• 전기화학회지
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• 제10권4호
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• pp.252-256
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• 2007

A series of spherical porous carbons were prepared via resorcinol-formaldehyde (RF) sol-gel polymerization in the presence of cationic surfactant (CTAB, cetyltrimethylammonium bromide), wherein the carbon sphere size was controlled by varying the CTAB introduction time after a pre-determined period of addition reaction (termed as "pre-curing"). The sphere size gradually decreases with an increase in the pre-curing time within the range of 30-150 nm. The carbons possess two types of pores; one inside carbon spheres (intra-particle pores) and the other at the interstitial sites made by carbon spheres (inter-particle pores). Of the two, the surface exposed on the former was dominant to determine the electric double-layer capacitor (EDLC) performance of porous carbons. As the intra-particle pores were generated inside RF gel spheres by gasification, the pore diameter was similar for all these carbons, thereby the pore length turned out to be a decisive factor controlling the EDLC performance. The charge-discharge voltage profiles and complex capacitance analysis consistently illustrate that the smaller-sized RF carbons deliver a better rate capability, which must be the direct result of facilitated ion penetration into shorter pores.

• 한국해양바이오학회지
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• 제2권1호
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• pp.55-59
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• 2007

The oil and concentrated protein powder from squid viscera was extracted and recovered by a semi-batch supercritical carbon dioxide ($SCO_2$) extraction system and the degree of oxidation in the extracted oil was measured in order to compare with extracted oils using organic solvents. The degree of storage in treated squid viscera by $SCO_2$ extraction was measured in order to compare with untreated squid viscera. As results obtained, it was found that the auto-oxidation of the oils using $SCO_2$ extraction occurred very slowly compared to the oils by organic solvent extraction. And the treated squid viscera by $SCO_2$ extraction was reached the point of initial rottenness slowly than untreated squid viscera.

• 한국분말재료학회지
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• 제11권4호
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• pp.279-287
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• 2004

탄소재료는 결정구조에 따라 카본블랙(carbon black), 그라파이트(graphite), 탄소섬유(carbon fiber) 등 다양한 형태가 있으며 그 응용 또한 광범위하다. 이는 탄소재료가 화학적으로 매우 안정하고, 열 및 전기전도성이 우수하며, 기계적인 특성면에서도 고강도, 고탄성율을 가지고 있어서 구조적으로 안정하기 때문이다. 특히 $C_{60}$(fullerene)와 탄소나노튜브(carbon naotube : CNT)등 근래 새로이 발견된 탄소물질들$^{1.2)}$ 은 그 독특한 결정구조와 성질로 인해 다양한 분야의 응용이 예상된다.

• Carbon letters
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• 제12권4호
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• pp.236-242
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• 2011

The oxyfluorination effects of activated carbon nanofibers (OFACFs) were investigated for $CO_2$ storage. Electrospun CFs were prepared from a polyacrylonitrile/N,N-dimethylformamide solution via electrospinning and heat treatment. The electrospun CFs were chemically activated in order to generate the pore structure, and then oxyfluorination was used to modify the surface. The samples were labeled CF (electrospun CF), ACF (activated CF), OFACF-1 ($O_2:F_2$ = 7:3), OFACF-2 ($O_2:F_2$ = 5:5) and OFACF-3 ($O_2:F_2$ = 3:7). The functional group of OFACFs was investigated using X-ray photoelectron spectroscopy analysis. The C-F bonds formed on surface of ACFs. The intensities of the C-O peaks increased after oxyfluorination and increased the oxygen content in the reaction gas. The specific surface area, pore volume and pore size of OFACFs were calculated by the Brunauer-Emmett-Teller and density functional theory equation. Through the $N_2$ adsorption isotherm, the specific surface area and pore volume slightly decreased as a result of oxyfluorination treatment. Nevertheless, the $CO_2$ adsorption efficiency of oxyfluorinated ACF improved around 16 wt% due to the semi-ionic interaction effect of surface modificated oxygen functional groups and $CO_2$ molecules.

• 한국가스학회지
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• 제18권5호
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• pp.26-32
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• 2014

CCS(Carbon Capture and Storage)는 제철, 철강, 발전소 등에서 발생되는 $CO_2$를 포집 및 저장하는 기술로서, 지구 온난화의 주범인 $CO_2$를 감축시키는 효과적인 기술이다. CCS 포집 기술과 저장 기술은 집중적인 개발을 도모하고 있으며, 현재 실증단계에 있다. 그러나 상용화 단계에 이르기 위해서는 포집, 저장 기술을 비롯하여 수송기술까지도 구성 요소에 대한 안전성 확보가 필요하다. 특히, 수송기술은 CCS 특성상 파이프라인을 이용한 수송기술이 적합하지만, $CO_2$ 파이프라인 운용 사례가 부족하여, 파이프라인 또는 구성 요소(밸브 등)에 대한 적합한 재질을 선택해야 한다. 본 연구에서는 $CO_2$ 파이프라인에 사용 가능한 고무재질을 알아보고자 여러 분야에서 사용되는 고무 재질을 $CO_2$에 침지하여 압력 온도 변화에 따른 부피변화를 비교 분석 하였다.

• 임산에너지
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• 제23권2호
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• pp.1-8
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• 2004

본 연구는 강원도 홍천군 운두령 일대에 설치된 잣나무 등 6개소 생장고정조사구를 대상으로 생장변화를 구명하고, 탄소저장량 및 흡수량을 산정하여 운두령 산림관리에 기초적인 자료를 제공하고자 하였다. 임분생장변화는 유령림인 잣나무와 낙엽송 임분에서 연년수고생장과 흉고직경생장이 점진적으로 진행되었으며, 그 외 임분은 이들보다는 생장율이 낮은 것으로 나타났다. 직경급 분포 및 직경변화 예측에 있어서 신갈나무와 혼효림에서의 직경급분포는 현재와 유사할 것으로 예측되며, 잣나무와 낙엽송 등은 유령림인 관계로 비대생장 속도가 빨라 대다수의 현재 직경급이 상위경급으로 이동할 것이 예측되었다. 2003년도말 현재 운두령 모델림내의 총탄소량은 전년에 비해 $2.7\%$인 149,000탄소톤 증가하였으며, 임상별로 보면 활엽수가 $50\%$, 흔효림 $34\%$, 침엽수림 $16\%$ 순이었다. 2003년도 한 해 동안 산림의 생장에 의해 흡수${\cdot}$저장한 총탄소량은 156,813탄소톤이며, 순탄소흡수량은 148,664탄소톤으로 전년 대비 2.613탄소톤$(1.8\%)$이 증가하였다. 임상별로는 침엽수림$(3.3\%)$, 흔효림$(3.1\%)$, 활엽수림$(2.8\%)$ 순으로 나타났다. 결과적으로 운두령모델림은 온실가스 측면에서 볼 때 순흡수원으로 작용하고 있으며, 그 순흡수량도 최근 조금씩 늘어나고 있는 경향을 보이고 있다.

• 전력전자학회:학술대회논문집
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• 전력전자학회 2014년도 추계학술대회 논문집
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• pp.93-94
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• 2014

본 논문의 주제는 가파도 마이크로 그리드에 적용한 1MVA급 배터리 에너지 저장시스템(BESS-Battery Energy Storage System)을 소개하는 것이다. 에너지 저장장치가 디젤발전기와의 연계 및 독립운전 하여 탄소 배출 없이(Carbon-Free) 가파도 전체 부하에 전원을 공급하는 실증 사례를 살핀다.

• 대한화학회지
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• 제59권5호
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• pp.429-433
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• 2015

The binding ability and hydrogen storage capacity of nitrogen doped carbon nanotube with divacancy (4NDCN_xNT) that is decorated with transition metals was investigated based on density functional theory calculations. Results indicate that scandium shows an ideal reversible hydrogen binding capability with promising system-weight efficiency compared with other transition metals when functionalized with 4ND-CN_xNT. The (Sc/4ND)₁₀-CN_xNT can store up to 50H₂ molecules, corresponding to a maximum gravimetric density of 5.8 wt%. Detailed structural stability and electronic properties were reported as hydrogen molecules were absorbed. It takes about 0.16 eV/H₂ to add one H₂ molecule, which assures reversible storage of H₂ molecules under ambient conditions.

• 정보저장시스템학회논문집
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• 제10권1호
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• pp.14-18
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• 2014

Adhesion between carbon nanotube (CNT) arrays is measured and characterized for number of different contact areas. The CNT arrays are directly grown on an electrostatic microactuator, and they make contact with each other during the growth process. The pull-out force is precisely applied by the microactuator while the contact status is identified by measuring electrical resistance between the CNT arrays. We have designed different contact areas of 1000, 6000, and 8500 ${\mu}m^2$ between the CNT arrays, and the corresponding adhesion increases from 0.9 to 3.7 ${\mu}N$ as the contact area increases.

• 정보저장시스템학회논문집
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• 제9권2호
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• pp.36-41
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• 2013

Frictional behavior of a single carbon nanotube(CNT) was investigated using molecular dynamics simulation. A single CNT aligned horizontally on silver or graphene substrate was modeled to evaluate its frictional behavior such as frictional force and rolling/sliding motion with respect to potential parameter and lattice structure of the substrate. As a result, it was found that friction and rolling was affected by adhesion between two surfaces and period of the rolling depended on lattice distance of the substrate.