• Title/Summary/Keyword: cement hardened

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Synthesis and Hydration of Modified Belite Cement Clinker (Modified Belite Cement Clinker의 합성 및 수화반응)

  • 김창범;한기성;최상흘
    • Journal of the Korean Ceramic Society
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    • v.27 no.2
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    • pp.195-200
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    • 1990
  • For the development of low energy cement, the belite cement clinker of calcium sulphoaluminate ferrite type was synthesized at 130$0^{\circ}C$ and containing C2S, C4A3S as the major minerals along with C3A, C4AF, CS by using limestone, dolomite, clay, iron ore, gypsum and alumina as raw materials. At over 130$0^{\circ}C$, C4A3S was decomposed and thus C3A was increased. When hydrated, this cement was hardened, producing ettringite, CSH, etc.

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Correlations between the Impedance and Compressive Strength of Hardened Cement According to the Aggregate Type

  • Hojin Kim;Jinju Kim;Sungyu Park;Je Hyun Bae
    • Journal of Electrochemical Science and Technology
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    • v.15 no.2
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    • pp.242-252
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    • 2024
  • To date, methods used to assess the interfacial transition zone (ITZ), which represents the boundary between the aggregate and paste inside concretes, have primarily relied on destructive tests, and non-destructive tests has received little attention until recently. This study assessed the interfaces of concretes with lightweight aggregates based on electrochemical impedance spectroscopy (EIS) for high-strength concretes and examined the possibility of estimating the compressive strength of concretes through non-destructive testing using EIS. The experimental results revealed that the impedance of the hardened cement increased with increasing compressive strength and aggregate density. In particular, when the results of impedance measurement were displayed as a Nyquist plot, the intercept of the x-axis depicting the effective conductivity was proportional to the compressive strength. Furthermore, an equivalent circuit was selected to interpret the correlation between cement aggregates and impedance. Consequently, the compressive strength was found to increase with the value of the resistances of the electrolyte filled in continuous pores in the cement aggregate. And, the pores formed in the ITZ affect this value. The resistance at the ITZ for different aggregates was also obtained, and it was found that the resistance was consistent with the results predicted by SEM images of the ITZ and correlated with the strength of the concretes. The proposed method can be used as a way to easily determine the strength of cement according to differences in aggregate.

Evaluation of Chloride ions Diffusion on Hardened Cement paste And Durability of Concrete Specimen Using Inorganic Coating Material (무기질 도료를 이용한 시멘트 경화체의 C1 ̄이온확산과 콘크리트의 내구성 평가)

  • 김인섭;이종규;추용식;김병익;신영훈
    • Proceedings of the Korea Concrete Institute Conference
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    • 2001.11a
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    • pp.221-226
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    • 2001
  • Chloride diffusion effect of cement paste, freezing and thawing test, carbonation of concrete specimen were carried out using inorganic coating material. According to the chloride ions diffusion test, it is elucidated that permeability and diffusion coefficient of Cl ̄ ions and apparent coefficient of coated cement paste is smaller than plain cement paste. A durability of coated concrete specimen was enhanced by the experiment result of concrete carbonation and freezing thawing test.

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Experimental evaluation of the performance of self-compacting concrete contains nano clay and nano egg shell

  • Hilal, Nahla N.;Hadzima-Nyarko, Marijana
    • Advances in concrete construction
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    • v.13 no.5
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    • pp.349-360
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    • 2022
  • The rising prices of landfills and the lack of cement production are motivating researchers to be more interested in using wastes to produce concrete mixtures materials. The use of waste materials such as eggshell and matakoline waste not only reduces landfill costs and space, but also reduces the cost of cement production for the concrete mixture. However, recycling waste materials has become critical in order to effectively manage environmental sustainability. The purpose of this paper is to investigate the appropriate properties of self-compacting concrete (SCC) by incorporating waste materials such as crushed ceramics as coarse aggregate and nano egg shell (NES) and nanoclay (NC) as cement replacements. Fresh properties of SCC, such as segregation, flow time and diameter, V-funnel, H2/H1 ratio, and fresh unit weight of concrete mixtures, as well as hardened properties, such as 7, 14, and 28 days compressive strength and 28 and 90 days flexural strength, were measured for this purpose. The presence of NC in the SCC mixture enhanced the compressive strength of the concrete when 5% of NES was added or in the case without the addition of NES compared to the control mixture. The flexural strength enhanced with the incorporation of NC in the SCC increased the flexural strength of the concrete compared to the control mixture, but the incorporation of 5% of NES decreased the flexural strength compared to the mixtures with NC. These results prove the possibility of using crushed ceramics as the coarse aggregate, and NES and NC as substitutes for 5, 7, and 10% of the cement in SCC, because the properties of such SCC in hardened and fresh states are satisfactory.

Resistance to Sea Water of Hardened Cement with Calcium Sulfoaluminate Type Expansive Additives(I) (칼슘 설포알루미네이트계 팽창재를 혼합한 시멘트 경화체의 내해수성(I))

  • 전준영;송종택
    • Journal of the Korean Ceramic Society
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    • v.40 no.3
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    • pp.234-240
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    • 2003
  • Hardened cement pastes of OPC which contains 10 wt% CSA type expansive additives were immersed in aqueous solution of 10 wt% MgS $O_4$.7$H_2O$ and then investigated by compressive strength, XRD. SEM and DSC etc.. According to the results including the hydration products and the microstructure of the hardened paste, the case of CSA type expansive additives[No. 6(C/(equation omitted) : 2.29, A/(equation omitted) : 0.16)] prepared from raw materials increased the resistance to $Mg^{2+}$, S $O_4$$^{2-}$ ion diffusion than that of OPC paste due to the densification by the formation of fine ettringite in the first stage and the hydrates according to $\beta$-C$_2$S hydration in the late period.

Microstructure Properties of Cement Matrix Exposed to High Temperature (고온에 노출 된 시멘트 매트릭스의 미세구조 특성)

  • Lee, Gun-Young;Lee, Gun-Cheol;Choi, Jung-Gu;Gao, Shan;Heo, Young-Sun
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2015.11a
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    • pp.24-25
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    • 2015
  • To secure fundamental materials for the performance change in concrete structure damaged by fire, this study analyzed SEM and XRD of hardened cement depending on high temperature conditions. As a result, at more than 200℃, SEM and XRD were not observed because of dehydration of Ettringite; at more than 500℃, calcium hydroxide was rapidly decomposed; at more than 700℃, calcium oxide was found; at 1000℃, the highest peak point appeared.

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An Experimental Study on the Ultra High Strength Concrete(Fc=1,200kg/$\textrm{cm}^2$) (1,200kg/$\textrm{cm}^2$ 초고강도 콘크리트에 관한 실험적 연구)

  • 소현창;박태규;김재우;정병욱
    • Proceedings of the Korea Concrete Institute Conference
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    • 1994.10a
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    • pp.133-136
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    • 1994
  • This study is to investigate properties of the ultra high-strength concrete using silica rume and fly ash. For this purpose, the properties of fresh concrete and hardened concrete are examined with varing water-cement ratio, silica fume and fly ash content and so on. From these test results, it is possible to maunfacture the miximum strength of 1, 200kg/$\textrm{cm}^2$ with cement content 800kg/$\textrm{m}^3$, 18% water-cement ratio, 105 silica fume content.

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A Study on the Properties of High Performance Concrete Using Low Heat Portland(Type IV) Cement (저열 포틀랜드(4종)시멘트를 사용한 고유동, 고강도콘크리트에 관한 연구)

  • 최광일;김기수;하재담;김동석;이순기;이동윤
    • Proceedings of the Korea Concrete Institute Conference
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    • 1997.10a
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    • pp.422-429
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    • 1997
  • In recent years, concrete construction have become larger and higher and are demanding high performance concrete with lower heat to prevent thermal cracking, far greater workability, high strength and durability. Application of low heat portland(Type IV) cement for the high performance concrete is the best solution to satisfied those requirements. Here are explained the basic properties of fresh concrete as well as hardened concrete of high performance concrete using low that portland cement.

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Physical Properties of Concrete using Industrial By-Products as Binder (산업부산물을 결합재로 이용한 콘크리트의 물리적 특성)

  • 강내민;문경주;소양섭
    • Proceedings of the Korea Concrete Institute Conference
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    • 2003.05a
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    • pp.79-82
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    • 2003
  • In this study, non-sintering cement is produced by only blending granulate blast furnace slag with phosphogypsum as main materials, and small amounts of hydrate lime or waste lime as activators. This paper was investigated physical properties of fresh concrete and hardened concrete using non-clinker cement according to various mixing ratio. Results obtained from this study have shown that concrete using non-clinker cement could be used for structural concrete and concrete 2th production as binder.

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