DOI QR코드

DOI QR Code

A Study on the Correlation between Heavy Metal Content of Cement Products and Waste Used in Cement Industry

시멘트 산업에 투입되는 폐기물과 시멘트 제품의 중금속 함유량과의 상관관계 분석연구

  • Kim, Yong-Jun (Resource Recirculation Research Division, Environmental Resources Research Department, National Institute of Environmental Research) ;
  • Um, Nam-Il (Resource Recirculation Research Division, Environmental Resources Research Department, National Institute of Environmental Research) ;
  • Kim, Woo-Il (Resource Recirculation Research Division, Environmental Resources Research Department, National Institute of Environmental Research) ;
  • Lee, Young-Kee (Resource Recirculation Research Division, Environmental Resources Research Department, National Institute of Environmental Research) ;
  • Kim, Ki-Heon (Resource Recirculation Research Division, Environmental Resources Research Department, National Institute of Environmental Research)
  • 김용준 (국립환경과학원 자원순환연구과) ;
  • 엄남일 (국립환경과학원 자원순환연구과) ;
  • 김우일 (국립환경과학원 자원순환연구과) ;
  • 이영기 (국립환경과학원 자원순환연구과) ;
  • 김기헌 (국립환경과학원 자원순환연구과)
  • Received : 2018.07.30
  • Accepted : 2018.10.20
  • Published : 2018.12.31

Abstract

We investigated the effects of heavy metals in cement in the last 3 years and the amount of waste in the cement manufacturing process. The result shows that the average $Cr^{6+}$ content in cement products is controlled at 10 mg/kg. Cu and Pb have lower detection tendency in white cement than in ordinary portland cement. In addition, heavy metals such as Cd show a certain level of detection regardless of the input wastes. Copper slag and phosphate gypsum are the main influencing factors on the heavy metals in cement products. In auxiliary fuels, plastics waste and wood waste are considered to affect heavy metals in cement products. Alternative raw materials are considered to be affected by the alternative raw materials managed as byproducts. In the case of supplementary fuels, auxiliary fuels managed as waste instead of auxiliary fuels managed as byproducts affect the heavy metals in cement. This study examined the input amount without considering the heavy metals in each waste. Therefore, the result may vary in different situations, and further research must be conducted to supplement the findings. However, if the heavy-metal contents in the waste are constant, it can be used as a reference material for the control of heavy metals in cement products.

Keywords

Acknowledgement

Supported by : 국립환경과학원

References

  1. Korea Ministry of Environment : Improvement plan for environmental management of cement kiln (2008)
  2. National Institute of Environmental Research : The results of heavy metals in cement monitoring, www.nier.go.kr (access date: June 27, 2018)
  3. Park, S. O., Kang, Y. Y., Hwang, D. G., Kim, Y. J., Ryu, H. Y., Hong, S. Y., Jeon, T. W. and Shin, S. K. : Correlation alnalysis of co-processing waste materials and heavy metal contents in cement products, Journal of Korea Society of Waste Management, Vol. 34, No. 5, pp. 449-457 (2017) https://doi.org/10.9786/kswm.2017.34.5.449
  4. Korea Ministry of Environment : Wastes control act (2018)
  5. Downard, J., Singh, A., Bullard, R., Jayarathne, T., Rathnayake, C. M., Simmons, D. L., Wels, B. R., Spark, S. N., Peters, T., Beardsley, D., Stanier, C. O. and Stone, E. A. : Uncontrolled combustion of shredded tires in a landfill-part 1: Characterization of gaseous and particulate emissions, Atmospheric Environment, Vol. 104, pp. 195-204 (2015) https://doi.org/10.1016/j.atmosenv.2014.12.059
  6. Umwelt Bundes Amt in Germany : Heavy metals in cement and concrete resulting from the co-incineration of waste in cement kilns with regard to the legitimacy of waste utilisation, pp. 15-19 (2003)
  7. Korea Cement Association : Inside data of waste input by cement maker 2015-2017 (2018)
  8. Ahn, J. O. : Statistical analysis of biomedical data using SPSS 18.0, Hannarae Publishing Co., pp. 283-287 (2011)
  9. Kim, K. H., Kim, S. C., Song, G. J. and Seo, Y. C. : Emission characteristics of metal elements from a MSW incinetator, Journal of the Korean Society of Combustion, Vol. 8, No. 1, pp. 1-8 (2003)
  10. Lee, S. H., Hwang, H. J., Lee, J. K. and Chu, Y. S. : Review of the heavy metals in ordinary portland cement, Magazine of the Korea Concrete Institute, Vol. 19, No. 2, pp. 28-33 (2007) https://doi.org/10.22636/MKCI.2007.19.2.28
  11. Korea Ministry of Environment : Waste control act (2017)
  12. National Institute of Environmental Research : Research of proposal content standard of hazardous substances in the cement products (2015)