• Title/Summary/Keyword: calibration equation

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NEAR INFRARED REFLECTANCE SPECTROSCOPY AS A TOOL TO PREDICT QUALITATIVE AND QUANTITATIVE MEAT AND BONE MEAL PRESENCE IN COMPOUND FEEDS

  • Fernandez, Maria;Martinez, Adela;Modrono, Sagrario;De La Roza, Begona
    • Proceedings of the Korean Society of Near Infrared Spectroscopy Conference
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    • 2001.06a
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    • pp.1269-1269
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    • 2001
  • The Bovine Spongiform Encephalopathy (BSE) is one of the more important problems that have affected the economy of european cattles and the Public Safety. Their transmission is mainly through digestive system, and the compound feeds made with animal proteins are one source of infection for healthy cows. Nowadays the official method for meat and bone meal (MBM) detection in compound feeds is a microscopy technique. However, this methodology is subjective, and that alter the fact to make one exhaustive quantitative analysis and one differentiation between mammalian and poultry bones. In addition, the separation of the differents fractions in a sample by density before the analysis, requires the use of organochlorates products as $CCl_4$, which produce serious damages in the atmosphere ozone content. NIR methodology is another possible way to confirm and identifying animal ingredients in compound feeds, Its capabilities for quantitative and qualitative analysis of foods and feeds has been enought demonstrated. The objective of this work was to use NIR as a tool to make an qualitative and quantitative analysis and a prediction of the meat and bone meal presence in compound feeds from North Spain cattle farms. Using a global population of compound feeds, on make three different groups depending of MBM percentage presence (0, 0-100, 100), to build and validate one calibration equation to determine MBM content and make one discriminant analysis between these three groups. The preliminary dates obtained with another differents samples of known composition showed promising results.

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MEASUREMENTS OF METABOLIC PARAMETERS IN LACTATING DAIRY COWS WITH NEAR INFRARED SPECTROSCOPY ANALYSIS USING CATTLE FAECAL SAMPLES

  • De la roza, Begona;Martinez, Adela;Modrono, Sagrario;Argamenteria, Alejandro
    • Proceedings of the Korean Society of Near Infrared Spectroscopy Conference
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    • 2001.06a
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    • pp.1629-1629
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    • 2001
  • The knowledge of the nutrition in animal production is difficult to assess due of difficulty to determine the amount and quality of feeds intake, mainly if forages are the most important compound in the diet. It must be able to know responses to the metabolic process in lactating dairy cows earring out feeds evaluation trials. These metabolism studies with cows, requires measurements of: I) The amount of all feeds consumed. II) Excretion of faeces. III) Excretion of urine. Taking as a basis these trials, forage and total intake, dietary digestibility and balances of nitrogen and energy can be calculated. However, these feeds evaluation experiments with animals are very time consuming and expensives. The faeces excreted by animals containt undigested residues of the diet consumed. For this reason, their analysis can be an successful tool to determine the amount and quality of feed intake and other important biological parameters. The aim of this work was to know if faeces analysis by NIR could be used to determine with enough accuracy some attributes of different lactating dairy cows diets, using a global equation, developed on an heterogeneus population. For this purpose a total of 79 faecal samples from eight grass, three grass silages and two maize silages metabolic trials, on six cows each one, were used to constitute the initial population. The calibration equations were developed to predict forage and total intake, organic matter digestibility, digestibility coefficient of crude energy and digestibility energy. The combination of several trials with different diets and animal conditions gave promising results.

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Measurement and Analysis of Free Water Evaporation at HaeNam Paddy Field (해남 농경지에서의 자유 수면 증발 관측과 해석)

  • Han Jin-Su;Lee Bu-Yong
    • Korean Journal of Agricultural and Forest Meteorology
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    • v.7 no.1
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    • pp.91-97
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    • 2005
  • Class A evaporation pan has been used throughout the world to measure free water evaporation mainly by manual observation once a day. In this study, a new automatic water level measurement method is used for understanding of free water evaporation and numerical analysis. This new technique measures the weight of buoyancy bar in water, and does not need calibration because it is not affected by water density change with water temperature. Field observations of evaporation were made near Haenam Meteorological Station over paddy field located in southwestern Korea from 20 April to 30 May 2004 and the data from ten clear days (16 - 25 May) were used for this analysis. The observed total evaporation was about 50.7mm during this period whereas the estimated from an empirical equation was 50.4mm. As expected, the pan evaporation is well correlated with wind speed and the vapor pressure deficit between the water surface and the air.

Development of Electronic Mapping System for N-fertilizer Dosage Using Real-time Soil Organic Matter Sensor (실시간 토양 유기물 센서와 DGPS를 이용한 질소 시비량 지도 작성 시스템 개발)

  • 조성인;최상현;김유용
    • Journal of Biosystems Engineering
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    • v.27 no.3
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    • pp.259-266
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    • 2002
  • It is crucial to know spatial soil variability for precision farming. However, it is time-consuming, and difficult to measure spatial soil properties. Therefore, there are needs fur sensing technology to estimate spatial soil variability, and for electronic mapping technology to store, manipulate and process the sampled data. This research was conducted to develop a real-time soil organic matter sensor and an electronic mapping system. A soil organic matter sensor was developed with a spectrophotometer in the 900∼1,700 nm range. It was designed in a penetrator type to measure reflectance of soil at 15cm depth. The signal was calibrated with organic matter content (OMC) of the soil which was sampled in the field. The OMC was measured by the Walkeley-Black method. The soil OMCs were ranged from 0.07 to 7.96%. Statistical partial least square and principle component regression analyses were used as calibration methods. Coefficient of determination, standard error prediction and bias were 0.85 0.72 and -0.13, respectively. The electronic mapping system was consisted of the soil OMC sensor, a DGPS, a database and a makeshift vehicle. An algorithm was developed to acquire data on sampling position and its OMC and to store the data in the database. Fifty samples in fields were taken to make an N-fertilizer dosage map. Mean absolute error of these data was 0.59. The Kring method was used to interpolate data between sampling nodes. The interpolated data was used to make a soil OMC map. Also an N-fertilizer dosage map was drawn using the soil OMC map. The N-fertilizer dosage was determined by the fertilizing equation recommended by National Institute of Agricultural Science and Technology in Korea. Use of the N-fertilizer dosage map would increase precision fertilization up to 91% compared with conventional fertilization. Therefore, the developed electronic mapping system was feasible to not only precision determination of N-fertilizer dosage, but also reduction of environmental pollution.

Evaluation of Modeling Approach for Suspended Sediment Yield Reduction by Surface Cover Material using Rice Straw at Upland Field (모델링 기법을 이용한 밭의 볏짚 지표피복의 부유사량 저감효과 평가 방법)

  • Park, Youn Shik;Kum, Donghyuk;Lee, Dong Jun;Choi, Joongdae;Lim, Kyoung Jae;Kim, Ki-sung
    • Journal of Korean Society on Water Environment
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    • v.32 no.1
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    • pp.108-114
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    • 2016
  • Sediment-laden water leads to water quality degradation in streams; therefore, best management practices must be implemented in the source area to control nonpoint source pollution. Field monitoring was implemented to measure precipitation, direct runoff, and sediment concentrations at a control plot and straw-applied plot to examine the effect on sediment reduction in this study. A hydrology model, which employs Curve Number (CN) to estimate direct runoff and the Universal Soil Loss Equation to estimate soil loss, was selected. Twenty-five storm events from October 2010 to July 2012 were observed at the control plot, and 14 storm events from April 2011 to July 2011 at the straw-applied plot. CN was calibrated for direct runoff, and the Nash-Sutcliffe efficiency and coefficient of determination were 0.66 and 0.68 at the control plot. Direct runoff at the straw-applied plot was calibrated using the percentage direct runoff reduction. The estimated reduction in sediment load by direct runoff reduction calibration alone was acceptable. Therefore, direct runoff-sediment load behaviors in a hydrology model should be considered to estimate sediment load and the reduction thereof.

Effect of Ethanol on the Protolytic Properties of the Vitamins B Group

  • Ghasemi, J.;Shiri, F.
    • Journal of the Korean Chemical Society
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    • v.51 no.1
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    • pp.21-30
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    • 2007
  • A multiwavelength spectrophotometric titration method was applied to study protolytic constants of four water-soluble vitamins, folic acid(vitamin B9 or B0), thiamine(vitamin B1), riboflavin(vitamin B2) and pyridoxal (vitamin B6) in binary ethanol-water mixtures at 25oC and an ionic strength of 0.1M NaNO3. The protolytic equilibrium constants, spectral profiles, concentration diagrams and also the number of components has been calculated from the curve fitting of the pH-absorbance data with appropriate mass balance equations by an established factor analysis model. DATAN program was used for determination of acidity constant and SPECFIT program was used for calculation of standard deviations and partial correlation coefficients. A glass electrode calibration procedure based on the four parameter equation pH=α+SpcH+JH+[H+]+ JOH-Kw/[H+] based on the Gran,s plots was used to obtain pH-readings in the concentration scale (pcH). The effect of the solvent on the protolytic constants was discussed.

Estimation of uncertainty for the determination of residual flubendazole in pork (돼지고기 중 플루벤다졸 잔류분석의 불확도 추정)

  • Kim, MeeKyung;Park, Su-Jeong;Lim, Chae-Mi;Cho, Byung-Hoon;Kwon, Hyun-Jeong;Kim, Dong-Gyu;Chung, Gab-Soo
    • Korean Journal of Veterinary Research
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    • v.47 no.2
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    • pp.139-145
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    • 2007
  • Measurement uncertainty could play an important role in the assessment of test results in laboratories and industries. We investigated measurement uncertainties possibly included in determination of flubendazole, a benzimidazole anthelmintic, in pork by HPLC. The concentration of flubendazole was 62.69 ng/g in a sample of pork. Uncertainty was estimated in the analytical procedure of flubendazole. A model equation was made for determination of flubendazole in pork. The four uncertainty components such as weight of sample, volume of sample, calibration curve, and recovery were selected to estimate measurement uncertainties. Standard uncertainty was calculated for each component and all the standard uncertainties were combined. The combined standard uncertainty was expanded to a sample population as an expanded uncertainty. The expanded uncertainty was calculated using k value on Student's t-table and effective degrees of freedom from Welch-Satterthwaite formula. The expanded uncertainty was calculated as 3.45 with the combined standard uncertainty, 1.584 6 and the k value, 2.18. The final expression can be ($62.69{\pm}3.45$) ng/g (confidence level 95%, k = 2.18). The uncertainty value might be estimated differently depending on the selection of the uncertainty components. It is difficult to estimate all the uncertainty factors. Therefore, it is better to take several big effecting components instead of many small effecting components.

Simulation of Soil Erosion due to Snow Melt at Alpine Agricultural Lands (고령지 농경지에서 융설에 의한 토양유실량 모의)

  • Heo, Sung-Gu;Lim, Kyoung-Jae;Kim, Ki-Sung;Myung, SaGong;An, Jae-Hun
    • Proceedings of the Korean Society of Agricultural Engineers Conference
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    • 2005.10a
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    • pp.241-246
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    • 2005
  • Doam watershed is located at alpine areas in the Kangwon province. The annual average precipitation, including snow accumulation during the winter, at the Doam watershed is significantly higher than other areas. Thus, pollutant laden runoff and sediment discharge from the alpine agricultural fields are causing water quality degradation at the Doam watershed. To estimate soil erosion from the agricultural fields, the Universal Soil Loss Equation (USLE) has been widely used because of its simplicity to use. The USLE rainfall erosivity (R) factor is responsible for impacts of rainfall on soil erosion. Thus, use of constant R factor for the Doam watershed cannot reflect variations in precipitation patterns, consequently soil erosion estimation. In the early spring at the Doam watershed, the stream flow increases because of snow melt, which results in erosion of loosened soil experiencing freezing and thaw during the winter. However, the USLE model cannot consider the impacts on soil erosion of freezing and thaw of the soil. Also, it cannot simulate temporal changes in USLE input parameters. Thus, the Soil and Water Assessment Tool (SWAT) model was investigated for its applicability to estimate soil erosion at the Doam watershed, instead of the widely used USLE model. The SWAT hydrology and erosion/sediment components were validated after calibration of the hydrologic component. The $R^2$ and Nash-Sutcliffe coefficient values are higher enough, thus it was found the SWAT model can be efficiently used to simulate hydrology and sediment yield at the Doam watershed. The effects of snow melt on SWAT estimated stream flow and sediment were investigated using long-term precipitation and temperature data at the Doam watershed. It was found significant amount of flow and sediment in the spring are contributed by melting snow accumulated during the winter. Thus, it is recommend that the SWAT model capable of simulating snow melt and long-term weather data needs to be used in estimating soil erosion at alpine agricultural land instead of the USLE model for successful soil erosion management at the Doam watershed.

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Estimation of Runoff Curve Number for Chungju Dam Watershed Using SWAT (SWAT을 이용한 충주댐 유역의 유출곡선지수 산정 방안)

  • Kim, Nam-Won;Lee, Jin-Won;Lee, Jeong-Woo;Lee, Jeong-Eun
    • Journal of Korea Water Resources Association
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    • v.41 no.12
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    • pp.1231-1244
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    • 2008
  • The objective of this study is to present a methodology for estimating runoff curve number(CN) using SWAT model which is capable of reflecting watershed heterogeneity such as climate condition, land use, soil type. The proposed CN estimation method is based on the asymptotic CN method and particularly, it uses surface flow data simulated by SWAT. This method has advantages to estimate spatial CN values according to subbasin division and to reflect watershed characteristics because the calibration process has been made by matching the measured and simulated streamflows. Furthermore, the method is not sensitive to rainfall-runoff data since CN estimation is on a daily basis. The SWAT based CN estimation method is applied to Chungju dam watershed. The regression equation of the estimated CN that exponentially decays with the increase of rainfall is presented.

Evaluation of Critical Flow Factor in Natural Gas Flow Measurement Using Sonic Nozzle and International Comparison Results (소닉노즐을 이용한 천연가스 유량측정에서 임계유동인자 계산 및 국제비교 결과)

  • Ha, Youngcheol;Her, Jaeyoung
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.23 no.7
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    • pp.911-917
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    • 1999
  • The sonic nozzle is widely used as reference device for calibrating flowmeters In gas flow measurement and its use requires the Critical Flow Factor(CFF) based on the thermodynamic properties of the gas at the nozzle throat. ISO-9300 provides the calculating method of the factor. But since the CFF from this method show an error over ${\pm}0.5%$ In specific conditions and of ${\pm}0.1{\sim}{\pm}0.2%$ in common Natural Gas(NG) custody transfer condition. this method cannot be applied for gas flow measurement with sonic nozzle. Each research bodies or organizations of the world have joined in order to calculate the CFF more accurately. They have performed these works using their own method and compared the results with each other under the management of ISO. KOGAS have joined those works, because the high-pressure natural gas flow calibration facility of KOGAS will be constructed in late 1999, and then had necessities to calculate a CFF accurately. The calculation method of KOGAS was using the equation of state from AGA-8('94), high accuracy model of ideal gas properties and the solutions of thermodynamic equations. The evaluation results have had a very good consistency within ${\pm}0.05%$ in most NO custody transfer conditions compared to the speed of sound for methane and also shown that the CFF was within ${\pm}0.1%$ compared to the results of other works of the world.