• Title/Summary/Keyword: carbon density

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Electrochemical Performance of Carbon-PTFE Electrode with High Capacitance and Density for EDLC (EDLC용 고용량, 고밀도 Carbon-PTFE 전극의 전기화학적 특성)

  • Kim, Ick-Jun;Jeon, Min-Je;Yang, Sun-Hye;Moon, Seong-In;Kim, Hyun-Soo
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2006.06a
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    • pp.541-542
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    • 2006
  • This work describes the effect of the number of roll pressing and the composition of carbon black on the electric and mechanical properties of carbon-PTFE electrode, in which composition is MSP 20 : carbon black : PTFE = 95-X : X : 5 wt.%. It was found that the best electric and mechanical properties were obtained for sheet electrode roll pressed about 15 times and for sheet electrode, in which composition is MSP 20 : carbon black : PTFE = 80 : 15 : 5 wt.%. These behaviors could be explained by the network structure of PTFE fibrils and conducting paths linked with carbon blacks, respectively. On the other hand, cell capacitor using the sheet electrode with 15 wt.% of carbon black attached on aluminum current collector with the electric conductive adhesive, in composition is carbon black : CMC = 70 : 30 wt.%, has exhibited the best rate capability between $0.5mA/cm^2{\sim}100mA/cm^2$ current density and the lowest ESR.

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Assessment of Carbon Storage Capacity of Stands in Abandoned Coal Mine Forest Rehabilitation Areas over time for its Development of Management Strategy (폐탄광 산림복구지 관리방안 도출을 위한 산림복구 후 시간경과에 따른 임분탄소저장량 평가)

  • Mun Ho Jung;Kwan In Park;Ji Hye Kim;Won Hyun Ji
    • Journal of Environmental Science International
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    • v.32 no.4
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    • pp.233-242
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    • 2023
  • The objective of this study was to develop a management strategy for the recovery of carbon storage capacity of abandoned coal mine forest rehabilitation area. For the purpose, the biomass and stand carbon storage over time after the forest rehabilitation by tree type for Betula platyphylla, Pinus densiflora, and Alnus hirsuta trees which are major tree species widely planted for the forest rehabilitation in the abandoned coal mine were calculated, and compared them with general forest. The carbon storage in abandoned coal mine forest rehabilitation areas was lower than that in general forests, and based on tree species, Pinus densiflora stored 48.9%, Alnus hirsuta 41.1%, and Betula platyphylla 27.0%. This low carbon storage is thought to be caused by poor growth because soil chemical properties, such as low TOC and total nitrogen content, in the soil of abandoned coal mine forest rehabilitation areas, were adverse to vegetation growth compared to those in general forests. DBH, stand biomass, and stand carbon storage tended to increase after forest rehabilitation over time, whereas stand density decreased. Stand' biomass and carbon storage increased as DBH and stand density increased, but there was a negative correlation between stand density and DBH. Therefore, after forest rehabilitation, growth status should be monitored, an appropriate growth space for trees should be maintained by thinning and pruning, and the soil chemical properties such as fertilization must be managed. It is expected that the carbon storage capacity the forest rehabilitation area could be restored to a level similar to that of general forests.

Rh-doped carbon nanotubes as a superior media for the adsorption of O2 and O3 molecules: a density functional theory study

  • Cui, Hao;Zhang, Xiaoxing;Yao, Qiang;Miao, Yulong;Tang, Ju
    • Carbon letters
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    • v.28
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    • pp.55-59
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    • 2018
  • Transition-metal-embedded carbon nanotubes (CNTs) have been accepted as a novel type of sensing material due to the combined advantage of the transition metal, which possesses good catalytic behavior for gas interaction, and CNTs, with large effective surface areas that present good adsorption ability towards gas molecules. In this work, we simulate the adsorption of $O_2$ and $O_3$ onto Rh-doped CNT in an effort to understand the adsorbing behavior of such a surface. Results indicate that the proposed material presents good adsorbing ability and capacities for these two gases, especially $O_3$ molecules, as a result of the relatively large conductivity changes. The frontier molecular orbital theory reveals that the conductivity of Rh-CNT would undergo a decrease after the adsorption of two such oxidizing gases due to the lower electron activity and density of this media. Our calculations are meaningful as they can supply experimentalists with potential sensing material prospects with which to exploit chemical sensors.

Influence of Carbon Black Contents and Rubber Compositions on Formation of Wear Debris of Rubber Vulcanizates

  • Choi, Sung-Seen;Yang, Seong Ryong;Chae, Eunji;Son, Chae Eun
    • Elastomers and Composites
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    • v.55 no.2
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    • pp.108-113
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    • 2020
  • Wear particles of the model tread compounds for bus and truck tires were made using a laboratory abrasion tester and characterized based on their size distributions, shapes, and crosslink densities. The influence of the carbon black contents and rubber compositions (NR= 100 and NR/BR= 80/20) on the production of wear particles was investigated. The wear particles were separated according to size using a sieve shaker. The shape properties of the wear particles were analyzed using an image analyzer and scanning electron microscopy (SEM). Their shapes were observed as tiny stick cookies or sausages with bumpy surfaces. The particle size distribution tended to be smaller with increasing carbon black content. Moreover, the particle size distributions of the NR = 100 samples were larger than that of the NR/BR blend samples. There were different filaments in the wear particles. The filament diameters tended to be thinner with increasing carbon black content. The crosslink density increased with increasing carbon black content, and the crosslink densities of the NR= 100 samples were lower than those of the NR/BR blend ones. The particle size distribution tended to be smaller with increasing crosslink density. Based on the experimental results, the wear particles can be produced by detaching debris from the main body through repetitive strain and recovery.

Hybrid Capacitors Using Organic Electrolytes

  • Morimoto, T.;Che, Y.;Tsushima, M.
    • Journal of the Korean Electrochemical Society
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    • v.6 no.3
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    • pp.174-177
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    • 2003
  • Electric double-layer capacitors based on charge storage at the interface between a high surface area activated carbon electrode and an electrolyte solution are characterized by their long cycle-life and high power density in comparison with batteries. However, energy density of electric double-layer capacitors obtained at present is about 6 Wh/kg at a power density of 500W/kg which is smaller as compared with that of batteries and limits the wide spread use of the capacitors. Therefore, a new capacitor that shows larger energy density than that of electric double-layer capacitors is proposed. The new capacitor is the hybrid capacitor consisting of activated carbon cathode, carbonaceous anode and an organic electrolyte. Maximum voltage applicable to the cell is over 4.2V that is larger than that of the electric double-layer capacitor. As a result, discharged energy density on the basis of stacked volume of electrode, current collector and separator is more than 18Wh/l at a power density of 500W/l.

Carbon Sequestration of Teak (Tectona grandis Linn. f.) Plantations in the Bago Yoma Region of Myanmar

  • Oo, Thaung Naing;Lee, Don Koo;Combalicer, Marilyn
    • Journal of Korean Society of Forest Science
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    • v.96 no.5
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    • pp.602-608
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    • 2007
  • Forest plantations become important strategy not merely for the financial aspect, but for carbon sequestration and ecosystem stability. Forest plantations increase the density of the forest biomass, which reduce the increase in atmospheric carbon dioxide. Biomass density is also a useful variable for comparing structural and functional attributes of forest ecosystems across a wide range of environmental conditions. In this study, carbon sequestration of teak (Tectona grandis Linn. f.) in the individual tree and plantation levels estimation was carried out Site-specific allometric equation for the estimation of teak tree biomass was developed based on the direct measurement of fifteen (15) harvested trees in the Oak-twin Township of the Bago Yoma Region, Myanmar. A regression equation of the diameter at breast height (DBH) and the aboveground biomass (carbon content) was constructed to estimate the carbon storage level of plantations, which averaged 79 ton/ha. The average carbon accumulation in the soil (up to 30 cm in depth) was estimated 38.89 ton/ha, The highest mean annual increment (MAI) of total carbon was found in the 6-yr-old teak plantation (12.10 ton/ha/yr) whereas the lowest MAI was in the 26-yr-old teak plantation (4.31 ton/ha/yr).

Electronic transport properties of linear carbon chains encapsulated inside single-walled carbon nanotubes

  • Tojo, Tomohiro;Kang, Cheon Soo;Hayashi, Takuya;Kim, Yoong Ahm
    • Carbon letters
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    • v.28
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    • pp.60-65
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    • 2018
  • Linear carbon chains (LCCs) encapsulated inside the hollow cores of carbon nanotubes (CNTs) have been experimentally synthesized and structurally characterized by Raman spectroscopy and transmission electron microscopy. However, in terms of electronic conductivity, their transportation mechanism has not been investigated theoretically or experimentally. In this study, the density of states and quantum conductance spectra were simulated through density functional theory combined with the non-equilibrium Green function method. The encapsulated LCCs inside (5,5), (6,4), and (9,0) single-walled carbon nanotubes (SWCNTs) exhibited a drastic change from metallic to semiconducting or from semiconducting to metallic due to the strong charge transfer between them. On the other hand, the electronic change in the conductance value of LCCs encapsulated inside the (7,4) SWCNT were in good agreement with the superposition of the individual SWCNTs and the isolated LCCs owing to the weak charge transfer.

The geometry change of carbon nanofilaments by SF6 incorporation in a thermal chemical vapor deposition system

  • Kim, Sung-Hoon
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.21 no.3
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    • pp.119-123
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    • 2011
  • Carbon nanotilaments (CNFs) could be synthesized on nickel catalyst layer-deposited silicon oxide substrate using $C_2H_2$ and$H_2$ as source gases under thermal chemical vapor deposition system. By the incorporation of $SF_6$ as a cyclic modulation manner, the geometries of carbon coils-related materials, such as nano-sized coil and wave-like nano-sized coil could be observed on the substrate. The characteristics (formation density and morphology) of as-grown CNFs with or without $SF_6$ incorporation were investigated. Diameter size reduction for the individual CNFs-related shape and the enhancement of the formation density of CNFs-related material could be achieved by the incorporation of $SF_6$ as a cyclic modulation manner. The cause for these results was discussed in association with the slightly increased etching ability by $SF_6$ addition and the sulfur role in SF 6 for the geometry change.

A Study on Stabilization and Mechanical Properties of Polyacrylonitrile-based Fiber with Itaconic acid (이타콘산을 함유한 폴리아크릴로니트릴계 전구체섬유의 열안정화 및 그 물성에 관한 연구)

  • 신익기;이신희;박수민
    • Textile Coloration and Finishing
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    • v.15 no.2
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    • pp.76-85
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    • 2003
  • In this study, a continuous stabilization process is used to make high-performance carbon fiber from polyacrylonitrile(PAM)-based fibers. The effect of oxygen content of PAN-based fiber on the stabilization process and the properties of the resultant carbon fibers is investigated. In order to research the progress of stabilization reaction FT-IR, elemental analysis, density, DSC, etc are used. Stabilization is carried out in air atmosphere from the 200 to $300^\circ{C}$ temperature range. An increase of PAN-based fibers diameter reduces the oxygen content during the continuous stabilization process. A higher oxygen content increase the density, tensile strength and modulus in the resultant carbon fibers. The most appropriate oxygen content in the stabilized fiber should be about 12%. Fibers having more than 2% oxygen content yield carbon fibers with inferior properties. Those carbon fibers also have sufficient commercial availability.

Performance Behavior by H2 and CO as a Fuel in Intermediate Temperature Solid Oxide Fuel Cell (IT-SOFC) (중.저온형 고체산화물 연료전지에서 연료로 공급되는 CO 와 H2 가 성능에 미치는 영향)

  • Park, Kwang-Jin;Bae, Joong-Myeon
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.32 no.12
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    • pp.963-969
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    • 2008
  • The performance behavior of solid oxide fuel cell using $H_2$ and CO as fuels was investigated. The power densities and impedance results showed a little variation as the ratio of $H_2$ and CO changed. However, when the pure CO was used as a fuel, area specific resistance (ASR), especially low frequency region, was increased. This might be due to carbon deposition on anode. The maximum power density was 60% lower using CO than using $H_2$. Carbon deposition reduced after constant current was applied. The SOFC performance was recovered from the carbon deposition after applying constant current during 100h.