• Title/Summary/Keyword: carbon effect

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Effect of Carbon on the Coefficient of Thermal Expansion of As-Cast Fe-3 0 wt.%Ni-12.5wt.% Co-xC Invar Alloys

  • 김봉서;유경재;김병걸;이희웅
    • Transactions of Materials Processing
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    • v.8 no.3
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    • pp.247-247
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    • 1999
  • The segregation (distribution) of nickel and the composition of its constituents influence the low thermal expansion characteristics (Invar effect) in Fe-30 wt.% Ni-12.5 wt.% Co-xC Invar alloy. The change of coefficient of the thermal expansion and magnetic properties were studied as an aspect of carbon addition causing the segregation of Ni in primary austenite of as-cast Fe-30 wt.% Ni-12.5 wt.% Co Invar alloy. The coefficient of thermal expansion of Fe-30 wt.% Ni-12.5 wt.% Co-xC Invar alloy showed its lowest value at 0.08 wt.% carbon, increased with increasing carbon content in the range of 0.08-1.0 wt.%C, kept constant at 1.0-2.0 wt.%C and decreased at carbon higher than 2.0 wt.%. The effective distribution of the coefficient of nickel in as-cast Fe-30 wt.% Ni-12.5 wt.% Co-xC Invar alloy increased with increasing carbon content. The volume fraction of they phase of Fe-30 wt.% Ni-12.5 wt.% Co-xC alloy increased with increasing carbon content. The microstructure of Fe-30 wt.% Ni-12.5 wt.% Co-xC alloy changed with the carbon content was independent of the coefficient of thermal expansion. The Curie temperature changed linearly with the carbon content and was similar to the change of the coefficient of thermal expansion. Moreover, the coefficient of thermal expansion decreased when the ratio of saturation magnetization to Curie temperature ($\sigma_s/T_c$) increased, decreasing the Curie temperature and showed a specific relationship with the magnetic properties of the Fe-30 wt.% Ni-12.5 wt.% Co-xCInvar alloy.

An Experimental Study on the Development of Electro Magnetic Pulse Shielding Cement Using Milled Carbon Fiber (저 직경 카본섬유를 사용한 전자기 펄스 차폐 시멘트 개발에 관한 실험적 연구)

  • Min, Tae-Beom
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.8 no.4
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    • pp.429-435
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    • 2020
  • In this study, physical properties and EMP shielding performance evaluation of cement paste according to the amount of milled carbon fiber was conducted to develop EMP shielding cement using carbon fiber. The length of the milled carbon fiber used was 100㎛, and it was used as a cement admixture because it showed a powdery form to the naked eye. As a result of the experiment, when 5% of the amount of cement was used, the milled carbon fiber was effective in compressive strength and EMP shielding, and the shielding effect did not increase when used beyond that. As a result of examining the EMP shielding performance according to the thickness of the specimen, the plain without milled carbon fiber had no effect of increasing the shielding rate according to the thickness. The shielding performance of the specimens using the milled carbon fiber increased as the thickness increased. Therefore, in order to increase the EMP shielding rate when comparing and evaluating the performance according to the amount of milled carbon fiber used and the thickness of the specimen, 5% of the milled carbon fiber used is optimal. In addition, the method of increasing the thickness is considered to be effective.

Flexural evaluation of Textile Reinforced Concrete Panel (TRC) with mesh pre-stretching effect

  • Rose Dayaana Amran;Irvin Liow Jun Ann;Geok Wen Leong;Chee Ghuan Tan;Kim Hung Mo;Kok Seng Lim;Fadzli Mohamed Nazri
    • Advances in concrete construction
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    • v.17 no.3
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    • pp.127-133
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    • 2024
  • Textile reinforced concrete (TRC) has gained attention as a viable alternative to conventional reinforced concrete due to its improved mechanical properties and design adaptability. Despite significant research into the mechanical properties of TRC, studies regarding the flexural effect of pre-stretching with different numbers of textile reinforcements are currently limited. Therefore, this research focuses on assessing the flexural characteristics of TRC panels with the incorporation of mesh pre-stretching. Additionally, the study compares the flexural behaviour between alkali-resistant (AR) glass fibre TRC and carbon fibre TRC. A three-point bending test was conducted to assess the flexural behaviour of TRC, investigating the impact of the number of textile layers and the application of pre-stretching on flexural strength and post-cracking stiffness. The findings, exhibited by the flexural stress vs. displacement curve, indicate that applying pre-stretching to carbon fibre TRC effectively increases the flexural strength of carbon textiles and enhances post-cracking stiffness. Moreover, the greater the number of carbon textiles, the higher the flexural stress of the specimens, provided the textiles are placed in the tensile zone. Nevertheless, when comparing carbon fibre TRC with AR glass fibre TRC, it is found that the increase in flexural strength is more significant for carbon fibre TRC. Overall, applying pre-stretching to carbon fibre significantly improves the TRC's flexural performance, specifically during the post-cracking stage and in crack distribution. Furthermore, due to the higher elastic modulus and tensile strength of carbon fibre, TRC reinforced with carbon textiles shows greater flexural strength and ductility compared to AR glass fibre TRC.

Compensation of Aethalometer Black Carbon Data Observed at a Gwangju Site (광주 도심지역에서 측정한 Aethalometer 검댕입자 자료의 보정)

  • Park, Seung-Shik;Jung, Jung-H.;Cho, Sung-Y.;Kim, Seung-Jai
    • Journal of Korean Society for Atmospheric Environment
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    • v.25 no.6
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    • pp.571-578
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    • 2009
  • $PM_{2.5}$ black carbon (BC) concentrations were measured to investigate the filter spot loading effect in raw BC data at 5-minute time-based resolution using a single-wavelength aethalometer at a Gwangju site. Also the elemental carbon (EC) concentrations from 24-hr integrated filter-based measurements of $PM_{2.5}$ particles were determined to compare with the loading compensated BC values. Close examination of the time-series BC data showed clearly the "gaps" when the filter tape advances, suggesting the correction of raw BC data. Therefore, we calculated the average BC concentration in each range of attenuation (ATN) to decide if there was (or was not) an effect on the aethalometer data according to the loading of the filter spot. A consistent decrease of average BC concentration was found with increasing ATN values for every month, suggesting there was a consistent "spot loading effect" in the raw BC data. The loading compensated BC concentration according to a simple compensation model with loading effect was 1.01~1.15 times greater than the raw BC data. The 24-hr average concentration of EC observed during summer sampling period was about 3% higher than the original 24-hr average BC value and 2% lower than the loading compensated BC concentration.

Effect of O2 Plasma Treatments of Carbon Supports on Pt-Ru Electrocatalysts

  • Park, Soo-Jin;Park, Jeong-Min;Seo, Min-Kang
    • Bulletin of the Korean Chemical Society
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    • v.31 no.2
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    • pp.331-334
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    • 2010
  • In the present study, carbon supports mixed with purified multi-walled carbon nanotubes (MWNTs) and carbon blacks (CBs) were used to improve the cell performance of direct methanol fuel cells (DMFCs). Additionally, the effect of $O_2$ plasma treatment on CBs/MWNTs supports was investigated for different plasma RF powers of 100, 200, and 300 W. The surface and structural properties of the CBs/MWNTs supports were characterized by FT-IR, X-ray photoelectron spectroscopy (XPS), X-ray diffraction (XRD), and inductive coupled plasma-mass spectrometer (ICP-MS). The electrocatalytic activity of PtRu/CBs/MWNTs catalysts was investigated by cyclic voltammetry measurement. In the experimental results, the oxygen functional groups of the supports were increased with increasing plasma RF power, while the average Pt particle size was decreased owing to the improvement of dispersibility of the catalysts. The electrochemical activity of the catalysts for methanol oxidation was gradually improved by the larger available active surface area, itself due to the introduction of oxygen functional groups. Consequently, it was found that $O_2$ plasma treatments could influence the surface properties of the carbon supports, resulting in enhanced electrocatalytic activity of the catalysts for DMFCs.

Screen-printed carbonaceous matrrials for photocapacitor electrode (스크린 프린터에 의한 광캐패시터용 카본 전극 제작)

  • Choi, Woo-Jin;Kwak, Dong-Joo;Sung, Youl-Moon;Ha, Soon-Ho
    • Proceedings of the Korean Institute of IIIuminating and Electrical Installation Engineers Conference
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    • 2009.10a
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    • pp.411-414
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    • 2009
  • Photo-capacitor electrodes are attracting great attention because of their high capacitance and potential applications in electronic devices. Carbon capacitor, active carbon capacitor and its combination will be fabricated using simple sandwich capacitor electrode method as carbonaceous material on each type of capacitor electrodes with 20 ${\times}$ 15 mm cell size. Carbon/active carbon cell was fabricated using sol-gel process with 120oC dry temperature in l hour and using sintering process with 500oC in 2 hour. The effect of sintering temperature on carbon properties was also investigated with X-ray diffraction technique to get the best sintering temperature. The detail of fabrication process will be explained. Elemental composition in electrode material can be measured using quantitative spectroscopic as and a cyclic voltammetric technique was used to study the combined effects of electrode material and effect of annealing temperature and also time on the capacitance of thermally treated in capacitor electrode. In this work, characterization impedance technique is used to measurement of capacitance and giving complementary results. Active carbon as carbonaceous material has a better capacitance in charge/discharge process with mean thickness $32{\mu}m$ and with particle size $1{\mu}m$ to $4.5{\mu}m$ in 20 ${\times}$ 15 mm sample size of capacitor electrode.

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Nondestructive Damage Sensitivity of Carbon Nanotube and Nanofiber/Epoxy Composites Using Electro-Micromechanical Technique and Acoustic Emission (Electro-Micromechanical 시험법과 음향방출을 이용한 탄소 나노튜브와 나노섬유 강화 에폭시 복합재료의 비파괴적 손상 감지능)

  • Kim, Dae-Sik;Park, Joung-Man;Lee, Jae-Rock;Kim, Tae-Wook
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 2003.04a
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    • pp.117-120
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    • 2003
  • Electro-micromechanical techniques were applied using four-probe method for carbon nanotube (CNT) or nanofiber (CNF)/epoxy composites with their content. Carbon black (CB) was used to compare with CNT and CNF. The fracture of carbon fiber was detected by nondestructive acoustic emission (AE) relating to electrical resistivity for double-matrix composites test. Sensing for fiber tension was performed by electro-pullout test under uniform cyclic strain. The sensitivity for fiber damage such as fiber fracture and fiber tension was the highest for CNT/epoxy composites, and in CB case they were the lowest compared with CNT and CNF. Reinforcing effect of CNT obtained from apparent modulus measurement was the highest in the same content. The results obtained from sensing fiber damage were correlated with the morphological observation of nano-scale structure using FE-SEM. The information on fiber damage and matrix deformation and reinforcing effect of carbon nanocomposites could be obtained from electrical resistivity measurement as a new concept of nondestructive evaluation.

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Effect of Carbon Dioxide in the Air on Zinc-air Cell (대기중의 이산화탄소가 공기-아연전지에 미치는 영향)

  • Kim, Nam-In;Park, Ki-Hong;Choi, Yong-Kook;Lee, Woo-Tae
    • Applied Chemistry for Engineering
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    • v.10 no.2
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    • pp.177-182
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    • 1999
  • The electrolyte was brought into contact with air and potassium carbonate concentration was measured with various contact time in order to check the effect of carbon dioxide in the air on zinc-air cell. The relationship between potassium carbonate concentration in electrolyte and battery capacity was also studied. The potassium carbonate concentration increased due to carbon dioxide absorption with increasing contact time with air, but the cell capacity linearly decreased with increasing potassium carbonate concentration in the electrolyte. The rate of carbon dioxide absorption was mainly affected by the pore size of hydrophobic membrane. Our study showed that adapting the pore of hydrophobic membrane decreased the loss of cell discharge performance due to the presence of carbon dioxide or water vapor in the atmosphere.

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Thermoelectric Seebeck and Peltier effects of single walled carbon nanotube quantum dot nanodevice

  • El-Demsisy, H.A.;Asham, M.D.;Louis, D.S.;Phillips, A.H.
    • Carbon letters
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    • v.21
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    • pp.8-15
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    • 2017
  • The thermoelectric Seebeck and Peltier effects of a single walled carbon nanotube (SWCNT) quantum dot nanodevice are investigated, taking into consideration a certain value of applied tensile strain and induced ac-field with frequency in the terahertz (THz) range. This device is modeled as a SWCNT quantum dot connected to metallic leads. These two metallic leads operate as a source and a drain. In this three-terminal device, the conducting substance is the gate electrode. Another metallic gate is used to govern the electrostatics and the switching of the carbon nanotube channel. The substances at the carbon nanotube quantum dot/metal contact are controlled by the back gate. Results show that both the Seebeck and Peltier coefficients have random oscillation as a function of gate voltage in the Coulomb blockade regime for all types of SWCNT quantum dots. Also, the values of both the Seebeck and Peltier coefficients are enhanced, mainly due to the induced tensile strain. Results show that the three types of SWCNT quantum dot are good thermoelectric nanodevices for energy harvesting (Seebeck effect) and good coolers for nanoelectronic devices (Peltier effect).

Review of the Existing Relative Biological Effectiveness Models for Carbon Ion Beam Therapy

  • Kim, Yejin;Kim, Jinsung;Cho, Seungryong
    • Progress in Medical Physics
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    • v.31 no.1
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    • pp.1-7
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    • 2020
  • Hadron therapy, such as carbon and helium ions, is increasingly coming to the fore for the treatment of cancers. Such hadron therapy has several advantages over conventional radiotherapy using photons and electrons physically and clinically. These advantages are due to the different physical and biological characteristics of heavy ions including high linear energy transfer and Bragg peak, which lead to the reduced exit dose, lower normal tissue complication probability and the increased relative biological effectiveness (RBE). Despite the promising prospects on the carbon ion radiation therapy, it is in dispute with which bio-mathematical models to calculate the carbon ion RBE. The two most widely used models are local effect model and microdosimetric kinetic model, which are actively utilized in Europe and Japan respectively. Such selection on the RBE model is a crucial issue in that the dose prescription for planning differs according to the models. In this study, we aim to (i) introduce the concept of RBE, (ii) clarify the determinants of RBE, and (iii) compare the existing RBE models for carbon ion therapy.