• Title/Summary/Keyword: calcium-sulfo-aluminate

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Basic Study on Development of Ultra-high Strength Grout for Offshore Wind Turbines (해상풍력 발전기용 초고강도 그라우트 개발을 위한 기초적 연구)

  • Lim, Myung-Kwan;Ha, Sang-Su
    • KIEAE Journal
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    • v.15 no.1
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    • pp.155-160
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    • 2015
  • The annual average of energy sources is continuously increasing at a rate of 5.8%, and particularly, the power generation proportion of new/renewable energy is increasing significantly. Furthermore, South Korea has established a national energy master plan for 2008-2030 and is aiming at obtaining approximately 11% of total energy production from the wind turbine sector. Although offshore wind turbines are similar to wind turbines installed on land, they require materials with excellent dynamic properties and durability to prevent damage due to seawater at the lower parts and connecting parts. The lower parts of wind turbines are submerged in seawater, and the upper and lower parts are connected by filling the connecting part with grout. This paper describes the test results of the process of determining the mix ratios to develop ultra-high grout for offshore wind turbines. There is virtually no relevant technology regarding grout for offshore wind turbines in South Korea that can be referenced for the process of determining the mix ratios. Therefore, tests were conducted for determining compression strength, elastic modulus, flexural strength, density, constructability (floor test), and early strength by referencing a high-performance grout produced in South Korea, and the mixing process for achieving the goal strengths was described using the Korean Industrial Standards (KS) as the reference.

Characterizations of High Early-Strength Type Shrinkage Reducing Cement and Calcium Sulfo-aluminate by Using Industrial Wastes

  • Lee, Keon-Ho;Nam, Seong-Young;Min, Seung-Eui;Lee, Hyoung-Woo;Han, Choon;Ahn, Ji-Whan
    • Journal of the Korean Ceramic Society
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    • v.53 no.2
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    • pp.215-221
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    • 2016
  • In this study, the utilization of the by-products of various industries was examined using raw materials of CSA high-functional cement such as coal bottom ash, red mud, phosphate gypsum, etc. Technology to improve energy efficiency and reduce $CO_2$ was developed as part of the manufacturing process; this technology included lower temperature sintering ($150{\sim}200^{\circ}C$) than is used in the OPC cement manufacturing process, replacement of CSA cement with the main raw material bauxite, and a determination of the optimum mix condition. In order to develop CSA cement, a manufacturing system was established in the Danyang plant of the HANIL Cement Co. Ltd., in Korea. About 4,200 tons of low purity expansion agent CSA cement (about 16%) and about 850 tons of the lime-based expansion agent dead burned lime (about 8%) were produced at a rate of 60 tons per hour at the HANIL Cement rotary kiln. To improve the OPC cement properties, samples of 10%, 13%, and 16% of CSA cement were mixed with the OPC cement and the compressive strength and length variation rate of the green cement were examined. When green cement was mixed with each ratio of CSA cement and OPC cement, the compressive strength was improved by about 30% and the expansibility of the green cement was also improved. When green cement was mixed with 16% of CSA cement, the compressive strength was excellent compared with that of OPC cement. Therefore, this study indicates the possibility of a practical use of low-cost CSA cement employing industrial wastes only.

Evaluation of Crack Resistant Performance in Cement Mortar with Steel Fiber and CSA Expansion Admixture (CSA 팽창재를 혼입한 강섬유 보강 모르타르의 균열 저항성능 평가)

  • Ahn, Jung-Kil;Park, Ki-Tae;Kwon, Seung-Jun
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.18 no.3
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    • pp.125-132
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    • 2014
  • Steel fiber is a effective composite for crack resistance and improve structural performance under tensile loading. This study presents an evaluation of crack resistance and structural performance in cement mortar with steel fiber and expansion agent through internal chemical prestressing. For this work, cement mortar samples with 10% replacement of cement binder with CSA (Calcium-Sulfo-Aluminate) expansion agent and 1% volume ratio of steel fiber are prepared. Including basic mechanical properties, initial cracking load and fracture energy are evaluated in cement mortar beam with notch. Initial cracking load and fracture energy in cement mortar with CSA and steel fiber increase by 1.75 and 1.41~1.53 times compared with those in cement mortar with steel fiber. With optimum mix design for steel fiber and CSA expansive agent, the composite with chemical prestressing can be applied to various members and effectively improve crack resistance to external loading.

Influence of Alkali Activator Type and Amount of Addition on CO2 Uptake of GGBFS Geopolymer Pastes Containing Zeolite (알칼리계 활성화제의 종류 및 첨가량이 고로슬래그-제올라이트 지오폴리머 페이스트의 탄소포집에 미치는 영향에 관한 연구)

  • Jang-Hyun Park;Hyo-Min Kim
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.11 no.2
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    • pp.112-119
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    • 2023
  • In this study, the variations in CO2 uptake according to the type and amount of alkali-based activator (Ca(OH)2, CSA) of geopolymer paste were evaluated. As the amount of activator added to the geopolymer paste increased, the fluidity of the paste is decreased and the compressive strength increased. According to the type of activator, it was confirmed that the addition of Ca(OH)2 had a greater effect on improving the compressive strength than CSA. As a result of changes in chemical properties according to carbonation curing, the amount of C-S-H and C-A-S-H gels produced before carbonation increased as the amount of activator increased, and amount of CaCO3 produced after carbonation increased. The reactivity of the blast furnace slag and zeolite increased due to the addition of the activator, and the reactivity tended to increase as the amount of addition increased. As a result of CO2 uptake, 10.3 wt% when Ca(OH)2 10 % was added and 8.77 wt% when CSA 10 % was added was confirmed. It increased by 421 % and 388 % respectively, compared to the case where no activator was added.

Tension-Stiffening and Cracking Behavior of 100 MPa Shrinkage-Compensated Ultra High-Strength Strain-Hardening Cement Composite (UHS-SHCC) Ties (100 MPa급 수축보상 초고강도 변형경화형 시멘트 복합체를 사용한 인장부재의 인장강성 및 균열특성)

  • Song, Young-Jae;Yun, Hyun-Do
    • Journal of the Korea Concrete Institute
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    • v.25 no.4
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    • pp.371-379
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    • 2013
  • This paper investigates the cracking and tension-stiffening behavior of 100 MPa shrinkage-compensated strain-hardening cement composite (SHCC) and conventional concrete tie elements in monotonic and cyclic tension. Strain and surface crack formation of tension ties were monitored with two strain displacement transducers and a photo microscope with a lens of magnification 50 times. Three different cement composites such as conventional concrete, shrinkage-compensated SHCC, and normal SHCC were used in the tie specimens to investigate the influence of the cement composite type on the tension stiffening and cracking behavior. Test results indicated that initial shrinkage of the ultra high-strength cement composites is greatly reduced as the 10% replacement of cement by the shrinkage-compensating admixture based on calcium sulfo-aluminate (CSA). The test results on the SHCC tension ties showed that the first cracking load decreases proportionally to the initial shrinkage strain. Reinforced ultra high-strength SHCC ties with the initial shrinkage compensation exhibited improved tension stiffening and smaller crack spacings, i.e. the reduction in crack width. Cyclic loading did not have a significant effect on tension stiffening and cracking behavior of tension ties with normal concrete and SHCC materials.

Engineering Performance and Applicability of Eco-Friendly Concrete for Artificial Reefs Using Electric Arc Furnace Slags (전기로 슬래그를 활용한 인공리프용 친환경콘크리트의 공학적 성능 및 적용성)

  • Jo, Young-Jin;Choi, Se-Hyu
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.35 no.3
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    • pp.533-544
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    • 2015
  • Unlike the concrete structure built on land, that exposed to the marine environment is greatly degraded in durability due to the exposure to not only the physical action caused by sea wind, tide, and wave, but also the harsh conditions, including the chemical erosion and freeze-thaw which result from $SO_4{^{2-}}$, $Cl^-$ and $Mg^{2+}$ ions in seawater. In the process of the large scaled construction of submerged concrete structures, of course environmental hazardous substance, such as alkaline (pH) and heavy metals, may be leached. Thus, this issue needs to be adequately reviewed and studied. Therefore, this study attempted to develop a CSA (Calcium Sulfo Aluminate) activator using electric arc furnace reducing slags, as well as the eco-friendly concrete for artificial reefs using electric arc furnace oxidizing slag as aggregate for concrete. The strength properties of the eco-friendly concrete exposed to the marine environment were lower than those of the normal concrete by curing 28 days. This suggest that additional studies are needed to improve the early strength of the eco-friendly concrete. With respect to seawater resistance of the eco-friendly concrete, the average strength loss against 1 year of curing days reached 8-9%. the eco-friendly concrete using high volume of ground granulated blast furnace slags and high specific gravity of electronic arc furnace oxidizing slag demonstrated the sufficient usability as a freeze-thaw resistant material. With respect to heavy metal leaching properties of the eco-friendly concrete, heavy metal substances were immobilized by chemical bonding in the curing process through the hydration of concrete. Thus, heavy metal substances were neither identified at or below environmental hazard criteria nor detected, suggesting that the eco-friendly concrete is safe in terms of leaching of hazardous substances.