• Applied Chemistry for Engineering
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• v.17 no.5
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• pp.532-538
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• 2006

The carbonization and activation conditions for the PAN-based ACF of various grade were investigated to obtain the optimun activation condition with high surface area. And the surface properties and the absorption performance of toxic gas for terror were examined toward the PAN-ACF with the highest surface area. In the test results the surface area increased with increase of the activation temperature, but decreased with increase of the carbonization temperature. After carbonization condition ($900^{\circ}C$-15min) and activation condition ($900^{\circ}C$-30 min), we got the ACF with the highest surface area of $1204m^2/g$. In the absorption test of iodine and toxic gas for terror, this ACF showed more excellent absorption performance than the existing carbon-based adsorbent. Also, in order to give the function characteristic for a selective absorption, the stable nanoparticles of the Ag, Pt, Cu, Pd were prepared and impregnated on the PAN-based ACF in replacement of the existing method supporting metal catalysis. And were analyzed the surface characteristics and the $SO_{2}$ adsorption characteristics. In the $SO_{2}$ absorption performance test of the PAN-ACF with the impregnated nanoparticles, it wasn't change breakthrough time of Ag, Pt, Cu nanoparticle supported the PAN-ACF comparing with breakthrough time (326 sec) of the non supported PAN-ACF but Pd nanoparticle supported the PAN-ACF achieved excellent $SO_{2}$ absorption performance which has break-through time 925 sec.

• Journal of the Korean Wood Science and Technology
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• v.26 no.2
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• pp.6-15
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• 1998

A total of forty five-ply, 30- by 30-cm lauan and larch plywood sheets were manufactured in the laboratory using commercial urea and phenol resin adhesives; half of these sheets were treated with fresh concrete. Each sheet was carbonized for 2, 4, and 6hours at $400^{\circ}C$, $600^{\circ}C$, and $750^{\circ}C$, respectively, and their physical properties were measured. The yie1d of charcoal decreased as carbonization temperature and time increased. Charcoal yield was greater in plywood than in veneer, and slightly greater in plywood treated with concrete compared to untreated plywood. Plywood manufactured with phenol resin adhesive had higher pH, higher equilibrium moisture content (EMC), and greater adsorption of methylene-blue dye compared to plywood manufactured with urea resin. For concrete-treated plywood, pH was greater than 10 even when the sheets were carbonized for 2hours at $400^{\circ}C$. Although the EMC of the phenol resin plywood was higher than that of the urea resin plywood, EMC of the phenol resin was lower than that of the urea resin. The larch phenol resin plywood that was carbonized for 6 hours at $750^{\circ}C$ adsorbed more methylene-blue than did the commercia1 wood-based activated charcoal as a result of total pore volume and surface area.

• Journal of the Korean Society of Propulsion Engineers
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• v.25 no.4
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• pp.36-42
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• 2021

In this study, the impregnation of Lyocell fabrics was performed using phosphoric acid, ammonium phosphate, diammonium hydrogen, triammonium phosphate as phosphorus flame retardant, to fabricate continuous graphite fabrics using lyocell fiber. The physical and chemical structure changes were investigated by thermogravimetric, Fourier-transform infrared spectroscopy, C-nuclear magnetic resonance, X-ray diffraction, and weight analyses, By analyzing the thermal behavior of phosphorus flame retardant, conditions for the temperature, gas, and residual time of the pyrolysis process were set. Graphite fabrics with a tensile strength of 1,007.19±11.47 N/5 cm and yield of 25.3% were fabricated using continuous pyrolysis, carbonization and graphitization process.

• Journal of Korea Foresty Energy
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• v.22 no.3
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• pp.49-56
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• 2003

As a part of agricultural utilization of charcoal and pyroligneous acid, the effect of wood carbonization products on the growth of red pepper and soil microorganisms was investigated. The treatment of charcoal and pyroligneous acid provided good growth conditions to microorganisms through neutralizing soil acidity and improving the physicochemical properties of soil. Therefore the density of useful microorganism in the soil has been increased. In the growth of red pepper, the length, diameter, and the fruit numbers of red pepper have been increased by treating with wood carbonization products. It was especially shown that yield has increased about 50% in the fruit number, by treating charcoal 1kg, 1000 time-diluted solution of pyroligneous acid and bacteria, compared with the control. It was estimated that increasing the length of seedling and the diameter of red pepper stem contributed to the resistance against the prerequisites of various environmental changes in open field. Therefore, the final yield would be increased. In the antagonism experiment of red pepper mold (Colletotrichum gloeosporioides), the mold became extinct in the 2- and 10-time diluted solution of pyroligneous acid, compared with the control. On the other hand, their growth speed was delayed in the 100- and 1000 time-diluted solution.

• Applied Chemistry for Engineering
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• v.33 no.1
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• pp.28-37
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• 2022

The lignite and bituminous coal are mainly used in thermal power plant. They exhaust green house gas (GHG) such as CO₂, and become deplete, thus require alternative energy resources. To solve the problem, the hydrochar production from biomass is suggested. In this study, both hydrothermal carbonization (HTC) and solvothermal carbonization (STC) were used to produce high quality hydrochar. To improve the reactivity of water solvent process in HTC, STC process was conducted using ethanol solution. The experiments were carried out by varying the solid-liquid ratio (1:4, 1:8, 1:12), reaction temperature (150~300 ℃) and retention time (15~120 min) using kenaf. The characteristic of hydrochar was analyzed by EA, FT-IR, TGA and SEM. The carbon content of hydrochar increased up to 48.11%, while the volatile matter decreased up to 39.34%. Additionally, the fuel characteristic of hydrochar was enhanced by reaction temperature. The results showed that the kenaf converted to a fuel by HTC and STC process, which can be used as an alternative energy source of coal.

• Analytical Science and Technology
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• v.30 no.4
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• pp.174-181
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• 2017

Bio-liquid is a liquid by-product of the hydrothermal carbonization (HTC) reaction, converting wet biomass into solid hydrochar, bio-liquid, and bio-gas. Since bio-liquid contains various compounds, it requires efficient sampling method to extract the target compounds from bio-liquid. In this research, fatty acid methyl ester (FAME) in bio-liquid was extracted based on hollow fiber supported liquid phase microextraction (HF-LPME) and determined by Gas Chromatography-Flame Ionization Detector (GC-FID) and Gas Chromatography/Mass Spectrometry (GC/MS). The well-known major components of biodiesel, including methyl myristate, palmitate, methyl palmitoleate, methyl stearate, methyl oleate, and methyl linoleate had been selected as standard materials for FAME analysis using HF-LPME. Physicochemical properties of bio-liquid was measured that the acidity was 3.30 (${\pm}0.01$) and the moisture content was 100.84 (${\pm}3.02$)%. The optimization of HF-LPME method had been investigated by varying the experimental parameters such as extraction solvent, extraction time, stirring speed, and the length of HF at the fixed concentration of NaCl salt. As a result, optimal conditions of HF-LPME for FAMEs were; n-octanol for extraction solvent, 30 min for extraction time, 1200 rpm for stirring speed, 20 mm for the HF length, and 0.5 w/v% for the concentration of NaCl. Validation of HF-LPME was performed with limit of detection (LOD), limit of quantitation (LOQ), dynamic range, reproducibility, and recovery. The results obtained from this study indicated that HF-LPME was suitable for the preconcentration method and the quantitative analysis to characterize FAMEs in bio-liquid generated from food waste via HTC reaction.

• Journal of Soil and Groundwater Environment
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• v.19 no.1
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• pp.1-7
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• 2014

When processing the biomass by Hydrothermal carbonization (HTC), a slow pyrolysis process, it produces bio-gas, biooil, and biochar. Among these end products, biochar is known for isolating or storing carbon and being used as a soil amendment. In this study, the characteristics of biochar generated by HTC at $250^{\circ}C$ for 1 hour, 2 hours, 3 hours, and 20 hours with synthetic food wastes and wood wastes were analyzed for potential uses in soil contaminated with heavy metals. The yield of biochar (weight %) increased when the ratio of wood wastes increased and showed a decreasing tendency as reaction time increased. Elemental analysis of biochar based on various conditions showed a maximum of 70% carbon (C) content. The carbon content showed an increasing tendency with the increase of wood wastes. Iodine adsorption test was peformed to determine the optimum reaction condition, which was 15% wood waste for mixing ratio and 2 hours for reaction time. Using biochar generated at the optimum condition, its capability of adsorbing heavy metals (Cd, Cu, Pb, Zn, Ni) was evaluated. It was concluded that lead (Pb) was removed efficiently while zinc (Zn) and nickel (Ni) were hardly adsorbed by biochar.

• Journal of the Korean Home Economics Association
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• v.42 no.8
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• pp.113-121
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• 2004

This study used cupric sulfate as a bum-out agent. The concentration of cupric sulfate, temperature and time were varied with glycerin included or excluded on the properties of polyester ground fabrics. The results are as follows. The effect of carbonization with glycerin included was decreased, but removal of carbide with glycerin included was easier than that with glycerin excluded. The white index and tensile strength of polyester ground fabrics were decreased as the processing concentration, temperature and time increased. The shrinkage was increased as the processing concentration, temperature and time increased. The optimum conditions with cupric sulfate as the bum-out agent was 5％ concentration, 140$^{\circ}C$, 3min., and 3kgf/cm$^2$ and with cupric sulfate added to glycerin was 5％ concentration, 150$^{\circ}C$, 5min., and 3kgf/cm$^2$.

• Journal of the Korean Wood Science and Technology
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• v.36 no.3
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• pp.39-46
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• 2008

Repeated impregnation and carbonization processes were performed to prepare high-density woodceramics using a sawdust board. The physical properties were investigated to confirm morphological and structural changes of one-time and two-time phenolic resin-treated and carbonized woodceramics. As comparing between one-time and two-time carbonized woodceramics, the weight and the density of the two-time carbonized woodceramics decreased with an increase of the amount of impregnated phenolic resin. In addition, when the amount of impregnated phenolic resin was about 40% in these woodceramics, the two-time carbonized woodceramics showed higher weight (23.8%) and density (30.0%) than the one-time treatment.

• Fire Science and Engineering
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• v.33 no.6
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• pp.120-125
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• 2019

A real-scale combustion test was conducted on a vinyl flooring in a divided space, with 50 mL of an inflammable liquid sprayed on it. The combustion behavior of the vinyl flooring was studied in real time, and the carbonization patterns of the surface and cross-sections of the carbonized vinyl floor were analyzed. When the flame ignited by gasoline reached its peak, a continuously flaming region, intermittent flaming region, plume region, etc., were formed. The combustion of 50 mL gasoline on vinyl flooring took 26 s, and a halo pattern was observed. This test involved spraying kerosene evenly on the vinyl flooring and attempting to ignite the flooring using a gas torch, which failed. After the combustion of the vinyl flooring was complete, its carbonized range was measured to be 600 mm in length and 380 mm in width, and the carbonized area was 1000 ㎟. Heat transformed the coated layer of surface of the carbonized vinyl flooring into a carbonized layer, which became harder. The analysis of cross-section of the boundary surface of the carbonized vinyl flooring using a stereoscopic microscope showed that the vinyl flooring was bubbling, and that the white boundary layer at the bottom of the coated layer had disappeared.