• Title/Summary/Keyword: carbon composites

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Electrical Properties of PTFE for Circuit Breaker (차단기용 PTFE의 전기적 특성)

  • Park, Hoy-Yul;Kang, Dong-Pil;Ahn, Myeong-Sang;Lee, Tae-Hui;Myung, In-Hae;Lee, Tae-Joo
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2003.11a
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    • pp.204-207
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    • 2003
  • This paper presents the electrical properties of PTFE (polytetrafluoroethylene) nozzle for circuit breaker. PTFE has been used widely as a nozzle material for circuit breaker. In the arcing environment in a circuit breaker, radiation is considered to be the major energy transport mechanism from the arc to the wall. The fraction of the radiation power is emitted out of the arc and reaches the nozzle wall, causing ablation at the surface and in the depth of the wall. The energy concentration in the material lead to the depolymerization and eventually lead to the generation of decomposed gas as well as some isolated carbon particles. The generation of the decomposed gas in the depth of the material causes inner explosion. The surface of nozzle becomes uneven. The flow of gas is not uniform due to the unevenness of the surface. Adding some fillers into PTFE is expected to be efficient for improving the endurability against radiation. In this experiment, three kinds of fillers that have endurance in the high temperature environment were added into PTFE. Dielectric constant, dissipation factor, electrical resistivity and dielectric strength of PTFE composites were investigated.

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Large Area Deposition of Biomimetic Polydopamine-Graphene Oxide Hybrids using Langmuir-Schaefer Technique (랭뮤어-쉐퍼 기법 이용 생체모사 폴리도파민-산화그래핀 복합체 대면적 적층 기법 연구)

  • Kim, Tae-Ho;Song, Seok Hyun;Jo, Kyung-Il;Koo, Jaseung
    • Journal of Adhesion and Interface
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    • v.20 no.3
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    • pp.110-115
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    • 2019
  • Graphene oxide has been gathering interests as a way to exfoliate graphene. Since the oxidation group of graphene oxide can hydrogen bond with various functional groups, tremendous efforts have been actively conducted to apply various applications. However, graphene oxide alone cannot substantially possess the mechanical properties required for the practical application. Therefore, in this study, polydopamine, which is a bio-mimetic mussel protein-inspired material, was combined with graphene oxide to form a large-area composite membrane at the liquid-gas interface. In addition, the morphology of the polydopamine-graphene oxide composite thin film was also controlled to obtain a composite membrane having a nano-wrinkle structure. It can be expected to be used in the next generation seawater desalination membranes or carbon composites because it can form mechanically superior and sophisticated nanostructures.

Gas Permeation Study of Fuel Hose Composed as Inner Material of FKM Rubber (FKM 고무를 내층재료로 한 연료호스의 가스 투과성 연구)

  • Kim, Do-Hyun;Doh, Kyung-Hwan;Park, Hyun-Ho;Lee, Chang-Seop
    • Elastomers and Composites
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    • v.40 no.2
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    • pp.83-92
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    • 2005
  • To develop an automotive fuel hose suitable to the international environmental regulation, FKM rubber materials as an inner material of fuel hole were prepared with different chemical compositions. Measurement of the properties of thermal resistance, oil resistance, fuel resistance, gas permeability including fundamental properties were performed to investigate compatibility for a fuel hose material. Fundamental properties, thermal resistance, oil resistance, fuel resistance and permeability of FKM rubber materials were improved with fluorine content. When the carbon content was 20 phr, FKM compounds with fluorine contents of 66%, 09% and 71% were shown to satisfy the specification oi fuel hose. The gas permeability of NBR and FKM compounds was measured on the mixed fuel oils prepared with isooctane-toluene and gasoline-methanol. FKM rubber materials showed a small difference in penetrated amount of fuel and showed a permeability superior to NBR material. he permeability of FKM rubber materials was not influenced by the contents of fuel oil. Thermal properties of 69% FKM rubber experienced by permeability testing were not variated.

Studies on the Physical Properties of Synthetic Rubber Blends Containing Rein-forcing Fillers (보강성 충전제를 함유한 합성고무 블렌드의 물리적 특성에 관한 연구)

  • Go, Jin-Hwan;Lee, Seog
    • Elastomers and Composites
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    • v.33 no.4
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    • pp.231-237
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    • 1998
  • In order to investigate the physical properties of rubber blend compound, this experiment was carried out on the cure rate, loss tangent, reinforcement and abrasion properties of S-SBR (solution styrene-butadiene rubber) blends containing silane coupled silica and E-SBR (emulsion styrene-butadiene rubber) blends containing carbon black as a model compound. E-SBR blend showed the highest total bound rubber(TBR), while S-SBR blends showed constant TBR level regardless of rubber type. Rapid cure rate was achieved when the styrene and vinyl content of rubber microstructure decreased and TBR content of rubber compounds increased. The modulus as the index of rubber reinforcement showed the linear relation with TBR content. The large amount of PICO loss was observed when the styrene and vinyl content of rubber microstructure increased, while the small amount of PICO loss was observed when the ratio of bu-tadiene increased in the S-SBR blends with silane copuled silica. The high loss tangent at $0^{\circ}C$, the low loss tangent at $60^{\circ}C$, and the large difference of loss tangent were shown in the S-SBR blends with high styrene content compared to E-SBR blend.

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Effects of Vulcanization Type end Temperature on Physical Properties of Natural Rubber Compounds (가황형태 및 온도가 천연고무 컴파운드의 물리적 특성에 미치는 영향)

  • Rhee, John-M.;Yoon, Chan-Ho;Huh, Yang-Il;Han, Seung-Cheol;Nah, Chang-Woon
    • Elastomers and Composites
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    • v.35 no.3
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    • pp.173-179
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    • 2000
  • Cure characteristics. tensile properties, and dynamic properties were investigated on the carbon black-filled natural rubber compounds, in which three typical vulcanization types conventional vulcanization(Conv), semi-efficient(Semi-EV), and efficient(EV) vulcanizations were used. The effects of vulcanization temperature on both the mechanical property and aging resistance of rubber compounds were also investigated. The Conv cure system showed a slightly slower rate of vulcanization than those of Semi-EV and EV ones. On the other hand, it showed a higher value in the maximum torque of cure curve. Higher tensile moduli were observed in Conv system than those in Semi-EV and EV ones, while lower elongation at break were obtained in Conv one. The tensile strength at break were found to be about the same for three cute systems. Hardness, modulus, and tensile strength decreased with increasing the vulcanization temperature, and the degree of changes in the properties was found to be smaller for EV and Semi-EV systems than that in Conv one. The EV system was found to be superior in thermal-aging resistance to Conv one.

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Wear Particulate Matters and Physical Properties of ENR/BR Tread Compounds with Different Ratio of Silica and Carbon Black Binary Filler Systems

  • Ryu, Gyeongchan;Kim, Donghyuk;Song, Sanghoon;Lee, Hyun Hee;Ha, Jin Uk;Kim, Wonho
    • Elastomers and Composites
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    • v.56 no.4
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    • pp.234-242
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    • 2021
  • The demand for truck bus radial (TBR) tires with enhanced fuel efficiency and wear resistance have grown in recent years. In addition, as the issue of particulate matter and air pollution increases, efforts are being made to reduce the generation of particulate matter. In this study, the properties of epoxidized natural rubber (ENR) containing a silica-friendly functional group were evaluated by considering it as a base rubber and varying the silica ratio in this binary filler system. The results showed that the wear resistance of the NR/BR blend compound decreased as the silica ratio increased. In contrast, the ENR/BR blend compound exhibited an increase in wear resistance as the silica ratio was increased. In particular, the ENR-50/BR blend compound showed the best wear resistance due to the presence of several epoxide groups. Furthermore, we observed that for tan 𝛿 at 60℃, higher epoxide content resulted in the higher Tg of the rubber, indicating a higher tan 𝛿 at 60℃. On the other hand, it was confirmed that increasing the silica ratio decreased the value of tan 𝛿 at 60℃ in all compounds. In addition, we measured the amount of wear particulate matters generated from the compound wear. These measurements confirmed that in the binary filler system, regardless of the filler type, the quantity of the generated wear particulate matters as the filler-rubber interaction increased. In conclusion, the silica filled ENR/BR blend compound exhibited the lowest generation of wear particulate matters.

Poly(vinyl alcohol)-based Polymer Electrolyte Membrane for Solid-state Supercapacitor (고체 슈퍼캐퍼시터를 위한 폴리비닐알콜 고분자 전해질막)

  • Lee, Jae Hun;Park, Cheol Hun;Park, Min Su;Kim, Jong Hak
    • Membrane Journal
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    • v.29 no.1
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    • pp.30-36
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    • 2019
  • In this study, we reported a solid-state supercapacitor consisting of titanium nitride (TiN) nanofiber and poly(3,4-ethylenedioxythiophene) polystyrene sulfonate (PEDOT-PSS) conducting polymer electrode and poly(vinyl alcohol) (PVA)-based polymer electrolyte membrane. The TiN nanofiber was selected as electrode materials due to high electron conductivity and 2-dimensional structure which is beneficial for scaffold effect. PEDOT-PSS is suitable for organic/inorganic composites due to good redox reaction with hydrogen ions in electrolyte and good dispersion in solution. By synergetic effect of TiN nanofiber and PEDOT-PSS, the PEDOT-PSS/TiN electrode showed higher surface area than the flat Ti foil substrate. The PVA-based polymer electrolyte membrane could prevent leakage and explosion problem of conventional liquid electrolyte and possess high specific capacitance due to the fast ion diffusion of small $H^+$ ions. The specific capacitance of PEDOT-PSS/TiN supercapacitor reached 75 F/g, which was much higher than that of conventional carbon-based supercapacitors.

Characteristics of CFRP strengthened tubular joints subjected to different monotonic loadings

  • Prashob, P.S.;Shashikala, A.P.;Somasundaran, T.P.
    • Steel and Composite Structures
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    • v.32 no.3
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    • pp.361-372
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    • 2019
  • Tubular joints are used in the construction of offshore structures and other land-based structures because of its ease of fabrication. These joints are subjected to different environmental loadings in their lifetime. At the time of fabrication or modification of an existing offshore platform, tubular joints are usually strengthened to withstand the environmental loads. Currently, various strengthening techniques such as ring stiffeners, gusset plates are employed to strengthen new and existing tubular joints. Due to some limitations with the present practices, some new techniques need to be addressed. Many researchers used Fibre Reinforced Polymer (FRP) to strengthen tubular joints. Some of the studies were focused on axial compression of Glass Fibre Reinforced Polymer (GFRP) strengthened tubular joints and found that it was an efficient technique. Earlier, the authors had performed studies on Carbon Fibre Reinforced Polymer (CFRP) strengthened tubular joint subjected to axial compression. The study steered to the conclusion that FRP composites is an alternative strengthening technique for tubular joints. In this work, the study was focused on axial compression of Y-joint and in plane and out of plane bending of T-joints. Experimental investigations were performed on these joints, fabricated from ASTM A106 Gr. B steel. Two sets of joints were fabricated for testing, one is a reference joint and the other is a joint strengthened with CFRP. After performing the set of experiments, test results were then compared with the numerical solution in ANSYS Parametric Design Language (APDL). It was observed that the joints strengthened with CFRP were having improved strength, lesser surface displacement and ovalization when compared to the reference joint.

Strengthening of concrete damaged by mechanical loading and elevated temperature

  • Ahmad, Hammad;Hameed, Rashid;Riaz, Muhammad Rizwan;Gillani, Asad Ali
    • Advances in concrete construction
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    • v.6 no.6
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    • pp.645-658
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    • 2018
  • Despite being one of the most abundantly used construction materials because of its exceptional properties, concrete is susceptible to deterioration and damage due to various factors particularly corrosion, improper loading, poor workmanship and design discrepancies, and as a result concrete structures require retrofitting and strengthening. In recent times, Fiber Reinforced Polymer (FRP) composites have substituted the conventional techniques of retrofitting and strengthening of damaged concrete. Most of the research studies related to concrete strengthening using FRP have been performed on undamaged test specimens. This contribution presents the results of an experimental study in which concrete specimens were damaged by mechanical loading and elevated temperature in laboratory prior to application of Carbon Fiber Reinforced Polymer (CFRP) sheets for strengthening. The test specimens prepared using concrete of target compressive strength of 28 MPa at 28 days were subjected to compressive and splitting tensile testing up to failure and the intact pieces of the failed specimens were collected for the purpose of repair. In order to induce damage as a result of elevated temperature, the concrete cylinders were subjected to $400^{\circ}C$ and $800^{\circ}C$ temperature for two hours duration. Concrete cylinders damaged under compressive and split tensile loads were re-cast using concrete and rich cement-sand mortar, respectively and then strengthened using CFRP wrap. Concrete cylinders damaged due to elevated temperature were also strengthened using CFRP wrap. Re-cast and strengthened concrete cylinders were tested in compression and splitting tension. The obtained results revealed that re-casting of specimens damaged by mechanical loadings using concrete & mortar, and then strengthened by single layer CFRP wrap exhibited strength even higher than their original values. In case of specimens damaged by elevated temperature, the results indicated that concrete strength is significantly dropped and strengthening using CFRP wrap made it possible to not only recover the lost strength but also resulted in concrete strength greater than the original value.

Prediction of Material Properties of Carbon Fiber Prepreg in the Laminated Composite Using Reverse Analysis with Dynamic Characteristics (동적 특성이 고려된 역해석를 이용한 적층 복합재료 내부의 탄소섬유 프리프레그의 물성 예측)

  • Hwang, Mun-Young;Kang, Lae-Hyong
    • Composites Research
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    • v.32 no.4
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    • pp.177-184
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    • 2019
  • If what the mechanical properties according to a layer have was found out by analyzing the already fabricated composite, it could be possible to develop the composite of the better performance than the existing products. In this study, we tried to calculate the mechanical properties of the inner prepreg lamina by applying the reverse design technique to the composite structure made by laminating prepregs. When the physical quantities obtained by the simple tensile test are used alone and the physical quantities obtained by the tensile test and the mode analysis are used at the same time, the results of this study show that the accuracy of the latter is higher Finally, the maximum error of $E_1$ predicted was 0.09% and the maximum error of predicted $E_2$ was 7%.