• Title/Summary/Keyword: cell temperature

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태양전지용 CdS 박막의 제조 조건에 따른 전기적 광학적 특성에 관한 연구 (A Study on the Electrical and Optical Properties of CdS Thin Films Deposited with Different Conditions for Solar Cell Applications)

  • 이재형
    • 한국전기전자재료학회논문지
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    • 제21권7호
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    • pp.620-628
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    • 2008
  • Cadmium sulphide (CdS) thin film, which is used as a window layer of heterojunction solar cell, on the glass substrate was deposited by vacuum evaporation. Effects of deposition conditions such as the source and substrate temperature on electrical and optical properties of CdS films was investigated. As the source temperature was increased, the deposition rate of CdS films was increased. In addition, the optical transmittance and the electrical resistivity of CdS films were decreased as the source temperature was increased. This results were attributed to the increase of excess Cd amount in the film. The crystal structure of CdS films exhibited the hexagonal phase with preferential orientation of the (002) plane. As the substrate temperature was increased, the crystal structure of CdS films was improved and the resistivity of the films was increased due to the decrease of excess Cd in film.

일산화탄소 저감을 위한 개질가스의 전이반응 연구 (Investigation of the Water Gas Shift from Reforming Gas for CO Removal)

  • 김성천;윤문중;전영남
    • 대한기계학회논문집B
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    • 제31권10호
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    • pp.855-859
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    • 2007
  • Hydrogen as an energy carrier in fuel cell offers perhaps the largest potential benefits of reduced emissions of pollutants and greenhouse gases. The generation of high-purity hydrogen from hydrocarbon fuels is essential for efficient operation of fuel cell. Reduction of carbon monoxide to an acceptable level of 10ppm involves high temperature and low temperature water gas shift (WGS), followed by selective oxidation of residual carbon monoxide. The WGS reactor was designed and tested in this study to produce hydrogen-rich gas with CO to less than 5000 ppm. In the water gas shift operation, gas emerges from the reformer is taken through a high temperature shift (HTS) catalyst to reduce the CO concentration to about $2{\sim}4%$ followed to about 5000 ppm via a low temperature shift (LTS) catalyst.

백시트 종류에 따른 태양전지 모듈의 방열 특성 평가 (Evaluation of Heat Transfer Characteristics of PV Module with Different Backsheet)

  • 배수현;오원욱;강윤묵;이해석;김동환
    • Current Photovoltaic Research
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    • 제6권2호
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    • pp.39-42
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    • 2018
  • When the PV module is illuminated in a high temperature region, solar cells are also exposed to the high temperature external environment. The operating temperature of the solar cell inside the module is increased, which causes the power drops. Various efforts have been made to reduce the operating temperature and compensate the power of solar cells according to the outdoor temperature such as installing of a cooling system. Researches have been also reported to lower the operating temperature of solar cells by improving the heat dissipation properties of the backsheet. In this study, we conducted a test to measure the internal temperature of each module components and the external temperature when the light was irradiated according to the surrounding temperature. Backsheets with different thermal conductivities were compared in the test. Finally, in order to explain the temperature difference between the solar cell and the outside of the module, we proposed an evaluation method of the heat transfer characteristics of photovoltaic modules with different backsheet.

연료전지 자동차 열방출 시스템의 설계 (Design of a Heat Release System for Fuel Cell Vehicles)

  • 김민수;김성철;박민수;정승훈;윤석호
    • 신재생에너지
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    • 제1권4호
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    • pp.49-54
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    • 2005
  • There is close relation between the heat generation in the fuel cell stack and the fuel performance. In PEM fuel cell vehicles, the stack coolant temperature is about $65^{\circ}C$, which is far lower than that for general automobile engine. Therefore, it is hard to release heat generated in the stack by using a radiator of limited size because of the reduced temperature difference between the coolant and the ambient air. In this study, indirect stack cooling system using $CO_2$ heat pump was designed and its stack cooling performance in releasing heat to the ambient was investigated. This work focuses on a series of processes that grasp the relation among the fuel cell power, the radiator capacity and the stack temperature. The purpose of this work is to find out a way to properly release sufficient amount of heat through the finite sized radiator, so that the slack power generation can not be deteriorated due to the stack temperature increase. The optimization between the compressor power consumption and the fuel cell output power can be carried out to maximize the performance of fuel cell system.

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Fabrication and Characterization of Composite LSCF-Ag Cathode for Solid Oxide Fuel Cells using Electron Beam Irradiation Process

  • Kang, Hyun Suk;Jung, Yung-Min;Song, Rak-Hyun;Peck, Dong-Hyun;Park, ChangMoon;Lee, Byung Cheol
    • Bulletin of the Korean Chemical Society
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    • 제35권10호
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    • pp.2969-2973
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    • 2014
  • A new process to fabricate a composite LSCF-Ag cathode material for SOFCs by electron beam (e-beam) irradiation process has been suggested for operation under intermediate temperature range of $600-700^{\circ}C$. A composite LSCF-Ag cathode with uniformly coated Ag nanoparticles on the surface of the LSCF material was prepared by a facile e-beam irradiation method at room temperature. The morphology of the composite LSCF-Ag material was analyzed using a TEM, FE-SEM, and EDS. The prepared composite LSCF-Ag material can play a significant role in increasing the electro-catalytic activities and reducing the operating temperature of SOFCs. The performance of a tubular single cell prepared using the composite LSCF-Ag cathode, YSZ electrolyte and a Ni/YSZ anode was evaluated at reduced operating temperature of $600-700^{\circ}C$. The micro-structure and chemical composition of the single cell were investigated using a FE-SEM and EDS.

고온 고분자전해질 연료전지 박판형 분리판의 유로 설계 및 스택 성능 평가 (Flow Field Design and Stack Performance Evaluation of the Thin Plate Separator for High Temperature Polymer Electrolyte Membrane Fuel Cell)

  • 김지홍;김민진;김진수
    • 한국수소및신에너지학회논문집
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    • 제29권5호
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    • pp.442-449
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    • 2018
  • Research on High temperature polymer electrolyte fuel cell (HT-PEMFC) has actively been conducted all over the world. Since the HT-PEMFC can be operated at a high temperature of $120-180^{\circ}C$ using phosphoric acid-doped polybenzimidazole (PBI) electrolyte membrane, it has considerable advantages over conventional PEMFC in terms of operating conditions and system efficiency. However, If the thermal distribution is not uniform in the stack unit, degradation due to local reaction and deterioration of lifetime are difficult to prevent. The thin plate separator reduces the volume of the fuel cell stack and improves heat transfer, consequently, enhancing the cooling effect. In this paper, a large area flow field of thin plate separator for HT-PEMFC is designed and sub-stack is fabricated. We have studied stack performance evaluation under various operating conditions and it has been verified that the proposed design can achieve acceptable stack performance at a wide operating range.

직접에탄올 연료전지의 운전조건에 관한 연구 (A Study on an Operating Conditions for the Direct Ethanol Fuel Cell)

  • 김영춘;구본국;장문국;지학배;한상보;박재윤
    • 전기학회논문지
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    • 제60권11호
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    • pp.2076-2082
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    • 2011
  • The goal of this paper is to find an operating conditions of the single direct ethanol fuel cell such as the cell temperature, and flow rates of ethanol and oxygen. To investigate the output characteristics, the electrical current increased from 0[A] with interval of 0.001[A] every 2[s], and the cell voltage was increased until the voltage became 0.05[V]. Related to the effect of the cell temperature, the output characteristics both voltage and power were increased upto 80[$^{\circ}C$] according to the increase of the current density, but those were decreased over that temperature. In addition, the optimal flow rate of ethanol in anode was identified as of 2[mL/min] due to the dependence of generation rate such as the hydrogen ion and electron. And the flow rate of oxygen in cathode was desirable to about 300[sccm/min], it might be affected by the chemical reaction rate of the water formation among hydrogen ion, electron, and oxygen. Consequently, the fundamental conditions were identified in this work, and it will be carried out to find the best conditions of membrane by the effect of the plasma surface treatment, and the effect of other catalysts except for a platinum.

고온형 고분자 전해질 연료전지 스택 내부의 냉각판 수가 스택에 미치는 열 영향성의 수치적 연구 (Analysis of Thermal Effect by Coolant Plate Number in High-Temperature Polymer Electrolyte Membrane Fuel Cell Stack)

  • 최병욱;주현철
    • 한국수소및신에너지학회논문집
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    • 제26권2호
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    • pp.127-135
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    • 2015
  • High-Temperautre Polymer Electrolyte Membrane Fuel Cell (HT-PEMFC) with phosphoric acid-doped polybenzimidazole (PBI) membrane has high power density because of high operating temperature from 100 to $200^{\circ}C$. In fuel cell stack, heat is generated by electrochemical reaction and high operating temperature makes a lot of heat. This heat is caouse of durability and performance decrease about stack. For these reasons, heat management is important in HT-PEMFC. So, we developed HT-PEMFC model and study heat flow in HT-PEMFC stack. In this study, we placed coolant plate number per cell number ratio as variable and analysed heat flow distribution in stack.

광도전성저항 안정화회로를 채택한 가변온도형 열선유속계의 출력특성에 관한 실험적 연구 (Experimental Study on Output Characteristics of a Variable Temperature Anemometer Adopting a Photoconductive Cell and Stabilizing Circuit)

  • 이신표
    • 대한기계학회논문집B
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    • 제25권9호
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    • pp.1201-1208
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    • 2001
  • Variable temperature anemometer(VTA) has greater sensitivity than a conventional constant temperature anemometer(CTA). In order to design a reliable VTA system, however, an elaborate photoconductive cell stabilizing circuit which plays a key role in setting wire-overheat ratio should be firstly developed. In this study, a stabilizing circuit which adopts proportional-integral analog controller was proposed and thoroughly tested for its accuracy and reproducibility. In contrast to the available circuit suggested by Takagi, the present circuit has characteristic that the resistance of a photoconductive cell increases with the increase of input voltage, which makes the current circuit very suitable for the design of VTA. Finally, VTA adopting stabilizing circuit was made and the enhanced sensitivity of the VTA was validated experimentally by comparing the calibration curves of VTA and CTA.

플렉서블 CIGS 태양전지의 고온고습 환경 고장 기구 분석 (Evaluation of Failure Mechanism of Flexible CIGS Solar Cell Exposed to High Temperature and Humid Atmosphere)

  • 김혁수;변재원
    • 한국신뢰성학회지:신뢰성응용연구
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    • 제16권1호
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    • pp.41-47
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    • 2016
  • Purpose: The purpose of this study was to evaluate electrical and structural degradation of flexible CIGS sollar cell exposed to high temperature and humid atmosphere. Method: Accelerated degradation was performed for various time under $85^{\circ}C/85%RH$ and then electrical and structural properties were analyzed by 4-point probe method, scanning electron microscopy (SEM), energy dispersive spectroscopy (EDS), and X-ray diffraction (XRD). Results: Sheet resistance of the top ITO layer increased with exposure time to the high temperature and humid atmosphere. Blunting of the protrusion morphology of ITO layer was observed for the degraded specimen, while no phase change was detected by XRD. Oxygen was detected at the edge area after 300 hours of exposure. Conclusion: Increase in electrical resistance of the degraded CIGS solar cell under high temperature and humid environment was attribute to the oxygen or water absorption.