• Title/Summary/Keyword: cell cycles

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1-Ethyl-1-Methyl Piperidinium Bis(Trifluoromethanesulfonyl)Imide as a Co-Solvent for Li-ion Battery Electrodes (혼합 용매로서의 1-Ethyl-1-Methyl Piperidinium Bis(Trifluoromethanesulfonyl)Imide의 리튬 이차 전지용 전극별 거동)

  • Koh, Ah Reum;Kim, Ketack
    • Journal of the Korean Electrochemical Society
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    • v.17 no.2
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    • pp.103-110
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    • 2014
  • In the study, a room temperature ionic liquids as a co-solvent was used to evaluate the feasibility with various electrodes in Li-ion batteries. 1-Ethyl-1-methyl piperidinium bis(trifluoromethanesulfonyl) imide(PP12 TFSI) is an ionic liquid that melts at $85^{\circ}C$. Pure PP12 TFSI is not able to be used as an electrolyte because it is a solid salt at room temperature. PP12 TFSI is mixed with EC/DEC(1/1 vol.%) to prepare mixed solvents. The electrolyte 1.5M $LiPF_6$ in a mixed solvent having 44 wt.% PP12 TFSI is prepared to evaluated the various electrodes. The electrolytes provides good cycles life of cells with $LiNi_{0.5}Mn_{1.5}O_4(LNMO)$, $LiFePO_4(LFP)$, $Li_4Ti_5O_{12}(LTO)$ and artificial graphite. Further improvement of the cell performances can be accomplished by enhancing wettability of electrolytes to electrodes.

Effect of Lithium Bis(oxalate)borate as an Electrolyte Additive on Carbon-coated SiO Negative Electrode (탄소가 코팅된 일산화규소(SiO) 음극에서 전해질 첨가제로서 Lithium Bis(oxalato)borate의 영향)

  • Kim, Kun Woo;Lee, Jae Gil;Park, Hosang;Kim, Jongjung;Ryu, Ji Heon;Kim, Young-Ugk;Oh, Seung M.
    • Journal of the Korean Electrochemical Society
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    • v.17 no.1
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    • pp.49-56
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    • 2014
  • As an electrolyte additive, the effects of lithium bis(oxalate)borate (LiBOB) on the electrochemical properties of a carbon-coated silicon monoxide (C-coated SiO) negative electrode are investigated. The used electrolyte is 1.3M $LiPF_6$ that is dissolved in ethylene carbonate (EC), fluoroethylene carbonate (FEC), and diethyl carbonate (DEC) (5:25:70 v/v/v) with or without 0.5 wt. % LiBOB. In the LiBOB-free electrolyte, the film resistance is not so high in the initial period of cycling that lithiation is facilitated to generate the crystalline $Li_{15}Si_4$ phase. Due to repeated volume change that is caused by such a deep charge/discharge, cracks form in the active material to cause a resistance increase, which eventually leads to capacity fading. When LiBOB is added into the electrolyte, however, more resistive surface film is generated by decomposition of LiBOB in the initial period. The crystalline $Li_{15}Si_4$ phase does not form, such that the volume change and crack formation are greatly mitigated. Consequently, the C-coated SiO electrode exhibits a better cycle performance in the later cycles. At an elevated temperature ($45^{\circ}C$), wherein the effect of film resistance is less critical, the alloy ($Li_{15}Si_4$ phase) formation is comparable for the LiBOB-free and added cell to give a similar cycle performance.

Dual-mode Pseudorandom Number Generator Extension for Embedded System (임베디드 시스템에 적합한 듀얼 모드 의사 난수 생성 확장 모듈의 설계)

  • Lee, Suk-Han;Hur, Won;Lee, Yong-Surk
    • Journal of the Institute of Electronics Engineers of Korea SD
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    • v.46 no.8
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    • pp.95-101
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    • 2009
  • Random numbers are used in many sorts of applications. Some applications, like simple software simulation tests, communication protocol verifications, cryptography verification and so forth, need various levels of randomness with various process speeds. In this paper, we propose a fast pseudorandom generator module for embedded systems. The generator module is implemented in hardware which can run in two modes, one of which can generate random numbers with higher randomness but which requires six cycles, the other providing its result within one cycle but with less randomness. An ASIP (Application Specific Instruction set Processor) was designed to implement the proposed pseudorandom generator instruction sets. We designed a processor based on the MIPS architecture,, by using LISA, and have run statistical tests passing the sequence of the Diehard test suite. The HDL models of the processor were generated using CoWare's Processor Designer and synthesized into the Dong-bu 0.18um CMOS cell library using the Synopsys Design Compiler. With the proposed pseudorandom generator module, random number generation performance was 239% faster than software model, but the area increased only 2.0% of the proposed ASIP.

Time-synchronized measurement and cyclic analysis of ultrasound imaging from blood with blood pressure in the mock pulsatile blood circulation system (박동 혈액 순환 모의 시스템에서 시간 동기화된 혈압 및 혈액의 초음파 영상 측정 및 주기적 분석)

  • Min, Soohong;Jin, Changzhu;Paeng, Dong-Guk
    • The Journal of the Acoustical Society of Korea
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    • v.36 no.5
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    • pp.361-369
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    • 2017
  • Hemodynamic information in the carotid artery bifurcation is very important for understanding the development and progression mechanisms of cerebrovascular disease and for its early diagnosis and prediction of the progress. In this paper, we constructed a mock pulsatile blood circulation system using an anthropomorphic elastic vessel of the carotid artery bifurcation and ex vivo pig blood to acquire ultrasound images from blood and vessels synchronized with internal pressure while controlling the blood flow. Echogenicity, blood flow velocity, and blood vessel wall motion from the ultrasound images, and internal blood pressure were extracted over a cycle averaged from five cycles when the pulsatile pump rates are 20 r/min, 40 r/min, and 60 r/min. As a result, respectively, the peak systolic blood flow velocities were 20 cm/s, 25 cm/s, and 40 cm/s, the blood pressure differences were 30 mmHg, 70 mmHg, and 85 mmHg, the arterial walls were expanded to 0.05 mm, 0.15 mm, and 0.25 mm. Time-delayed cyclic variation of echogenicity compared to blood flow and pressure was observed, but the variation was minimal at 20 r/min. Time-synchronized cyclic variations of these parameters are important information for accurate input parameters and validation of the computational hemodynamic experiments which will provide useful information for the development and progress mechanisms of carotid artery stenosis.

A small-area implementation of public-key cryptographic processor for 224-bit elliptic curves over prime field (224-비트 소수체 타원곡선을 지원하는 공개키 암호 프로세서의 저면적 구현)

  • Park, Byung-Gwan;Shin, Kyung-Wook
    • Journal of the Korea Institute of Information and Communication Engineering
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    • v.21 no.6
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    • pp.1083-1091
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    • 2017
  • This paper describes a design of cryptographic processor supporting 224-bit elliptic curves over prime field defined by NIST. Scalar point multiplication that is a core arithmetic function in elliptic curve cryptography(ECC) was implemented by adopting the modified Montgomery ladder algorithm. In order to eliminate division operations that have high computational complexity, projective coordinate was used to implement point addition and point doubling operations, which uses addition, subtraction, multiplication and squaring operations over GF(p). The final result of the scalar point multiplication is converted to affine coordinate and the inverse operation is implemented using Fermat's little theorem. The ECC processor was verified by FPGA implementation using Virtex5 device. The ECC processor synthesized using a 0.18 um CMOS cell library occupies 2.7-Kbit RAM and 27,739 gate equivalents (GEs), and the estimated maximum clock frequency is 71 MHz. One scalar point multiplication takes 1,326,985 clock cycles resulting in the computation time of 18.7 msec at the maximum clock frequency.

N-glycoproteomic analysis of human follicular fluid during natural and stimulated cycles in patients undergoing in vitro fertilization

  • Lim, Hee-Joung;Seok, Ae Eun;Han, Jiyou;Lee, Jiyeong;Lee, Sungeun;Kang, Hee-Gyoo;Cha, Byung Heun;Yang, Yunseok
    • Clinical and Experimental Reproductive Medicine
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    • v.44 no.2
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    • pp.63-72
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    • 2017
  • Objective: Hyperstimulation methods are broadly used for in vitro fertilization (IVF) in patients with infertility; however, the side effects associated with these therapies, such as ovarian hyperstimulation syndrome (OHSS), have not been well studied. N-glycoproteomes are subproteomes used for the remote sensing of ovarian stimulation in follicular growth. Glycoproteomic variation in human follicular fluid (hFF) has not been evaluated. In this study, we aimed to identify and quantify the glycoproteomes and N-glycoproteins (N-GPs) in natural and stimulated hFF using label-free nano-liquid chromatography/electrospray ionization-quad time-of-flight mass spectrometry. Methods: For profiling of the total proteome and glycoproteome, pooled protein samples from natural and stimulated hFF samples were selectively isolated using hydrazide chemistry to obtain the total proteomes and glycoproteomes. N-GPs were validated by the consensus sequence N-X-S/T (92.2% specificity for the N-glycomotif at p<0.05). All data were compared between natural versus hyperstimulated hFF samples. Results: We detected 41 and 44 N-GPs in the natural and stimulated hFF samples, respectively. Importantly, we identified 11 N-GPs with greater than two-fold upregulation in stimulated hFF samples compared to natural hFF samples. We also validated the novel N-GPs thyroxine-binding globulin, vitamin D-binding protein, and complement proteins C3 and C9. Conclusion: We identified and classified N-GPs in hFF to improve our understanding of follicular physiology in patients requiring assisted reproduction. Our results provided important insights into the prevention of hyperstimulation side effects, such as OHSS.

Analysis of receptor like kinase (RLK) gene to stress in rice (Oryza sativa L.) using real-time PCR (Real-time PCR을 이용한 스트레스에 따른 벼의 Receptor like kinase (RLK) 유전자의 발현 변화 분석)

  • Kang, Min-Hee;Kim, Il-Wook;Han, Sang-Hoon;Yun, Choong-Hyo;Yoon, Byoung-Su
    • Journal of Plant Biotechnology
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    • v.35 no.4
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    • pp.281-290
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    • 2008
  • In plant, Receptor-like kinases (RLKs) are protein family, though its function is not yet understood, consisted of a predicted signal sequence, single transmembrane region, and cytoplasmic kinase domain. RLKs are involved in hormonal response pathways, cell differentiation, plant growth and development, self-incompatibility, and symbiont and pathogen recognition. In this study, expression levels of RLG1, RLG5, RLG6, RLG#6, RLG8, RLG10, RLG17, RLG18 and RLG20 were analyzed by Real-time PCR, when rice (Oryzae sativa) was treated abiotic stress. The expression levels of all RLGs were compared each other by analyzed value of threshold cycles ($C_T$). Consequently, RLGs were suppressed by NaCl as salinity stress, and expression of each RLK genes were showed difference treated salicylic acid and wound, respectively. However, All RLGs were induced under low temperature condition. Therefore, our results indicate protection-function of RLK genes to be an early response of rice against cold weather.

Characteristics of Li-ion battery using polymeric gel electrolytes reinforced with glass fiber cloth (유리섬유 cloth가 보강된 겔상의 고분자 필름을 전해질로 이용한 리튬이온 전지의 특성)

  • Park Ho Cheol;Kim Sang Hern;Chun Jong Han;Ko Jang Myoun;Jo Soo Ik;Sohn Hun-Joon
    • Journal of the Korean Electrochemical Society
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    • v.3 no.2
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    • pp.100-103
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    • 2000
  • Polymeric gel electrolytes based on polyacrylronitile blended with poly(vinylidene fluoride-co-hexafluoro-propylene)(P(VdF-co-HFP), which were reinforced with glass fiber cloth(GFC) to increase the mechanical strength, were prepared for the practical use in secondary battery. Test cell consisting of $LiCoO_2$ as a cathode and mesophase pich-based ca.bon fiber (MCF) as an anode material showed a capacity of 110 mAh/g based on the cathode weight at 0.2C rate at room temperature. Over $80\%$ of initial capacity was retained after 400cycles, indicating that GFC is suitable for a reinforcing material to increase the mechanical strength of gel based electrolytes.

High Voltage Performance of the Electrical Double Layer Capacitor with Various Electrolytes (다양한 전해액을 적용한 전기이중층 커패시터의 고전압 특성 연구)

  • Kim, Jung Wook;Choi, Seung-Hyun;Kim, Jeom-Soo
    • Journal of the Korean Electrochemical Society
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    • v.20 no.2
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    • pp.34-40
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    • 2017
  • Electric double layer capacitors (EDLC: electric double layer capacitors) have drew attention as an energy storage device for the next generation because of their outstanding power capability and durability. But their usage is somewhat limited due to low energy density over secondary batteries. One of methods to improve the energy of EDLC is expanding the voltage window of cell operation by increasing the charge cut-off voltage. In this study, $SBP-BF_4$ (spirobipyrrolidinium tetrafluoroborate), $TEA-BF_4$ (tetraethylammonium tetraflouroborate) and $EMI-BF_4$ (1-ethyl-3-methylimidazolium tetrafluoroborate) in AN (acetonitrile) were selected to evaluate the possibility of application at high voltage environment. The LSV (linear sweep voltammetry) measurements showed that the 1.5M SBP-BF4/AN electrolyte was stable over a wide potential window and showed the best electrochemical performance compared to other combinations of electrolytes at high voltage environments (over 3.0 V). Furthermore, TMSP (tris(trimethylsilyl) phosphite) was applied to 1.5M SBP-BF4/AN in order to maintain stable performance at high voltage for the long period of time. The electrolyte with TMSP additive showed the capacity retention of 93% after 10,000 cycles at 3.3 V.

Study on the Reproductive Function in Transgenic Pig Harboring Human Erythropoietin (hEPO) Gene

  • Lee, Hyun-Gi;Lee, Hwi-Cheul;Chung, Hak-Jae;Hwang, In-Sul;Choi, Myoung-Seob;Byun, Sung-June;Lee, Seung-Hoon;Kim, Min-Ji;Woo, Jae-Seok;Chang, Won-Kyong;Lee, Poong-Yeon;Lee, Hoon-Taek;Park, Jin-Ki
    • Reproductive and Developmental Biology
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    • v.32 no.2
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    • pp.117-121
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    • 2008
  • Our previous study showed that transgenic (TG) pigs harboring human EPO (hEPO) gene have been shown to have reproductive disorders, including low pregnancy rates, irregular estrus cycle and low little size. To investigate these reasons, we assessed estrus behavior (standing response) and plasma $17{\beta}$-estradiol ($E_2$) level, which partly reflect reproductive function, during the estrus cycles after synchronization and superovulation by hormone treatments. Then, we analysed blood composition and expression of hEPO gene in TG pigs. Pigs were injected with PG600. After 10 days, pigs were fed with Regumate porcine for 6 days. Blood samples were collected from jugular vein. Analysis of blood composition and $E_2$ level were measured by Hemavet 950 and $E_2$ ELISA kit, respectively. And, the expression of hEPO gene in reproductive organs was quantitated by real-time RT-PCR. The percentage of estrus behavior in TG was significantly decreased. Hematocrit (HCT), hemoglobin (Hb) concentration and red blood cell (RBC) number were significantly higher in TG than wild type (WT). On the other hand, high expression of hEPO gene in TG was observed in the mammary gland as well as in the uterus. Moreover, plasma $E_2$ level was significantly higher in TG than WT. These results suggest that nonspecific expression of hEPO gene in the other organs of TG may affect blood composition and plasma $E_2$ level, thereby causing reproductive disorders.