• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2001년도 가을 학술발표회 논문집
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• pp.221-226
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• 2001

Chloride diffusion effect of cement paste, freezing and thawing test, carbonation of concrete specimen were carried out using inorganic coating material. According to the chloride ions diffusion test, it is elucidated that permeability and diffusion coefficient of Cl￣ ions and apparent coefficient of coated cement paste is smaller than plain cement paste. A durability of coated concrete specimen was enhanced by the experiment result of concrete carbonation and freezing thawing test.

• Corrosion Science and Technology
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• 제4권4호
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• pp.130-135
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• 2005

In this study, accelerated corrosion tests were conducted on concrete specimens with and without accelerated carbonation beforehand for the purpose of elucidating the effects of carbonation, cover depth, and water-cement ratio (W/C) on the reinforcement corrosion. During testing, the corrosion current between the anode steel and cathode stainless steel was measured to continuously monitor the progress of corrosion throughout the test period, thereby investigating the mechanism of reinforcement corrosion and the relationship between corrosion and crack width, as well as other parameters.

• 한국구조물진단유지관리공학회 논문집
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• 제18권6호
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• pp.30-40
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• 2014

최근 전력 전송을 위해 지하에 건설되는 전력구 구조물이 증가함에 따라, 이러한 구조물의 수명 연장은 매우 중요한 문제로 대두되고 있다. 현재까지의 현장 및 실험결과들은 콘크리트 내부의 철근이 콘크리트 피복의 탄산화 현상에 의해 부식될 수 있음을 보이고 있으며, 이러한 탄산화에 의한 철근의 부식은 구조물 주변의 높은 이산화탄소 농도에 의해 빈번히 발생할 가능성을 내포하고 있다. 따라서, 본 연구에서는 실제 전력구 현장에서의 철근 깊이와 탄산화 깊이를 측정한 결과를 바탕으로 우리나라의 전력구 콘크리트 구조물에 대한 탄산화 위험도를 평가하였다. 현장 데이터를 기반으로 철근 주변에서의 탄산화에 의한 전력구의 사용수명을 평가하였으며, 이를 위해 확률론적 방법인 몬테카를로 기법을 적용하였다. 또한 균열을 유발한 시험체에 대한 탄산화 촉진 실험을 수행하여, 그 실험결과를 바탕으로 균열을 고려한 경우의 전력구의 사용수명을 수치적으로 평가하고 분석하였다.

• 한국구조물진단유지관리공학회 논문집
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• 제14권1호
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• pp.141-147
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• 2010

일반적으로 일반대기중의 $CO_2$ 농도는 낮기 때문에 자연상태에서는 중성화정도는 매우 느리게 된다. 따라서 콘크리트의 중성화 정도를 평가하기 위해서는 일반적으로 진행속도를 빠르게 하기 위하여 촉진 시험조건하에서 진행하게 된다. 따라서 본 논문은 $CO_2$의 확산 및 $Ca(OH)_2$와의 반응을 바탕으로 한 수학적 모델을 통하여 일반대기환경하에서의 콘크리트 중성화 진행을 예측하고자 한다. 이를 위하여 본 논문에서는 촉진 중성화시험을 통하여 얻어진 실험치와 가장 유사한 $CO_2$ 확산계수를 채택하여 일반대기환경에서의 중성화진행을 예측하고자 하였다. 그 결과 $CO_2$ 확산계수를 이용한 수학적 모델을 통하여 마감재 종류에 관계없이 일반대기환경에서의 콘크리트 중성화진행속도를 예측할 수 있었다.

• 한국건설순환자원학회논문집
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• 제5권1호
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• pp.85-93
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• 2017

본 연구에서는 국내에서 생산되고 있는 콘크리트용 순환 굵은골재 및 순환잔골재를 사용하여 콘크리트의 설계기준 강도(21, 35, 50MPa) 및 순환골재의 혼입조건 변화가 콘크리트의 탄산화 거동에 미치는 영향을 분석하였다. 실험결과 순환 굵은골재의 혼입률 변화에 따른 콘크리트의 슬럼프는 순환골재를 혼입하지 않은 경우에 비해 동등하거나 양호한 유동성을 나타내는 것으로 나타났으며, 순환 잔골재를 혼입한 경우는 혼입률이 증가함에 따라 슬럼프가 감소되는 결과를 나타냈다. 또한, 순환 굵은골재 및 순환 잔골재의 혼입률이 증가할수록 콘크리트의 압축강도는 감소하는 것으로 나타났으며, 순환골재 혼입률이 50%를 초과할 경우 급격한 강도 감소 경향을 나타냈다. 그리고 탄산화 깊이는 모든 순환골재 종류에서 혼입률이 증가함에 따라 최대 40%까지 증가하는 결과를 나타냈으며 낮은 강도 수준의 콘크리트 일수록 순환골재 활용에 따른 탄산화 저항성 저하 정도가 큰 것으로 나타났다. 그리고 콘크리트의 압축강도가 증가할수록 순환골재 혼입에 따른 영향은 감소되어, 고강도 영역에서는 일반 콘크리트와 유사한 탄산화 특성을 발현하는 것으로 분석되었다. 따라서 순환골재를 콘크리트용 재료로 대량 활용하기 위해서는 콘크리트의 탄산화 저항성의 개선 위한 혼화재료의 적용 또는 배합설계상 조정을 통한 강도의 개선 등이 필요할 것으로 판단된다.

• 한국세라믹학회지
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• 제54권5호
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• pp.380-387
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• 2017

In this study, unstable CaO was converted into a stable Ca compound by using carbonation in a circulating fluidized bed boiler of fly ash to confirm material usability as cement admixture; also undertaken was carbonation test and mortar to examine chemical and physical change by measuring absorption rate and compressive strength. To investigate the chemical properties of circulating fluidized bed boiler fly ash, XRD and TG-DTA were used to determine how the properties of the reaction product change quantitatively during carbonation. In order to stabilize CaO, carbonation of CaO is considered to be the most desirable process. This is because $CaCO_3$, which is a Ca compound, was produced by carbonate reaction of unstable CaO, and decrease of the absorption rate and improvement of the compressive strength were observed when the carbonated fly ash was replaced with cement.

• Architectural research
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• 제4권1호
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• pp.39-44
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• 2002

Recently, the coal-ash production has been increased by increase of consumption of electric power. So it is important to secure a reclaimed land from pollution and develop practical application of coal ash. This is an experimental study to compare and analyze the properties of concrete using high volume of coal ash (including fly ash and bottom ash) as a part of fine aggregate. For this purpose, the mix proportions of concrete according to replacement ratio of coal ash (10, 20, 35, 50%) were selected. And then air content, slump, setting time, bleeding content, chloride content, compressive strength and carbonation test were performed. According to test results, it was found that the bleeding content of concrete using the coal ash decreased according to increase of replacement ratio. And the chloride content of concrete using the bottom ash as a part of fine aggregate increased as the replacement ratio of bottom ash increased, but it is satisfied with the total chloride content of concrete recommended by KCI - $0.3kg/m^3$ below. Also, the compressive strength of concrete using the bottom ash was similar to that of plain concrete(BA 0) after 28days of curing and the carbonation depth of concrete increased as the replacement ratio increased. However, the carbonation depth of concrete using the fly ash decreased as the replacement ratio of fly ash increased.

• Computers and Concrete
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• 제23권5호
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• pp.351-359
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• 2019

In this study, the calcium hydroxide, an inherent product of cement hydration, was treated using biomimetic carbonation method of incorporating stearic acid to generate the hydrophobic calcium carbonate on concrete surface. Carbonation reaction was carried out at various $CO_2$ pressure and temperatures and utilizing the Scanning Electron Microscope (SEM), chloride-ion penetration test apparatus, and compression test machine to investigate the hydrophobicity, durability, and mechanical properties of the synthesized products. Experimental results indicate that the calcium stearate may change the surface property of concrete from hydrophilicity to hydrophobicity. Increasing reaction temperature can change the particles from irregular shapes to needle-rod structures with increased shear stress and thus favorable to hydrophobicity and microhardness. The contact angle against water for the concrete surface was found to increase with increasing $CO_2$ pressure and temperature, and reached to an optimum value at around $90^{\circ}C$. The maximum static water contact angle of 128.7 degree was obtained at the $CO_2$ pressure of 2 atm and temperature of $90^{\circ}C$. It was also found that biomimetic carbonation increased the permeability, acid resistance and chloride-ion permeability of the concrete material. These unique results demonstrate that the needle-rod structures of $CaCO_3$ synthetized on concrete surface could enhance hydrophobicity, durability, and mechanical properties of concrete.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2006년도 춘계 학술발표회 논문집(II)
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• pp.569-572
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• 2006

This study was performed to investigate the characteristics of carbonation for latex modified concrete with fly ash and blast furnace slag. The experimental variables consisted of ground granulated blast-furnace slag contents (0%, 30%, 50%), fly ash contents (0, 30%) latex contents (0, 5, 10, 15%). Two different methods of carbonation test such as $CO_2$ gas and 5% sulphuric acid digestion resistance test were varied in this study.

• Corrosion Science and Technology
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• 제4권2호
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• pp.69-74
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• 2005

The carbonation of concrete is one of the major factors that cause durability problems in concrete structures. The rate of carbonation depends largely upon the diffusivity of carbon dioxide in concrete. The purpose of this study is to identify the diffusion coefficients of carbon dioxide for various concrete mixtures. To this end, several series of tests have been planned and conducted. The test results indicate that the diffusion coefficient increases with the increase of water-cement ratio. The diffusion coefficient decreases with the increase of relative humidity at the same water-cement ratio. The diffusion of carbon dioxide reached the steady state within about five hours after exposure. The content of aggregates also influences the diffusivity of carbon dioxide in concrete. It was found that the diffusion coefficient of cement paste is larger then that of concrete or mortar. The quantitative values of diffusivity of carbon dioxide in this study will allow more realistic assessment of carbonation depth in concrete structures.