• 제목/요약/키워드: carbon addition

검색결과 3,184건 처리시간 0.03초

탄소나노튜브의 중저온에서의 화학적 합성 (Synthesis of Carbon Nanotubes by Chemical Method at Warm Temperatures)

  • 안중호;이상현;김용진;정형식
    • 한국분말재료학회지
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    • 제13권5호
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    • pp.305-312
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    • 2006
  • Amorphous carbon nanotubes were synthesized by a reaction of benzene, ferrocene and Na mixture in a small autoclave at temperatures as low as $400^{\circ}C$. The resulting carbon nanotubes were short and straight, but their inner hole was filled with residual products. The addition of quartz to the reacting mixture considerably promoted the formation of carbon nanotubes. A careful examination of powder structure suggested that the nanotubes in this process were mainly formed by surface diffusion of carbon atoms at the surface of solid catalytic particles, not by VLS(vapor-liquid-solid) mechanism.

환경보호와 목재의 이용 (Environmental Conservation and Wood Utilization)

  • 장상식
    • Journal of the Korean Wood Science and Technology
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    • 제22권3호
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    • pp.51-58
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    • 1994
  • Environmental conservation has become one of the greatest concerns of all the people in the world. This issue is related to wood utilization in two major view points such as carbon dioxide emitted by the use of manufacturing energy and absorbed during the growth of trees. Wood construction materials require less manufacturing energy, which, in turn, means less carbon dioxide emission. In addition, wood keeps absorbed carbon in itself as far as it is not burnt. Therefore, wood is environmentally superior to other materials in terms of potential effects on atmospheric carbon dioxide. As examples of the environmental effect of wood utilization, the following two results were obtained: 1) If wood construction becomes popular in Korea as in Japan, more than 24% of carbon dioxide emission during construction of residential housings can be reduced: and 2) If aluminum windows are substituted by wood windows, more than 19% of carbon dioxide emission can be reduced. If the principle of "cut and plant" is kept well, wood is the best construction material for environmental protection as well as human residence.

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Effect of crystallinity on the electrochemical properties of carbon black electrodes

  • Yoo, Hye-Min;Heo, Gun-Young;Park, Soo-Jin
    • Carbon letters
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    • 제12권4호
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    • pp.252-255
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    • 2011
  • Carbon-based electric double-layer capacitors are being evaluated as potential energy-storage devices in an expanding number of applications. In this study, samples of carbon black (CB) treated at different temperatures ranging from $650^{\circ}C$ to $1100^{\circ}C$ were used as electrodes to improve the efficiency of a capacitor. The surface properties of the heat-treated CB samples were characterized by X-ray photoelectron spectroscopy and X-ray diffraction. The effect of the heat-treatment temperature on the electrochemical behaviors was investigated by cyclic voltammetry and in galvanostatic charge-discharge experiments. The experimental results showed that the crystallinity of the CBs increased as the heat-treatment temperature increased. In addition, the specific capacitance of the CBs was found to increase with the increase in the heat-treatment temperature. The maximum specific capacitance was 165 $F{\cdot}g-1$ for the CB sample treated at $1000^{\circ}C$.

Morphologies and surface properties of cellulose-based activated carbon nanoplates

  • Lee, Seulbee;Lee, Min Eui;Song, Min Yeong;Cho, Se Youn;Yun, Young Soo;Jin, Hyoung-Joon
    • Carbon letters
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    • 제20권
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    • pp.32-38
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    • 2016
  • In this study, cellulose nanoplates (CNPs) were fabricated using cellulose nanocrystals obtained from commercial microcrystalline cellulose (MCC). Their pyrolysis behavior and the characteristics of the product carbonaceous materials were investigated. CNPs showed a relatively high char yield when compared with MCC due to sulfate functional groups introduced during the manufacturing process. In addition, pyrolyzed CNPs (CCNPs) showed more effective chemical activation behavior compared with MCC-induced carbonaceous materials. The activated CCNPs exhibited a microporous carbon structure with a high surface area of 1310.6 m2/g and numerous oxygen heteroatoms. The results of this study show the effects of morphology and the surface properties of cellulose-based nanomaterials on pyrolysis and the activation process.

In-situ rf treatment of multiwall carbon nanotube with various post techniques for enhanced field emission

  • Ahn, Kyoung-Soo;Kim, Jun-Sik;Kim, Ji-Hoon;Kim, Chae-Ok;Hong, Jin-Pyo
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2003년도 International Meeting on Information Display
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    • pp.859-862
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    • 2003
  • Well-aligned multiwall carbon nanotubes (MWCNTs) were prepared at low temperature of 400 $^{\circ}C$ by utilizing a radio frequency plasma-enhanced chemical vapor deposition (rf-PECVD) system. The MWCNTs were treated by an external rf plasma source and an ultra-violet laser in order to modify structural defect of carbon nanotube and to ablate possible contamination on carbon nanotube surface. Structural properties of carbon nanotubes were investigated by using a scanning electron microscopy (SEM), Raman spectroscopy, Fourier transformer Infrared spectroscopy (FTIR) and transmission electron microscope (TEM). In addition, the emission properties of the MWNTs were measured for the application of field emission display (FED) in near future. Various post treatments were found to improve the field emission property of carbon nanotubes.

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Electrical and Mechanical Properties of Graphite Nanosheet/Carbon Nanotubes-filled Epoxy Nanocomposites

  • Kim, Ki-Seok;Choi, Kyeong-Eun;Park, Soo-Jin
    • Carbon letters
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    • 제10권4호
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    • pp.335-338
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    • 2009
  • In this work, the effect of co-carbon fillers on the electrical and mechanical properties of epoxy nanocomposites was investigated. The graphite nanosheets (GNs) and multi-walled carbon nanotubes (MWNTs) were used as co-carbon fillers. The results showed that the electrical conductivity of the epoxy nanocomposites showed a considerable increase upon an addition of MWNTs when GNs were fixed at 2 wt.%. This indicated that low content GNs formed the bulk conductive network and then MWNTs added were intercalated between the GN layers, resulted in the formation of additional conductive pathway. Furthermore, the flexural strength of the epoxy nanocomposites was enhanced with increasing the MWNT content. It was probably attributed to the flexible MWNTs compared with rigid GNs, resulted in the enhancement of the mechanical properties.

탄소섬유그리드 보강 휨부재의 거동에 대한 실험적 연구 (An Experimental Study on the Behavior of Carbon Fiber Grid Reinforced Flexural Members)

  • 박제용;안동준;정상균;윤순종
    • 한국복합재료학회:학술대회논문집
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    • 한국복합재료학회 1999년도 추계학술발표대회 논문집
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    • pp.154-159
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    • 1999
  • In this paper we present tile results of an experimental investigation on the physical and mechanical properties of carbon fiber grid, polymer mortar, and carbon fiber grid reinforced plain concrete flexural members. In order to repairing and reinforcing damaged and/or deteriorated existing concrete structural members, new materials have been developed and utilized in the construction industries. But the physical and mechanical behaviors of the material are not well understood. To use the material effectively various aspects of the material must be throughly investigated analytically as well as experimentally. In this investigation we found the physical and mechanical properties of carbon fiber grid and polymer mortar which are directly utilized in the repair and reinforcement design of damaged or deteriorated concrete structures. In addition, we also investigate the strengthening effect of carbon fiber grid on the plain concrete flexural test specimens. It was found that the material can be used to repair and strengthen the concrete structures effectively.

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델파이방법을 이용한 저탄소 농촌마을 계획기술에 관한 연구 (A Study on the Development of Planning Technique in Low Carbon Rural Village by Using Delphi Method)

  • 김은자;이창훈;임창수;최진아;이정원
    • 농촌계획
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    • 제18권1호
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    • pp.29-45
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    • 2012
  • The purpose of this study is to develop planning technique for low carbon rural village planning. planning techniques (169 cases : waterside Technique 87, inland Technique 82) were extracted through a various previous studies and literature. planning techniques of 43 cases for low carbon rural village have been developed by the importance validity evaluation for planning techniques using the Delphi Method. Developed techniques can be utilized to plan low carbon rural village for Sustainable Rural Development. In addition, these techniques will be able to contribute to recognition of the need about low carbon rural village and the development of national green strategy.

일반탄소강의 상변태 중 발열 특성 해석 (Characteristics of Heat Generation during Transormation in Carbon Steels)

  • 한흥남
    • 한국소성가공학회:학술대회논문집
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    • 한국소성가공학회 2000년도 춘계학술대회논문집
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    • pp.196-201
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    • 2000
  • A thermodynamic model was developed to analyze the characteristics of the heat generation during transformation of austenite in 0.186wt% and 0.458 wt%. carbon steels. The heat capacity and the heat evolved during transformation were formulated as functions of temperature and chemical composition for ferrite bainite and pearlite. in addition using the transformation dilatometer the transformation heat evolved during cooling was measured and the transformation behavior was observed. It was found that the heat capacity of ferrite was similar to those of pearlite and bainite. The heat capacity of ferrite was greater than that of bainite which was greater than that of pearlite. The molar heat of transformation to pearlite was greater than that to bainite which was greater than that to ferrite. The heats were found to be increased with decreased temperature and increasing the carbon content, It was also observed that the thermodynamic model. The heat of transformation in the higher carbon steel was greater than that in the lower carbon one. This was attributed to the lower transformation temperature and the greater amount of transformed pearlite in the higher carbon steel.

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Geometry variation for as-grown carbon coils under the minimized sulfur additive condition

  • Lee, Seok-Hee;Kim, Sung-Hoon
    • 한국결정성장학회지
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    • 제22권5호
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    • pp.213-217
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    • 2012
  • Carbon coils could be synthesized on nickel catalyst layer-deposited silicon oxide substrate using $C_2H_2$ and $H_2$ as source gases under thermal chemical vapor deposition system. By the incorporation of $SF_6$ additive in cyclic modulation manner, the dominant formation of the nanosized carbon coils could be achieved with maintaining the minimized sulfur additive amount. The geometry variation of the as-grown carbon coils, such as linear type, microsized coil type, wavelike nanosized coil type, and nanosized coil type, were investigated according to the different cyclic modulation manner of $SF_6$ flow. $SF_6$ gas incorporation develops the coil-type geometry. Furthermore, the higher flow rate of $SF_6$ gas increased the amount of the nanosized carbon coils. The slightly increased etching ability by $SF_6$ addition seems to be the cause for these results.