• Resources Recycling
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• v.30 no.6
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• pp.68-75
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• 2021

This study aims to investigate the manufacturing process of calcium chloride-based special cement, i.e., CCA (calcium chloro aluminate, C₁₁A₇·CaCl₂), which uses limestone, by using one type of random industrial by-product, domestic coal ash, cement kiln dust. The manufacturing process of was examined in detail, and the results suggested that the amount of CCA synthesized increased with an increase in the firing temperature. The manufacturing process of CCA was investigated at 1200℃, which was determined as the optimum firing temperature. The results showed that in general, the amount of CCA synthesized tended to increase with an increase in the firing time; however, the clinker melted when the firing time was more than 30 min, thereby suggesting that a firing time of less than 20 min would be suitable for the clinkering process. The optimal firing conditions for manufacturing CCA were obtained as follows: heating rate of 10 ℃/min, firing temperature of 1200 ℃, and holding time of 20 min. The results also suggest that manufacturing CCA will be easier when high chlorine-containing cement kiln dust is used.

• Environmental Engineering Research
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• v.14 no.4
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• pp.212-219
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• 2009

Emission characteristics of air pollutants from three commercially operating cement kilns co-burning waste were investigated. The major heavy metals emitted were mercury (Hg), zinc (Zn), nickel (Ni), chromium (Cr), lead (Pb), cadmium (Cd), and arsenic (As) Removal efficiency of the bag filter was above 98.5% for heavy metals (except Hg), and above 60% for Hg. Higher fractions of heavy metals entering the bag filter were speciated to cement kiln dust. On average, 3.3% of the -heavy metals of medium and low toxicity (Pb, Ni, and Cr) entering the bag filter were released into the atmosphere. Among highly toxic heavy metals, 0.14% of Cd, 0.01% of As, and 40% of Hg entering the bag filter were released into the atmosphere. In passing through the bag filter, the proportion of oxidized Hg in all cases increased. Emission variations of hazardous air pollutants in cement kilns tested were related to raw materials, fuel, waste feed and operating conditions. Volatile organic compounds detected in gas emissions were toluene, acrylonitrile benzene, styrene, 1,3-butadiene, and methylene chloride. Although hazardous air pollutants in emissions from cement kilns co-burning waste were within the existing emission limit, efforts are required to minimize their levels.

• Journal of the Korea Institute of Building Construction
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• v.7 no.1 s.23
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• pp.71-77
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• 2007

This paper is to investigate the effect of the curing temperature on strength development of concrete incorporating cement kiln dust(CKD) and blast furnace slag (BS) quantitatively. Estimation of the compressive strength of the concrete was conducted using the equivalent age equation and the rate constant model proposed by Carino. Correction of Carino model was studied to secure the accuracy of strength development estimation by introducing correction factors regarding rate constant and age. An increasing curing temperature results in an increase in strength at early age, but with the elapse of age, strength development at high curing temperature decreases compared with that at low curing temperature. Especially, the use of BS has a remarkable strength development at early age and even at later age, high strength is maintained due to accelerated pozzolanic activity resulting from high temperature. Whereas, at low curing temperature, the use of BS leads to a decrease in compressive strength. Accordingly, much attention should be paid to prevent strength loss at low temperature. Based on the strength development estimation using equivalent age equation, good agreements between measured strength and calculated strength are obtained.

• Journal of the Korea Institute of Building Construction
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• v.7 no.2 s.24
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• pp.77-83
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• 2007

This study investigated the fundamental properties of the lightweight foamed concrete depending on various admixtures, and the results were summarized as following. When 20% of cement kiln dust(CKD) and 0.002% of stabilizing agent were mixed to lightweight foamed concrete, it was necessary to use a superplasticizer because flowability was decreased. However, it could reduce sinking depth which were the extensive trouble of lightweight foamed concrete. Bulk density was divided into '0.4' and '0.5' grades on KS according to unit volume weight. The compressive strength was less than that of plain concrete when admixtures were applied, but the results exceeded the minimum strength of the each grades on KS. Totally, it is found that the combination of 20% of CKD and 0.002% of stabilizing agent makes it possible to reduce a sinking depth, recycle resources, and save cost when were mixed.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2005.11a
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• pp.75-78
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• 2005

This raper investigates the effect of curing temperature on strength development of concrete incorporating cement kiln dust(CKD) and blast furnace slag (BS) quantitatively. Estimation of compressive strength of concrete was conducted using equivalent age equation and rate constant model. An increasing curing temperature results in an increase in strength at early age, but with the elapse of age, strength development at high curing temperature decreases compared with that at low curing temperature. Especially, the use of 35 has a remarkable strength development at early age and even at later age, high strength is maintained due to accelerated pozzolanic activity resulting from high temperature. Whereas, at low curing temperature, the use of BS leads to a decrease in compressive strength. Accordingly, much attention should be paid to prevent strength loss at low temperature. Based on the strength development estimation using equivalent age equation, good agreements between measured strength and calculated strength are obtained.

• Advances in nano research
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• v.4 no.3
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• pp.181-195
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• 2016

Addition of nano-$SiO_2$ (NS) to geopolymer composites has been studied through measurement of compressive strengths, FTIR and XRD analysis. Alumino-silicate materials are coarse aggregate included waste concrete and demolished walls with its cementing binder, cement kiln dust (CKD) used and can possess a pronouncing activation for the geopolymer reaction resulting from the high alkali contents within. Materials prepared at water/binder ratios in a range of 0.30: 0.40 under curing of $40^{\circ}C$ and 100% Relative Humidity (R.H.), while the used activator is sodium hydroxide in the ratio of 2 wt. %. First, CKD is added in the ratio from 10 up to 50 wt., %, and the demolished walls was varied depending on the used CKD content, while using constant ratio of waste concrete (40 wt., %). Second step, depending on the optimum CKD ratio resulted from the first one (40 wt. %), so the control geopolymer mix composed of cement kiln dust, demolished walls and waste concrete in the ratio (40:20:40, wt %). Nano-silica partially replaced waste concrete by 1 up to 8%. Results indicated that, compressive strengths of geopolymer mixes incorporating nano-silica were obviously higher than those control one, especially at early ages and specially with 3%NS.

• Journal of the Korea Institute of Building Construction
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• v.9 no.5
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• pp.119-125
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• 2009

In this paper, the engineering properties and estimation of drying shrinkage of concrete incorporating fly ash (FA), blast furnace slag (BS) and cement kiln dust (CKD) were discussed. FA, BS and CKD contents ranged from 0% to 20%. Water to binder ratio (W/B) also ranged from 40 to 50 %, with a 5% interval. For estimating drying shrinkage, an exponential model proposed by the author was applied, According to results, the use of FA, BS and CKD resulted in a decrease of flowability and air contents. As expected, the use of admixtures also decreases the early age strength of concrete, while at later age, due to a pozzolanic reaction of FA and BS, the compressive strength was recovered to a value comparable with that of plain concrete. For drying shrinkage, the use of admixtures led to an increase in the drying shrinkage of concrete. The exponential model suggested by the author showed good agreement between the calculated and experimental values both at early age and at later age.

• Applied Chemistry for Engineering
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• v.30 no.6
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• pp.726-730
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• 2019

The removal of calcium ions using zeolite to solve problems of the CaCO₃ manufacturing process using cement kiln dust was investigated. To do so, a modified zeolite was employed and experiments were conducted to select the optimal zeolite type considered the binding cation and structure, evaluate the removal performance of calcium ions, the influence of the type and concentration of the modifying solution, and the removal selectivity when K coexists. Among five zeolites, 13X zeolite was found to have the best calcium ion removal performance, and it was confirmed that the removal performance was enhanced when KCl was used as a modifying solution instead of NaCl. This study is expected to be the basis for the solution of carbonation process and high concentration of KCl recovery technology.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2006.05a
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• pp.35-38
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• 2006

This study investigated fundamental properties of lightweight foamed concrete using cement kiln dust (CKD) and both fly ash(FA) and stability agent. Test results showed that concrete incorporating more amounts of admixture decreased slump flow and it caused increase of superplasiticizer in order to secure the fluidity performance. In addition concrete adding stability agent showed stable flow state, resisting segregation of materials and decreasing bleeding capacity. Sinking depth of concrete incorporating 20% of CKD and adding 0.002% of stability agent was indicated at 0mm. For the properties of hardened concrete. compressive strength of concrete incorporating CKD declined due to a lower appearance density, compared with other specimens. The difference of that was not very significant and the value of ail specimen was higher than KS range. Moreover strength of concrete incorporating CKD was even higher at curing temperature $5^{\circ}C$. Tensile strength ratio of concrete incorporating CKD was indicated between 0.50 to 0.59, which is higher value than control concrete. Heat conductivity of concrete incorporating FA was under the KS range while concrete incorporating 20% of CKD was satisfied in KS. Concrete adding stability agent improved insulation performance due to the lower heat conductivity. In conclusion, it is possible that concrete incorporating 20% of CKD and adding 0.002% of stability agent can secure high quality of lightweight foamed concrete.

• Resources Recycling
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• v.25 no.3
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• pp.63-73
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• 2016

With the purpose of concentrating the magnesium from seawater, in this study, we have conducted experiments to precipitate the magnesium using three precipitants (NaOH, cement kiln dust, and paper sludge ash), and then extract it using sulfuric acid. Results show that the precipitation and extraction performance does not depend so significantly on the kind of precipitant: for all the precipitants used, the precipitation efficiency is measured almost 100% and the extraction efficiency is in the short range of 77 - 89%. The magnesium concentration in the extract is measured 4975 - 5775 mg/L, implying that the magnesium in seawater should be 3.8 - 4.4 times concentrated through the precipitation and extraction reactions. The reaction efficiency of the industrial by-product used as a precipitant in this study is almost 100% similar to those of the other existing expensive precipitants.