• Title/Summary/Keyword: carbon additive

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Graphitization of Petroleum Cokes by Aluminum Catalyst (Aluminum 촉매에 의한 석유 Cokes의 흑연화)

  • 염희남;김경자;정윤중
    • Journal of the Korean Ceramic Society
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    • v.32 no.6
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    • pp.677-684
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    • 1995
  • The effect of catalytic graphitization of petroleum cokes by the addition of aluminum were investigated. The degree of graphitization carbon body only fired at 230$0^{\circ}C$ was 0.5. But when the aluminum additive was added, the degree of graphitization was increased to 0.93. And Ts-effect was appeared as the catalytic effect. This effect was occurred by the formation-decomposition of aluminum carbide through the reaction of aluminum and cokes.

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Evaluation of the Asph81t Mixture Performance with Waste Materials

  • Lee, Kwan-Ho;Lovell, C
    • Geotechnical Engineering
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    • v.12 no.3
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    • pp.17-34
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    • 1996
  • The objective of this paper is to evaluate the asphalt mixture performance with pyrolyzed carbon black(CBP) and air -cooled iron blast furnace slag. Marshall mix design was performed to determine the optimum binder content, The optimum binder content ranged from 6.3 percent to 7.75 percent. Dynamic creep testing was carried out using mixtures at the optimum binder content. Based on the test results, the use of pyrolyzed carbon black and slag in the asphalt pavement showed a positive result, such as the increase of Marshall stability, the decrease of the strain rate and the decrease in the mix stiffness rate at high temperature(5$0^{\circ}C$) and 137.9 kPa confinement. Within the limits of this research. it was concluded that pyrolyzed carbon black as an additive and slag as a coarse aggregate could be used to produce an asphalt paving mixture that has good stability, stiffness, and rutting resistance.

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Effect of Injection Stage of SF6 Gas Incorporation on the Limitation of Carbon Coils Geometries (육불화황 기체의 주입단계에 따른 탄소코일 기하구조의 제약)

  • Kim, Sung-Hoon
    • Journal of the Korean Vacuum Society
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    • v.20 no.5
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    • pp.374-380
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    • 2011
  • Carbon coils could be synthesized on nickel catalyst layer-deposited silicon oxide substrate using $C_2H_2$ and $H_2$ as source gases and $SF_6$ as an additive gas under thermal chemical vapor deposition system. The characteristics (formation density and morphology) of as-grown carbon coils according to the injection stage of $SF_6$ gas incorporation were investigated. A continuous injecting of $SF_6$ gas flow could give rise to many types of carbon coils-related geometries, namely linear tub, micro-sized coil, nano-sized coil, and wave-like nano-sized coil. However, the limitation of the geometry as the nano-sized geometries of carbon coils could be achieved by the incorporation of $SF_6$ in a short time (1 min) during the initial deposition stage. A delayed injection of a short time $SF_6$ gas flow can deteriorate the limitation of the geometries. It confirms that the injection time and its starting point of $SF_6$ gas flow would be very important to determine the geometries of carbon coils.

A Study on the Behavior of the Burn-On in Sand Mold (주형사의 소착거동에 관한 연구)

  • Gwak, Chang-Seop
    • Journal of the Korean Society for Precision Engineering
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    • v.2 no.3
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    • pp.41-46
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    • 1985
  • The behavior of the burn-on in sand mold has been investigated by varying the pouring metal, bonding materials, additive materials and molding sand. The results obtained from thease experiments are as follows; 1) The burn-on layer of silica sand decreased in order of carbon steel, gray cast iron and stainless steel, and thease burn layer proceeded mostly by producing FeO. 2) The burning reaction of silica sand mold in carbon steel castings declined with increasingly bentonite content, but water-glass scarcely took part in the burn-on reaction. 3) The addition of feldspar and seacoal to silica sand promoted the inhibiting burn-on. 4) The burn-on layer of sand mold decreased of silica sand, chromite sand and olivine sand.

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Enhancement of Catalytic Activity of Pt/Alumina by a Novel Pretreatment Method for the CO Oxidation for Fuel Cell Applications (연료전지용 CO의 산화를 위한 백금/알루미나 촉매의 성능향상에 관한 연구)

  • Jo, Myung-Chan
    • Journal of Environmental Science International
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    • v.17 no.12
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    • pp.1307-1314
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    • 2008
  • Hydrogen gas is used as a fuel for the proton exchange membrane fuel cell (PEMFC). Trace amount of carbon monoxide present in the reformate $H_2$ gas can poison the anode of the PEMFC. Therefore, preferential oxidation (PROX) of CO is essential for reducing the concentration of CO from a hydrogen-rich reformate gas. In this study, conventional Pt/$Al_2O_3$ catalyst was prepared for the preferential oxidation of CO. The effects of catalyst preparation method, additive, and hydrogen on the performances of PROX reaction of CO were investigated. Water treatment and addition of Ce enhanced catalytic activity of the Pt/$Al_2O_3$ catalyst at low temperature below $100^{\circ}C$.

Effects of heat-treatment temperature on carbon-based composites with added illite

  • Jeong, Eui-Gyung;Kim, Jin-Hoon;Lee, Young-Seak
    • Carbon letters
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    • v.12 no.2
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    • pp.95-101
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    • 2011
  • To investigate new applications for illite as an additive for carbon-based composites, the composites were prepared with and without illite at different heat-treatment temperatures. The effects of the heat-treatment temperature on the chemical structure, microstructure, and thermal oxidation properties of the resulting composites were studied. As the heat-treatment temperature was increased, silicon carbide SiC formation via carbothermal reduction increased until all the added illite was consumed in the case of the samples heat-treated at $2,300^{\circ}C$. This is attributed to the intimate contact between the $SiO_2$ in the illite and the phenol carbon precursor or the carbon fibers of the preform. Among composites prepared at all temperatures, those with illite addition exhibited fewer pores, voids, and interfacial cracks, resulting in larger bulk densities and lower porosities. A delay of oxidation was not observed in the illite-containing composites prepared at $2,300^{\circ}C$, suggesting that the illite itself absorbed energy for exfoliation or other physical changes. Therefore, if the illite-containing C/C composites can reach a density generally comparable to that of other C/C composites, illite may find application as a filler for C/C composites. However, in this study, the illite-containing C/C composites exhibited low density, even when prepared at a high heat-treatment temperature of $2300^{\circ}C$, although the thermal oxidation of the resulting composites was improved.

Mesoporous Carbon Additives for Long Cycle Life Sulfur Cathodes of Li-S Batteries

  • Koh, Jeong Yoon;Kim, Tae Jeong;Park, Min-Sik;Kim, Eun Hee;Kim, Seok;Kim, Ki Jae;Yu, Ji-Sang;Kim, Young-Jun;Jung, Yongju
    • Bulletin of the Korean Chemical Society
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    • v.35 no.11
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    • pp.3331-3335
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    • 2014
  • We examine the potential use of disordered mesoporous carbon as a functional additive for confining dissolved Li-polysulfides and improving the cycling performance of Li-S batteries. To promote a better understanding of the correlation between the total pore volume of disordered mesoporous carbon and the cycling performance of Li-S batteries, a series of disordered mesoporous carbons with different total pore volumes are successfully synthesized using a commercial silica template. Based on the electrochemical and structural analyses, we suggest that the total pore volume of disordered mesoporous carbon is a predominant factor in determining its capability for either the absorption or adsorption of Li-polysulfides, which is primarily responsible for enhancing the cycling performance. The addition of disordered mesoporous carbon is also effective in enhancing the homogeneous distribution of active sulfur in the cathode, thereby affecting the cycling performance.

Improvement on Voltage Delay with Variation on Carbon Cathode Forming Density (양극의 밀도 조절을 통한 리튬전지의 초기전압지연 개선)

  • Lim, Man-Kyu;Chun, Soon-Yong
    • Journal of the Institute of Electronics Engineers of Korea SC
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    • v.45 no.6
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    • pp.60-66
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    • 2008
  • The operating voltage of Li/SOCl2 battery decrease immediately when we give a load battery stored for long time. It is called voltage delay. We cannot rapidly operate equipment at emergence situation because the voltage delays. So we have to overcome voltage delay. We reported the results improved voltage delay in this paper through the control of the carbon cathode forming density. It is the classic method in order to control of voltage delay that is coating polymer in the lithium surface or put in the additive to electrolyte. If the carbon cathode forming density decreases, the operating voltage of battery becomes to increasing because solution resistance of battery reduce.

Magnesium diboride(MgB2) wires for applications

  • Patel, Dipak;Kim, Jung Ho
    • Progress in Superconductivity and Cryogenics
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    • v.18 no.1
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    • pp.1-5
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    • 2016
  • Field and temperature dependence of the critical current density, Jc, were measured for both un-doped and carbon doped $MgB_2/Nb/Monel$ wires manufactured by Hyper Tech Research, Inc. In particular, carbon incorporation into the $MgB_2$ structure using malic acid additive and a chemical solution method can be advantageous because of the highly uniform mixing between the carbon and boron powders. At 4.2 K and 10 T, Jc was estimated to be $25,000-25,300Acm^{-2}$ for the wire sintered at $600^{\circ}C$ for 4 hours. The irreversibility field, $B_{irr}$, of the malic acid doped wire was approximately 21.0 - 21.8 T, as obtained from a linear extrapolation of the J-B characteristic. Interestingly enough, the Jc of the malic acid doped sample exceeds $10^5Acm^{-2}$ at 6 T and 4.2 K, which is comparable to that of commercial Nb-Ti wires.

Volume Resistivity, Specific Heat and Thermal Conductive Properties of the Semiconductive Shield in Power Cables

  • Lee Kyoung-Yong;Choi Yong-Sung;Park Dae-Hee
    • KIEE International Transactions on Electrophysics and Applications
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    • v.5C no.3
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    • pp.89-96
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    • 2005
  • To improve the mean-life and reliability of power cables, we have investigated the volume resistivity and thermal properties demonstrated by changing the content of carbon black, an additive of the semiconductive shield for underground power transmission. Nine specimens were made of sheet form for measurement. Volume resistivity of the specimens was measured by a volume resistivity meter after 10 minutes in a preheated oven at temperatures of both 25$\pm$1[$^{\circ}C$] and 90$\pm$ 1[$^{\circ}C$]. As well, specific heat (Cp) and thermal conductivity were measured by Nano Flash Diffusivity and DSC (Differential Scanning Calorimetry). The ranges of measurement temperature were from 0[$^{\circ}C$] to 200[$^{\circ}C$], and heating temperature was 4[$^{\circ}C$/min]. From these experimental results, volume resistivity was high according to an increase of the content of carbon black. Specific heat was decreased, while thermal conductivity was increased according to a rise in the content of carbon black. Furthermore, both specific heat and thermal conductivity were increased by heating temperature because the volume of materials was expanded according to a rise in temperature.