• Title/Summary/Keyword: catalyst effectiveness

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Performance Study on Odor Reduction of Indole/Skatole by Composite

  • Young-Do Kim
    • Journal of Wellbeing Management and Applied Psychology
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    • v.7 no.3
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    • pp.67-72
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    • 2024
  • This study developed a dry composite module-type deodorization facility with Twisting airflow changes and two forms (catalyst, adsorbent) within one module. Experiments were conducted to evaluate the reduction efficiency of odor substances C8H7N and C9H9N. The device combines UV oxidation using TiO2, catalytic oxidation using MnO2, and adsorption using A/C in five different methods. Data analysis of experimental results utilized the statistical package program Python 3.12. The program applied frequency analysis of odor removal efficiency, one-way ANOVA, and post-hoc tests, with statistical significance determined by p-value to ensure reliability and validity of the measurements. Results indicated that the highest removal efficiency of C8H7N and C9H9N was achieved by the UV+A/C method, suggesting the superior effectiveness and efficiency of the developed device. Combining multiple processes and technologies within one module enhanced odor treatment efficiency compared to using a single method. The device's modularity allows for flexibility in adapting to various sewage treatment scenarios, offering easy maintenance and cost-effective deodorization. This composite reaction module device can apply multiple technologies, such as biofilters, plasma, activated carbon filters, UV-photocatalysis, and electromagnetic-chemical systems. However, this study focused on UV-photocatalysis, catalysts, and activated carbon filters. Ultimately, the research demonstrates the practical applicability of this innovative device in real sewage treatment operations, showing excellent reduction efficiency and effectiveness by integrating UV oxidation, TiO2 photocatalysis, MnO2 catalytic oxidation, and A/C adsorption within a modular system.

Solution-Processed Metal Oxide Thin Film Nanostructures for Water Splitting Photoelectrodes: A Review

  • Lee, Mi Gyoung;Park, Jong Seong;Jang, Ho Won
    • Journal of the Korean Ceramic Society
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    • v.55 no.3
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    • pp.185-202
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    • 2018
  • Photoelectrochemical (PEC) cells can convert solar energy, the largest potential source of renewable energy, into hydrogen fuel which can be stored, transported, and used on demand. In terms of cost competitiveness compared with fossil fuels, however, both photocatalytic efficiency and cost-effectiveness must be achieved simultaneously. Improvement of cost-effective, scalable, versatile, and eco-friendly fabrication methods has emerged as an urgent mission for PEC cells, and solution-based fabrication methods could be capable of meeting these demands. Herein, we review recent challenges for various nanostructured oxide photoelectrodes fabricated by solution-based processes. Hematite, tungsten oxide, bismuth vanadate, titanium oxide, and copper oxides are the main oxides focused on, and various strategies have been attempted with respect to these photocatalyst materials. The effects of nanostructuring, heterojunctions, and co-catalyst loading on the surface are discussed. Our review introduces notable solution-based processes for water splitting photoelectrodes and gives an outlook on eco-friendly and cost-effective approaches to solar fuel generation and innovative artificial photosynthesis technologies.

Listeners' Perception of Intended Emotions in Music

  • Chong, Hyun Ju;Jeong, Eunju;Kim, Soo Ji
    • International Journal of Contents
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    • v.9 no.4
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    • pp.78-85
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    • 2013
  • Music functions as a catalyst for various emotional experiences. Among the numerous genres of music, film music has been reported to induce strong emotional responses. However, the effectiveness of film music in evoking different types of emotions and its relationship in terms of which musical elements contribute to listeners' perception of intended emotion have been rarely investigated. The purpose of this study was to examine the congruence between the intended emotion and the perceived emotion of listeners in film music listening and to identify musical characteristics of film music that correspond with specific types of emotion. Additionally, the study aimed to investigate possible relationships between participants' identification responses and personal musical experience. A total of 147 college students listened to twelve 15-second music excerpts and identified the perceived emotion during music listening. The results showed a high degree of congruence between the intended emotion in film music and the participants' perceived emotion. Existence of tonality and modality were found to play an important role in listeners' perception of intended emotion. The findings suggest that identification of perceived emotion in film music excerpts was congruent regardless of individual differences. Specific music components that led to high congruence are further discussed.

Preparation of pitch from pyrolized fuel oil by electron beam radiation and its melt-electrospinning property

  • Jung, Jin-Young;Lee, Young-Seak
    • Carbon letters
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    • v.15 no.2
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    • pp.129-135
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    • 2014
  • Spinnable pitch for melt-electrospinning was obtained from pyrolized fuel oil by electron beam (E-beam) radiation treatment. The modified pitch was characterized by measuring its elemental composition, softening point, viscosity, molecular weight, and spinnability. The softening point and viscosity properties of the modified pitch were influenced by reforming types (heat or E-beam radiation treatment) and the use of a catalyst. The softening point and molecular weight were increased in proportion to absorbed doses of E-beam radiation and added $AlCl_3$ due to the formation of pitch by free radical polymerization. The range of the molecular weight distribution of the modified pitch becomes narrow with better spinning owing to the generated aromatic compounds with similar molecular weight. The diameter of melt-electrospun pitch fibers under applied power of 20 kV decreased 53% ($4.7{\pm}0.9{\mu}m$) compared to that of melt-spun pitch fibers ($10.2{\pm}2.8{\mu}m$). It is found that E-beam treatment for reforming could be a promising method in terms of time-savings and cost-effectiveness, and the melt-electrospinning method is suitable for the preparation of thinner fibers than those obtained with the conventional melt-spinning method.

Growth and Characterization of P-type Doping for InAs Nanowires during Vapor-liquid-solid and Vapor-solid Growth Mechanism by MOCVD

  • Hwang, Jeongwoo;Kim, Myung Sang;Lee, Sang Jun;Shin, Jae Cheol
    • Proceedings of the Korean Vacuum Society Conference
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    • 2014.02a
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    • pp.328.2-328.2
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    • 2014
  • Semiconductor nanowires (NWs) have attracted research interests due to the distinct physical properties that can lead to variousoptical and electrical applications. In this paper, we have grown InAs NWs viagold (Au)-assisted vapor-liquid-solid (VLS) and catalyst-free vapor-solid (VS) mechanisms and investigated on the p-type doping profile of the NWs. Metal-organic chemical vapor deposition (MOCVD) is used for the growth of the NWs. Trimethylindium (TMIn) and arsine (AsH3) were used for the precursor and diethyl zinc (DEZn) was used for the p-type doping source of the NWs. The effectiveness of p-type doping was confirmed by electrical measurement, showing an increase of the electron density with the DEZn flow. The structural properties of the InAs NWs were examined using scanning electron microscopy (SEM) and transmission electron microscopy (TEM). In addition, we characterize atomic distribution of InAs NWs using energy-dispersive X-ray spectroscopy (EDX) analysis.

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Study on Heat Transfer Characteristics by Heater Conditions of Hydrogen Sensor for Fuel Cell Electric Vehicle (연료전지 자동차용 수소센서의 히터 조건에 따른 열전달 특성에 관한 연구)

  • Suh, Hocheol;Park, Kyoungsuk
    • Transactions of the Korean Society of Automotive Engineers
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    • v.21 no.1
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    • pp.23-29
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    • 2013
  • In recent years, development of energy conversion systems using hydrogen as an energy source has been accelerated globally. Even though hydrogen is an environment-friendly energy source, safety and effectiveness issues in storage, transportation, and usage of hydrogen should be clearly resolved in every application. Therefore, sensors for detecting hydrogen leakage, especially for fuel cell electric vehicles, should be designed to have much higher resolution and accuracy in comparison with conventional gas sensors. In this study, we conducted to determine the design parameters for the semiconductor hydrogen sensor with optimized sensing conditions under the thermal distribution characteristic and thermal transfer characteristic. The heat generation study on power supply voltage was studied for correlation analysis of thermal energy according to the power supply voltage variation from 1.0 voltage to 10.0 voltage every 0.5 voltage. And we studied for the temperature coefficient of resistance with hydrogen sensor.

Synthesis of Amino-type Anion Exchanger from Acrylic Acid Grafted Polypropylene Nonwoven Fabric and Its Ion-Exchange Property (아크릴산 그라프트 폴리프로필렌 부직포로부터 아민형 음이온 교환체의 합성 및 이온교환특성(I))

  • Park, Hyun-Ju;Na, Choon-Ki
    • Journal of Korean Society of Environmental Engineers
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    • v.28 no.5
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    • pp.527-534
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    • 2006
  • The purpose of this study is the development of more effective filter-type polymer adsorbent for removal of anionic pollutants from wastewater. In order to synthesize the polymer adsorbent that possesses anionic exchangeable function, carboxyl(-COOH) group of PP-g-AA nonwoven fabric was converted into amine($-NH_2$) group by the chemical modification using diethylene triamine(DETA). FT-IR data indicate that amine group was introduced into PP-g-AA through amidation of grafted acrylic acid by reaction with DETA. The degree of amination increased with increase in the reaction time and temperature of the chemical modification process, and was significantly improved by the pre-swelling treatment of PP-g-AA with solvent and addition of metal chlorides as a catalyst in following order as $NH_4OH>MeOH{\geq}HCl{\geq}H_2O\;and\;AlCl_3>FeCl_3{\geq}SnCl_2{\gg}ZnCl_2{\geq}FeCl_2$, respectively. However, the addition of catalyst limited the reusability of DETA, hence was less useful from the viewpoint of cost effectiveness and waste management. The anion exchange capacity of the aminated PP-g-AA(PP-g-AA-Am) increased with increase in the degree of amination, but it reached maximum value at the degree of amination as about $50{\sim}60%$. The anion exchange capacity of PP-g-AA-Am was higher than those of commercial anion resins.

Production of Chitosan from Crabshells using Microwave (마이크로파를 이용한 게껍질로부터 키틴/키토산 분리제조반응)

  • Choi, Guang Jin
    • Clean Technology
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    • v.7 no.4
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    • pp.281-290
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    • 2001
  • A microwave-assisted process to prepare chitosan from natural crabshells has been investigated. This study was primarily to examine the effectiveness of microwave as clean energy for chitosan preparation. Several human-edible organic acids were used as clean catalyst, possibly to improve the current HCl-based hydrolysis process of polymeric chitosan. The microwave was found to be effective substantially in reducing the reaction time. Nonetheless, no beneficial effect of microwave other than time, such as the chemical selectivity, was hardly observed. The organic acids were very effective in the hydrolysis reaction of polymeric chitosan. Their catalytic behavior was greatly improved especially when reactions were performed under pressure. In the case of autoclave reaction for 60 minutes at $120^{\circ}C$, viscous solution of polymeric chitosan (mol. wt. > 300,000) turned into thin solutions of water-like viscosity, which means chitosan molecules were decomposed to very small-sized oligomers.

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A Study on the Dieless Wire Drawing Using Microwave (마이크로웨이브를 이용한 Dieless Wire Drawing 에 대한 연구)

  • Huh You;Kim S.H.;Kim J.S.;Kim I.S.;Paik Y.N.
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2005.06a
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    • pp.942-945
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    • 2005
  • Micron-sized metal wires are widely used in industries such as filtration, catalyst and composite materials, etc. In the wire drawing process, the die that is used conventionally is an effective and, at the same time, sensitive component. However, a typical array of the dies has caused many problems in the wire drawing process, e.g., large frictional force on the interface between wire and the resulting high heat generation, precise adjustment of the dies, extended cooling system, die abrasion, etc.. Because of these problems, there have been many works that are aiming at improving the efficiency of wire drawing process by analyzing the die geometry and by applying advanced die material to prolong the die life or even at developing a dieless wire drawing system. This paper is dealing with developing a new wire drawing system that is applicable to reduce the wire drawing steps with high draw ratio. The new wire drawing system does not use the dies, but use the self-induced heater that works on the basis of the resonant phenomenon of wire material. The electromagnetic wave is the heating source. The results of the study on the diameter reduction and microwave flow analysis show that the heating effectiveness of the wire is influenced by the energy distribution in the microwave propagation chamber. We can obtain diameter-reduced wires by using microwave in the dieless drawing process. Microwave as a heating source is capable of producing wires without applying dies in wire drawing process.

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A Study of Efficacy of Physical Water Treatment Devices for Mineral Fouling Mitigation Using Artificial Hard Water (인공 경수를 이용한 미네랄 파울링 저감에 물리적 수처리 기기들의 효과에 관한 연구)

  • Pak, Bock Choon;Kim, Sun Do;Baek, Byung Joon;Lee, Dong Hwan
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.29 no.11 s.242
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    • pp.1229-1238
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    • 2005
  • The objective of the present study was to investigate the efficacy of physical water treatment (PWT) technologies using different catalytic materials and an electronic anti-fouling device in the mitigation of mineral fouling in a once-through flow system with mini-channel heat exchanger. Effects of flow velocity and water hardness on the effectiveness of PWT technologies were experimentally studied. The artificial water hardness varied from 5.0 to 10 mo1/m$^{3}$ as CaCO$_{3}$. For 10 mo1/m$^{3}$ solution, fouling resistance reduced by 13-40$\%$ depending on flow velocity and types of PWT devices. On the other hand, fouling resistance reduced by 21-29$\%$ depending on the PWT devices for 5 mo11m3 solutions. The PWT device using alloy of Cu and Zn as catalyst (CM2) was slightly more effective than the others. SEM photographs of scale produced from the 10 mol/m$^{3}$ solution at 1.0 m/s indicated that calcium carbonate scales without PWT devices were needle-shaped aragonite, which is sticky, dense and difficult to remove. Scales with the PWT devices showed a cluster of spherical or elliptic shape crystals. Both the heat transfer test results and SEM photographs strongly support the efficacy of PWT technologies using catalytic materials and an electronic anti-fouling device in the mitigation of mineral fouling.