products to reduce cement usage emitted at a high rate of $CO_2$ gas, to examine sludge recycling strategy more than 200,000ton emitted at local dyeing complex, we suggest basic data research about non-cement matrix properties of utilizing dyeing sludge carbide. As a result, the more dyeing sludge carbide replacement ratio gets higher, the more air content and flow rise. Also, as the dyeing sludge carbide replacement ratio increase more, flexural strength and compressive strength go down.

Evaluation of SHCC on Direct Tensile Load using Acoustic Emission Technique (음향방출기법을 이용한 혼입되는 섬유의 종류에 따른 SHCC의 직접인장거동특성 평가)

  • Kim, Yun-Su;Yun, Hyun-Do;Jeon, Esther;Park, Wan-Shin
    • Proceedings of the Korea Concrete Institute Conference
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    • 2008.04a
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    • pp.177-180
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    • 2008
  • SHCC shows the high energy tolerance capacity due to the interfacial bonding of the fibers to the cement matrix. For effective material design and application of SHCC, it is needed to investigate the damage process and micro-fracture mechanism of cement matrix reinforced with different types of fibers. The objective of this paper is to investigate the direct tensile response of cement composites reinforced with single and hybrid fibers using acoustic emission(AE) technique. In this study, the correlations between AE signal and result of the direct tensile response of SHCC. For these purposes, three kinds of fibers were used: PET1.5%, PET1.0+PE0.5%, PET1.0%+PVA0.5%. The result of the direct tensile response of SHCC, for the same volume fraction of fibers, ultimate strength of PET-PE specimen was 2.7 times higher than specimens with PET fibers. And from AE signal value, AE event numbers and cumulative energy were different according to kind of fiber because of the different material properties of reinforced fiber.

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Influence of Cement Matrix's Compressive Strength and Replacement of Expansive Admixture on the Mechanical Properties of Synthetic Polyethylene (PE) Fiber-Reinforced Strain-Hardening Cement-Based Composites (SHCCs) (압축강도와 팽창재 대체에 따른 폴리에틸렌 합성섬유로 보강된 변형 경화형 시멘트 복합체의 역학적 특성)

  • Song, Young Jae;Yun, Hyun Do;Min, Byung Sung;Rokugo, Keitetsu
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.16 no.2
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    • pp.95-103
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    • 2012
  • In order to improve the dimensional stability and mechanical performance of cement-based composites, the effect of an expansive admixture based on calcium sulphoaluminate (CSA) on the shrinkage and mechanical properties of strain-hardening cement-based composite (SHCC), which exhibits multiple cracks and pseudo strain-hardening behavior in the direct tension, is investigated. Polyethylene fibers reinforced SHCC mixtures with three levels (30, 70, and 100MPa) of compressive strength were compared through free shrinkage, compressive strength, flexural strength, and direct tensile strength measurements. The SHCC mixtures were cast with and without replacing 10% of Portland cement content with CSA admixture. According to test results, CSA admixture is effective in reducing shrinkage of SHCC material. SHCC mixture with CSA admixture exhibited a little higher strength than companion mixture without CSA admixture.

Micro-shear bond strengths of resin-matrix ceramics subjected to different surface conditioning strategies with or without coupling agent application

  • Gunal-Abduljalil, Burcu;Onoral, Ozay;Ongun, Salim
    • The Journal of Advanced Prosthodontics
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    • v.13 no.3
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    • pp.180-190
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    • 2021
  • Purpose. This study aimed to assess the influence of various micromechanical surface conditioning (MSC) strategies with or without coupling agent (silane) application on the micro-shear bond strength (µSBS) of resin- matrix ceramics (RMCs). Materials and Methods. GC Cerasmart (GC), Lava Ultimate (LU), Vita Enamic (VE), Voco Grandio (VG), and Brilliant Crios (BC) were cut into 1.0-mm-thick slices (n = 32 per RMC) and separated into four groups according to the MSC strategy applied: control-no conditioning (C), air-borne particle abrasion with aluminum oxide particles (APA), 2W- and 3W-Er,Cr:YSGG group coding is missing. The specimens in each group were further separated into silane-applied and silane-free subgroups. Each specimen received two resin cement microtubules (n = 8 per subgroup). A shear force was applied to the adhesive interface through a universal test machine and µSBS values were measured. Data were statistically analyzed by using 3-way ANOVA and Tukey HSD test. Failure patterns were scrutinized under stereomicroscope. Results. RMC material type, MSC strategy, and silanization influenced the µSBS values (P<.05). In comparison to the control group, µSBS values increased after all other MSC strategies (P<.05) while the differences among these strategies were insignificant (P>.05). For control and APA, there were insignificant differences between RMCs (P>.05). The silanization decreased µSBS values of RMCs except for VE. Considerable declines were observed in GC and BC (P<.05). Conclusion. MSC strategies can enhance bond strength values at the RMC - cement interface. However, the choice of MSC strategy is dependent on RMC material type and each RMC can require a dedicated way of conditioning.

Multi-Scale finite element investigations into the flexural behavior of lightweight concrete beams partially reinforced with steel fiber

  • Esmaeili, Jamshid;Ghaffarinia, Mahdi
    • Computers and Concrete
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    • v.29 no.6
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    • pp.393-405
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    • 2022
  • Lightweight concrete is a superior material due to its light weight and high strength. There however remain significant lacunae in engineering knowledge with regards to shear failure of lightweight fiber reinforced concrete beams. The main aim of the present study is to investigate the optimum usage of steel fibers in lightweight fiber reinforced concrete (LWFRC). Multi-scale finite element model calibrated with experimental results is developed to study the effect of steel fibers on the mechanical properties of LWFRC beams. To decrease the amount of steel fibers, it is preferred to reinforce only the middle section of the LWFRC beams, where the flexural stresses are higher. For numerical simulation, a multi-scale finite element model was developed. The cement matrix was modeled as homogeneous and uniform material and both steel fibers and lightweight coarse aggregates were randomly distributed within the matrix. Considering more realistic assumptions, the bonding between fibers and cement matrix was considered with the Cohesive Zone Model (CZM) and its parameters were determined using the model update method. Furthermore, conformity of Load-Crack Mouth Opening Displacement (CMOD) curves obtained from numerical modeling and experimental test results of notched beams under center-point loading tests were investigated. Validating the finite element model results with experimental tests, the effects of fibers' volume fraction, and the length of the reinforced middle section, on flexural and residual strengths of LWFRC, were studied. Results indicate that using steel fibers in a specified length of the concrete beam with high flexural stresses, and considerable savings can be achieved in using steel fibers. Reducing the length of the reinforced middle section from 50 to 30 cm in specimens containing 10 kg/m3 of steel fibers, resulting in a considerable decrease of the used steel fibers by four times, whereas only a 7% reduction in bearing capacity was observed. Therefore, determining an appropriate length of the reinforced middle section is an essential parameter in reducing fibers, usage leading to more affordable construction costs.

Design and Constructibility of an Engineered Cementitious Composite Produced with Cement-based Mortar Matrix and Synthetic Fibers (시멘트계 모르타르 매트릭스를 활용한 섬유복합재료 ECC(Engineered Cementitious Composite)의 설계와 시공 성능)

  • Kim, Yun-Yong
    • Composites Research
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    • v.20 no.2
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    • pp.21-26
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    • 2007
  • This paper summarizes the design procedure and constructibility of an ECC (Engineered Cementitious Composite), which is a synthetic fiber-reinforced composite produced with the Portland cement-based mortar matrix. This study employs a stepwise method to develop useful ECC in construction field, which possesses different fluid properties to facilitate diverse types of processing (i.e., self-consolidating or spray processing). To control the rheological properties of the composite, the aggregates and reinforcing fibers were initially selected based on micromechanical analysis and steady-state cracking theory. The stability and consequent viscosity of the suspensions were then mediated by optimizing the dosage of the chemical and mineral admixtures. The rheological properties altered through this approach were revealed to be effective in obtaining ECC-hardened properties, represented by pseudo strain-hardening behavior in uniaxial tension, allowing the readily achievement of the desired function of the fresh ECC.

A Study on NOx Emission Control Methods in the Cement Firing Process Using Data Mining Techniques (데이터 마이닝을 이용한 시멘트 소성공정 질소산화물(NOx)배출 관리 방법에 관한 연구)

  • Park, Chul Hong;Kim, Yong Soo
    • Journal of Korean Society for Quality Management
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    • v.46 no.3
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    • pp.739-752
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    • 2018
  • Purpose: The purpose of this study was to investigate the relationship between kiln processing parameters and NOx emissions that occur in the sintering and calcination steps of the cement manufacturing process and to derive the main factors responsible for producing emissions outside emission limit criteria, as determined by category models and classification rules, using data mining techniques. The results from this study are expected to be useful as guidelines for NOx emission control standards. Methods: Data were collected from Precalciner Kiln No.3 used in one of the domestic cement plants in Korea. Thirty-four independent variables affecting NOx generation and dependent variables that exceeded or were below the NOx emiision limit (>1 and <0, respectively) were examined during kiln processing. These data were used to construct a detection model of NOx emission, in which emissions exceeded or were below the set limits. The model was validated using SPSS MODELER 18.0, artificial neural network, decision treee (C5.0), and logistic regression analysis data mining techniques. Results: The decision tree (C5.0) algorithm best represented NOx emission behavior and was used to identify 10 processing variables that resulted in NOx emissions outside limit criteria. Conclusion: The results of this study indicate that the decision tree (C5.0) can be applied for real-time monitoring and management of NOx emissions during the cement firing process to satisfy NOx emission control standards and to provide for a more eco-friendly cement product.

Resistance of Cementitious Binders against a Fall in the pH at Corrosion Initiation

  • Song, Ha-Won;Jung, Min-Sun;Ann, Ki Yong;Lee, Chang-Hong
    • Corrosion Science and Technology
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    • v.8 no.3
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    • pp.110-115
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    • 2009
  • At the onset of corrosion of steel in concrete, hydrogen ions usually evolve in the process of electrochemical reaction, thereby decreasing the pH of the pore solution, which can be buffered by cement hydration products, as being representatively illustrated by calcium hydroxide. Hence, a fall in the pH is dependent on properties of cement hydration (i.e. hydration products and degree of hydration). The present study tested acid neutralization capacity (ANC) of cementitious binders of OPC(Ordinary Portland Cement), 30% PFA(Pulverized Fuel Ash), 60% GGBS(Ground Granulated Blast Furnace Slag), 10% SF(Silica Fume) to quantify the resistance of cement matrix to a pH fall. Cement pastes were cast at 0.4 of a free W/C ratio with 1.5% chlorides by weight of binder in cast. Powder samples obtained crushed and ground specimen after 200 days of curing were diluted in still water combined with different levels of 1M nitric acid solution, ranging from 0.5 to 20 mol/kg. Then, the pH of diluted solution was monitored until any further change in the pH did not take place. It was seen that the pH of the diluted solution gradually decreased as the molar amount of nitric acid increased. At some particular values of the pH, however, a decrease in the pH was marginal, which can be expressed in the peak resistances to a pH fall in the ANC curve. The peaks occurred at the variations in the pH, depending on binder type, but commonly at about 12.5 in the pH, indicate a resistance of precipitated calcium hydroxide. The measurement of water soluble chloride at the end of test showed that the amount of free chloride was significantly increased at the pH corresponding to the peaks in the ANC curve, which may reflect the adsorption of hydration products to chlorides.