• Asian Journal of Atmospheric Environment
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• v.4 no.3
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• pp.115-140
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• 2010

Great concerns about atmospheric aerosols are attributed to their multiple roles to atmospheric processes. For example, atmospheric aerosols influence global climate, directly by scattering or absorbing solar radiations and indirectly by serving as cloud condensation nuclei. They also have a significant impact on human health and visibility. Many of these effects depend on the size and composition of atmospheric aerosols, and thus detailed information on the physicochemical properties and the distribution of airborne particles is critical to accurately predict their impact on the Earth's climate as well as human health. A single particle analysis technique, named low-Z particle electron probe X-ray microanalysis (low-Z particle EPMA) that can determine the concentration of low-Z elements such as carbon, nitrogen and oxygen in a microscopic volume has been developed. The capability of quantitative analysis of low-Z elements in individual particle allows the characterization of especially important atmospheric particles such as sulfates, nitrates, ammonium, and carbonaceous particles. Furthermore, the diversity and the complicated heterogeneity of atmospheric particles in chemical compositions can be investigated in detail. In this review, the development and methodology of low-Z particle EPMA for the analysis of atmospheric aerosols are introduced. Also, its typical applications for the characterization of various atmospheric particles, i.e., on the chemical compositions, morphologies, the size segregated distributions, and the origins of Asian dust, urban aerosols, indoor aerosols in underground subway station, and Arctic aerosols, are illustrated.

• Journal of Astronomy and Space Sciences
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• v.15 no.1
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• pp.163-174
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• 1998

To study the origin of organic matter in meteorite, terrestrial rocks which contain or-ganic compounds similar to the ones found in carbonaceous chondrites are studied and compared with Muchison meteorite. Hydrocarbon molecules were extracted by benzene and methanol from bituminous coal and oil shale and the extracts were partitioned into aliphatic, aromatic, and polar fractions by silica gel column chromatography. Carbon isotopic ratios in each fractions were analysed by GC-C-IRMS. Molec-ular compound identifications were carried by GC-MS Engine. Bituminous coal and oil shale show the organic compound composition similar to that of meteorite. Oil shale has a wide range of ${\delta}^{13}C,-20.1%_0~-54.4%_0$ compared to bituminous coal, $-25.2%_0~34.3%_0$. Delta values of several molecular compounds in two terrestrial samples are different. They show several distinct distributions in isotopic ratios compared to those of meteorite; Murchison meteorite has a range of ${\delta}^13C\;from\;-13%_0\;to\;+30%_0$. These results provide interpretation for the source and the formation condition of each rock, in particular alteration and migration processes of organic matter. Especially, they show an important clue whether some hydrocarbon molecules observed in meteorite are indigenous or not.

• Journal of Astronomy and Space Sciences
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• v.15 no.1
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• pp.151-162
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• 1998

Infrared absorption spectra of 9 bulk samples and 3 acid residues of meteorites were obtained in the mid-infrared region ($4000~400cm^{-1}$). From the know composition of meteorites studied, the possible absorption modes were investigated. Most bands of bulk samples occur in the region below $1200cm^{-1}$ and they are due to metallic oxides and silicates. The spectra of each group can be distinguished by its own characteristic bands. Acid residues show very distinct features from their bulk samples, and absorp-tion bands due to organic compounds are not evident in their spectra. Quantiative analyses for two carbonaceous (Allende CV3 and Murchison CM2) and one ordinary (Carraweena L3.9) chondrites were performed for the presence of fullerene ($C_{60}$) in the meteorites. We calculated the concentration of $C_{60}$ in the acid residues by curve-fitting the spectra with Gaussian functions. The upper limit of $C_{60}$ concentration in these meteorites appears to be less than an order of a few hundred ppm.

• Water for future
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• v.26 no.3
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• pp.75-85
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• 1993

In this study, reach boundaries in QUAL2E Model were set by the locations of point-waste discharge or tributary input and measured or direct calculated hydrologic factors were used in computation as much as possible. South Platte Experimental River in Colorado, USA was selected as a target river and data collected during September 1991 and January 1992 periods were used for calibration and verification, respectively. Constituents modeled in this study are 5-day carbonaceous biochemical oxygen demand(CBOD$) and dissolved oxygen(DO). The good agreement was obtained between a calculated using this model and observed, less than 5% to DO and about 20% to CBOD$. According to the result of water-quality prediction, experimental river is classified as the 4th category by the criteria of environmental protection agency in the USA in 2001.

• The Bulletin of The Korean Astronomical Society
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• v.41 no.2
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• pp.40.2-40.2
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• 2016

The attenuation of starlight by dust in galactic environments is investigated through models of radiative transfer in a spherical, clumpy interstellar medium (ISM). We show that the attenuation curves are primarily determined by the wavelength dependence of absorption rather than by the underlying extinction (absorption+scattering) curve; the observationally derived attenuation curves cannot constrain a unique extinction curve unless the absorption or scattering efficiency is specified. Attenuation curves consistent with the Calzetti curve are found by assuming the silicate-carbonaceous dust model for the Milky Way (MW), but with the $2175{\AA}$ bump suppressed or absent. The discrepancy between our results and previous work that claimed the Small Magellanic Cloud dust to be the origin of the Calzetti curve is ascribed to the difference in adopted albedos; we use the theoretically calculated albedos whereas the previous ones adopted empirically derived albedos from observations of reflection nebulae. It is found that the model attenuation curves calculated with the MW dust are well represented by a modified Calzetti curve with a varying slope and UV bump strength. The strong correlation between the slope and UV bump strength, as found in star-forming galaxies at 0.5 < z < 2.0, is well reproduced if the abundance of the UV bump carriers is assumed to be 30-40% of that of the MW-dust; radiative transfer effects lead to shallower attenuation curves with weaker UV bumps as the ISM is more clumpy and dustier. We also argue that some of local starburst galaxies have a UV bump in their attenuation curves, albeit very weak.

• The Bulletin of The Korean Astronomical Society
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• v.41 no.2
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• pp.49.1-49.1
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• 2016

Asteroid taxonomy dates back to the mid-1970's and is based mostly on broadband photometric and spectroscopic observations in the visible wavelength. Different taxonomic classes have long been characterized by spectral slope shortward of 0.75 microns and the absorption band in 1 micron, the principal components. In this way, taxonomic classes are grouped and divided into four broad complexes; silicates (S), carbonaceous (C), featureless (X), Vestoids (V), and the end-members that do not fit well within the S, C, X and V complexes. The past decade witnessed an explosion of data due to the advent of large-scale asteroid surveys such as SDSS. The classification scheme has recently been expanded with the analysis of the SDSS 4th Moving Object Catalog (MOC 4) data. However, the boundaries of each complex and subclass are rather ambiguously defined by hand. Furthermore, there are only few studies on asteroid taxonomy using Johnson-Cousins filters, and those were conducted on a small number of objects, with significant uncertainties. In this paper, we present our preliminary results for a new taxonomic classification of asteroids using SMASS, Bus and DeMeo (2014) and the SDSS MOC 4 datasets. This classification scheme is simply represented by a triplet of photometric colors, either in SDSS or in Johnson-Cousins photometric systems.

• Carbon letters
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• v.10 no.3
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• pp.181-189
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• 2009

Activated carbon spheres (ACS) were prepared at different heating rates by carbonization of the resole-type phenolic beads (PB) at $950^{\circ}C$ in $N_2$ atmosphere followed by activation of the resultant char at different temperatures for 5 h in $CO_2$ atmosphere. Influence of heating rate on porosity and temperature on carbon structure and porosity of ACS were investigated. Effect of heating rate and temperature on porosity of ACS was also studied from adsorption isotherms of nitrogen at 77 K using BET method. The results revealed that ACS have exhibited a BET surface area and pore volume greater than $2260\;m^2/g$ and $1.63\;cm^3/g$ respectively. The structural characteristics variation of ACS with different temperature was studied using Raman spectroscopy. The results exhibited that amount of disorganized carbon affects both the pore structure and adsorption properties of ACS. ACS were also evaluated for structural information using Fourier Transform Infrared (FTIR) Spectroscopy. ACS were evaluated for chemical composition using CHNS analysis. The ACS prepared different temperatures became more carbonaceous material compared to carbonized material. ACS have possessed well-developed pores structure which were verified by Scanning Electron Microscopy (SEM). SEM micrographs also exhibited that ACS have possessed well-developed micro- and meso-pores structure and the pore size of ACS increased with increasing activation temperature.

• Journal of Environmental Science International
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• v.20 no.2
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• pp.215-222
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• 2011

The adsorption behavior of nitrate nitrogen was investigated from aqueous solution using char prepared from oak chip. The removal rate of nitrate nitrogen was found to be dependent on temperature and it is increased as the temperature increase. Adsorption equilibrium data of nitrate nitrogen on oak char. reasonably fitted Langmuir and Freundlich isotherm models. The adsorption energy obtained from D-R model was 12.5 kJ/mole at $20^{\circ}C$ indicating an ion exchange process as primary adsorption mechanism. Thermodynamic parameters such as ${\Delta}G^o$, ${\Delta}H^o$, and ${\Delta}S^o$ were -23.76 kJ/mole, 26.1 kJ/mole and 89.7 J/K mole at $20^{\circ}C$, respectively, indicated that the nature of nitrate nitrogen adsorption is spontaneous and endothermic.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.35 no.12
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• pp.1317-1324
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• 2011

We propose a method operated in a vehicle to measure light absorption of particles in atmosphere. The advantage of this method is that it is insensitive to light scattering and hence can be used for the direct measurement of the light absorption coefficient without suffering from light scattering. With this method atmospheric light absorption can be measured at a time constant of 10 s. Further, our method allows for the real-time measurement of light absorption near a highway. The light absorption coefficients were high near a race track, an airport and the main gate where vehicles emitted carbonaceous particles.

• Proceedings of the KIEE Conference
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• 1999.11d
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• pp.860-862
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• 1999

we have grown vertically aligned carbon nanotubes on a large area of Co-Ni codeposited Si substrates by thermal chemical vapor deposition using $C_{2}H_{2}$ gas. The carbon nanotubes grown by the thermal chemical vapor deposition are multi-wall structure, and the wall solace of nanotubes is covered with defective carbons or carbonaceous particles. The carbon nanotubes range from 50 to 120nm in diameter and about $130{\mu}m$ in length at $950^{\circ}C$. The turn-on voltage was about $0.8V/{\mu}m$ with a current density of $0.1{\mu}A/cm^2$ and emission current reveals the Fowler-Nordheim mode.