• International Journal of Human Ecology
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• v.8 no.1
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• pp.1-8
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• 2007

Degradation of cellulose during prolonged exposure in atmospheric conditions has been recognized as one of main problems in preserving cellulose-made products. The purpose of this research was therefore to study effects of borohydride reduction in improving both the color and strength retention of cotton fabrics artificially aged at temperatures ranging from $100^{\circ}C$ to $150^{\circ}C$. Results indicated that the fabrics treated with either sodium or tetramethylammonium borohydrides (TMA) were degraded at rates about one-half that of water-washed cotton. These results were consistent over the temperature range. Calculation of the activation energy (Ea) by different methods showed $Ea\;=\;25.5{\pm}\;1.5\;Kcal$, in keeping with measurements made by others at lower temperatures. The TMA-treatment was effective in minimizing discoloration of the fabrics with pre-baking, but not of the un-prebaked fabrics.

• Textile Coloration and Finishing
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• v.17 no.4 s.83
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• pp.35-40
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• 2005

Researches to preserve and restore the excavated cellulose fabrics as costume heritages have been carried out. In this study, in order to artificially restore an excavated cellulose fabrics, acid-treated cellulose fabrics were prepared. Three kinds of cellulose fabrics were used for an experiment. Three kinds of cellulose fabrics were treated by the acid aqueous solution for the various strength retention ($100\%,\;80\%,\;60\%,\;40\%,\;20\%$). The fine structure and physical properties of acid treated cellulose fabrics were investigated with various techniques such as wide-angle X-ray diffraction, tensile test, weight loss, shrinkage, SEM etc. Tensile strength and strain of cellulose fabrics decreased with increasing acid treatment time. However, weight loss and shrinkage increasing slightly. The crystal diffraction intensity was not changed. SEM results of acid-treated cellulose fabrics show that the surface was damaged.

• Bulletin of the Korean Chemical Society
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• v.33 no.12
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• pp.4122-4126
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• 2012

Cellulose-graft-poly (L-lactide) (cellulose-g-PLLA) was successfully prepared via ring-opening polymerization (ROP) by using 4-dimethylaminopyridine (DMAP) as an organic catalyst in an ionic liquid 1-allyl-3-methylimidazolium chloride (AmimCl). The structure and morphology of the polymer was characterized by nuclear magnetic resonance (NMR) and transmission electron microscope (TEM). From wide-angle X-ray powder diffraction (WAXD) and degradation test (by acid, alkaline, PBS and enzyme solution), changes in the crystalline structure as a result of degradation was also investigated. The results indicated that materials which have low degree of crystallinity showing higher degradability, however, in acid liquor, enzyme solution, alkaline liquor and PBS system, the degradation rate of the polymer decreased by the above sequence. Moreover, with the further increase of graft degree of this material, its degradation degree decreased.

• The Korean Journal of Food And Nutrition
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• v.4 no.1
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• pp.99-107
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• 1991

Lignocellulose and lignolic compounds were absolutely given much weight In the biosphere, and their degradation was essential for continuous biological carbon circulation. Whereas aerobic cellulolytic microorganism dissolved the cellulose into their elements in the first stage, strict anaerobic cellulolytic microorganism's role was taken I increasing interest through the recent research. It was reviewed that anaerobic microbial degradation process of lignocellulose and its derivatives (cellulose, lignin, oligolignol and monoaromatic compound), and function of anaerobic microorganism on the. environmental ecology.

• KSBB Journal
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• v.8 no.3
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• pp.237-242
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• 1993

Chitin-based fibers have low mechanical strength and hence cannot be used as surgery fiber due to fast degradation In tissues. A new fiber Chitulose was made by mixing chitin with cellulose, both of which have similar structure. A mixture of dimethylacetamide (DMAc) and 6% lithium chloride (LiCl) was found to be an effective solvent system for dissolvoing chitin and cellulose. The Chitulose fiber made by wet spinning of a mixture of chitin and cellulose resulted in the highest degree of strength and flexibility when the ratio of chitin to cellulose was 1.5; 0.2. The fiber maintained mechanical structure even after autoclaving, indicating thermal stability. A biodegradability test of the Chitulose fiber by imbeding in a rat showed that degradation was initiated in 14 days and completely done in 40 days.

• Journal of Korea Technical Association of The Pulp and Paper Industry
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• v.31 no.2
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• pp.1-7
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• 1999

In this paper, five lignin model compounds (vanilly alcohol, veratryl alcohol, veratryl methyl carbinol, biseugenol) and three cellulose model compounds (${\alpha}$-D-glucos, methyl-${\beta}$-D-glucopyra-noside, D-cellobiose) were used to study the degradation rates of lignin and cellulose with chlorine dioxide. Biseugenol, which has unsaturated structure on the side chain of aromatic ring, was found to react with chlorine dioxide very quickly and consume large amount of chlorine dioxide. Phenolic structures, represented by veratryl alcohol and apocynol, react with chlorine dioxide much faster than nonphenolic structures represented by veratryl alcohol and veratryl methyl carbinol. The degradations of cellulose models were generally very slight, the corder of reaction rate being ${\alpha}$-D-glucose > D-cellobiose > methyl-${\alpha}$-D-glucopyranoside.

• Journal of Radiation Industry
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• v.17 no.4
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• pp.501-508
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• 2023

There are various factors that have a negative impact on safety over a long period of time after the closure of a radioactive waste disposal facility. In particular, it is important to limit substances that accelerate radionuclide migration while inhibiting adsorption between radionuclides and the subsurface medium. Through this study, a method for deriving a quantitative criteria evaluation method is proposed for cellulose among materials that accelerate the movement of these radionuclides after closure of the disposal facility. Since Sweden's SKB is representative worldwide for preparing criteria for cellulose in disposal facilities, it analyzed Sweden's acceptance criteria method and presented a method that can be applied domestically. The decomposition characteristics of cellulose and the adsorption and dissolution characteristics of ISA among degradation products were reviewed, and quantitative analysis of cement materials that create a high pH environment favorable for cellulose decomposition was also included. In addition, the total amount of the finally disposable cellulose material can be derived by using the volume information of the waste containing the cellulose material. Through this methodology for calculating the total amount of cellulose, it is expected that subsequent studies will be conducted to secure data reflecting the environmental conditions of radioactive waste disposal facilities in Korea. In addition, it is expected to be utilized as a good method to evaluate the impact of other complexing agents other than cellulose and to suggest the amount of disposal.

• Asian-Australasian Journal of Animal Sciences
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• v.14 no.4
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• pp.501-506
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• 2001

This experiment was conducted to evaluate the effects of supplemental unsaturated fatty acids (UFA) on fermentation characteristics, especially on gas production, cellulose degradation and volatile fatty acid (VFA) concentration by mixed ruminal microorganisms. In order to attain this objective, unsaturated fatty acids including oleic acid (C 18:1), linoleic acid (C18:2) and arachidonic acid (C22:4) were added at varying level. Mixed ruminal microbes used in this experiment were obtained from the rumen of a cannulated Holstein cow. Medium pH values after 7 d incubation were significantly affected by type and level of unsaturated fatty acids (p<0.01). All of UFA inhibited total gas production, and especially treatment of arachidonic acid at the levels of 0.01% gave the lowest gas. production after 7 d incubation (p<0.01). Comparison of the population of protozoa revealed that UFA did not have any significant effect on the total protozoa number. The addition of UFA did not effect dry matter degradation. Volatile fatty acid (VFA) composition of the culture was influenced little by UFA, although the considerable amount of iso-type VFA were detected in UFA supplemented incubations. The ratio of acetic acids to propionic acids, however, was lower than control in all the treatments after 7 d incubation (p<0.01).

• The Transactions of The Korean Institute of Electrical Engineers
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• v.59 no.5
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• pp.912-917
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• 2010

It was known that oil-filled transformer's life depended on insulating paper which was applied to transformers for insulating of transformer. Therefore when paper was aged, its electrical, mechanical and chemical characteristics were changed. Especially if operating temperature was high, paper was quickly damaged. As cellulose paper which was mainly used for solid insulation of transformers was degraded, the cellulose polymer chains broke down into shorter lengths and gases such as CO, $CO_2$, $CH_4$, $C_2H_4$ and so on were produced from paper. Also by-product known as furan compounds were producted from paper and it were dissolved within insulating oil. In this paper accelerating aging cell was aged during 60 hours at 100, 150, 180 and $200^{\circ}C$, respectively, so evaluating the chemical characteristics of cellulose paper by thermal. An it were performed analysis such as tensile strength(TS), dissolved gas analysis(DGA) and high performance liquid chromatography(HPLC). Also for analyzing of correlation between insulating degradation characteristics, it was performed linear regression method as statistical treatment.

• Journal of the Korean Society of Tobacco Science
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• v.21 no.2
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• pp.136-143
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• 1999

This study was conducted to evaluate the degradation characteristics of waste cigarette filters under 0, 5, 10, and 15cm in depth from soil surface by environmental conditions. Weather was the most important factor during degradation of waste cigarette filters in this study. Bulking of cellulose acetate filaments exposed on soil surface was observed after 2 months, but the form of filter was kept up after 12 months. The treated cigarette filters in soil landfill revealed a little different degradation pattern at each soil landfill depth, The sample in 5cm depth of soil was more degraded then other site. A fluffy appearance of cellulose acetate filaments in the control filter rods was also developed more strongly in soil landfill then on soil surface. From the observation of waste cigarette filters by scanning electron microscopy, much degradation of the fiber of waste cigarette filters could be ascertained in soil landfill. The weight of waste cigarette filters under 5cm from soil surface was reduced about 50%, and the tensile strength of the samples in soil surface and under 5cm from soil surface were reduced 66.0% and 92.4%, respectively. The microbial experiment date that the viable cell number in microbial population and cellulolytic microorganisms showed the maximum values under 5cm from soil surface, suggest that microorganisms in soil play an important roll in the degradation of acetate cigarette filters.