• Title/Summary/Keyword: cell cycling

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Influence of Loading on the Corrosion of Reinforcing Bar (철근콘크리트 보의 철근부식에 미치는 하중의 영향에 관한 연구)

  • 김형래;윤상천;지남용
    • Journal of the Korea Concrete Institute
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    • v.11 no.3
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    • pp.171-179
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    • 1999
  • The present research investigated the interaction among loading level, corrosion rate and flexural deflection of reinforced concrete beams. 10cm$\times$15cm$\times$110cm reinforced concrete beams were prepared and subjected to different levels of flexural loading, including 0%, 45% and 75% of the ultimate load. The beams with either a pre-load or a sustained load were also exposed to a laboratory environment with ponding and wetting/drying cycling at room temperature. Half cell potential and galvanized current measurements were taken to monitor corrosion process of reinforcing steel. After corrosion initiation, external current was applied to some of the beams to accelerate corrosion propagation. The beam deflections were recorded during the entire tests. The results indicate that loading level has significant effect on corrosion rate. The beams under a sustained load had much higher corrosion rate than the pre-loaded and then unloaded beams. Significant corrosion may result in an increase in beam deflection and affect serviceability of the structure. The present research may provide an insight into structural condition evaluation and service life predictions of reinforced concrete.

The analysis of growth and electrical characteristics of micro-crack with thermal effect in PV module (PV 모듈에서 온도 영향에 의한 micro-crack 성장과 전기적 특성 분석)

  • Song, Young-Hun;Kang, Gi-Hwan;Yu, Gwon-Jong;Ahn, Hyung-Gun;Han, Deuk-Young
    • Proceedings of the KIEE Conference
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    • 2011.07a
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    • pp.1318-1319
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    • 2011
  • In this paper, we analyzed of growth and electrical characteristics of micro-cracks with thermal effect in PV module. The micro-cracks are increasing the breakage risk over the whole value chine from the wafer to the finished module, because the wafer or cell is exposed to mechanical stress. we experimentally analyze the direct impact of micro-cracks on the module power and the consequences after artificial aging. The first step, we made micro-cracks in PV module by mechanical load test according to IEC 61215. Next, PV modules applied the thermal cycling test, because microcracks accelerated aging by thermal cycling test. according to IEC61215. Before every test, we checked output and EL image of PV module.

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Cobalt Oxide Nanorods Prepared by a Template-Free Method for Lithium Battery Application

  • Kim, Seong-Jun;Kim, Eun-Ji;Liu, Meilin;Shin, Heon-Cheol
    • Journal of Electrochemical Science and Technology
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    • v.7 no.3
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    • pp.206-213
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    • 2016
  • Transition metal oxide-based electrodes for lithium ion batteries have recently attracted much attention because of their high theoretical capacity. Here we report the electrochemical behavior of cobalt oxide nanorods as anodes, prepared by a template-free, one-step electrochemical deposition of cobalt nanorods, followed by an oxidation process. The as-deposited cobalt has a slightly convex columnar structure, and controlled thermal oxidation produces cobalt oxides of different Co/O ratios, while the original shape is largely preserved. As an anode in a rechargeable lithium battery, the Co/O ratio has a strong effect on initial capacity and cycling stability. In particular, the one-dimensional Co@CoxOy core shell structure obtained from a mild heat-treatment results in superior cycling stability.

Electrical Degradation of Stator Bars for Large Turbine Generator after 1000 Thermal Cycles (대형 터빈 발전기용 고정자 권선의 1000 thermal cycle 후 전기적 특성 변화)

  • Kang, Myung-Guk;Kim, Tae-Hee;Lee, Jai-Kwun
    • Proceedings of the KIEE Conference
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    • 2007.07a
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    • pp.975-976
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    • 2007
  • Thermal and mechanical stresses, caused by repetitive start and stop and load fluctuation during long time operation, on winding stator bars are one of the main causes for electrical degradation of insulating materials. To understand the degradation process, we manufactured bar specimens with the same processes that make generator winding stator bars and the specimens were subjected to various degrees of thermal cycling. Measurements of the insulation properties, such as dissipation factor, tip-up and partial discharge, for un-aged specimens and for specimens aged by thermal cycling at 50, 100, 250, 500 and 1000 thermal cycles were performed. Finally all specimens were tested to obtain electrical breakdown voltages. In this paper we present the data and electrical degradation analysis results obtained during this program.

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Electrochemical Signal Amplification by Redox Cycling in Distance-Controlled Nanogap Devices

  • Park, Dae Keun;Park, Jong Mo;Shin, Jong-Hwan;Yun, Wan Soo
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.08a
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    • pp.269-269
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    • 2013
  • Redox cycling in between the two working electrodes in an electrochemical cell can lead a great signal enhancement. In this work, we report on a systematic examination of current amplification along with the decrease in the gap distance of a nanogap device which was fabricated by the combination of photo and chemical lithography [1]. The gap distance was controlled by the chemical lithographic process of surfacecatalyzed growth of metallic layer on pre-defined electrodes with wider initial gap. Enhancement of the redox current of ferri/ferrocyanide was observed upon gap distance reduction and the current is amplified about a thousand times in this redox system when the gap distance was decreased from 200 nm to 30 nm. The experimental results were discussed on the basis of the cyclic voltammetry (CV), atomic force microscopy (AFM) and scanning electron microscopy (SEM).

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Effects of Various Quinones (Menadione, Benzoquinone and 2,3-Dimethoxy-1,4-naphthoquinone) on Rat Platelets (Quinones (menadione, benzoquinone, 및 2,3-dimethoxy-1,4-naphthoquinone)의 혈소판 세포독성)

  • 승상애;이무열;이주영;김미정;정진호
    • Toxicological Research
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    • v.12 no.2
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    • pp.289-293
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    • 1996
  • Our previous studies demonstrated that quinone (menadione) is cytotoxic to rat platelets. In an attempt to assess the relative contributions of redox cycling and/or arylation in quinone-induced cytotoxicity, we have studied three quinones with different mechanisms: 2, 3-dimethoxy-1, 4-naphthoquinone (DMNQ; pure redox cycler), menadione (both redox cycler and arylator), and 1, 4-benzoquinone (pure arylator). The order of redox cycling capacity in platelet rich plasma (PRP) isolated from rats was menadione>DMNQ>1, 4-benzoquonone, which was consistent with the previous studies using isolated hepatocytes. 1, 4-Benzoquinone was more toxic to rat platelets than menadione, while DMNQ did not cause cell death at all. Lactate dehydrogenase inhibition studies revealed that 1, 4-benzoquinone inhibited significantly in a time-dependent manner, while menadione and DMNQ did not at all. These results suggested that arylation by quinone compounds might play a critical role in quinone-induced cytotoxicity in rat platelets.

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Improved Surface Plasmon Resonance Sensing Sensitivity due to an Electrochemically Potential-Induced Gold Reconstruction

  • Choi, Baeck B.;Kim, Bethy;Chen, Yiqi;Jiang, Peng
    • Journal of Electrochemical Science and Technology
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    • v.12 no.2
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    • pp.167-172
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    • 2021
  • he progressively improved sensing sensitivity (∆λSPR/∆n, nm/RIU) to detect the refractive index is observed on the SPR platform of an Au-covered epoxy gratings in an increase in potential cycling in a typical three-electrode cell. Here, a DVD-R optical disc was used as a structure template to prepare an Au-covered epoxy gratings, and the newly formed reverse track pitch structure on the epoxy substrate was used as a working electrode directly in aqueous sulfuric acid solution. It is expected that Au reconstruction by potential cycling in sulfuric acid electrolyte increases the packing density of Au atoms in the grain boundary and improves the propagation of electromagnetic waves.

Charge/discharge Properties of $V_{6}O_{13}$ Composite/Li Cell with Solid Polymer Electrolyte (고체 고분자 전해질을 사용한 $V_{6}O_{13}$ Composite/Li Cell의 충방전 특성)

  • Kim, J.U.;Yu, Y.H.;Jeong, I.S.;Park, B.K.;Gu, H.B.;Moon, S.I.
    • Proceedings of the KIEE Conference
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    • 1996.07c
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    • pp.1414-1417
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    • 1996
  • The purpose of this study Is to research and develop $V_{6}O_{13}$ composite cathode for lithium thin film battery. $V_{6}O_{13}$ represents a class of cathode active material used in Li rechargeable batteries. In this study, we investigated cyclic voltammetry and charge/discharge characteristics of $V_6O_{13}$/SPE/Li cells. Cyclic voltammogram of $V_{6}O_{13}$/SPE/Li cell at scan rate 1mV/sec showed reduction peaks of 2.25V and 2.4V and oxidation peaks of 2.4V and 2.2V. The discharge curve of $V_{6}O_{13}$/SPE/Li cell showed 4 potential plateaus. The discharge capacity was decreased in the beginning of charge/discharge cycling. After 8th cycling, the discharge capacity was stable. The discharge capacity of 1st cycle and 15th cycle was 290mAh/g and 147mAh/g at $25^{\circ}C$, respectively.

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Electrical Properties of Supercapacitor with Polyaniline and Polythiophene (Polyaniline과 Polythiophene을 사용한 supercapaccitor의 전기적 특성)

  • 강광우;김종욱;구할본
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2000.07a
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    • pp.487-490
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    • 2000
  • The purpose of this study is to research and develop conducting polymer(CP) composite electrode for supercapacitor. Electrochemical capacitor(supercapacitor) cell of CP composite electrode with 1M LiClO$_4$PC bring out good capacitor performance below 4V. The radius of semicircle of CP composite cell with PAn composite electrode adding l5wt%SP270(PAnS15) and PT composite electrode adding 50wt%SP270 (PTS50) was absolutely small. The total resistance of supercapacitor cell mainly depended on internal resistance of the electrode. The discharge capacitance of supercapacitor cell with PTS50(+)/PAnS15(-) in 1st and 20th cycles was 38F/g and 28F/g at current density of 1mA/cm$^2$. Supercapacitor cell with PTS50(+)/PAnS15(-) showed good capacitance and stability with cycling.

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The end effector of circadian heart rate variation: the sinoatrial node pacemaker cell

  • Yaniv, Yael;Lakatta, Edward G.
    • BMB Reports
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    • v.48 no.12
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    • pp.677-684
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    • 2015
  • Cardiovascular function is regulated by the rhythmicity of circadian, infradian and ultradian clocks. Specific time scales of different cell types drive their functions: circadian gene regulation at hours scale, activation-inactivation cycles of ion channels at millisecond scales, the heart's beating rate at hundreds of millisecond scales, and low frequency autonomic signaling at cycles of tens of seconds. Heart rate and rhythm are modulated by a hierarchical clock system: autonomic signaling from the brain releases neurotransmitters from the vagus and sympathetic nerves to the heart's pacemaker cells and activate receptors on the cell. These receptors activating ultradian clock functions embedded within pacemaker cells include sarcoplasmic reticulum rhythmic spontaneous Ca2+ cycling, rhythmic ion channel current activation and inactivation, and rhythmic oscillatory mitochondria ATP production. Here we summarize the evidence that intrinsic pacemaker cell mechanisms are the end effector of the hierarchical brain-heart circadian clock system.