• Journal of Korean Society of Forest Science
• /
• v.84 no.1
• /
• pp.103-113
• /
• 1995

To estimate buffer capacity and sensitivity of forest ecosystem to acid rain in Taejon, ionic components of throughfall, stemflow, soil leachate, and open rain in Pinus rigida and Quercus variabilis forest were analysed. The spatial sensitivity based on parent rock and forest type was given by IDRISI of GIS which created imagery conversion from soil and vegetation map. Parent rocks and soils were classified into acidic, sedimentary, metamorphic rock and then subdivided based on $SiO_2$ content. Average pH of vegetation leachate was higher in throughfall but lower in stemflow than open rain and higher in Quercus variabilis forest than in Pinus rigida forest. The flow of $SO{_4}^{2-}$, $NO_3{^-}$ and $Cl^-$ through vegetation leaching(throughfall plus stemflow) into soil were 7.2, 4.3, and 2.5 times, respectively, higher in Pinus rigida forest and 4.4, 2, and 2.5 times, respectively, higher in Quercus variabilis forest than in open field. But the concentration of exchangeable cations was 4.1 times higher in Pinus rigida forest and 4.6 times higher in Quercus variabilis forest than in open field. Average pH of soil leachate was lower than that of throughfall, but higher than that of stemflow. The concentration of exchangeable canons and $Al^{3+}$ in soil leachate were more in Pinus rigida forest than in Quercus variabilis forest and increase signficantly with the increase of acidic deposits. Pinus forest had more deposition and canopy interception of acidic pollutants and more nutrient loss than Quercus forest, and Quercus forest had more cation exchange and proton consumption and than consequently had less nutrient loss and better buffer capacity than Pinus forest. The 69% of forest soils was distributed on acidic rock, 25% of it on metamorphic rock, and 6% of it on intermediate and basic rock. Acidic rock residuals which had low very canon exchange capacity and high sensitivity to acid rain occupied a half of total forest land in Taejon area. Therefore forests in Taejon showed high vulnerability to acid rain and will receive much more stress with the increase of acid rain precursors.

• Journal of Bio-Environment Control
• /
• v.21 no.2
• /
• pp.102-107
• /
• 2012

This study was carried out to investigate the optimum soil environmental conditions of ten contents on production of high quality fruit in 'Hongro' apple. The soil and fruit characteristics were analyzed at total 60 orchards in major apple producing areas such as Chungju, Moonkyeung, Yeongju, Andong, Yeosan and Yeongcheon (10 orchards an area). The soil environmental factors affected fruit weight were the highest relative contribution in saturated hydraulic conductivity of 33.3%. The cation was 24.6%, the bulk density, soil texture and solid phase were also high as relative contribution. The fruit weight was influenced by soil physical properties more than soil chemical properties. The soil environmental factors affected sugar content were highest soil texture of 21.9%, and the CEC and bulk density were low as relative contribution. The fruit coloring was the highest relative contribution in phosphate of 55.9%. While saturated hydraulic conductivity and organic matter content were low. The coloring was influenced by soil chemical properties more than soil physical properties. Fruit coloring was high influenced over 70% by soil physical properties. Finally, relative contribution on fruit quality related with sugar content, fruit weight, and coloring were high influenced by cultivation layer depth of 25.8%, soil texture 22.2%, and soil pH of 21.0% but bulk density and solid phase were low relative contribution. The fruit growth and soil chemical properties in 'Hongro' apple were very closely related. Therefore, orchard soil management to produce high quality fruit was very importance drainage management and organic matter application. We concluded that scientific soil management is possible by quanlifiable of soil management factors.

• Journal of the Mineralogical Society of Korea
• /
• v.28 no.3
• /
• pp.255-263
• /
• 2015

To investigate the effect of the weathering process of biotite on Cs sorption, sorption experiment of Cs with $10^{-3}M$ solution was carried out on the biotite reacted at different reaction times at pH 2 and 4, and 1 M solutions of Na, K, Ca, Mg, Rb, and Cs. Peak changes were observed for some samples by XRD, indicating that new mineral phase formed by biotite weathering. Among several factors, cations in solutions have the most significant influence on the mineralogical changes. The samples reacted with Na showed the most outstanding change with increasing peak width and appearance of $12{\AA}$ peak and $14{\AA}$ peak. This new peaks indicate the formation of hydrobiotite and vermiculite. The new peaks had stronger peak intensity for the sample reacted at pH 4 than that at pH 2, probably due to the fast dissolution of small particles and edges and resultant decrease in the formation of expandable layers. The biotite reacted at Mg solution showed small intensity at $14{\AA}$. Based on XRD results, the degree of biotite weathering was in the order of Na, Mg, and Ca. The samples reacted with K, Rb, Cs solutions did not show noticeable mineralogical changes caused by weathering. The amount of sorbed Cs on weathered biotite showed close relationship with the degree of weathering indicated by XRD. At both pH 2 and 4, the biotite reacted with Na solution showed the highest Cs sorption, and those with Mg and Ca solutions showed the next highest ones. The sorbed amounts of Cs on the bitote reacted with K, Rb, Cs solutions were relatively low. This indicates that at the Cs concentration ($10^{-3}M$) which we used for this experiment and which was much higher than the maximum Cs concentration sorbed on the frayed edge site, expandable layer plays more important role than frayed edge. In the cases of K, Rb, and Cs solutions, Cs sorption was decreased because K is the same cations as the one in the interlayer or the sorption of Rb and Cs on the frayed edge prevents the formation of expandable layers.

• Journal of Korean Society of Forest Science
• /
• v.88 no.4
• /
• pp.541-554
• /
• 1999

The objectives of this study were to examine the amount of nutrient input by throughfall and stemflow, and the nutrient dynamics by throughfall, stemflow and soil solution among Piuns koraiensis, Larix leptolepis and hardwood forests including oaks at Kwangju-Gun, Kyonggi-Do. A total amount of rainfall during the study period was 1410.1mm. Of the total rainfall, 85% was from throughfall at the L. leptolepis stand, 84.5% at the thinned P. koraiensis stand, 83.2% at the unthinned P. koraiensu stand and 81.2% at the hardwood stand, showing greater throughfall at the conifer stand than at the hardwood stand. Stemflow showed 2.7% of rainfall at the hardwood stand, 1.3% at the unthinned P. koraiensis stand, 1.2% at the thinned P. koraiensis stand and 0.8% at the L. leptolepis stand, showing greater stemflow at the hardwood stand than at the conifer stand. Ion concentration of stemflow was greater than those of rainfall and throughfall. The conifer stand showed higher ion concentration than the hardwood stand both for cation and anion. The ion concentrations of throughfall and stemflow were higher in the descending order : $NH{_4}^+$-N > $K^+$ > $K^+$ > $Na^+$ > $Mg^{2+}$ for cations and $SO{_4}^{2-}$ > $NO{_3}^-$-N > $Cl^-$-N for anions. After the precipitation passed through the canopy, $K^+$ increased most at the hardwood stand, whereas $NH{_4}^+$-N did most at the P. koraiensis and L. leptolepis stands. The ion concentration of soil solution was higher in the descending order : $Ca^{2+}$ > $Mg^{2+}$ > $Na^+$ for cations and $NO{_3}^-$-N > $Cl^-$ > $SO{_4}^{2-}$ for anions. $NH{_4}^+$-N and $K^+$ seemed to be supplied primarily from atmospheric deposition while $Ca^{2+}$, $Mg^{2+}$ and $Na^+$ from weathering.

• Journal of Korean Society of Forest Science
• /
• v.88 no.4
• /
• pp.498-509
• /
• 1999

This study aims to clarify the effect of forest management practices(thinning and pruning) in forest hydrological processes on electrical conductivity to get the fundamental information on the facilitation of purifying water quality after forestry practices. Rainfall, throughfall, stemflow, soil and stream water were sampled at the study sites which consist of Abies holophylla and Pinus koraiensis in Kwangnung Experimental Forest for 6 months from March 1 to August 4, 1998. In case of deviding into forest hydrological processes, multiple regression equations of electrical conductivity and total amount of anion, $NO{_3}^-$ of throughfall, stemflow, soil water of management site in Abies holophylla shows high significance. And multiple regression equations of electrical conductivity and total amount of anion, $SO{_4}^{2-}$, $Cl^-$ of throughfall, stemflow, soil water of non-management site in Abies holophylla shows high significance. Multiple regression equations of electrical conductivity and $NO{_3}^-$, before non-rain days of throughfall, stemflow, soil water of management site in Pinus koraiensis shows high significance. And multiple regression equations of electrical conductivity and total amount of ion, $NO{_3}^-$, $K^+$, pH, total amount of anion of throughfall, stemflow, soil water of non-management site in Plinus koraiensis shows high significance. Multiple regression equations of electrical conductivity and pricipitation, total amount of ion, $Na^+$ of stream water in Abies holophylla and Pinus koraiensis shows high significance. In case of combining into forest hydrological processes, multiple regression equations of electrical conductivity and total amount of cation and anion, $Na^+$, $Cl^-$, and pH in rainfall, throughfall, stemflow, soil and stream water shows high significance.

• Journal of Korean Society of Forest Science
• /
• v.83 no.4
• /
• pp.460-472
• /
• 1994

This study has been conducted to give some ideas for reasonable ecological management of Taejon city and its adjacent forest ecosystem against the effect of acid rain. Rain monitoring points to analyse its components represented 1 point in industrial area, 4 points in commercial area, 4 points in residential area, and 5 points in suburban area and forest survey was done in 7 forest sites adjacent to rain monitoring points. Transformed vegetation index(TVI) based on Landsat TM data was analysed for forest area. Taejon area was seriously contaminated by air pollutants and average concentration of anions in precipitation were 20.16mg/l for $SO_4{^{2-}}$, 3.65mg/l for $NO_3{^-}$, and 3.09mg/l for $Cl^-$. Anion in precipitation were $1.09mg/m^2/month$ for $SO_4{^{2-}}$, $0.23mg/m^2/month$ for $NO_3{^-}$, and $0.20mg/m^2/month$ for $Cl^-$. Cation in precipitation were $0.14mg/m^2/month$ for $Ca^{2+}$, $0.10mg/m^2/month$ for $NH_4{^+}$, $0.08mg/m^2/month$ for $Na^+$, $0.07mg/m^2/month$ for $K^+$, and $0.08mg/m^2/month$ for $Mg^{2+}$. The region with the highest concentration of $SO_4{^{2-}}$, $NO_3{^-}$, and $Cl^-$ in rain was industrial area. $SO_4{^{2-}}$, $NO_3{^-}$, and $Cl^-$ concentrations in industrial area were 43.08, 3.88, and 3.64ppm, respectively. Forest soil showed strongly acidic ranging pH4.16-4.94. Transformed vegetation index(TVI) were 3.11 in Dangsan, 4.00 in Kyechoksan, 4.13 in Bomunsan, 4.18 in Kabhasan, 3.34 in Bongsan, 4.13 in Sikchangsan, and 4.20 in Seongchisan. Dangsan forest located near in industrial area showed the lowest TVI.

• KOREAN JOURNAL OF CROP SCIENCE
• /
• v.57 no.3
• /
• pp.238-247
• /
• 2012

To determine the possibility of solidified se wage sludge for use as a soil cover material in reclaimed land, the growth of energy crops and soil chemical properties investigated in each experimental plots during 2 years (2010 and 2011). The experimental plots consisted of the mixing with solidified sewage sludge plot (SS50), the covering with solidified sewage sludge plot (SS100), and the original reclaimed land plot (ORL) on reclaimed land for the intended landfill in Sudokwon Landfill Site Management Corporation (SLC). Plant height, measured in the second year (2011), was highest in the Geodae 1 grown at plots treated with solidified sewage sludge. The growth of energy crops cultivated in both SS50 and SS100 were better than in ORL. The contents of organic matter (OM) and total nitrogen (T-N) at both SS50 and SS100 were considerably higher than that of the ORL over 2 years. However, the soil from ORL showed higher salinity with high contents of exchangeable $Na^+$ cation than that of SS50 and SS100 over 2 years. We consider that soil chemical and physical properties on reclaimed land used in this study could be improved by the application of solidified sewage sludge due to following reasons. Firstly, the application of solidified sewage sludge may provide soil nutrients on reclaimed land i.e. the growth of energy crops better than in ORL, resulted in more OM and T-N contents in SS50 and SS100. Secondly, the top layers mixed or covered with solidified sewage sludge on reclaimed land may be prevented the salinity accumulation due to capillary rise to surface soil, and improved the cultivation layer for effectively propagating the rhizomes of energy crops. Thus the solidified sewage sludge may be a great soil cover materials for cultivation of bioenergy crops in reclaimed land.

• The Korean Journal of Pesticide Science
• /
• v.16 no.3
• /
• pp.202-208
• /
• 2012

A high-performance liquid chromatographic (HPLC) method was developed to determine residues of cyromazine, a triazine insecticide, in agricultural commodities. Cyromazine was extracted with 90% aqueous methanol from representative crops which comprised brown rice, oyster mushroom, oriental melon, watermelon, and Chinese cabbage. Following to evaporation of methanol in the extract, the aqueous concentrate was acidified to form the protonated cyromazine. Dichloromethane partition was then applied to remove nonpolar co-extractives in the aqueous phase. Strong cation-exchange chromatography using Dowex 50W-X4 resin was employed for final purification of the extract. Cyromazine was successfully separated on a Zorbax SB-Aq $C_{18}$ column showing high retention for polar compounds. Cyromazine was sensitively quantitated by ultraviolet absorption at 214 nm. Limit of quantitation (LOQ) of the method was 0.04 mg/kg irrespective of sample types. Each crops were fortified at 3 different concentrations of cyromazine for recovery test. Mean recoveries from samples fortified at LOQ~2.0 mg/kg in triplicate ranged 80.2~103.3% in five agricultural commodities. Relative standard deviations in recoveries were all less than 6%. A selected-ion monitoring LC/MS method with electrospray ionization in positive-ion mode was also provided to confirm the suspected residue. The proposed method was reproducible and sensitive enough to routinely determine and inspect the residue of cyromazine in agricultural commodities.

• Journal of Soil and Groundwater Environment
• /
• v.10 no.3
• /
• pp.32-37
• /
• 2005

The soil properties of the royal tombs (managed by cultural properties administration) located in Seoul and suburban Gyonggi area were investigated to see the influence of the change in soil environment on the royal tomb s이I. To compare the soil chemical properties of four royal tombs soil of Changdeokgung, Jongmyo, Seooneung, and Dongguneung, pH, organic content, available phosphate, extractable calcium, extractable potassium, extractable magnesium, cation exchange capacity, degree of base saturation, and total nitrogen content were measured. The concentrations of Cd, Pb, and Cu measured as the degree of heavy metal contamination can be an indication of atmospheric pollution in the soil environment. To estimate the degree of soil compaction, soil hardness, pore space, porosity, bulk density, and soil atmosphere were analyzed. Through these studies, following conclusions were made: 1. The soil hardness and pore space which can be used as indexes of soil compaction, were worse in the soil of Seooneung than in those of Changdeokgung and Dongguneury. These phenomena seem to be the result of increase in visitors in Seooneung and Dongguneung better and soil management in Changdeokgung and Dongguneung. When three different regions of forest area, prohibited area, and soil compaction area in Seooneung soil were compared, the degree of compaction in the forest area was less than compaction area, indicating the need for the employment of soil resting period in the compaction area. 2. The pH measurements of all four royal tombs soil were higher in top soil than sub soil. The higher soil pH values in Jongmyo and Seooneung seem to result from the application of soil conditioner. In the case of Seooneung, the values for soil pH and organic content were higher in the forest area than those in compaction area. It is thought that active soil management was employed in the forest area through application of organic matters and soil conditioners. 3. The heavy metal contents from soil of Changdeokgung and Jongmyo were higher than that from soil of Dongguneung. Since Changdeokgung and Jongmyo are located inside Seoul, it is thought that the high level of heavy metal concentrations in these royal tomb soil is the result of accumulation of pollutants from the city.

• Korean Journal of Weed Science
• /
• v.1 no.1
• /
• pp.57-68
• /
• 1981

To clarify the mode of uptake of butachlor (2-chloro-2', 6'-diethyl-N-(butoxymethyl) acetanilide) by rice seedlings, its phytotoxic action to growth and physiological activities, studies were conducted with rice seedlings, at the 6th or 7th leaf-stage, which were treated with nutrient solution containing butachlor 0, 1.8, 3.6, 7.2, 10.8 or 14.4 ppm for 1, 2 or 4 days, in other case, the solutions were thereafter renewed with the untreated nutrient solution for further growth. Uptake of butachlor by rice seedlings increased linearly with increase of its concentration and duration of uptake. Butachlor inhibited root growth more than shoot growth, furthermore, the inhibitory effect on the shoot growth was greater in height than in weight or leafing rate. After 4 day-treatment, the rates of shoot growth in weight were delayed for 4 days. Butachlor inhibited water uptake rapidly and linearly with increase of its external concentration. The reduced uptake of water was followed by slow increase in the stomatal resistance of leaves. Upon completion of butachlor treatment, rate of water uptake was recovered rapidly, but the stomatal resistance with lag in time. Butachlor did not affect the uptake of cation such as ammonium, potassium and calcium, but inhibited substantially uptake of nitrate in proportion to its concentration. Especially, butachlor did not affect synthesis and degradation of nitrate reductase. In addition, butachlor has shown much greater binding to the lipidic substances from rice roots than the proteinous material. The primary mechanism of phytotoxic action of butachlor does not seem to be its effect on the protein synthesis, but great affinity to membranes. The inhibition of water uptake, and its subsequent closure of stomates is thought very important for reduced growth under mild phytotoxicity.