• Bulletin of the Korean Chemical Society
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• v.17 no.12
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• pp.1109-1111
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• 1996

The Podand Ⅰ (Figure 1) has been studied as cation carrier in a bulk liquid membrane system. Ag+ and some other transition metal ions (M2+=Cu, Ni, Co, Zn, and Cd) have been transported using the podand as carrier in a bulk liquid membrane system. Studies on the transport of equimolar mixtures of two or three competing components have also been carried out with the same system. Ag+ exhibited a higher transport rate than the other M2+ in the competitive experiments. Ligand structure and the equilibrium constant for complex formation are important parameters in the transport of the metal ions.

• Fibers and Polymers
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• v.3 no.1
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• pp.14-17
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• 2002

Development of a novel fixed site carrier membrane (FCM), supported by PET fabric for metal ion separation is reported. The membranes were prepared by dipping PET fabric into the methylene chloride solution of Poly(5-vinyl-m-phe-nylene-m'-phenylene-32-crown-10) (P(VCE)), a polymeric metal ion carrier. It was found that the flux of mono-valent metal ion transported across the membrane is signif=cantly differed from each other and the flux decreases in the order $Cs^+$>$Rb^+$>$K^+$>$Na^+$>$Li^+$ irrespective to the anion except perchlorate anion. It was explained in terms of the stability of the complex, formed by crown ether unit of the P(VCE) and the various metal ions, meanwhile, the lower rate of transport in the presence of perchlorate anion was ascribed to its low hydrophilicity.

• Korean Journal of Materials Research
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• v.9 no.5
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• pp.473-477
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• 1999

Xerographic properties of double-layer photoconductor doped with 4-butyl-4'-methoxyazobenzene (BMAB) as charge-carrier transport material were investigated. BMAB can undergo reversible trans-cis isomerization by light with appropriate wavelength. In the results of measured surface voltage properties for photoconductor doped with BMAB, TNF: BMAB(4-wt%) sample with trans form showed the lowest dark decay, the lowest residual voltage, and the highest sensitivity among cis form. The trans isomer of BMAB has ordering orientation because the molecule possesses a rodlike shape, while the cis isomer has random orientation due to its bent shape. Therefore the molecular arrangement of trans form enhanced charge-carrier transport mobility.

• Membrane and Water Treatment
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• v.9 no.1
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• pp.23-31
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• 2018

In this study, a new method called as multi-dropped liquid membrane (MDLM) which is more practical and more effective than other liquid membrane techniques is applied for transport of Zn(II) has been studied. HCl as the stripping solution and D2EHPA dissolved in kerosene as the membrane solution, has been examined. The effects of stripping solution concentration, carrier concentration, temperature and pH in the feed phase on the transport of Zn(II) have also been investigated. As a result, the optimum transport conditions of Zn(II) were obtained, i.e., the concentration of HCl solution was 0.25 M, the concentration of D2EHPA was $8{\times}10^{-3}M$, and pH value in the donor phase was 5.00. Under the optimum conditions, the transport percentage of Zn(II) was up to >99% during the transport time of 80 min when the initial concentration of Zn(II) was $120mgL^{-1}$. The activation energy is calculated as $5.30kcalmol^{-1}$. The value of calculated activation energy indicates that the process is diffusionally controlled by Zn(II) ions. The experiments have demonstrated that D2EHPA derivative is a good carrier for Zn(II) transport through MDLM in the study.

• Coupled systems mechanics
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• v.6 no.1
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• pp.75-96
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• 2017

As electron donor/acceptor materials for organic photovoltaic cells, small-molecules donors/acceptor are attracting more and more attention. In this work, we investigated the electronic structures, electrochemical properties, and charge carrier transport properties of four recently-synthesized small-molecule donors/acceptor, namely, DPDCPB (A), DPDCTB (B), DTDCPB (A1), and DTDCTB (B1), by a series of ab initio calculations. The calculations look into the electronic structure of singly oxidized and reduced molecules, the first anodic and cathodic potentials, and the electrochemical gaps. Results of our calculations were in accord with those from experiments. Using Marcus theory, we also computed the reorganization energies of hole/electron hoppings, as well as hole/electron transfer integrals of multiple possible molecular dimer configurations. Our calculations indicated that the electron/hole transport properties are very sensitive to the relative separations/orientations between neighboring molecules. Due to high reorganization energies for electron hopping, the hole mobilities in the molecular crystals are at least an order of magnitude higher than the electron mobilities.

• The Korean Journal of Air & Space Law and Policy
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• v.27 no.2
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• pp.107-142
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• 2012

An aircraft has been one of the most important transportation means and disputes due to damage caused by delay of the aircraft happen many times out of ones related to the air transport. In 2011, the Air Transport Act in Commercial Law was established to regulate national air transport and the legislative system of air carrier's liability to handle delay of passengers or baggage was legislated here. Although there are some clauses related to the legislative system of air carrier's liability, they are very important because they deal with disputes due to damage caused by delay of the aircraft. The Air Transport Act in Commercial Law has a good point of adopting the global standard of 1999 Montreal Convention, but it has also a bad point of having the problems of 1999 Montreal Convention. There are some contents to be modified in the Air Transport Act in Commercial Law. First, the definition of 'Delay of Aircraft' needs to be enacted because it is important to materialize air carrier's liability due to damage caused by delay. Second, it is necessary to modify the clause in which air carrier's liability due to damage caused by delay of passengers is divided into two things, one is in case of national air transport and the other is in case of international air transport, and the limited amount of air carrier's liability in national air transport is eight times less than the latter because they are not so helpful to air carriers but too disadvantageous to aircraft passengers. Third, it is also necessary to amend the clause in which the limited amount of air carrier's liability due to damage caused by loss damage or delay of baggage has been legislated same without classifying the case into loss damage and delay, because they are generally different from each other in terms of extent of damage, therefore the limited amount of air carrier's liability by delay of baggage should be classified into in case of loss damage and in case of delay. It is desired that the Air Transport Act in Commercial Law including the clauses related to air carrier's liability by aircraft damage be developed continually by sufficient study and discussion about the necessity of amending it such as the one mentioned above.

• Proceedings of the Membrane Society of Korea Conference
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• 2002.05a
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• pp.106-109
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• 2002

No Abstract, See Full-text

• Proceedings of the Korean Fiber Society Conference
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• 2001.10a
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• pp.219-222
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• 2001

Membranes which selectively transport specific metals on an industrial scale is much useful in a number of applications, such as aqueous stream purification, catalyst and recycling of the reactants, the applications in metal ion sensing and so forth. Numerous studies have been already made to use liquid, supported liquid and, emulsion liquid membranes (LM) for selective carriers for metal ion transport. (omitted)

• Macromolecular Research
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• v.12 no.2
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• pp.145-155
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• 2004

Facilitated transport membranes for the separation of olefin/paraffin mixtures have long been of interest in separation membrane science because olefins, such as propylene and ethylene, which are important chemicals in petrochemical industries, are currently separated by energy-intensive cryogenic distillation processes. Recently, solid polymer electrolyte membranes containing silver ions have demonstrated remarkable performance in the separation of olefin/paraffin mixtures in the solid state and, thus, they can be considered as alternatives to cryogenic distillation. Here, we review recent progress, and critical issues affecting in the use of facilitated olefin transport membranes; in particular, we provide a general overview with reference to carrier properties, transport mechanisms, and separation performance.

• Journal of the Korean Institute of Telematics and Electronics
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• v.15 no.2
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• pp.19-21
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• 1978

The electrical drift mobility of charge carrier of Cholesteryl Benzoate was measured by Polarity inversion method in the temperature range 140~ 185$^{\circ}C$. with a view to revealing the mechanism of charge carrier transport. The electrical drift mobility of charge carrier of that increased from 2.5$\times$10-7$\textrm{cm}^2$/V.sec to 2.0$\times$10-6$\textrm{cm}^2$/v.sec as the temperature increased. As a result of the experiment, the mechanism of current transport is believed to be ionic mechanism.