• Journal of the Korea institute for structural maintenance and inspection
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• v.16 no.5
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• pp.59-67
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• 2012

During the manufacturing of Portland cement, CO2 gas is also necessarily produced through both decarbonation of calcium carbonate and kiln burning. By partially replacing the Portland cement with limestone powder, which is an inert filler in a concrete mixture, CO2 consumption can be reduced in a construction field. This study is to investigate the fundamental durability characteristics of limestone powder added concrete. Experimental variable was the replacement ratio of limestone powder from 0% to 25% with 5% increment. Durability characteristics were investigated by resistance to freeze-thaw, alkali-silica reaction and de-icing chemical in addition to the properties of fresh concrete. From test results, it was observed that the addition of limestone powder did not significantly affect the resistance to freeze-thaw reaction and de-icing chemical. The addition of limestone powder reduced the occurrence potential of alkali-silica reaction by reducing an alkali content in Portland cement.

• Elastomers and Composites
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• v.38 no.4
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• pp.342-353
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• 2003

This work is about the development of jet-fuel resistant PVC sealant using a polyester plasticizer. PVC copolymer was compounded with adipic acid glycol(Songcizer P-3000) or DOP plasticizers. Fuel-immersed and non-immersed penetration, solubility, flow, and elongation by tensile adhesion of PVC compounds were measured. Penetration increase by fuel immersion and solubility of PVC compounds with adipic acid glycol polyester plasticizer were smaller than those of PVC compounds with DOP plasticizer. Elongation by tensile adhesion test of PVC compound containing 500 phr of Songcizer P-3000 decreased proportionally to the content of DCDP (dicyclopentadiene) base petroleum resin adhesion promoter. Calcium carbonate($CaCO_3$) filler inhibited the diffusion of fuel in all the PVC compounds and decreased the solubility of PVC compounds containing Songcizer P-3000.

• Journal of the Korean Institute of Gas
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• v.2 no.3
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• pp.1-11
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• 1998

To increase peel strength, low temperature properties and flowability of pressure sensitive adhesives(PSA) used in a heat shrinkable sheet, these properties were evaluated by changing each components in type and content. In this study, Isobutylene-co-Isoprene Rubber (IIR) which has good wetherability was selected as a base polymer. Instead of rosin ester, petroleum resin was selected as a tackifier because of superior peel strength. By decreasing petroleum resin contents, flowability of PSA was decreased. High molecular weight of polybutene was better than low molecular weight for the peel strength of PSA. Large particle size of carbon black showed better properties than small one in peel strength and brittleness temperature. By adding calcium carbonate, the cost of compound was able to be reduced. But it must be used with carbon black.

• Journal of the Korean earth science society
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• v.24 no.5
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• pp.477-490
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• 2003

Bottom sediments from Youngil Bay, East Coast of Korea, were analyzed for grain composition as well as elemental compositions and total organic carbon (TOC) content in order to investigate the spatial variability and content of metal elements. Grain size distribution of the sediments seems to be controlled by anticlockwise current pattern with bottom topography of the study area. Spatial variability of TOC and all elemental contents reflects those of grain size, but an exception was found in the harbor area (Old-Port): their contents are high in the central part of the bay with the muddy sediment and decrease toward the sand-dominated coastal zone. However, contents of Ca, Sr, K are high in the sand-dominated coastal zone and contents of some heavy metals (Cd, Cu, Zn) are high in the Old-Port area and the mouth of Hyeongsan River. The correlation matrix and R-mode factor analyses reveal that four important factors controlling the distribution of metals in the bay are sediment grain size (or quartz dilution effect), the formation of sulfide minerals associated with decomposition of organic matters under anoxic geochemical environment, calcium carbonate (mainly shell fragments) and coarse-grained feldspar mineral. According to the metal content of labile fraction an CER (concentration enrichment ratio) value, high accumulation of some heavy metals in the harbor area seems to result not formed by early diagenetic processes under anoxic environment.

• Journal of the Korea institute for structural maintenance and inspection
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• v.20 no.5
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• pp.75-84
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• 2016

This paper presents an investigation of the mechanical properties on non-sintered cement pastes immersed in sea waters at three different temperatures. The non-sintered cement pastes were synthesized using blended binder(Class F fly ash; FA and ground granulated blast furnace slag; GGBFS) and alkali activator(sodium hydroxide and sodium silicate). Binders were prepared by mixing the FA and GGBFS in different blend weight ratios of 6:4, 7:3 and 8:2. The alkali activators were used 5wt% of blended binder, respectively. Calcium carbonate was used as an chemical additive. The compressive strength, bulk density and absorption of alkali-activated FA-GGBFS blends pastes were measured at 3 and 28 days after immersed in sea waters at three different temperatures($5^{\circ}C$, $15^{\circ}C$ and $25^{\circ}C$). The XRD and SEM tests of the pastes were conducted at 28 days. Water-soluble chloride(free chloride) and acid-soluble chloride(total chloride) contents in the pastes were also measured after 28 days immersion in sea water. The experimental results showed that increasing the content of FA in alkali-activated FA-GGBFS blends pastes immersed in sea water increases the absorption, water-soluble chloride content and acid-soluble chloride content, and reduces the compressive strength and bulk density. And it was found that there was a variation of strength change for the alkali-activated FA-GGBFS blends pastes immersed in sea waters at three different temperatures that depends on the blending ratio of FA and GGBFS.

• The Korean Journal of Quaternary Research
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• v.5 no.1
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• pp.15-31
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• 1991

A total of 90 surface sediment samples, collected from the continental margin area bordering east and southeast coast of Korea, were subject to the geochemical analyses with the aim of filling the gap in our knowledge of this environment. The analyzed items included the major elements (Al, Fe, Mg, Ca, K, Na, p and Mn), organic carbon, and some trace metals (Ba, Co, Cu, Sr and Zn). The sediment grain-size exerted a predominant influence on the contents of most elements, with the exceptions of Ca, K, Sr and Ba. The Ca and Sr contents, being closely interrelated each other, were mainly controlled by the calcium carbonate content. The K content, on the other hand, appeared to be influenced by both illite and feldspar. The Ba content showed a certain relationship with that of K, suggesting a common source of these two elements; potassium feldspar. The R-mode factor analysis result also reaffirmed the above-mentioned controlling factors on the sediment geochemistry. The grain-size dependency of trace metals obscures their areal distribution pattern from the total contents. However, with the metal/aluminum ratios we could differentiate the subtle difference in the metal enrichment. Hence, sediments of the southern coastal area appear to receive some anthropogenic inputs of metals, though the effect is still negligible.

• Elastomers and Composites
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• v.55 no.4
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• pp.306-313
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• 2020

To investigate the reinforcing effects of functional fillers in nitrile rubber (NBR) materials, high-structure carbon black (HS45), coated calcium carbonate (C-CaCO3), silica (200MP), and multi-walled carbon nanotubes (MWCNTs) were used as functional filler, and carbon black (SRF) as a common filler were used for oil-resistant rubber. The curing and mechanical properties of HS45-, 200MP-, and MWCNT-filled NBR compounds were improved compared to those of the SRF-filled NBR compound. The reinforcing effect also increased with a decrease in the particle size of the fillers. The C-CaCO3-filled NBR compound exhibited no reinforcing effect with increasing filler concentration because of their large primary particle size (2 ㎛). The reinforcing behavior based on 100% modulus of the functional filler based NBR compounds was compared by using several predictive equation models. The reinforcing behavior of the C-CaCO3-filled NBR compound was in accordance with the Smallwood-Einstein equation whereas the 200MP- and MWCNT-filled NBR compounds fitted well with the modified Guth-Gold (m-Guth-Gold) equation. The SRF- and HS45-filled NBR compounds exhibited reinforcing behavior in accordance with the Guth-Gold and m-Guth-Gold equations, respectively, at a low filler content. However, the values of reinforcement parameter (100Mf/100Mu) of the SRF- and HS45-filled NBR compounds were higher than those determined by the predictive equation model at a high filler content. Because the chains of SRF composed of spherical filler particles are similarly changed to rod-like filler particles embedded in a rubber matrix and the reinforcement parameter rapidly increased with a high content of HS45, the higher-structured filler. The reinforcing effectiveness of the functional fillers was numerically evaluated on the basis of the effectiveness index (��SRF/��f) determined by the ratio of the volume fraction of the functional filler (��f) to that of the SRF filler (��SRF) at three unit of reinforcing parameter (100Mf/100Mu). On the basis of their effectiveness index, MWCNT-, 200MP-, and HS45-filled compounds showed higher reinforcing effectiveness of 420%, 70%, and 20% than that of SRF-filled compound, respectively whereas C-CaCO3-filled compound exhibited lower reinforcing effectiveness of -50% than that of SRF-filled compound.

• Journal of Wetlands Research
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• v.17 no.3
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• pp.293-302
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• 2015

This study investigated sediment oxygen consumption rates and geochemical characteristics of sediment in hypoxic area of the Gamak Bay based on the chamber experiments and geochemical analyses. The organic carbon contents of surface sediment in the Gamak Bay showed that the inner bay area has higher organic carbon content than those of the outer bay. They toward the outer bay, contents dropped off. The vertical profiles of calcium carbonate ($CaCO_3$) content at piston core sediment assumed that the hypoxia have been frequently occurred during past century in the northern inner bay. The benthic chamber experiments were conducted in February, May, August and November 2010, 2011 in the hypoxic area of the Gamak Bay. In the sediment incubation experiment with chamber at site C3 in the northern inner bay and site C17 in the southern outer bay, the sediment oxygen consumption rate ranged from $3.98mmol\;m^{-2}d^{-1}$ to $12.43mmol\;m^{-2}d^{-1}$ and $3.28mmol\;m^{-2}d^{-1}$ to $8.18mmol\;m^{-2}d^{-1}$, respectively. When the oxygen was completely depleted, the toxic hydrogen sulfide was released with $1.38mmol\;m^{-2}d^{-1}$ and $1.3mmol\;m^{-2}d^{-1}$, respectively.

• Journal of the Korea Concrete Institute
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• v.18 no.2 s.92
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• pp.227-232
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• 2006

This article presents the results of experimental study that investigates the effect of filler and shrinkage reducing agent influencing on the strength properties of MMA-modified polymer paste that was produced to develop the surface-repair and coating materials of the concrete structures. Results show that the flexural and compressive strengths of the polymer paste increased 29 and 27%, respectively, when the aluminum hydroxide completely replaced the calcium carbonate as the filler Furthermore, when the shrinkage reducing agent was used 30%, both strengths decreased about 29% comparing to when the agent was not used. As in the cases of flexural and compressive strengths, the adhesive strength increased as the content of aluminum hydroxide as the filler increased, and it decreased as the content of shrinkage reducing agent increased. The adhesive strength with a dry concrete substrate turned out to be $30{\sim}40%$ higher than that with a wet concrete substrate.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.32 no.4
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• pp.151-158
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• 2022

In this study, the waste concrete sample obtained as various particle size (0~2.36 mm) was carried out the basic measurements and carbonation for analyzing the possibility of its carbonation. It was then investigated some analysis such as crystallization (XRD pattern), microstructure (SEM), and the production of CaCO₃ through the ignition loss (TG-DTA). The content of CaCO₃ in the waste concrete sample before carbonation was found in 14.51 % and 28.52 % after carbonation in 24 hours. Moreover, the content of CaCO₃ carbonated in 24 hours with fine grinded waste concrete sample was 32.73 %. The carbonation of the waste concrete sample was rapidly performed up to 6 hours, but gradually increased from 12 to 24 hours. Especially, the amount of CaCO₃ between 12 and 24 hours was only produced 2.32 %. The calcite-shaped CaCO₃ crystals after carbonation of the waste concrete sample were found in microstructure and their peaks were strongly detected on XRD pattern.