• Title/Summary/Keyword: cation exchange capacity

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Studies on the Heavy Metals in Paddy Rice and Soils in Jang-hang Smelter (제연소인근지역(製鍊所隣近地域)의 토양(土壤) 및 수도체중(水稻體中) 중금속함량(重金屬含量)에 관(關)한 조사연구(調査硏究))

  • Kim, Seong-Jo;Ryang, Hwan-Seung
    • Korean Journal of Soil Science and Fertilizer
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    • v.18 no.4
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    • pp.336-347
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    • 1985
  • Soils and rice plants subject to smoke from the Jang-hang Smelter were samples at two depths to assess the nature and extend of Cd, Cu, Pb, and Zn contamination, particularly with respect to distance from pollution source. Soils at east site within 1km of the center of the smelter were highly contaminated with Cd, Cu, Pb, and Zn. Metal levels in the smoke-polluted area were higher in surface soil than in subsurface soil, and decreased rapidly with distance reaching nearly background levels at 5km from pollution source. A position correlation was found between contents of total and 0.1 N HCl-extractable, or 1.0N $CH_3COONH_4$- extractable heavy metals in surface soils of pollution. Contents of heavy metals in soils were positively correlated with soil organic matter and cation exchange capacity. The contents of heavy metals in brown rice collected from the paddy field around the Jang-hang Smelter were in the range of 0.23-1.33 ppm for Cd, 2.39-6.25 for Cu, 0.95-8.32 ppm for Pb and 14.60-27.31 for Zn. The contents of Cd, Cu, and Zn in rice straw were positively correlated with those in the brown rice. Negative correlation was found between the contents of Cd, Cu, Pb, and Zn in brown rice and the distance from the source.

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The Soil Improvement and Plant Growth on the Newly-Reclaimed Sloped Land -I. Effects of Vinyl Mulching and Zeolite Application on Silage Corn (신개간경사지(新開墾傾斜地) 토양개량(土壤改良)과 작물생육(作物生育)에 관(關)한 연구(硏究) -I. 청예용(靑刈用) 옥수수에 대(對)한 비닐피복(被覆) 및 Zeolite 시용(施用) 효과(效果))

  • Hur, Bong-Koo;Jo, In-Sang;Um, Ki-Tae
    • Korean Journal of Soil Science and Fertilizer
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    • v.22 no.1
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    • pp.25-30
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    • 1989
  • A field experiment was carried out to evaluate the effects of zeolite application and vinyl mulching on the changes in soil physico-chemical properties and yield of silage corn on the newly-reclaimed sloped land. Corn (Suweon 19) was cultivated under 4 application levels of zeolite, 0, 500, 1,000 and 1,500 kg/10a, with and without vinyl mulching, and various soil physico-chemical properties and corn growth were investigated. Soil physical properties, such as cation exchange capacity and water stable aggregates, were increased, but soil hardness was decreased by zeolite application. The porosity and temperature of soil were increased greatly by vinyl mulching. The differences between daily maximum and minimum soil temperature were large in beginning stages of crop growth, but those were decreased to $2^{\circ}C$ after mid-August. Zeolite application enhanced the plant growth and increased yields by 3-37% compare to control, also vinyl mulching brought to increase the corn yields by 17-23%. Water stable aggregates was correlated with soil hardness, and silage yields were highly correlated with porosity, air phase and water stable aggregates.

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Granulation of Artificial Zeolite for the Simultaneous Removal of Nitrogen and Phosphorous from the Wastewater (질소, 인 동시 제거용 입상 인공제올라이트 제조)

  • Lee, Deog-Bae;Lee, Kyeong-Bo;Han, Sang-Soo;Henmi, Teruo
    • Korean Journal of Soil Science and Fertilizer
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    • v.31 no.1
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    • pp.67-71
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    • 1998
  • This study was carried out to granulate artificial zeolite powder that remove ammonium nitrogen and phosphorous simultaneously in wastewater treatment. Optimum water content was required for 30 percent volume to granulate artificial zeolite with 1.7mm diameter and 1~2cm length using granulator. Portland cement could remove much $NH_4{^+}$ and $PO_4{^{3-}}$ from the wastewater than other binding materials. Mixed 33, 25. 20. 16 percent of portland cement to artificial zeolite powder(v/v), cation exchange capacity of the granulars were 66.5, 81.4, 126.8, $151.2cmol^+kg^{-1}$ and hardness of that were 176.1, 24.4, 4.1, $0.4kg\;cm^{-2}$, respectively. Content of portland cement in the granular were related with removal of $PO_4{^{3-}}$ positively and that of $NH_4{^+}$ negatively. Shaked 1g of the granulars that made of portland cement 33 percent with 40ml synthetic wastewater containing $NH_4{^+}$ $1545mgl^{-1}$ and $PO_4{^{3-}}$ $417mgl^{-1}$, 99.4 percent of $NH_4{^+}$ and 90.3 percent of $PO_4{^{3-}}$ were removed simultaneously after 48 hours shaking. The longer shaking, the more $NH_4{^+}$ and $PO_4{^{3-}}$were removed. The artificial zeolite granular had both micropore and macropore that could be useful in the wastewater purification.

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Effects of Rice Straw Incorporation by Cutting Methods on Soil Properties and Rice Yield in a Paddy Field (볏짚 혼입이 논 토양개선 및 쌀수량에 미치는 영향)

  • Yang, Chang-Hyu;Kim, Taek-Kyum;Ryu, Jin-Hee;Lee, Sang-Bog;Kim, Sun;Baek, Nam-Hyun;Choi, Weon-Young;Chung, Doug-Young;Kim, Si-Ju
    • Korean Journal of Soil Science and Fertilizer
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    • v.43 no.6
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    • pp.1047-1050
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    • 2010
  • This study was to investigate the effects of rice straw incorporation by cutting height on paddy soil fertility. The average residual amount of rice straw by cutting height were showed 1,420 kg $ha^{-1}$, 1,850 kg $ha^{-1}$, and 2,400 kg $ha^{-1}$ for depths of 10 cm, 15 cm, and 20 cm, respectively. For soil physical properties, soil hardness and bulk density were decreased while porosity was increased by rice straw incorporation. But soil organic matter (SOM), available silicate content, and cation exchange capacity (CEC) were significantly decreased when rice straw was removed from the field. These results indicated that the SOM as residual amount of rice straw was influenced by level of cutting height. Milled rice yield was increased by 28% and 32% for cutting heights of 15 cm and 20 cm, compared with that of control, respectively. The number of spikelets per square meter and the percentage of ripeness were increased with increasing incorporation by lower level of cutting height of rice straw. Therefore, incorporation of rice straw practices under cutting method influenced soil improvement and rice yield in paddy field.

Effects of zinc-bearing palygorskite on rumen fermentation in vitro

  • Chen, Mengjiao;Xi, Yumeng;Zhang, Lin;Zeng, Hanfang;Li, Yeqing;Han, Zhaoyu
    • Asian-Australasian Journal of Animal Sciences
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    • v.32 no.1
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    • pp.63-71
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    • 2019
  • Objective: The aim of the study was to investigate the effect of zinc-bearing palygorskite (Zn-Pal) on rumen fermentation by in vitro gas-production system. Methods: In trial, 90 incubators were evenly divided into five groups: control (0% Zn-Pal), treatment I (0.2% Zn-Pal), treatment II (0.4% Zn-Pal), treatment III (0.6% Zn-Pal), and treatment IV (0.8% Zn-Pal). The contents of zinc for treatments were 0, 49, 98, 147, 196 mg/kg, respectively. The main chemical composition and microstructure of Zn-Pal was investigated by X-ray diffraction. The physicochemical features were evaluated by Zeta potential analysis, cation-exchange capacity, ethylene blue absorption and specific surface area (the Brunauer-Emmett-Teller method). In vitro gas production (GP) was recorded at 3, 6, 9, 12, 18, 24, 36, 48, 60, and 72 h incubation. Incubation was stopped at 0, 6, 12, 24, 48, and 72 h and the inoculants were tested for pH, microbial protein yield (MCP), $NH_3-N$, volatile fatty acids (VFAs), lipopolysaccharide (LPS). Results: The results showed that the GP in the treatment groups was not significantly different from the control groups (p>0.05). Compared to the control group, pH was higher at 24 h, 48 h (p<0.05), and 72 h (p<0.01) (range 6 to 7). The concentration of $NH_3-N$ in the three treatment groups was higher than in the control group at 24 h (p<0.01), meanwhile, it was lower at 48 h and 72 h (p<0.01), except in the treatment IV. The concentration of MCP in treatment I group was higher than in the control at 48 h (p<0.01). Compared with control, the LPS concentration in treatment III became lower at 12 h (p<0.05). Total VFAs in treatments were higher than in the control at 24 h, 48 h (p<0.05). Conclusion: These results suggest that the addition of Zn-Pal can improve the rumen fermentation, especially when adding 0.2% Zn-Pal.

The Statistical Study on the Effects of Physicochemical Properties of Soil on Single Extraction Methods for Heavy Metals (토양의 물리화학적 특성이 중금속 단일용출법에 미치는 영향에 대한 통계학적 연구)

  • Han, Hyeop-Jo;Song, Chang-Woo;Lee, Jong-Un
    • Economic and Environmental Geology
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    • v.54 no.2
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    • pp.259-269
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    • 2021
  • The effects of the physicochemical properties of soil such as soil pH, cation exchange capacity, and organic matter content on single extraction of Cd, Cr, Cu, Ni, Pb, and Zn using CaCl2, HOAc, HNO3, and DTPA were statistically investigated for 69 agricultural soils in Korea. Correlation analysis and multiple regression analysis were applied for soil samples which were grouped on the basis of average values of the physicochemical properties of the soil. Diluted HNO3 extracted higher concentrations of Cr, Cu, Ni, and Pb when compared with the other extractants, however, similar amounts of Cd and Zn were extracted by HOAc with HNO3. The results of correlation analysis indicated that DTPA extraction showed a high correlation with other single and pseudo-total extraction methods, and the physicochemical properties of soil influenced the concentrations of heavy metals leached by the single extraction methods. In the case of Zn, high correlations between pseudo-total and the studied single extraction methods were observed. As a result of regression analysis, it was found that the physicochemical properties of the soil could explain up to 74% of variances of the single extraction results. These results indicate that the physicochemical properties of the soil can have a direct influence on the concentrations of heavy metals extracted by the single extraction methods.

Community Structure and Ecological Characteristics of Berchemia berchemiaefolia Stands at Mt. Naeyon (내연산 망개나무 임분의 군집구조와 생태적 특성)

  • Yong Sik, Hong;I-Seul, Yun;Dong Pil, Jin;Chan Beom, Kim;Hak Koo, Kim;Jin Woo, Lee;Shin Koo, Kang
    • Journal of Korean Society of Forest Science
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    • v.111 no.4
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    • pp.538-547
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    • 2022
  • In this study, the population and community structure of Berchemia berchemiaefolia stands located at Mt. Naeyon (Gyeongbuk, Korea) were quantified, and multivariate analysis was done to determine the correlations between vegetation group types and environmental factors and to have reference data for the conservation and restoration of this species. In total, there were 164 B. berchemiaefolia trees in Mt. Naeyon. The average DBH of the trees was 24.5 cm, forming a normal distribution. It rarely appeared in an understory vegetation height of 3 m. About37.1% of the trees were branched. B. berchemiaefolia stands were classified into two groups: B. berchemiaefolia-Quercus serrata community and B. berchemiaefolia-Carpinus laxiflora community. Canopy gap, organic matter, exchangeable Ca, and cation exchange capacity were the major site characteristics affecting the distribution pattern of the stands. Currently, B. berchemiaefolia trees dominate in Mt. Naeyon, but depending on different habitat positions, the species was in a natural successional stage to C. laxiflora or C. cordata, which is a shade-tolerant species.

Changes of Rice Yield and Soil Physicochemical Properties in Long-term Dry Seeded Rice-Barley Double Cropping (건답직파 벼-보리 장기간 이모작 재배시 벼 수량 및 토양 물리화학성 변화)

  • Shin, Sang-Ouk;Park, Sung-Tae;Hwang, Chung-Dong;Hwang, Dong-Yong;Kim, Sang-Yeol;Moon, Huhn-Pal
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.46 no.6
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    • pp.459-463
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    • 2001
  • Changes of rice yield and soil physicochemical properties of the dry-seeded rice-barley double cropping system were investigated for 10 years from 1990 to 1999. Generally, seedling stand was more unstable in the rice-barley cropping system regardless of barley straw addition or removal than in the rice single cultivation as indicated by higher standard deviation of seedling stand across year. Rice yield in rice-barley double cropping cultivation was increased due to barley straw application starting from the second year, recording 2 to 19% increase (average of 9% for 10 years) due to higher spikelet number. Protein content and Mg/K equivalent ratio were similiar among the barley straw applied field, rice single crop and barley straw removed plots. Also, amylose content was not significantly different among cropping patterns. Physicochemical properties of soil was improved by applying the barley straw; soil porosity was higher and content of organic matter and cation exchange capacity of Ca increased but those of Mg and K did not differ.

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Phenotypical Characteristics Investigation and Selection of Superior Individuals from Natural Habitats of Sageretia thea in South Korea (국내 자생 상동나무 표현형 특성조사 및 우량 개체 선발)

  • Dae Hui Jeong;Hae Yun Kwon;Young Ki Kim
    • Korean Journal of Plant Resources
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    • v.37 no.2
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    • pp.214-224
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    • 2024
  • In this study, the growth, physical characteristics of fruit and soil chemistry were investigated by grouping S. thea populations. The soil for each group was sandy loam or sandy loam, and it was analyzed to be slightly acidic to neutral, with a pH ranging from 5.6 to 7.0. Additionally, the leaf size was highest in the G7 group, and overall fruit growth was highest in the G1 group, confirming differences between the groups. The sweetness ranged from 16.8° Brix to 12.3° Brix, indicating a higher sweetness compared to Vaccinium oldhamill, blueberry, and blackberry. The correlation analysis between soil chemistry and S. thea growth characteristics revealed a significant negative correlation between calcium (Ca) and fruit growth characteristics. Furthermore, a significant positive correlation was observed between sodium (Na) and fruit acidity, as well as between cation exchange capacity (CEC) and fruit hardness.

Growth environment characteristics of the habitat of Epilobium hirsutum L., a class II endangered wildlife species

  • Kwang Jin Cho;Hyeong Cheol Lee;Sang Uk Han;Hae Seon Shin;Pyoung Beom Kim
    • Journal of Ecology and Environment
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    • v.47 no.4
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    • pp.282-289
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    • 2023
  • Background: As wildlife habitats are being destroyed and growth environments are changing, the survival of animals and plants is under threat. Epilobium hirsutum L., a species that inhabits wetlands, has held legally protected status since 2012. However, no specific measures are currently in place to protect its habitat, leading to a decline in remaining populations as a result of land use change and human activities. Results: The growth environment (including location, climate, land use, soil, and vegetation) of the five habitat sites (Samcheok, Taebaek1, Taebaek2, Cheongsong, Ulleung) of E. hirsutum L. was investigated and analyzed. These habitats were predominantly situated in flat areas with gentle south-facing slopes, at an average altitude of 452.7 m (8-726 m) above sea level in Gangwon-do and Gyeongsangbuk-do. The average annual temperature ranged 11.5℃ (9.2℃-12.9℃), whereas the average annual precipitation ranged 1,304.5 mm (1,062.7-1,590.7 mm). The surrounding land use status was mainly characterized by mountainous areas, and human interference, such as agricultural land and roads, was commonly found in proximity to these natural habitats. Soil physicochemical analysis revealed that the soil was predominantly sandy loam with a slightly high sand content. The average pH measured 7.64, indicating an alkaline environment, and electrical conductivity (EC) averaged 0.33 dS/m. Organic matter (OM) content averaged 66.44 g/kg, available phosphoric acid (P2O5) content averaged 115.73 mg/kg, and cation exchange capacity (CEC) averaged 23.43 cmolc/kg. The exchangeable cations ranged 0.09-0.43 cmol+/kg for potassium (K), 10.23-16.21 cmol+/kg for calcium (Ca), 0.67-4.94 cmol+/kg for magnesium (Mg), and 0.05-0.74 cmol+/kg for sodium (Na). The vegetation type was categorized as E. hirsutum community with high numbers of E. hirsutum L., Persicaria thunbergii (Siebold & Zucc.) H. Gross, Phragmites japonica Steud., Humulus japonicus (Siebold & Zucc.), and Bidens frondosa L.. An ecological flora analysis, including the proportion of lianas, naturalized plants, and annual herbaceous plants, revealed that the native habitat of E. hirsutum L. was ecologically unstable. Conclusions: Analysis of the habitat of E. hirsutum L., a class II endangered wildlife species, provided essential data for local conservation and restoration efforts.