• 제목/요약/키워드: carbonaceous

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서울의 일차탄소성분 입자 농도 변화 및 관리 방향 (Trend and policy directions of primary carbonaceous aerosols in Seoul)

  • 최은락;이지이;김용표
    • 한국입자에어로졸학회지
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    • 제20권1호
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    • pp.13-24
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    • 2024
  • The concentrations of polycyclic aromatic hydrocarbons (PAHs) and elemental carbon (EC) in particulate matter, typical primary aerosols have decreased in Seoul between 2003 and 2018 (80% for PAHs and 85% for EC). The yearly mean benzo[a]pyrene (BaP) concentration has been lower than 1 ng/m3 since 2010-2011, the target value set by the European Union (EU) and China. A series of policies related to solid fuel and vehicle in South Korea and China should be effective in the reduction of the ambient PAHs and EC concentrations. But the emission data of PAHs and EC at both countries did not support that hypothesis. Possible causes are uncertainties in the emission inventories of primary carbonaceous aerosols in South Korea and China, although there may be a minor effect of the emissions from North Korea on the concentrations in Seoul. Thus the further policy directions against PAHs and EC such as improvements of emissions inventories and measurements, intensive regulation of non-road mobile sources and control of PAHs derivatives are discussed.

Sources of Carbonaceous Materials in the Airborne Particulate Matter of Dhaka

  • Begum, Bilkis A.;Hossain, Anwar;Saroar, Golam;Biswas, Swapan K.;Nasiruddin, Md.;Nahar, Nurun;Chowdury, Zohir;Hopke, Philip K.
    • Asian Journal of Atmospheric Environment
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    • 제5권4호
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    • pp.237-246
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    • 2011
  • To explore the sources of carbonaceous material in the airborne particulate matter (PM), comprehensive PM sampling was performed (3 to 14 January 2010) at a traffic hot spot site (HS), Farm Gate, Dhaka using several samplers: AirMetrics MiniVol (for $PM_{10}$ and $PM_{2.5}$) and MOUDI (for size fractionated submicron PM). Long-term PM data (April 2000 to March 2006 and April 2000 to March 2010 in two size fractions ($PM_{2.2}$ and $PM_{2.2-10}$) obtained from two air quality-monitoring stations, one at Farm Gate (HS) and another at a semi-residential (SR) area (Atomic Energy Centre, Dhaka Campus, (AECD)), respectively were also analyzed. The long-term PM trend shows that fine particulate matter concentrations have decreased over time as a result of government policy interventions even with increasing vehicles on the road. The ratio of $PM_{2.5}/PM_{10}$ showed that the average $PM_{2.5}$ mass was about 78% of the $PM_{10}$ mass. It was also found that about 63% of $PM_{2.5}$ mass is $PM_1$. The total contribution of BC to $PM_{2.5}$ is about 16% and showed a decreasing trend over the years. It was observed that $PM_1$ fractions contained the major amount of carbonaceous materials, which mainly originated from high temperature combustion process in the $PM_{2.5}$. From the IMPROVE TOR protocol carbon fraction analysis, it was observed that emissions from gasoline vehicles contributed to $PM_1$ given the high abundance of EC1 and OC2 and the contribution of diesel to $PM_1$ is minimal as indicated by the low abundance of OC1 and EC2. Source apportionment results also show that vehicular exhaust is the largest contributors to PM in Dhaka. There is also transported $PM_{2.2}$from regional sources. With the increasing economic activities and recent GDP growth, the number of vehicles and brick kilns has significantly increased in and around Dhaka. Further action will be required to further reduce PM-related air pollution in Dhaka.

수도권 지역의 탄소 성분 에어로졸 측정 연구: KORUS-AQ 2016 캠페인 기간을 중심으로 (A Study of Carbonaceous Aerosols Measurement in Metropolitan Area Performed during KORUS-AQ 2016 Campaign)

  • 정병주;배민석;안준영;이정훈
    • 한국대기환경학회지
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    • 제33권3호
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    • pp.205-216
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    • 2017
  • Carbonaceous aerosols such as the equivalent black carbon (eBC), the elemental carbon (EC) and the organic carbon (OC) were monitored at the Seoul Olympic Park site ($37.521^{\circ}N$, $127.124^{\circ}E$) during the KORUS-AQ 2016 campaign using a Multi Angle Absorption Photometer (MAAP) and an OCEC Analyzer. Averaged mass concentrations of eBC, EC and OC were presented as $2.46{\pm}1.52{\mu}g/m^3$, $1.01{\pm}0.60{\mu}g/m^3$ and $4.85{\pm}2.60{\mu}g/m^3$, respectively. OC/EC ratio and mass absorption cross-section (MAC) of light absorbing aerosols were calculated as 2.32 and $14.8m^2/g$, respectively. Diesel OC concentrations were estimated from a source profile of diesel vehicles as well. eBC mass concentrations measured from May $26^{th}$ to May $27^{th}$, 2016 showed 40% higher than averaged eBC mass concentrations during campaign period. $PM_{2.5}$ concentrations measured in this period were also higher than average $PM_{2.5}$ concentrations. High eBC concentrations were observed from May $29^{th}$ to May $31^{st}$, 2016 and from June $9^{th}$ to June $11^{th}$, 2016, possibly due to morning rush hour and the effect of temperature inversion at night. Diurnal variations of eBC, EC and Diesel OC showed a typical pattern of metropolitan area. In the weekend, however, diurnal variations of eBC, EC and Diesel OC mass concentrations were different from those measured in the weekday. It is expected that this study can help to understand the relationship between carbonaceous aerosols in a metropolitan area.

산성 에어로졸과 미세탄소 입자에 의한 도시지역 시정감쇄 (Visibility Impairment by Acidic Aerosol & Carbonaceous Particles in Urban Atmosphere)

  • 김경원;오승진;김영준;김문옥
    • 한국대기환경학회:학술대회논문집
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    • 한국대기환경학회 1999년도 추계학술대회 논문집
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    • pp.65-66
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    • 1999
  • 도시지역의 시정변화는 일정한 경향성을 지니는 일부 오염물질들의 배출에 의해 지배적인 영향을 받는 것으로 보고되고 있다. Sulfate, nitrate는 대기중의 상대습도와 밀접한 관계를 지니고 있어서, 일일주기로 증감하는 수증기와의 반응에 의하여 입자의 크기가 성장ㆍ감소하여 대상물체의 이미지 형성광(image forming light)을 산란시킴으로써 관측자의 시야 경로부터 빛을 이탈시키는 현상을 나타낸다.(중략)

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경유자동차 입자상물질의 휘발성에 대한 실험적 연구 (Experimental Study of Volatility of Diesel Exhaust Particles)

  • Gwon Sun-Park;Lee Gyu-Won;Saito K.;Shinozaki O.;Seto T.
    • 한국대기환경학회:학술대회논문집
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    • 한국대기환경학회 2002년도 춘계학술대회 논문집
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    • pp.229-230
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    • 2002
  • Diesel exhaust particles are mostly sub-micrometer agglomerates composed of carbonaceous primary particles ranging from 10 to 80nm, but contain also adsorbed or condensed hydrocarbons, hydrocarbon derivatives, sulfur compounds, and other materials. If particles are primarily composed of volatile materials, they have different health impacts from solid particles. Thus, the analysis of the volatility of diesel particles is one of an important diesel research area. (omitted)

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황사입자에 의한 미세탄소 입자의 응집 및 흡착 현상 (Agglomeration and Adsorption of Fine Carbonaceous Particles onto Asian Dust Particles.)

  • 김경원;김영준
    • 한국대기환경학회:학술대회논문집
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    • 한국대기환경학회 2002년도 추계학술대회 논문집
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    • pp.341-342
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    • 2002
  • 미세탄소입자는 원소탄소(elemental carbon)와 유기탄소(organic carbon)로 분류할 수 있다. 원소탄소는 불완전연소 과정에 발생하는 검댕(black soot), 원유의 정제과정에 발생하는 흑연(graphite), 자연상태에서 만들어진 다이아몬드의 3가지 형태로 존재한다. 이들 중 대기환경에 영향을 미치는 요소는 검댕입자로서 입경은 l$\mu\textrm{m}$이하이며, 일정한 형태를 지니고 있지 않다. (중략)

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ORGANIC DUST IN THE INTERSTELLAR MEDIUM

  • KWOK, SUN
    • 천문학논총
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    • 제30권2호
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    • pp.155-158
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    • 2015
  • The traditional view of dust in the interstellar medium is that it is made of graphite and silicates. In this paper, we discuss the evidence for complex organics being a major component of interstellar dust. Comparison between astronomical infrared spectra and laboratory spectra of amorphous carbonaceous materials suggests that organics of mixed aromatic-aliphatic structures are widely present in circumstellar, interstellar, and galactic environments. Scenarios for the synthesis of these compounds in the late stages of stellar evolution are presented.