• Title/Summary/Keyword: carbon structures

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On the mechanics of nanocomposites reinforced by wavy/defected/aggregated nanotubes

  • Heidari, Farshad;Taheri, Keivan;Sheybani, Mehrdad;Janghorban, Maziar;Tounsi, Abdelouahed
    • Steel and Composite Structures
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    • v.38 no.5
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    • pp.533-545
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    • 2021
  • What is desirable in engineering is to bring the engineering model as close to reality as possible while the simplicity of model is also considered. In recent years, several studies have been performed on nanocomposites but some of these studies are somewhat far from reality. For example, in many of these studies, the carbon nanotubes (CNTs) are assumed completely straight, flawless and uniformly distributed throughout the matrix but by studying nanocomposites, we find that this is not the case. In this paper, three steps have been taken to bring the presented models for nanocomposites closer to reality. One is that assuming the straightness of nanotubes is removed and the waviness is considered. Also, the nanotubes are not considered to be pristine and the influence of defect is included in accordance with reality. In addition, the approximation of uniform distribution of nanotubes is ignored and according to experimental observations, the effect of nanotube aggregation is considered. As far as we know, this is the first study on these three topics together in an article. Moreover, we also include the size effects in our models for nanocomposites. To show the accuracy of our models, our results are calibrated with experimental results and compared with theoretical model. For numerical examples, we present the buckling behaviors of nanocomposites including the size effects using nonlocal theory and compare the results of our models with the results of models with above-mentioned approximations.

Electron Transfer to Hydroxylase through Component Interactions in Soluble Methane Monooxygenase

  • Lee, Chaemin;Hwang, Yunha;Kang, Hyun Goo;Lee, Seung Jae
    • Journal of Microbiology and Biotechnology
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    • v.32 no.3
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    • pp.287-293
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    • 2022
  • The hydroxylation of methane (CH4) is crucial to the field of environmental microbiology, owing to the heat capacity of methane, which is much higher than that of carbon dioxide (CO2). Soluble methane monooxygenase (sMMO), a member of the bacterial multicomponent monooxygenase (BMM) superfamily, is essential for the hydroxylation of specific substrates, including hydroxylase (MMOH), regulatory component (MMOB), and reductase (MMOR). The diiron active site positioned in the MMOH α-subunit is reduced through the interaction of MMOR in the catalytic cycle. The electron transfer pathway, however, is not yet fully understood due to the absence of complex structures with reductases. A type II methanotroph, Methylosinus sporium 5, successfully expressed sMMO and hydroxylase, which were purified for the study of the mechanisms. Studies on the MMOH-MMOB interaction have demonstrated that Tyr76 and Trp78 induce hydrophobic interactions through π-π stacking. Structural analysis and sequencing of the ferredoxin domain in MMOR (MMOR-Fd) suggested that Tyr93 and Tyr95 could be key residues for electron transfer. Mutational studies of these residues have shown that the concentrations of flavin adenine dinucleotide (FAD) and iron ions are changed. The measurements of dissociation constants (Kds) between hydroxylase and mutated reductases confirmed that the binding affinities were not significantly changed, although the specific enzyme activities were significantly reduced by MMOR-Y93A. This result shows that Tyr93 could be a crucial residue for the electron transfer route at the interface between hydroxylase and reductase.

Compliance Validation Method of UAM Composite Part Manufacturing System based on Composite Material Qualification System (복합재료인증체계를 통한 UAM 용 복합재료 부분품 인증 적합성 확인 방안)

  • Cho, Sung-In;Yang, Yong Man;Jung, Seok-Ho;Kim, Je-Jun
    • Journal of Aerospace System Engineering
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    • v.16 no.3
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    • pp.35-41
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    • 2022
  • UAM (Urban Air Mobility) is a new safe, secure, and more sustainable air transportation system for passengers and cargo in urban environments. Commercial operations of UAM are expected to start in 2025. Since production rates of UAM are expected to be closer to cars than conventional aircraft, the airworthiness methodology for UAM must be prepared for mass production. Composite materials are expected to be mainly used for UAM structures to reduce weight. In this paper, the composite material qualification method was derived and the materials were applied for small aircraft application. It is expected to reduce the airworthiness certification time by applying composite material qualification system and its database.

Seismic response of NFRP reinforced RC frame with shape memory alloy components

  • Varkani, Mohamad Motalebi;Bidgoli, Mahmood Rabani;Mazaheri, Hamid
    • Advances in nano research
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    • v.13 no.3
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    • pp.285-295
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    • 2022
  • Creation of plastic deformation under seismic loads, is one of the most serious subjects in RC structures with steel bars which reduces the life threatening risks and increases dissipation of energy. Shape memory alloy (SMA) is one of the best choice for the relocating plastic hinges. In a challenge to study the seismic response of concrete moment resisting frame (MRF), this article investigates numerically a new type of concrete frames with nano fiber reinforced polymer (NFRP) and shape memory alloy (SMA) hinges, simultaneously. The NFRP layer is containing carbon nanofibers with agglomeration based on Mori-Tanaka model. The tangential shear deformation (TASDT) is applied for modelling of the structure and the continuity boundary conditions are used for coupling of the motion equations. In SMA connections between beam and columns, since there is phase transformation, hence, the motion equations of the structure are coupled with kinetic equations of phase transformation. The Hernandez-Lagoudas theory is applied for demonstrating of pseudoelastic characteristics of SMA. The corresponding motion equations are solved by differential cubature (DC) and Newmark methods in order to obtain the peak ground acceleration (PGA) and residual drift ratio for MRF-2%. The main impact of this paper is to present the influences of the volume percent and agglomeration of nanofibers, thickness and length of the concrete frame, SMA material and NFRP layer on the PGA and drift ratio. The numerical results revealed that the with increasing the volume percent of nanofibers, the PGA is enhanced and the residual drift ratio is reduced. It is also worth to mention that PGA of concrete frame with NFRP layer containing 2% nanofibers is approximately equal to the concrete frame with steel bars.

Prediction of Failure Behavior for Carbon Fiber Reinforced Composite Bolted Joints using Progressive Failure Analysis (점진적 파손해석을 이용한 탄소섬유강화 복합재료 볼트 조인트의 파손거동 예측)

  • Yoon, Donghyun;Kim, Sangdeok;Kim, Jaehoon;Doh, Youngdae
    • Composites Research
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    • v.34 no.2
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    • pp.101-107
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    • 2021
  • Composite structures have components and joints. Theses connections or joints can be potentially weak points in the structure. The failure mode of the composite bolted joint is designed as a bearing failure mode for structural safety. The load-displacement relation exhibits bearing failure mode shows a nonlinear behavior after the initial failure and progressive failure behavior. In order to accurately predict the failure behavior of composite bolted joints, this study modified the shear damage variable calculation process in the existing progressive failure analysis model. The results of the bearing stress-bearing strain of the composite bolted joint were predicted using the modified progressive failure analysis model, and the modified model was verified through comparison with the previous progressive analysis model.

Analytical investigation of the cyclic behaviour of I-shaped steel beam with reinforced web using bonded CFRP

  • Mohabeddine, Anis I.;Eshaghi, Cyrus;Correia, Jose A.F.O.;Castro, Jose M.
    • Steel and Composite Structures
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    • v.43 no.4
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    • pp.447-456
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    • 2022
  • Recent experimental studies showed that deep steel I-shaped profiles classified as high ductility class sections in seismic design international codes exhibit low deformation capacity when subjected to cyclic loading. This paper presents an innovative retrofit solution to increase the rotation capacity of beams using bonded carbon fiber reinforced polymers (CFRP) patches validated with advanced finite element analysis. This investigation focuses on the flexural cyclic behaviour of I-shaped hot rolled steel deep section used as beams in moment-resisting frames (MRF) retrofitted with CFRP patches on the web. The main goal of this CFRP reinforcement is to increase the rotation capacity of the member without increasing the overstrength in order to avoid compromising the strong column-weak beam condition in MRF. A finite element model that simulates the cyclic plasticity behavior of the steel and the damage in the adhesive layer is developed. The damage is modelled using the cohesive zone modelling (CZM) technique that is able to capture the crack initiation and propagation. Details on the modelling techniques including the mesh sensitivity near the fracture zone are presented. The effectiveness of the retrofit solution depends strongly on the selection of the appropriate adhesive. Different adhesive types are investigated where the CZM parameters are calibrated from high fidelity fracture mechanics tests that are thoroughly validated in the literature. This includes a rigid adhesive commonly found in the construction industry and two tough adhesives used in the automotive industry. The results revealed that the CFRP patch can increase the rotation capacity of a steel member considerably when using tough adhesives.

Effects of Reaction pH and Hardener Type on Reactivity, Properties, and Performance of Urea-Formaldehyde (UF) Resin

  • Park, Byung-Dae;Kim, Yoon Soo;So, Won Tek;Lim, Kie Pyo
    • Journal of the Korean Wood Science and Technology
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    • v.30 no.3
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    • pp.1-11
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    • 2002
  • This study was conducted to investigate the effects of reaction pH conditions and hardener types on the reactivity, chemical structure and adhesion performance of UF resins. Three different reaction pH conditions, such as traditional alkaline-acid (7.5 → 4.5), weak acid (4.5), and strong acid (1.0), were used to synthesize UF resins which were cured by adding three different hardeners (ammonium chloride, ammonium citrate, and zinc nitrate) to measure adhesion strength. Fourier transform infrared (FT-IR) and carbon-13 nuclear magnetic resonance (13C-NMR) spectroscopies were employed to study chemical structure of the resin prepared under three different reaction pH conditions. Adhesion strength of the resins cured with three different hardeners was determined with lap shear specimens in tension. The gel time of UF resins decreased with an increasing in the amount of both ammonium chloride and ammonium citrate added in the resins. However, the gel time increased for zinc nitrate. Both FT-IR and 13C-NMR spectroscopies showed that the strong reaction pH condition produce uronic structures in UF resin, while both alkaline-acid and weak acid conditions produce quite similar chemical species in the resins. The maximum adhesion strength was occurred with the resin prepared under strong acid pH condition. However, this study indicated that the weak acid reaction condition provide a balance between increasing resin reactivity and improving adhesion strength of UF resin. The measurement of formaldehyde emission from the panels bonded with the UF resins prepared is planned for future work.

Effectiveness study of a cement mortar coating based on dune sand on the carbonation of concrete

  • Korichi, Youssef;Merah, Ahmed;Khenfer, Med Mouldi;Krobba, Benharzallah
    • Advances in concrete construction
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    • v.13 no.4
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    • pp.315-325
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    • 2022
  • Reinforced concrete structures are exposed throughout their lifetime to the phenomenon of carbonation, which considerably influences their durability by causing corrosion of the reinforcements. The fight against this phenomenon is usually ensured by anti-carbonation coatings which have the possibility of limiting the permeability to carbon dioxide or with coatings which absorb the CO2 present in the air. A coating with good crack-bridging (sealing) capacity will prevent water from entering through existing cracks in concrete. Despite the beneficial effect of these coatings, their durability decreases considerably over time with temperature and humidity. In order to use coatings made from local materials, not presenting any danger, available in abundance in our country, very economical and easy to operate is the main objective of this work. This paper aim is to contribute to the formulation of a corrected dune sand-based mortar as an anti-carbonation coating for concrete. The results obtained show that the cement mortar based on dune sand formulated has a very satisfactory compressive strength, a very low water porosity compared to ordinary cement mortar and that this mortar allows an improvement in the protection of the concrete against the carbonation of 60% compared to ordinary cement mortar based on alluvial sand. Moreover, the formulated cement mortars based on dune sand have good adhesion to the concrete support, their adhesion strengths are greater than 1.5MPa recommended by the standards.

Flexural response of steel beams strengthened by fibre-reinforced plastic plate and fire retardant coating at elevated temperatures

  • Ahmed, Alim Al Ayub;Kharnoob, Majid M.;Akhmadeev, Ravil;Sevbitov, Andrei;Jalil, Abduladheem Turki;Kadhim, Mustafa M.;Hansh, Zahra J.;Mustafa, Yasser Fakri;Akhmadullina, Irina
    • Structural Engineering and Mechanics
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    • v.83 no.4
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    • pp.551-561
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    • 2022
  • In this paper, the effect of fire conditions according to ISO 834 standard on the behavior of carbon fibre-reinforced plastic (CFRP) reinforced steel beams coated with gypsum-based mortar has been investigated numerically. To study the efficiency of these beams, 3D coupled temperature-displacement finite element analyzes have been conducted. Mechanical and thermal characteristics of three different parts of composite beams, i.e., steel, CFRP plate, and fireproof coating, were considered as a function of temperature. The interaction between steel and CFRP plate has been simulated employing the adhesion model. The effect of temperature, CFRP plate reinforcement, and the fireproof coating thickness on the deformation of the beams have been analyzed. The results showed that within the first 120 min of fire exposure, increasing the thickness of the fireproof coating from 1 mm to 10 mm reduced the maximum temperature of the outer surface of the steel beam from 380℃ to 270℃. This increase in the thickness of the fireproof layer decreased the rate of growth in the temperature of the steel beam by approximately 30%. Besides excellent thermal resistance and gypsum-based mortar, the studied fireproof coating method could provide better fire resistance for steel structures and thus can be applied to building materials.

A Study on the Performance Evaluation of CNC Control Units of an Old Planar Miller Using Remanufacturing Technology (재제조 기술을 이용한 노후 플래너 밀러의 CNC 제어 장치 성능평가에 관한 연구)

  • Lee, Seong-Won;Chung, Won-Ji;Roh, Young-Hwa;Kong, Seok-Hwan;Lee, Hyun-Jun;Kim, Jin-Woo
    • Journal of the Korean Society of Industry Convergence
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    • v.25 no.6_2
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    • pp.1097-1102
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    • 2022
  • With the continuous development of the current industry, the current global environment is in a very serious situation, with resource supply and demand dependent on imports and huge costs for waste disposal due to the depletion of resources and mass generation of industrial waste. Its limitations have already been revealed in many fields, and the importance of re-manufacturing is drawing attention as a countermeasure to these problems. Re-manufacturing aims to recover products that are in the aging and disposal stages, recover to performance close to new products, and re-commercialize them. Among them, most of the machine tools are made of materials such as steel and cast iron with large structures, and raw materials are widely used when producing new products. In addition, since a lot of carbon is generated due to production, it is an object that can obtain a great re-manufacturing effect. Planner millers belonging to large machine tools are one of the machine tool equipment that can greatly reduce resources and energy through re-manufacturing because the structure is very large and the casting is several to tens of tons. Through this machine tool, performance tests and results are derived on the development of re-manufacturing source technology and domestic servo motor and CNC control device.