• Mass Spectrometry Letters
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• v.8 no.1
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• pp.14-17
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• 2017

The effect of cationization agent concentration on glycan detection via matrix-assisted laser desorption/ionization time-of-flight mass spectrometry (MALDI-TOF MS) was investigated using $Na^+$ ions in the form of NaCl as the cationization agent. NaCl solution concentrations ranging from 1 mM to 1 M were investigated. Glycans from ovalbumin were mixed with the cationization agent solution and the 2,5-dihydroxybenzoic acid (2,5-DHB) matrix solution in a volume ratio of 1:1:1. The resulting mixture was loaded onto the MALDI plate. Two MALDI-TOF MS instruments (Voyager DE-STR MALDI-TOF MS and Tinkerbell RT MALDI-TOF MS) were used for detection of glycans. The best detection, in terms of the number of identified glycans, the peak intensity, and the signal-to-noise (S/N) ratio, was obtained with NaCl concentrations of 0.01-0.1 M for both MALDI-TOF MS instruments.

• Mass Spectrometry Letters
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• v.7 no.4
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• pp.96-101
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• 2016

To determine the influence of the cationization agent on the collision activated dissociation (CAD) fragmentation behavior of oligosaccharides, the CAD spectra of the singly protonated, sodiated oligosaccharides and singly sodiated and dibenzo-18-crown-6 ether conjugated oligosaccharides were carefully compared. Each of these three different species showed quite different fragmentation spectra. The comparison of singly protonated and sodiated oligosaccharide CAD spectra revealed that different cationization agents affected the cationization agent adduction sites as well as the fragmentation sites within the oligosaccharides. When the mobility of $Na^+$ was limited by the dibenzo-18-crown-6 ether encapsulation agent, the examined linear oligosaccharides showed fragmentation patterns quite different from the unmodified ones. For the dibenzo-18-crown-6 ether conjugated oligosaccharides, the charge-remote fragmentation pathways were more likely to be activated than the chargedirected pathways. This work demonstrates that dibenzo-18-crown-6 ether conjugation can potentially provide a route to selectively activate the charge-remote fragmentation pathways, albeit to a limited extent, in tandem mass spectrometry studies.

• Fashion & Textile Research Journal
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• v.24 no.2
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• pp.260-266
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• 2022

Cellulose fiber is a material used in various fields. It is the most used type of fiber because of its excellent hygroscopicity and dyeability. Recently, as natural fiber materials have been highlighted due to the influence of eco-friendliness and well-being, bamboo fiber has become a commonly used eco-friendly fiber. Cellulose fibers are part of the -OH hydroxyl group, which means they are more chemically reactive than synthetic fibers. In this study, the cationization properties of bamboo-cotton blended fabrics cationized using CHPTAC (3-chloro-2-hydroxypropyl trimethyl ammonium chloride) in the PDC (padding-drying-curing) method were investigated. Various characteristics according to cationization were studied through elemental analysis, FT-IR (fourier-transform infrared spectroscopy) analysis, X-ray diffraction analysis, TGA (thermogravimetric) analysis, and SEM (scanning electron microscope) analysis. The nitrogen content of the cationized bamboo-cotton blended fabric increased with an increase in the concentration of the cationizing agent CHPTAC, and it was seen to be highly bound to cellulose molecules. As a result of the FT-IR analysis, both 100% pure cotton fabrics and CHPTAC-0 and CHPTAC-150 fabrics were seen to be typical cellulose. As a result of the X-ray diffraction analysis, both 100% pure cotton fabrics and CHPTAC-0 and CHPTAC-150 fabrics showed typical cellulose I structures. As a result of the X-ray diffraction analysis, both 100% pure cotton fabrics and CHPTAC-0 and CHPTAC-150 fabrics showed typical cellulose I structures. As the cationization progressed, micropores appeared on the surface of the blended fabric.

• Textile Coloration and Finishing
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• v.14 no.1
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• pp.18-26
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• 2002

Chitosan has reactive amino and hydroxyl groups which can be used to chemically alter its properties under the mild reaction conditions. Thus the cationization of Tencel with Chitosan is effective to modify the fabric. To investigate the modified properties of Tencel fabric, the tests were performed under the several finishing process with enzyme/glutaraldehyde/softener. The internal structure of Tencel which has the structure of cellulose II wasn't changed by enzyme, chitosan and crosslinking agent treatment and the thermal stability was improved by chitosan and crosslinking agent treatment. Wrinkle recovery angle under the dry condition increased highly until $0.1\textrm{mol}/\ell$ of glutaraldehyde concentration, and then decreased. Tensile strength of modified Tencel fabric decreased with increasing of weight loss, but it was improved more or less by chitosan, crosslinking agent and softener. Moisture regain was improved by enzyme and chitosan treatment. And antibacterial activity showed nearly 100% on Tencel fabric treated with 0.5% chitosan and adsorption of metal ion increased with increasing of chitosan concentration.

• Journal of the Korean Society of Clothing and Textiles
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• v.29 no.7 s.144
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• pp.987-996
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• 2005

For cationization, if chitosan, which has the affinity for a human body and reacts easily without inducing any pollution, is used, cationization of Tencel blended fabrics can be expected and further expansion of its use as a new susceptible material can be expected. Therefore, in this study, in order to compare a Tencel/cotton and a Tencel/Cotton/PET as Tencel blended fabrics with a Tencel single fabric, the fabric samples were used and processed with chitosan after NaOH pretreatment and enzyme treatment thereof, and then its adherent efficiency was enhanced by using a crosslinking agent, and then it was got to be finished with a softener. The fibril of Tencel fabric was controlled by enzyme treatment so that the surface of the Tencel blended fabrics got to be smooth. Chitosan adhered to the surface of the Tencel blended fabrics in the form of particles through its processing with chitosan. Chitosan treatment caused little change in the crystal structure thereof and the thermal stability of the Tencel/Cotton/PET fabric was slightly improved. The total hand value(THV) calculated on the basis of the change due to chitosan treatment was increased in all samples.

• Journal of the Korean Society of Clothing and Textiles
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• v.36 no.12
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• pp.1310-1317
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• 2012

This study examines the possibilities to improve natural dyestuff's (Pinux$^{TM}$) dyeability and colorfastness for C/R (Cotton/Rayon (40/60)) and W/T (Wool/Tencel (10/90)) knitted fabrics in cationizing and smectiting for pre-treatment, simultaneous-treatment and post-treatment process sequences; as well as various other treatment methods. The sample dyeability showed the strongest K/S value in the order of smectite (S) < cationization + smectite (C+S) < cationization (C); however, the K/S value showed a low level in the simultaneoustreatment method of smectite. Colorfastness to washing improved in the order of C < C+S < S, and after the smectite post-treatment process, C/R improved from Grade 1 to Grade 4 and W/T improved from Grade 1-2 to Grade 4. Colorfastness to perspiration generally improved in the same order as the colorfastness to washing and after the smectite post-treatment process C/R, W/T sample's acidic and alkaline colorfastness to perspiration improved greatly. As for the colorfastness to rubbing, the addition of smectite in the simultaneous-treatment and post-treatment processes resulted in improved wet-colorfastness; however, smectite showed less effect on the colorfastness to light compared to other colorfastness ratings.

• Journal of the Korean Society of Clothing and Textiles
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• v.31 no.12
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• pp.1672-1681
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• 2007

Cationization is effective to complement the defects of Tencel blended fabrics by introducing new functions. For this purpose, we used chitosan, which is congenial to the human body, free of pollution, and easily reacted. Then, we compared it to the Tencel single fabrics. To perform such effective cationization, the fabrics were treated with chitosan after NaOH pretreatment and enzyme treatment thereof. After that, the fabrics were treated with a crosslinking agent and a softner. The dyeing property of the cationized Tencel blended fabrics and reactive dye, which is a type of anionic dye, show a high concentration in neutral salt and excellent repulsive power between the fabrics and the decreased dyes. The dyeing property of the chitosan treated fabrics represented better performances than that of untreated fabric in the lower concentration of neutral salt. Meanwhile, when it was dyed with certain acid dyes, the dyeing property of the chitosan treated fabrics showed better results due to the reaction of an amine group, which was introduced by chitosan treatment. Thus, the verification of the cationization of the Tencel blended fabrics was performed. The washing fastness of the Tencel blended fabrics showed a little bit better than that of the Tencel single fabric, and it represented a better performance in the dye with a reactive dye than that of an acid dye.

• Bulletin of the Korean Chemical Society
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• v.23 no.2
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• pp.315-319
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• 2002

Visible surface-assisted desorption/ionization mass spectrometry (SALDI-MS) has been investigated for several small macromolecules deposited on the graphite plate using laser radiation at 532 nm where most of the macromolecules are transparent. The graphite surface functioned well as a photon absorbing material and an energy transfer mediator for visible light. The results show that visible SALDI is a much softer ionization technique than UV-MALDI and FAB-MS in our results with synthetic macromolecules, PPG, PPGMBE and cavitand molecules. For the SALDI of biomolecules, glycerol as a proton source was essential with the graphite plate. As in visible SALDI, the role division of the photon absorbing material and the cationization agent can provide a generality in mass spectrometric analysis of macromolecules compared with MALDI using the dual functional matrix.

• Textile Coloration and Finishing
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• v.14 no.3
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• pp.1-10
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• 2002

Tencel fabric cationized with chitosan can be effectively dyed with anionic dyes. To investigate the change of dyeing properties of cationized Tencel fabric, some experiments were performed under the several dyeing conditions with acid and reactive dyes. Whiteness index decreased with the increment of crosslinking agent concentration. The cationized Tencel fabric was dyed well by anionic dye such as acid dye, the dyeability of reactive dye was improved by addition of a little salt without alkali. The dye fixation on the cationized Tencel fabric was increased with chitosan concentration without electrolyte and alkali. The dyeability of Tencel treated with chitosan was better than controlled Tencel, especially under the acidic conditions. According to the number and the types of functional group of reactive dyes, dye affinity of the modified Tencel fabric varied and wash fastness of acid dye was better than reactive dye.

• Textile Coloration and Finishing
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• v.14 no.2
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• pp.77-77
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• 2002

Cotton fabrics dipped in cationic agent(3-chloro-2-hydroxypropyl trimethyl ammonium chloride) were irradiated with deep Ultra Violet Rays(UV), in the region of UV-C using the low pressure mercury lamp. The chemical changes of cationized cotton fabric surfaces were investigated by FT-IR analysis. The dyeabilities of the irradiated portions were investigated by dyeing with acid dyes. Deep UV(UV-C) irradiation broke O-H bonds in cotton fiber and oxidized the fibers. The dyeability of the UV irradiated portion were different from that of the portion not irradiated. Various pattern were gained from one bath dig dyeing by pattern mask. The tensile strengths of cotton fabrics were decreased in the UV irradiated portion. Washing fastness of cotton dyeings were good about 3∼4 grade and light fastness were fair about 2∼3 grade.