• Title/Summary/Keyword: cathode shape

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Synthesis of CNTs with Plasma Density and Tilt Degree of Substrate (플라즈마 밀도와 기판의 기울임 정도에 따른 탄소나노튜브의 성장)

  • Choi, Eun-Chang;Kim, Kyung-Uk;Hong, Byung-You
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.22 no.7
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    • pp.612-615
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    • 2009
  • We need to control the growth orientation of CNTs on a substrate for applications to various electric devices. Generally, the flow direction of feed gases and electric field between two electrode affect to growth orientations of CNTs. In this paper, we varied tilt degrees $(0^{\circ},\;20^{\circ},\;35^{\circ},\;50^{\circ},\;65^{\circ},\;90^{\circ})$ of substrates on a cathode and DC bias voltages (0, 500, 700 V) applied between two electrodes in order to change growth orientations of CNTs. We confirmed that tilt degrees of the substrate and variation of DC bias voltages affected to the shape and orientation of the grown CNTs on the substrate.

Nano Catalysts for Proton Exchange Membrane Fuel Cells

  • Kim, Su-Gil;Hwang, Seung-Jun;Im, Ji-Eun;Yu, Seong-Jong;Lee, Seung-Cheol;Im, Tae-Hun
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2012.05a
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    • pp.71.1-71.1
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    • 2012
  • Proton Exchange Membrane Fuel Cells (PEMFCs) have been of great interest particularly in the automobile industries because of their high energy density and low pollutant emission. However, some of the issues such as, the necessarily high contents of Pt catalysts and their slow kinetics of cathode oxygen reduction reaction remain as obstacles in the commercialization of the PEMFC. In this presentation, after brief explanation on basic principles of PEMFC and its application to FC vehicles, recent researches to improve the activity and durability of Pt-based nano catalysts toward oxygen reduction will be introduced. It covers size and shape control of Pt nano particle, binary and ternary Pt-M alloys, novel core-shell nano structures of Pt, and a little bit about non-Pt catalysts. Strategies and methodologies for design and synthesis of novel catalysts will also be included.

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An Analysis of Capacitance in Multi-electrode System by Surface-Contacted Elements (표면접촉요소에 의한 다중 전극계의 정전용량 해석)

  • Park, Pil-Yong;Choi, Seung-Kil;Shim, Jae-Hak;Kang, Hyung-Boo
    • Proceedings of the KIEE Conference
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    • 1999.07e
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    • pp.2287-2289
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    • 1999
  • In this paper, a new method for calculating capacitance in multi-electrode system with arbitrarily shape is presented. This new approach based on divergence theorem and Gauss's law is achieved by Surface-Contacted Element(SCE) for Gaussian surface. To evaluate capacitance in multi-electrode system, two dimensional finite element method using only the elements which is contacted one nod (PE: Point-Element) or two nod (FE: Face-Element) with surface is employed. The proposed SCE method has short computing time to calculate capacitance which is because it uses only SCE elements and needs one calculation loop while exiting FEM method in servral loops. This method is verified by application in calculating capacitance using potential detection device model which is composed with anode, cathode, and floating electrode.

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Electron Beam Behaviors by the Electrostatic Lens in Triode Field Emission Gun (3극 전계방출 전자총의 정전기 렌즈에 의한 전자빔 거동)

  • Kim, Chung-Soo;Kim, Dong-Hwan;Park, Man-Jin;Jang, Dong-Young;Han, Dong-Chul
    • Transactions of the Korean Society of Machine Tool Engineers
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    • v.16 no.6
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    • pp.163-167
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    • 2007
  • A field emission electron gun including 3 electrodes including one cathode and two anodes is very important for high resolution electron microscope. To have functions to control the initially-emitted electron beam, two anodes act as an electrostatic lens according to equipotential lines by adjusting the spot size, intensity, and working distance. To verify the action of the electron beam by the electrostatic lens by changing several parameters such as electrode shape, displacement and applied voltage to the electrodes, the two lenses were design and simulated and then their performances were analyzed with angular beam intensity(distribution), electrical optic axis variation and their stability.

Microstructure and Residual Stress of Metallic Thin Films According to Deposition Parameters

  • Park, Byung-Jun;Kim, Young-Man
    • Journal of Surface Science and Engineering
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    • v.36 no.1
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    • pp.1-8
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    • 2003
  • In general, the microstructure in thin films was known to evolve in similar manner according to the energy striking the condensing film at similar homologous temperature, Th for the materials of the same crystal structure. The fundamental factors affecting particle energy are a function of processing parameters such as working pressure, bias voltage, target/sputtering gas mass ratio, cathode shape, and substrate orientation. In this study, Al, Cu, Pt films of the same crystal structure of face centered cubic (FCC) have been prepared under various processing parameters. The influence of processing variables on the microstructures and residual stress states in the films has been studied.

Fabrication and characterization of ternary compound ZnCdS nanowires

  • Lee, Dong-Jin;Son, Moon-A;Kang, Tae-Won
    • Proceedings of the Korean Vacuum Society Conference
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    • 2010.02a
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    • pp.57-57
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    • 2010
  • Self assembled $Zn_{x-1}Cd_xS$ nanowires, synthesized on a Indium tin oxide coated glass substrate with low composition of Cd as x=0.09, were fabricated non-precursor via a co-evaporation method using of solid sources of CdS and ZnS. We studies that ZnCdS nanowires are dislocation-free and the single crystalline hexagonal wurtzite structure showed by transmission electron microscopy and selected area electron diffraction pattern. Cathode luminescence spectra showed an near band edge peak at 383nm originated from nanowires at 80K and 300K. Core level spectra of the Cd 3d, Zn 2p and S 2p in the ZnCdS nanorods were obtained by x-ray photoelectron spectroscopy. Prepared ZnCdS nanorods showed different shape with increase of substrate temperature at the growth.

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DIAMOND-LIKE CARBON FILMS FOR ANTIREFLECTION COATINGS OF GERMANIUM INFRATED OPTICAL LENSES

  • Kim, Seong-Young;Lee, Sang-Hyun;Lee, Jai-Sung
    • Journal of Surface Science and Engineering
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    • v.32 no.3
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    • pp.461-466
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    • 1999
  • Diamond-like carbon(DLC) films were directly deposited onto germanium(Ge) witness pieces and lenses by a capacitively coupled 13.56 MHz RF glow discharge plasma with $CH_4$ gas. The characterizations of DLC films were measured using a Raman and FTIR spectrometer. The configuration of Raman and FTIR spectra had a traditional shape. The IR transmittance was measured using an IR spectrophotometer. The maximum values of the IR transmission of Ge with the DLC/Ge/DLC, DLC/Ge/BBAR (broad band antireflection), DLC/Ge, and BBAR/Ge structures are 98%, 93%, 64%, and 63.5%, respectively, which come up to the theoretical values. The uniform DLC films were obtained by a rotation of the cathode at certain conditions.

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CNT-BASED FIELD EMISSION X-RAY SOURCE

  • Kim, Hyun Suk;Lee, Choong Hun
    • Proceedings of the Korean Vacuum Society Conference
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    • 2016.02a
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    • pp.433-433
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    • 2016
  • Carbon nanotubes (CNT) emitter has widely become an attractive mechanism that draws growing interests for cold cathode field emission. CNT yarns have demonstrated its potential as excellent field emitters. It was demonstrated that a small focal spot size was achieved by manipulating some electrical parameters, such as applied bias voltage at the mesh gate, and electrostatic focal lenses, geometrical parameters, such as axial distances of the anode, and the electrostatic focal lens from the cathode assembly, and the dimension of the opening of the electrostatic lens. Electrical-optics software was used to systematically investigate the behavior of the electron beam trajectory when the aforementioned variables were manipulated. The results of the experiment agree with the theoretical simulation results. Each variable has an individual effect on the electron beam focal spot size impinging on the target anode. An optimum condition of the parameters was obtained producing good quality of X-ray images. Also, MWCNT yarn was investigated for field emission characteristics and its contribution in the X-ray generation. The dry spinning method was used to fabricate MWCNT yarn from super MWCNTs, which was fabricated by MW-PECVD. The MWCNT yarn has a significant field emission capability in both diode and the triode X-ray generation structure compared to a MWCNT. The low-voltage-field emission of the MWCNT yarn can be attributed to the field enhancing effect of the yarn due to its shape and the contribution of the high-aspect-ratio nanotubes that protrude from the sides of the yarn. Observations of the use of filters on the development of X-ray images were also demonstrated. The amount of exposure time of the samples to the X-ray was also manipulated. The MWCNT yarn can be a good candidate for use in the low voltage field emission application of X-ray imaging.

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Shape Characteristics of Exhaust Plume of Dual-Stage Plasma Thruster using Direct-Current Micro-Hollow Cathode Discharge (직류 마이크로 할로우 음극 방전을 이용한 이단 마이크로 플라즈마 추력기의 배기 플룸의 형상 특성)

  • Ho, Thi Thanh Trang;Shin, Jichul
    • Journal of the Korean Society of Propulsion Engineers
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    • v.20 no.3
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    • pp.54-62
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    • 2016
  • Micro plasma thruster (${\mu}PT$) was studied experimentally with a dual-stage micro-hollow cathode discharge (MHCD) plasma. Electrostatic-like acceleration exhibiting more directional and elongated exhaust plume was achieved by a dual layer MHCD at the total input power less than 10 W with argon flow rate of 40 sccm. V-I characteristic indicated that there was an optimal regime for dual-stage operation where the acceleration voltage across the second stage remained constant. Estimated exhaust plume length showed a similar trend to the analytic estimate of exhaust velocity which scales with an acceleration voltage. ${\mu}PT$ with multiple holes exhibited similar performance with single-hole thruster indicating that higher power loading is possible owing to decreased power through each hole. Boltzmann plot of atomic argon spectral lines showed average electron excitation temperature of about 2.6 eV (~30,170 K) in the exhaust plume.

Effect of the Pore Structure on the Anodic Property of SOFC (SOFC 음극의 기공구조가 음극특성에 미치는 영향)

  • 허장원;이동석;이종호;김재동;김주선;이해원;문주호
    • Journal of the Korean Ceramic Society
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    • v.39 no.1
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    • pp.86-91
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    • 2002
  • Solid Oxide Fuel Cells (SOFC) are of great interest of next generation energy conversion system due to their high energy efficiency and environmental friendliness. The basic SOFC unit consists of anode, cathode and solid electrolyte. Among these components, anode plays the most important role for the oxidation of fuel to generate electricity and also behaves as a substrate of the whole cell. It is normally requested that the anode materials should have the high electrical conductivity and gas permeability to reduce the polarization loss of the cell. In this study, the effect of pore former on the microstructure of anode substrate was investigated and thus on the electrical conductivity and the gas permeability. According to the results, microstructure and electrical conductivity of anode substrate were greatly influenced by the shape of pore former and especially by the anisotrpy of the pore former. The use of anisotropic pore former is supposed to deteriorate the cell performance by which the electrical conduction path is disconnected but also the effective gas diffusion path for the fuel is reduced.