• Title/Summary/Keyword: cement

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Resistance of Alkali Activated Slag Cement Mortar to Sulfuric Acid Attack (알칼리 활성화 슬래그 시멘트 모르타르의 내황산성)

  • Min, Kyung-San;Lee, Seung-Heun
    • Journal of the Korean Ceramic Society
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    • v.44 no.11
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    • pp.633-638
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    • 2007
  • The setting time of alkali activated slag cement tends to be much faster than ordinary Portland cement, and its compressive strength had been higher from the 1 day but became lower than that of the cement on the 28 days. According to the results of the surface observation, weight loss, compressed strength, and erosion depth tests on the sulphuric acid solution. It has been drawn that alkali activated slag cement has a higher sulphate resistance than ordinary Portland cement, and in particular, the alkali activated slag cement added 5 wt% alumina cement has little deterioration on the sulphuric acid solution. The reason why the alkali activated slag cement has higher sulphate resistance than other hardened cement pastes is that it has no $Ca(OH)_2$ reactive to sulphate ion, and there is little $CaSO_4{\cdot}2H_2O$ production causing volume expansion, unlike other pastes. And it is supposed that $Al(OH)_3$ hydrates with high sulphate resistance, which is produced by adding the alumina cement increases the sulfate resistance.

Biomechanical three-dimensional finite element analysis of monolithic zirconia crown with different cement type

  • Ha, Seung-Ryong
    • The Journal of Advanced Prosthodontics
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    • v.7 no.6
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    • pp.475-483
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    • 2015
  • PURPOSE. The objective of this study was to evaluate the influence of various cement types on the stress distribution in monolithic zirconia crowns under maximum bite force using the finite element analysis. MATERIALS AND METHODS. The models of the prepared #46 crown (deep chamfer margin) were scanned and solid models composed of the monolithic zirconia crown, cement layer, and prepared tooth were produced using the computer-aided design technology and were subsequently translated into 3-dimensional finite element models. Four models were prepared according to different cement types (zinc phosphate, polycarboxylate, glass ionomer, and resin). A load of 700 N was applied vertically on the crowns (8 loading points). Maximum principal stress was determined. RESULTS. Zinc phosphate cement had a greater stress concentration in the cement layer, while polycarboxylate cement had a greater stress concentration on the distal surface of the monolithic zirconia crown and abutment tooth. Resin cement and glass ionomer cement showed similar patterns, but resin cement showed a lower stress distribution on the lingual and mesial surface of the cement layer. CONCLUSION. The test results indicate that the use of different luting agents that have various elastic moduli has an impact on the stress distribution of the monolithic zirconia crowns, cement layers, and abutment tooth. Resin cement is recommended for the luting agent of the monolithic zirconia crowns.

The Strength Characteristics of Solidified Sandy Soils with Mixing Conditions (배합조건에 따른 고결사질토의 강도특성)

  • Yu, Chan;Chang, Pyung-Wuck;Lee, Chang-No;Roh, Gwang-Ha
    • Proceedings of the Korean Geotechical Society Conference
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    • 1999.02a
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    • pp.84-95
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    • 1999
  • Laboratory experiments were performed to evaluate the strength characteristics of solidified sandy soils by portland cement with mixing conditions. Factors considered in the experiments were the fine content(<#200, %), cement content(%) and water-cement ratio and unconfined compressive strength tests were performed on samples at 7 and 28 cured day. Results of tests showed that for a low cement content(7%∼10%) the fine content was very important while for a high cement content the water-cement ratio was very important. For 7%∼10% cement content, the optimum fine content which gained maximum strength was about 30%. But for 13% cement content, low fine content and water-cement ratio were more useful than others. In the multi regression analysis, significant equation was gained.

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A Study on the Properties of the Confined water ratio for Binder type and Replacement ratio (결합재의 종류 및 치환율에 따른 구속수비의 특성에 관한 연구)

  • Kwon Yeong-Ho;Lee Hyun-Ho;Lee Hwa-Jin;Ha Jae-Dam
    • Proceedings of the Korea Concrete Institute Conference
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    • 2004.05a
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    • pp.584-587
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    • 2004
  • This research investigates the rheological behavior and the confined water ratio of the cement paste and binder condition in order to predict mix design proportion of the high flowing concrete. The purpose of this study is to determine the optimum replacement ratio of binders including fly ash, and lime stone powder by the cement weight. For this purpose, belite cement, blast furnace slag cement and ordinary portland cement are selected. As test results, the confined water ratio shows the following range ; OPC>blast furnace slag cement>belite cement. Therefore, belite cement is proved very excellent cementitious materials in a view point of the flowability. The optimum replacement ratio of lime stone powder is shown over $30\%$ in case of belite cement and about $10\%$ in case of slag cement type. Also, the optimum replacement ratio of fly ash is shown $30\%$ by the cement weight considering the confined water ratio and deformable coefficient of the paste condition.

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An Experimental Study on the Mechanical Properties of Fiber Reinforced Cement Composites Utilizing by-Products(II) (산업부산물을 활용한 섬유보강 시멘트 복합체의 역학적 특성에 관한 실험적 연구(II))

  • 박승범;윤의식;조청휘
    • Proceedings of the Korea Concrete Institute Conference
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    • 1993.10a
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    • pp.144-149
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    • 1993
  • The results of an experimental study on the manufacture and the mechanical properties of carbon fiber reinforced silica fume.cement composites and light weight fly ash.cement composites are presented in this paper. The CF reinforced silica fume.cement composites using silica fume early strength cement were prepared with Pan-derived or Pitch-derived CF, and Lt. Wt, fly ash.cement composites using fly ash, early strength cement, perlite and a small amount of foaming agent. As the test results show, the flexural strength, toughness and ductility of CF reinforced silica fume .cement composites were remarkably increased by fiber contents. Also, the manufacturing process technology of Lt. Wt. fly ash.cement composites was developed and its optimum mix proportions were proposed. And the compressive and flexural strength of the fly ash.cement composites by hot water cured were improved even more than by moist cured, but are decreased by increasing fly ash replaced ratio for cement.

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A Fundamental Study on the Estimation of Unit Cement Content in Hardened Concrete (Test Method by Sodium Gluconate) (경화 콘크리트의 단위 시멘트량 추정 방법에 관한 기초적 연구)

  • 김광서;유영호;박도경
    • Proceedings of the Korea Concrete Institute Conference
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    • 1996.04a
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    • pp.24-29
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    • 1996
  • The purpose of this study is to propose new estimation method of unit cement content in hardened concrete. In general, the quantity of cement in hardened concrete is tested by hydrochlonic acid dissolving cement paste, however, hydrochloric acid dissolves sea shell contained in sea sand and lime stone in concrete. Therefore, the tested cement content is apt to estimate greater than actual cement content. The sodium gluconate solution dissolves only cement in concrete, it is hard to dissolve sea shell and lime stone as CaCo3. The effects of the quantity, concentration and temperature of sodium gluconate solution, the ignition temperature, the ignition loss of cement on the cement content and the percentage of dissolution of cement were investigated to establish a test method. From the results of these tests, the fundamental test method for cement content of hardened concrete by sodium gluconate is proposed.

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EXPERIMENTAL STUDY ON SEALING QUALITY OF POLYCARBOXYLATE CEMENT USED AS ROOT CANAL SEALER (카복실레이트 세멘트를 근관(根管) 충전재(充塡材)로 사용(使用) 시(時) 근관(根管) 폐쇄성(閉鏁性)에 관(關)한 실험적(實驗的) 연구(硏究))

  • Hwang, Young-Hwan
    • Restorative Dentistry and Endodontics
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    • v.2 no.1
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    • pp.32-37
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    • 1976
  • The author has studied comparatively the sealing quality of polycarboxylate cement, one of the newest dental cement systems, and zinc oxide eugenol cement by means of penetration of 2% methylene blue solution through the root apex of human teeth in 72 cases as time elapsed. Followings are the results obtained from this study. 1) In all groups, there was no increase in penetration related to increased time of immersion in the dye. 2) In polycarboxylate cement groups, there was a significant difference in depth of dye penetration of each tooth, but in zinc oxide eugenol cement group, there was a slight difference. 3) The depth of dye penetration of zinc oxide eugenol cement group is slightly lower than that of poly carboxylate cement groups. 4) In polycarboxylate cement groups, Carbolit cement group showed comparatively lower grade of dye penetration than Carbo cement group.

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Hydration properties of cement pastes containing high-volume mineral admixtures

  • Tang, Chao-Wei
    • Computers and Concrete
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    • v.7 no.1
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    • pp.17-38
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    • 2010
  • This research aimed to investigate the influence of high-volume mineral admixtures (MAs), i.e., fly ash and slag, on the hydration characteristics and microstructures of cement pastes. Degree of cement hydration was quantified by the loss-on-ignition technique and degree of pozzolanic reaction was determined by a selective dissolution method. The influence of MAs on the pore structure of paste was measured by mercury intrusion porosimetry. The results showed that the hydration properties of the blended pastes were a function of water to binder ratio, cement replacement level by MAs, and curing age. Pastes containing fly ash exhibited strongly reduced early strength, especially for mix with 45% fly ash. Moreover, at a similar cement replacement level, slag incorporated cement paste showed higher degrees of cement hydration and pozzolanic reaction than that of fly ash incorporated cement paste. Thus, the present study demonstrates that high substitution rates of slag for cement result in better effects on the short- and long-term hydration properties of cement pastes.

Accelerated Chloride Diffusion Properties of Portland Cement Concrete (포틀랜드계 시멘트 콘크리트의 촉진 염화물 확산 특성)

  • 김진철;이찬영;이용은
    • Proceedings of the Korea Concrete Institute Conference
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    • 1999.10a
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    • pp.775-778
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    • 1999
  • Accelerated chloride diffusion tests were carried out to estimate the chloride diffusion coefficient of concrete using ordinary portland cement, low heat belite-rich portland cement, and sulphate resistant portland cement. Concrete using low heat belite-rich portland cement showed a high diffusion coefficient due to delayed hydration of low heat belite rich portland cement, while the diffusion coefficients of concrete using sulphate resistant portland cement and ordinary portland cement were low.

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