• Journal of the Korean Society of Clothing and Textiles
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• v.31 no.12
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• pp.1754-1760
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• 2007

To improve poor dye uptake of safflower yellow colorants, cellulose fibers were pretreated with chitosan. The effect of chitosan pretreatment on the dyeability of safflower yellow colorants to cotton, ramie, and rayon was investigated in terms of dye uptake, color, and colorfastness. Irrespective of fiber types, dye uptake increased continuously with increase in chitosan concentration. Chitosan pretreatment improved dye uptake up to 5.6 times for cotton, 7.2 times for ramie, and 3.7 times for rayon. For cotton and ramie, the shade of dyed fabric changed YR color to Y color with increase in chitosan concentration. Dyed rayon fabrics showed Y color irrespective of chitosan concentration. Shades got darker and deeper with increasing chitosan concentration. Shades of chitosan pretreated fabrics were shifted differently depending on dyeing temperature within same fabrics. In common, the color of all dyed fabrics changed to YR at 50 and $70^{\circ}C$ while Y color at 30 and $90^{\circ}C$. V and C value decreased with increase in dyeing temperature and resulted in darker and duller color, in general. Light fastness was fair while washing fastness was poor. It was confirmed that ultrasonic dyeing method enhanced dye uptake more than 30% for cotton and ramie fabrics compared to the conventional automatic machine dyeing method. However, no difference in dye uptake between two dyeing methods was found for rayon.

• Polymer(Korea)
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• v.37 no.1
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• pp.52-60
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• 2013

Partially hydrolyzed cellulose acetate (CA) fibers were prepared by treating CA fibers in aqueous $Na_2CO_3$ solutions of various concentrations. The deacetylation of CA fibers was confirmed through FTIR spectra and WAXD patterns. The hydrolysis was confined to the surface part of the CA fiber by controlling the treatment conditions. The resultant fibers had a sheath-core structure with a sheath component of regenerated cellulose and a core of non-hydrolyzed cellulose acetate. The SEM images of the surface-hydrolyzed CA fibers, the core of which was dissolved out using acetone as the solvent, showed that the sheath thickness increased with increasing alkaline concentration, indicating an increase in the hydrolyzed fiber, i.e., regenerated cellulose. Polarized FTIR analysis of the polyimide film rubbed with velvet fabrics of surface-hydrolyzed CA fibers showed that polyimide molecules were preferentially oriented to the rubbing direction.

• Textile Coloration and Finishing
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• v.14 no.3
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• pp.34-43
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• 2002

Abstract-Many studies have been carried out to improve the dyeability of anionic dyes onto cellulosic fibers. Modification of control using cationic compounds has been most widely used. In this study, an effort was made to cationize cotton fabrics using cellulose-reactive allylamine polymer, namely triazinyl N,N'-dimethyl-N,N'-diallyl ammonium chloride in the previous work. The results showed that the dye-uptake of treated cotton fabrics with acid dyes and reactive dyes markedly increased in the various dyeing conditions. In addition, the dyeing rate of cationized cotton was also faster than that of untreated counterpart. Furthermore, the antimicrobial property was also investigated to determine the effects of cationization.

• Textile Coloration and Finishing
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• v.13 no.3
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• pp.155-164
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• 2001

Textile wet-processing industry usually five rise to environmental pollution problems caused by using chemical substance. The objective of this study is to apply enzymes for wool and reduce the environmental problems. Three commercial protein degradation enzymes and a cellulose degradation enzyme as a reference were treated to prevent the shrinkage of wool fabric on laundering. Shrink resistant effects used change with the kinds of enzyme, the amount of enzyme, assistant chemicals, and the pre-treatment condition of wool fabric. When pre-treated with corona before enzyme treatment under ultrasonic condition, the weight loss was increased and strength was decreased and elongation was increased. Both corona pre-treatment and the addition of $Na_2SO_4$ also decreased shrinkage of wool fabrics on laundering. The existence of assistant chemicals increased alkali solubility of wool fabrics.

• The Research Journal of the Costume Culture
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• v.11 no.3
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• pp.423-430
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• 2003

Cotton fabric md nylon fabric were chosen as base fabric specimens for dyeing using Japanese pagoda tree colorants through chitosan, treatment. With the chitosan treatment, the dye-uptake of the treated fabric increased. This treatment is also expected to be effective in terms of environment-friendliness. The effect of the dyeing methods, mordanting or non-mordanting, and chitosan treatment on the dye-uptake and air permeability of the treated fabrics was investigated. In case of cotton fabric, Al mordanted dyeing resulted in higher dye-uptake through the chitosan treatment. Therefore, the chitosan treatment is effective in this case. Japanese pagoda tree seems to have direct affinity for nylon fabric without the mordanting treatment. In case of cotton fabric, it seems that the cellulose molecules, colorants, and the chitosan make a complex, thereby reducing the air permeability. In case of nylon fabric, due to the fact the Japanese pagoda tree colorant molecules form direct physical bonding with the nylon molecules, it seems that there is not much of air permeability reduction.

• Journal of the Korean Society of Clothing and Textiles
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• v.27 no.11
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• pp.1291-1299
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• 2003

In order to design the better brassiere in terms of appearance and functions, various parameters of the materials should be considered; in this study, fatigue properties and subjective sensation of wing materials and its relation to the preference for a brassiere was investigated. After the survey of commercially available products, five elastic fabrics such as cotton, Modal, polyester, nylon, and Tactel, all of which contain 10% polyurethane, were chosen as specimens. Fabric growth were determined to evaluate fatigue properties. Qmax was determined to evaluate the warm-cool feeling. For the sensory test, semantic differential scale which contains 15 adjectives were developed. Fatigue properties were very similar at the 20% elongation irrespective of the duration of tension, but at 40% and 100% elongation, man made fabric showed less growth than cellulose fabrics. The factor analysis showed four factors such as sense of warmth, smoothness, weight and elasticity. Preference of the specimens was ranked in the order of Tactel>Modal>cotton>nylon>polyester.

• Journal of the Korean Society of Clothing and Textiles
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• v.12 no.2 s.27
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• pp.181-188
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• 1988

Cotton fabrics were slack-mercerized in sodium hydroxide, ammonia water(min. $28{\%}\;NH_3$), and mixture of ammonia water/sodium hydroxide. The surface of treated cotton fabrics were observed through SEM, and the changes of fine structure were analyzed by X-ray diffractometer. In addition to that shrinkage was compared mutally, and tenacity-elongation compared, too. SEM photographs showed fibrls rearranged strightly toward fibre axis. X-ray diffraction represented increased amorphous fraction, and partial recrystallization into cellulose 2 lattic after treatment with sodium hydroxide and mixture of ammonia water/sodium hydroxide. The mercerization produced increased fibre tenacity-elongation with slark state. Lastly, the best condition of mercerization was $4\%/14\%$, $10^{\circ}C,\;5\~30$ min. in mixture of ammonia/sodium hydroxide.

• Textile Coloration and Finishing
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• v.25 no.4
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• pp.247-253
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• 2013

The enzyme-like catalytic functions of metal complex phthalocyanine derivatives those containing carboxylic acid groups could be applied as odor-removing systems and antibacterial systems. Pyromellitic dianhydride and 4-nitrophthalimide were used as starting material for synthesizing dinitro-tetracarboxylic acid iron phthalocyanine(compound 1). Then diamino-tetracarboxylic phthalocyanine(compound 2) was obtained by reduction of compound 1. For the formation of covalent bond with cellulose fiber, cyanuric chloride was introduced to the amino group of compound 2 by condensation reaction compound 3. The exhaustion method was employed for adsorbing compound 3 on cotton fiber. K/S values of each fabrics were measured by a CCM system and deodorizing rates were tested by a detector tube method for ammonia gas. K/S values of treated cotton fiber with compound 3 were arranged from 2.1 to 4.2 at $90^{\circ}C$ of exhaustion temperature. Deodorizing rates provided result of 81%, 84%, 88%, 91%, by passing time of 30 min, 60 min, 90 min, 120 min, respectively.

• 보존과학연구
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• s.34
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• pp.20-29
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• 2013

Paper, textile and wood materials are mainly consisted of cellulose. Cellulose is high molecule and make up the strong crystalline structure by hydrogen bonds. In particular, the polymerization degree of cellulose are closely related to the strength of fiber, and the permanence. the useful life of fiber, also depends on the degradation of this substance. The viscosity of cellulose is considered to be an important indicator of fiber damage in high molecule polymers. The viscosity measurements with CED solution is used to measure the molecular weight and the degree of polymerization of cellulose. Cellulose viscosity of wood fibers is measured with TAPPI standard method T230. However, TAPPI standard method T230 is difficult to completely dissolving the cellulose of high molecular weight and large degree of polymerization, such as Korea traditional papers and fabrics made with mulberry, ramie, cotton fibers. In this study, The high viscosity of hanji and fabric was measured with TAPPI standard method T254. T254 method is that the cellulose specimen with the proper amount of weaker (0.167M CED) solution, and completely dissolved with the stronger (1.0M CED) solution. It was found that cellulose with high degree of polymerization was dissolved more easily in general CED method.

• Textile Coloration and Finishing
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• v.23 no.3
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• pp.201-209
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• 2011

With a new method of applying chitosan and alginate onto cellulose, multi-coated cotton fabrics with chitosan and alginate were prepared and characterized. To coat cotton with chitosan, raw cotton was dipped in chitosan solution, mangled of 1kgf/$cm^2$, neutralized in 2 wt% NaOH soluton, washed, and dried at $60^{\circ}C$ oven. The chitosan-coated fiber was dipped in sodium alginate solution, 1kgf/$cm^2$ mangled, neutralized in 2 wt% $CaCl_2$ solution, washed, and dried at $60^{\circ}C$ oven, resulting in CCAC(coated cotton with chitosan and calcium alginate skin) fiber characteristics. Excellent absorbancy of distilled water and saline solution was observed by the absorption test on cotton fabric treated with CCAC(0.5 wt% calcium alginate) and 0.5 wt% calcium alginate respectively. The SEM photograph confirmed the uniform coating on the cotton fabric surface.