• 한국세라믹학회:학술대회논문집
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• 한국세라믹학회 2007년도 제34회 시멘트 심포지엄
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• pp.129-137
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• 2007

This paper presents a numerical model which can predict degree of hydration of cement mineral component, such as $C_{3}S$, $C_{2}S$, $C_{3}A$, $C_{4}AF$ and microstructure of hydrating cement as a function of water to cement ratio, cement particle size distribution, cement mineral components and temperature. In this model cement particles are parked randomly in cell space and hydration process is described using a multi-component integrated kinetic model. The simulation result of degree of hydration of cement mineral component agrees well with experiment result. The content of cement hydration product, such as CSH and CH can be obtained as an accompanied result during hydration process. By introducing of equal-area projection method, water withdrawl mechanism and contact area among cement particles can be considered in detail. By using proposed method, pore size distribution of hydrating cement is predicted.

• 한국폐기물자원순환학회지
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• 제35권8호
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• pp.721-730
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• 2018

We investigated the effects of heavy metals in cement in the last 3 years and the amount of waste in the cement manufacturing process. The result shows that the average $Cr^{6+}$ content in cement products is controlled at 10 mg/kg. Cu and Pb have lower detection tendency in white cement than in ordinary portland cement. In addition, heavy metals such as Cd show a certain level of detection regardless of the input wastes. Copper slag and phosphate gypsum are the main influencing factors on the heavy metals in cement products. In auxiliary fuels, plastics waste and wood waste are considered to affect heavy metals in cement products. Alternative raw materials are considered to be affected by the alternative raw materials managed as byproducts. In the case of supplementary fuels, auxiliary fuels managed as waste instead of auxiliary fuels managed as byproducts affect the heavy metals in cement. This study examined the input amount without considering the heavy metals in each waste. Therefore, the result may vary in different situations, and further research must be conducted to supplement the findings. However, if the heavy-metal contents in the waste are constant, it can be used as a reference material for the control of heavy metals in cement products.

• 콘크리트학회논문집
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• 제25권4호
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• pp.365-370
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• 2013

이 연구에서는 시멘트 생산공정에서 석회석 원료에 따른 $CO_2$ 배출량 및 그에 따른 물리적 특성을 파악하기 위해 국내 6개사의 보통포틀랜드시멘트에 대한 CaO 함유량 및 모르타르의 압축강도를 측정하였다. 탈탄산반응 시 발생되는 CaO와 각각의 시멘트에 함유된 석회석의 손실량에 대하여 CaO 함유량 및 압축강도, $CO_2$ 배출량과의 관계를 비교분석하였다. 단위 시멘트에 대한 $CO_2$ 배출량 산정 결과 석회석의 탈탄산에 따른 $CO_2$ 배출량이 전체 배출량의 67%가량 차지하였고, 시멘트 제조 시 공정관리에 따라 $CO_2$ 배출량에 차이가 있음을 확인하였다. 또한 $CO_2$ 배출의 주요 인자로 화석연료의 사용 및 재료 손실률이 지대한 영향을 미친다는 것을 확인하였다. 시멘트 내의 CaO 함유량이 증가함에 따라 압축강도 역시 증가하였으며, CaO 손실량이 클수록 CaO 함유량 및 압축강도는 감소하였으나 $CO_2$ 배출량은 증가함에 따라 시멘트 제조 시 CaO 생성량보다는 재료 및 공정관리가 $CO_2$ 배출에 더 영향력이 있음을 알 수 있었다. 그리고 포졸란계 혼화재인 PFA, GGBS를 사용함으로서 이에 따른 가격, $CO_2$ 배출 및 강도증진 효과가 있음을 확인하였다.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 1997년도 가을 학술발표회 논문집
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• pp.61-64
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• 1997

As construction technology advances, most of concrete structures are becoming larger and taller. Therefore, high strength and quality concrete is necessary for them. So, the proposal of using belite cement is investigated to satisfy high flowing, low heat, and high strength. In this study, the compressive strength, tensile strength, and modulous of elasticity of concrete using belite cement was considered according to the mix proposition condition as a water-cement ratio, unit cement content, and sand percentage.

• 한국세라믹학회지
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• 제40권7호
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• pp.702-708
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• 2003

포틀랜드 시멘트 양(중량)을 플라이 애쉬로 50 wt%까지 치환한 페이스트, 모르터 내지 콘크리트 시편을 만들어 플라이 애쉬가 모르터/콘크리트의 온도, 자유석회량 및 강도 등에 미치는 영향을 조사하였다. 페이스트의 수화열을 측정하여 환산식에 따라 일반 포틀랜드 시멘트 콘크리트의 경우와 비교할 때, 플라이 애쉬를 50 wt% 함유한 콘크리트의 양생 7일 온도(상승)는 약 45% 저하되었다. 전자의 경우 온도 상승은 33.4$^{\circ}C$이며 후자의 경우는 18.7$^{\circ}C$였다. 한편 철근 콘크리트의 제조에 사용되는 시멘트의 플라이 애쉬 함유량은 철근부식의 방지를 위하여 30 wt%를 초과하지 않는 게 바람직하다. 플라이 애쉬를 혼합한 콘크리트의 강도가 순수 포틀랜드 시멘트 콘크리트의 강도보다 양호하기 위해서는 양생기간이 28일 이상 되어야 한다. 그리고 플라이 애쉬 50 wt%를 함유한 시멘트를 가지고도 360 kg/$\textrm{cm}^2$ 이상의 28일 강도를 얻을 수 있었다.

• 한국구조물진단유지관리공학회 논문집
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• 제20권2호
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• pp.26-33
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• 2016

알칼리활성화 슬래그-레드머드 시멘트는 알칼리활성화 시멘트 연구의 일환으로서 시멘트 조성에서 알칼리자극제, 고로슬래그와 레드머드로 구성되어져 있으며, 포틀랜트 시멘트를 사용하지 않는 클링커 프리 시멘트(Clinker Free Cement)를 의미한다. 본 논문에서는 포틀랜트 시멘트를 전혀 사용하지 않고 고분자 유기화합물인 재유화형 분말 폴리머를 혼입한 알칼리활성화 슬래그 시멘트에 레드머드의 대체율을 달리하여 강도특성, 기공특성 등을 기존 포틀랜트 시멘트와 비교 평가하였다. 그 결과 알칼리활성화 시멘트에 레드머드를 대체할 경우 C-S-H 광물상과 에트린가이트가 주요 수화생성물로 포틀랜트 시멘트와 비교하여 조직이 치밀하고 대체율 10%까지는 압축강도 및 휨강도가 증가하였다.

• 한국농공학회지
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• 제17권4호
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• pp.3931-3942
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• 1975

This study was conducted to investigate the strength of soil cement for varied curing temperatures (0,10,20,30,40,50,60$^{\circ}C$) and cement content (3,6,9,12%) in four cement-stabilized soils (KY: sand, MH: sand, SS: sandy loam, JJ:loam). The experimental results obtained from unconfined compressive strength tests were as follows: 1. According to increase of curing temperature as 30,40,50, and 60$^{\circ}C$, the unconfiened compressive strength of soil cement increased, the rate of increase in the early curing period was large, and around 120 hours was suifficient curing time to complete hardening. 2. The strength at 10$^{\circ}C$ decreased to the rate of 30 to 40 percent than that of 20$^{\circ}C$ while the strength at 0$^{\circ}C$ was very small, strength of soil cement increased in cold weather unless that the temperature was below 0$^{\circ}C$ 3. The average maximum temperature, about 30$^{\circ}C$ during July and August in Korea may be recommended for a optimum construction period to increase the strength of soil cement. 4. Accelerated curing time that strength was equivalent to 28-Day norma1 curing decreased in accordance with the increase of curing temperature, and also accelerated curing decreased the effect of cement content. Accelerated curing that strength was equivalent to 28-day normal curing for soil cement of cement content 9% and temperature 60$^{\circ}C$ was 45 hours; KY, 50 hours: MH, 40 hours; SS, 34 hours; JJ. 5. According to the increase of the percent passing of No. 200 sieve, accelerated curing times became shorter to become the required stength. 6. Relation between accelerated curing times and normal curing days was showeda linear of which slope decreased in accordance with the increase of curing temperature, it may be expressed as follows: (1). 30$^{\circ}C$ t=3.6d+6(r=0.97) (2). 40$^{\circ}C$ t=3.2d-5.1(r=0.95) (3). 50$^{\circ}C$ t=2.1d-4.0(r=0.93) (4). 60$^{\circ}C$ t=1.4d+4.0(r=0.90) in which t=accelerate curing time. d=normal curing day. 7. Accelerated curing time that the strength was equivalent to 35kg/$\textrm{cm}^2$ which was the strength of cement brick was 96 hours at temperature 30$^{\circ}C$ to SS 9%, and 120 hours at temperature 50$^{\circ}C$ to JJ 9%, Consequently, a economic soil cement brick may be made in future.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2003년도 가을 학술발표회 논문집
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• pp.257-260
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• 2003

This study discusses the properties of shrinkage of high performance concrete with W/B and water content. According to results, drying shrinkage decrease of water content due to the influence of autogenous shrinkage. And drying shrinkage is reduced with a decrease of water content. As W/B decreases, autogenous shrinkage increases because shrinkage by hydration is generated greatly due to an increase of binder content. Also, as water content decreases, it is reduced because of a decrease of cement paste by cement content.

• International Journal of Concrete Structures and Materials
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• 제5권2호
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• pp.119-123
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• 2011

Presented in the paper are findings of a project that examined the effect of slag grade and cement source on the performance of concrete mixtures. Slag cement contents were 20, 40, and 60 percent of the total cementitious material content. Two grades of slag cement were examined (Gr. 100 and Gr. 120) along with two sources of Type I cement. Compressive strength, durability, and permeability were measured. The results showed that the cement source affected the early age strength of the mixtures. At 28 days of age, mixtures containing Gr. 120 slag cement had higher compressive strengths than mixtures containing Gr. 100 slag cement, but by 90 days of age, the trend reversed. As for the chloride ion penetrability, mixtures cast with Gr. 100 slag cement passed fewer coulombs at 28 and 90 days of age than similar mixtures containing Gr. 120 slag. Mixtures containing Gr. 120 slag had the greatest durability factors.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 1999년도 학회창립 10주년 기념 1999년도 가을 학술발표회 논문집
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• pp.175-178
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• 1999

In most domestic construction fields, excessive cement content has been used because of stubborn official inspection. The purpose of this study is to reduce the cement content of mix proportioning for the decrease of hydration heat, brittleness and drying shrinkage which governs durability of concrete significantly. Parameters includes the compressive strengths, type and dosage rate of chemical and mineral admixtures and types of concrete. It is found that the chemical admixture is efficient to the reduction of cement content for high strength concrete (400kg/$\textrm{cm}^2$) and the effectiveness of mineral admixtures in the low strength concrete is somewhat higher than the high strength concrete.