• Title/Summary/Keyword: cell stability

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Stability Assessment of Lead Sulfide Colloidal Quantum Dot Based Schottky Solar Cell

  • Song, Jung-Hoon;Kim, Jun-Kwan;An, Hye-Jin;Choi, Hye-Kyoung;Jeong, So-Hee
    • Proceedings of the Korean Vacuum Society Conference
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    • 2012.08a
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    • pp.413-413
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    • 2012
  • Lead sulfide (PbS) Colloidal quantum dots (CQDs) are promising material for the photovoltaic device due to its various outstanding properties such as tunable band-gap, solution processability, and infrared absorption. More importantly, PbS CQDs have large exciton Bohr radius of 20 nm due to the uniquely large dielectric constants that result in the strong quantum confinement. To exploit desirable properties in photovoltaic device, it is essential to fabricate a device exhibiting stable performance. Unfortunately, the performance of PbS NQDs based Schottky solar cell is considerably degraded according to the exposure in the air. The air-exposed degradation originates on the oxidation of interface between PbS NQDS layer and metal electrode. Therefore, it is necessary to enhance the stability of Schottky junction device by inserting a passivation layer. We investigate the effect of insertion of passivation layer on the performance of Schottky junction solar cells using PbS NQDs with band-gap of 1.3 eV. Schottky solar cell is the simple photovoltaic device with junction between semiconducting layer and metal electrode which a significant built-in-potential is established due to the workfunction difference between two materials. Although the device without passivation layer significantly degraded in several hours, considerable enhancement of stability can be obtained by inserting the very thin LiF layer (<1 nm) as a passivation layer. In this study, LiF layer is inserted between PbS NQDs layer and metal as an interface passivation layer. From the results, we can conclude that employment of very thin LiF layer is effective to enhance the stability of Schottky junction solar cells. We believe that this passivation layer is applicable not only to the PbS NQDs based solar cell, but also the various NQDs materials in order to enhance the stability of the device.

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Zeolite-Mediated Cation Exchange Enhances the Stability of mRNA during Cell-Free Protein Synthesis

  • Kim, You-Eil;Kim, Dong-Myung;Choi, Cha-Yong
    • Biotechnology and Bioprocess Engineering:BBE
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    • v.11 no.3
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    • pp.258-261
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    • 2006
  • The addition of zeolite particles enhances the stability of mRNA molecules in a cell-free protein synthesis system. When $20{\mu}g/{\mu}L$ of zeolite (Y5.4) is added to a reaction mixture of cell-free protein synthesis, a substantial increase in protein synthesis is observed. The stabilizing effect of zeolite is most dearly observed in an in vitro translation reaction directed by purified mRNA, as opposed to a coupled transcription and translation reaction. Upon the addition of zeolite in the in vitro translation reaction, the life span of the mRNA molecules is substantially extended, leading to an 80% increase in protein synthesis. The effect of zeolite upon the mRNA stability appears be strongly related to the cation exchange (potassium to sodium) reaction. Our results demonstrate the possibility of modifying this biological process using heterogeneous, non-biological substances in a cell-free protein synthesis system.

Study on the Air Foil Bearings of the Turbo-Expander for Fuel Cell System (연료 전지용 터보 익스펜더의 공기 포일 베어링에 대한 연구)

  • Lee Yong-Bok;Park Dong-Jin;Kim Chang-Ho
    • Tribology and Lubricants
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    • v.21 no.3
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    • pp.114-121
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    • 2005
  • As fuel cell system is environmental friendly generator, its performance depends on its air supply system. Because, fuel cell stack generates electrical energy by electron and the electron is generated by reacting between air and hydrogen. So, more and more compressed air is supplied, more and more the energy can be obtained. In this study, turbo-expander supported by air foil bearing is introduced as the air supply system used by fuel cell systems. The turbo-expander is a turbo machine which operates at high speed, so air foil bearings suit its purpose for the bearing elements. Analysis for confirming the stability and endurance is conducted. Based on FDM and Newton-Raphson method, characteristics of air foil bearing, dynamic coefficients, pressure field and load capacity, are obtained. Using the characteristics of air foil bearing, the rotordynamic analysis is performed by finite element method. The analysis (stability analysis and critical speed map) shows that turbo-expander is stability at running speed. After the analysis, the test process and results are presented. The goals of test are running up to 90,000 RPM, flow rate of 150 $m^3/h$ and pressure ratio of 1.15. The test results show that the aerodynamic performance and stability of turbo-expander are satisfied to the primary goals.

STABILITY OF FUZZY DYNAMIC CONTROL SYSTEM: The Cell-State Transition Method

  • Kang, Hoon
    • Proceedings of the Korean Institute of Intelligent Systems Conference
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    • 1993.06a
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    • pp.1078-1081
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    • 1993
  • The Objective of this paper is to provide fuzzy control designers with a design tool for stable fuzzy logic controllers. Given multiple sets of data disturbed by vagueness uncertainty, we generate the implicative rules that guarantee stability and robustness of closed-loop fuzzy dynamic systems. We propose the cell-state transition method which utilizes Hsu's cell-to-cell mapping concept [1]. As a result, a generic and implementable design methodology for obtaining a fuzzy feedback gain K, a fuzzy hypercube [2], is provided and illustrated with simple examples.

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Cell Opening of High Resilience Polyurethane Foam I. Concentration Effect of Polyether Type Cell Opener (고탄성 폴리우레탄 발포체의 기포개방 I. 폴리에테르형 기포개방제의 농도 영향)

  • 송기천;이상목;이동호
    • Polymer(Korea)
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    • v.25 no.5
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    • pp.679-690
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    • 2001
  • High resilience PU foams were prepared with polyether type cell opener. The influences of cell opener concentration on the kinetics, rheology, structural stability morphology and open cell content of the obtained foam were investigated and the role of cell opener during cell opening was determined. And mechanical properties as a function of cell opener concentration were studied. It was observed that urea formation reaction was delayed due to high hydrophilicity of cell opener The decrease of viscosity and the increase of tan $\delta$ were confirmed with increasing cell opener concentration so that the resulted foam had low structural stability and high open cell content. The deterioration of matrix and uniform dispersion of hydrogen-bonded urea in matrix with cell opener concentration was revealed by SEM analysis. As a result, elastic properties of the foam matrix were decreased due to high hydrophilicity of cell opener during the preparation of high resilience polyurethane foam and foam with high open cell content resulted. Hardness, tensile strength, tear strength, elongation of foam were decreased with increasing cell opener concentration.

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Stability and vibration behavior of cellular plates with different cell arrays using a numerical approach

  • Chuan-Xiong Li
    • Structural Engineering and Mechanics
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    • v.85 no.6
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    • pp.709-716
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    • 2023
  • In this paper, the shape factors of cellular meta-material plates (MMPs) having diverse cell arrays have been determined as the first attempt to finally examine their stability and vibrational frequencies. The MMPs are actually constructed from cylindrical or cubic cellular cores and two face sheets. Sandwich-like MMPs with circular and square holes in the face sheets have been selected in such a way that the effective material properties depend on the cellular architectures. For verifying the frequency results, finite element (FE) simulations are done in Abaqus software. Several graphical results have been represented to explore the effects of cellular architectures on vibrational frequencies and dynamic responses of the MMPs. Also, the deflection-frequency and stability curves in the case of forced vibrations have been plotted for diverse cell arrays.

Hydrocarbon Composite Membranes with Improved Oxidative Stability for PEMFC (산화안정성 향상을 위한 고분자연료전지용 탄화수소복합막의 제조 및 특성연구)

  • Lee, Hyejin;Choi, Young-Woo;Yang, Tae-Hyun;Bae, Byungchan
    • Journal of the Korean Electrochemical Society
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    • v.17 no.1
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    • pp.44-48
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    • 2014
  • Sulfonated poly(arylene ether sulfone)-cerium composite membranes with improved oxidative stability were prepared for proton exchange membrane fuel cell application. Oxidative stability of the composite membranes changed depending on the amount of incorporated metal. Their water uptake, IEC and proton conductivity were also affected. ICP analysis confirmed trace of cerium ion in the composite membranes and $^1H$-NMR indicated successful coordination of sulfonic acid groups with the metal ions. Increasing amount of the cerium ion resulted in decrease in proton conductivities and water uptake, but enhanced oxidative stabilities. A hydrogen peroxide exposure equipment was used for the test of oxidative stability of the composite membranes, which enabled to mimic fuel cell operating condition compared with conventional Fenton's test.

SENP2 Regulates Hepatocellular Carcinoma Cell Growth by Modulating the Stability of β-catenin

  • Shen, Huo-Jian;Zhu, Hong-Yi;Yang, Chao;Ji, Fu
    • Asian Pacific Journal of Cancer Prevention
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    • v.13 no.8
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    • pp.3583-3587
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    • 2012
  • SUMOylation has emerged as an important post-translational modification that modulates the localization, stability and activity of a broad spectrum of proteins. A dynamic process, it can be reversed by a family of SUMO-specific proteases (SENPs). However, the biological roles of SENPs in mammalian development and pathogenesis remain largely elusive. Here, we demonstrated that SENP2 plays a critical role in the control of hepatocellular carcinoma cell growth. SENP2 was found to be down-regulated in hepatocellular carcinoma (HCC) tissues and over-expression suppressed the growth and colony formation of HCC cells. In contrast, silencing of SENP2 by siRNAs promoted cancer cell growth. We further found that stability of ${\beta}$-catenin was markedly decreased when SENP2 was over-expressed. Interestingly, the decrease was dependent on the de-SUMOylation activity of SENP2, because over-expression of a SENP2 catalytic mutant form had no obviously effects on ${\beta}$-catenin. Our results suggest that SENP2 might play a role in hepatocellular carcinoma cell growth control by modulating the stability of ${\beta}$-catenin.

The Effect of sGO Content in sPEEK/sGO Composite Membrane for Unitized Regenerative Fuel Cell (일체형 재생연료전지 적용을 위한 sGO 함량 변화에 따른 sGO/sPEEK 복합막의 특성 평가)

  • Jung, Ho-Young;Kim, Min-Woo;Lim, Ji-Hun;Choi, Jin H.;Roh, Sung-Hee
    • KEPCO Journal on Electric Power and Energy
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    • v.2 no.1
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    • pp.127-131
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    • 2016
  • Polymer electrolyte membrane for unitized regenerative fuel cells requires high proton conductivity, high dimensional stability, low permeability, and low cost. However, DuPont's Nafion which is a commercial polymer electrolyte membrane has high permeability, high cost, and decreasing proton conductivity and dimensional stability over $80^{\circ}C$. To address these problems, sulfonated poly ether ether ketone (sPEEK) which is a low cost hydrocarbon polymer is selected as matrix polymer for the preparation of polymer electrolyte membrane. In addition, composite membrane with improved proton conductivity and dimensional stability is prepared by introducing sulfonated graphene oxide (sGO). The fundamental properties of polymer electrolyte membranes are analyzed by investigating membrane's water content, dimensional stability, proton conductivity, and morphology. The cell test is conducted to consider the possibility of application of sPEEK/sGO composite membrane for an unitized regenerative fuel cell.

Efficiency Improvement Research in Proton Exchange Membrane Fuel Cell (고분자전해질형 연료전지의 효율향상에 대한 연구)

  • Jang, Haer-Yong;Kim, Jun-Bom
    • Journal of the Korean Electrochemical Society
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    • v.8 no.4
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    • pp.149-154
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    • 2005
  • Fuel cell performance evaluation logic was developed using G-language (LabVIEW) to measure performance stability. Degree of stability and reliability of performance data were improved with averaged value and standard deviation method. Water injection system was introduced and the performance using this method was comparable to that of conventional humidification method. Water injection system has advantage of lowering operation energy consumption, reducing the number of parts needed in humidification, therefore increasing efficiency of fuel cell system. Fuel cell performance was decreased in case of low temperature operation such as sub freezing condition. Air purge method was tested to reduce the water content in cell fixture before sub freezing condition. The performance degradation due to low temperature operation was minimized by air purge method in medium size cell fixture ($25cm^2$) case.