• 제목/요약/키워드: carbon cycling

검색결과 244건 처리시간 0.029초

카본 CCL이 적용된 PCB의 열거동 및 신뢰성 특성 연구 (A Study on Thermal Behavior and Reliability Characteristics of PCBs with a Carbon CCL)

  • 조승현;김정철;강석원;성일;배경윤
    • 마이크로전자및패키징학회지
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    • 제22권4호
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    • pp.47-56
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    • 2015
  • 본 논문에서는 HDI(High Density Interconnection) 기판의 코어로 사용될 수 있는 카본 CCL(Copper Claded Layer)의 열거동 및 신뢰성 특성을 실험과 CAE를 이용한 수치해석을 통해 평가하였다. 카본 CCL의 특성평가를 위해 기존 FR-4 코어와 heavy cu 코어와 비교하였다. 연구결과에 의하면 pitch계열 카본코어가 적용된 PCB의 휨강도가 가장 높고 온도에 따른 변형량이 가장 낮았다. 또한, HDI 신뢰성평가 기준의 TC(Thermal Cycling), LLTS(Liquid-to-Liquid Thermal Shock), Humidity 실험을 통해 카본코어가 적용된 PCB는 신뢰성이 확보되었음을 확인하였다. 카본 파이버에 의한 불균일한 비아홀의 표면형상 여부와 드릴비트 마모 가능성을 분석하였는데 비아홀의 표면은 균일하고, 드릴비트의 표면도 매끄러워 카본 CCL의 우수한 드릴가공성도 확인하였다.

반복되는 열주기환경에 노출된 에폭시/탄소섬유 복합재료의 열산화 안정성 연구 (Thermo-Oxidative Stability of Epoxy/Carbon Fiber Composites under Thermal Cycling Conditions)

  • 남재도
    • 유변학
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    • 제10권2호
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    • pp.106-112
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    • 1998
  • 항공기용 소재로 개발된 에폭시/탄소섬유 복합재료가 매트릭스의 유리전이온도에 육 박하는 온도주기를 경험할 때 발생하는 복합재료의 구조 및 물성변화를 실험과 모델링을 통 하여 연구하였다. 복합재료의 표준 경화온도인 177$^{\circ}C$에서 2시간 체류시킨후 냉각시키는 바 복 열주기는 복합재료를 취약하게 하여 결국 표면에서부터 미세크랙이발생한다는 것을 알수 있었다. 이러한 열주기에 따른 미세크랙 현상은 매트릭스의 분해반응이 발생할수 있는 유효 표면적을 증가시키고 크랙을 통하여 산소의투과를 용이하게 함으로서 산화반응을 가속화하 여 복합재료시편의 무게감소를 가속화시키는 것으로 판단된다. 특히 본 연구에서는 등온과 등속도 승온조건을 주기적으로 반복하는 열주기 조건을 해석하기 위하여 열주기 조건을 특 정온도에서의 등오시간으로 전환할 수 있는 e-quivalent cycle time(ECT)를 제안하였고 이 를 이용하여 열주기에 의한 복합재료 손상의 가속/감속 현상을 규명할수있었다.

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Study on the Cycling Performances of Lithium-Ion Polymer Cells Containing Polymerizable Additives

  • Kim, Dong-Won
    • Bulletin of the Korean Chemical Society
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    • 제30권2호
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    • pp.319-322
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    • 2009
  • Gel polymer electrolytes were prepared by immersing a porous poly(vinylidene fluoride-co-hexafluoropropylene) membrane in an electrolyte solution containing small amounts of polymerizable additive (3,4-ethylenedioxythiophene, thiophene, biphenyl). The organic additives were electrochemically oxidized to form conductive polymer films on the electrode at high potential. With the gel polymer electrolytes containing different organic additive, lithium-ion polymer cells composed of carbon anode and LiCo$O_2$ cathode were assembled and their cycling performances were evaluated. Adding small amounts of thiophene or 3,4-ethylenedioxythiophene to the gel polymer electrolyte was found to reduce the charge transfer resistance in the cell and it thus exhibited less capacity fading and better high rate performance.

High Temperature Corrosion in Carbon-Rich Gases

  • Young, D.J.
    • Corrosion Science and Technology
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    • 제7권2호
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    • pp.69-76
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    • 2008
  • Common methods for large scale hydrogen production, such as steam reforming and coal gasification, also involve production of carbonaceous gases. It is therefore necessary to handle process gas streams involving various mixtures of hydrocarbons, $H_2$, $H_2O$, CO and $CO_2$ at moderate to high temperatures. These gases pose a variety of corrosion threats to the alloys used in plant construction. Carbon is a particularly aggressive corrodent, leading to carburisation and, at high carbon activities, to metal dusting. The behaviour of commercial heat resisting alloys 602CA and 800, together with that of 304 stainless steel, was studied during thermal cycling in $CO/CO_2$ at $650-750^{\circ}C$, and also in $CO/H_2/H_2O$ at $680^{\circ}C$. Thermal cycling caused repeated scale separation, which accelerated chromium depletion from the alloy subsurface regions. The $CO/H_2/H_2O$ gas, with $a_C=2.9$ and $p(O_2)=5\times10^{-23}$ atm, caused relatively rapid metal dusting, accompanied by some internal carburisation. In contrast, the $CO/CO_2$ gas, with $a_C=7$ and $p(O_2)=10^{-23}-10^{-24}$ atm caused internal precipitation in all three alloys, but no dusting. Inward diffusion of oxygen led to in situ oxidation of internal carbides. The very different reaction morphologies produced by the two gas mixtures are discussed in terms of competing gas-alloy reaction steps.

Inter-lamina Shear Strength of MWNT-reinforced Thin-Ply CFRP under LEO Space Environment

  • Moon, Jin Bum;Kim, Chun-Gon
    • Composites Research
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    • 제30권1호
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    • pp.7-14
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    • 2017
  • In this paper, the inter-lamina shear strength (ILSS) of multi-wall carbon nanotube (MWNT) reinforced carbon fiber reinforced plastics (CFRP) and thin-ply composites were verified under low earth orbit (LEO) space environment. CFRP, MWNT reinforced CFRP, thin-ply CFRP and MWNT reinforced thin-ply CFRP were tested after aging by using accelerated ground simulation equipment. The used ground simulation equipment can simulate high vacuum ($2.5{\times}10^{-6}torr$), atomic oxygen (AO, $9.15{\times}10^{14}atoms/cm^2{\cdot}s$), ultraviolet light (UV, 200 nm wave length) and thermal cycling ($-70{\sim}100^{\circ}C$) simultaneously. The duration of aging experiment was twenty hours, which is an equivalent duration to that of STS-4 space shuttle condition. After the aging experiment, ILSS were measured at room temperature ($27^{\circ}C$), high temperature ($100^{\circ}C$) and low temperature ($-100^{\circ}C$) to verify the effect of operation temperature. The MWNT and thin-ply shows good improvement of ILSS at ground condition especially with the thin-ply. And after LEO exposure large degradation of ILSS was observed at MWNT added composite due to the thermal cycle. And the degradation rate was much higher under the high temperature condition. But, at the low temperature condition, the ILSS was largely recovered due to the matrix toughening effect.

연속회분식 반응기(Sequencing Batch Reactor)를 이용한 분뇨중 유기물과 질소 및 인의 동시제거 (Removal of Simultaneously Biological Organic, Nitrogen, and Phosphorus Removal in Sequencing Batch Reactors using Night-soil)

  • 한기백;박동근
    • 한국환경과학회지
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    • 제6권6호
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    • pp.697-709
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    • 1997
  • Sequencing Batch Reactor(SBR) experiments for organics and nutrients removal have been conducted to find an optimum anaerobic/anoxic/aerobic cycling time and evaluate the applicability of oxidation-reduction potential(ORP) as a process control parameter. In this study, a 61 bench-scale plant was used and fed with night-soil wastewater in K city which contained TCODcr : 10, 680 mg/l, TBm : 6, 893 mg/l, $NH_4^+-N$ : 1, 609 mg/l, $PO_4^{3-}-P$ : 602 mg/l on average. The cycling time In SBRs was adjusted at 12 hours and 24 hours, and then certainly included anaerobic, aerobic and inoxic conditions. Also, for each cycling time, we performed 3 series of experiment simultaneously which was set up 10 days, 20 days and 30 days as SRT From the experimental results, the optimum cycling time for biological nutrient removal with nlght-soil wastewater was respctively 3hrs, 5hrs, 3hrs(anaerobic-aerobic-anoxic), Nitrogen removal efficiency was 77.9%, 77.9%, 81.7% for each SRT, respectively. When external carbon source was fed in the anoxic phase, ORP-bending point indicating nitrate break point appeared clearly and nitrogen removal efficiency increased as 96.5%, 97.1%, 98.9%. Phosphate removal efficiency was 59.8%, 64.571, 68.6% for each SRT. Also, we finded the applicability of ORP as a process control parameter in SBRs.

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폐기된 청바지를 활용한 생활용품 디자인 연구 (Up-cycling Product Development for Daily Household Supplies Utilizing Used Jeans)

  • 안인숙;김호경
    • 복식
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    • 제65권1호
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    • pp.76-88
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    • 2015
  • Excessive spending and the ever-changing fashion trends lead to an increase in material production to meet consumers' needs, which also in turn, increase the amount of industrial waste and many harmful pollutants. To address this problem, this study aimed to utilize discarded jeans' parts, reconstructing them into edgy and functional designs for everyday products. Six pairs of discarded jeans were collected and were used to create six types of functional products -three types of baskets, a bag, a slipper, and a key-holder. The benefits of up-cycling outweigh recycling because it not only increases the recycling rate, but also decreases the amount of energy and cost, thereby increasing the efficiency in recreating new innovative products. These proposed up-cycling ideas will serve as a great alternative for consumers to actively participate in reducing carbon emission, water usage, and waste to landfill by utilizing used clothing. This will guide how consumers can extend the life of their used clothing, utilize recyclable items more thoroughly, and keep used clothing out of landfills.

Alternatives for Quantifying Wetland Carbon Emissions in the Community Land Model (CLM) for the Binbong Wetland, Korea.

  • Eva Rivas Pozo;Yeonjoo Kim
    • 한국수자원학회:학술대회논문집
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    • 한국수자원학회 2023년도 학술발표회
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    • pp.413-413
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    • 2023
  • Wetlands are a critical component of the global carbon cycle and are essential in mitigating climate change. Accurately quantifying wetland carbon emissions is crucial for understanding and predicting the impact of wetlands on the global carbon budget. The uncertainty quantifying carbon in wetlands may comes from the ecosystem's hydrological, biochemical, and microbiological variability. The Community Land Model is a sophisticated and flexible land surface model that offers several configuration options such as energy and water fluxes, vegetation dynamics, and biogeochemical cycling, necessitating careful consideration for the alternative configurations before model implementation to develop a practical model framework. We conducted a systematic literature review, analyzing the alternatives, focusing on the carbon stock pools configurations and the parameters with significant sensitivity for carbon quantification in wetlands. In addition, we evaluated the feasibility and availability of in situ observation data necessary for validating the different alternatives. This analysis identified the most suitable option for our study site, the Binbong Wetland, in Korea.

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3-옥틸티오펜의 전기화학적 중합법에 의한 탄소재료의 표면 전착 (The Electrodeposition on Carbon Materials with In Situ Electrochemical Polymerization of 3-Octylthiophene)

  • 전재숙;김정재;이경우;김정수
    • 폴리머
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    • 제34권6호
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    • pp.511-516
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    • 2010
  • 탄소재료의 표면을 개질하고 이를 광전자 기능소자의 전극 재료로서 응용하는 가능성을 모색하기 위하여 탄소재료의 표면을 폴리(3-옥틸티오펜)으로 전기화학적 방법에 의하여 전착하는 것을 연구하였다. 전착의 기질로 사용되는 탄소재료의 형태로는 시판되는 탄소종이 및 탄소섬유를 택하였으며, 전기중합에 사용되는 단량체의 농도, 전해질의 농도, 인가전압의 변화, 순환전압전류법 사이클 회수를 달리하여 그 영향을 관찰하였다. 단량체의 농도와 전해질 농도의 증가, 인가전압의 증가, 순환전압전류법 사이클 회수의 증가에 따라 탄소종이와 탄소섬유에 중합된 폴리(3-옥틸티오펜)의 양이 증가함을 관찰하였으며, 중합속도에 미치는 영향을 각각의 변수에 대한 지수를 측정해서 분석하였다. 폴리(3-옥틸티오펜)이 중합된 탄소재료의 표면은 주사전자현미경을 통해 관찰하였고 그 구조를 FTIR-ATR로 분석하였다.