• 한국결정성장학회지
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• 제5권2호
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• pp.175-180
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• 1995

석탄회의 성상 해명의 일환으로서, 석회석의 열처리 조건과 광물조성의 관계를 검토했다. 석탄회의 주 광물조성은 mullite, quartz 및 유리상(약 20 ~ 25wt%)이었으며, $1000^{\circ}C $ 까지는 거의 변화가 없었다. 안산의 석탄회 중에는 calcite가 함유되었으며, $1200^{\circ}C $ 에서 calcite 분해로부터 온 CaO, quartz 및 유리상 중의$Al_2O_3$가 반응하여 anorthite($CaO{\cdot}Al_2O_3{\cdot}2SiO_2$)로 바뀌는 것을 알 수 있었다.

• 자원환경지질
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• 제24권2호
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• pp.177-186
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• 1991

Ogchon Supergroup directly contacts with Choseon Supergroup in the northern area of Worak-san, where evidences indicating thrust-fault formed during $D_2$-deformation are observed. On footwall of thrust fault, calcite veins in Gounri Formation belonging to Choson Supergroup may be deformed during thrust faulting($D_2$). Calcite veins are parallel to axial plane cleavage($S_2$) of $F_2$ fold and truncate slaty cleavage($S_1$). Therefore, we can use deformation twins in calcite grains of the veins as a marker for inferred differential stress operated upon thrust faulting. The inferred differential stresses are estimated at 190 Mpa from K, sample. The stress from K, sample close to the contact between Ogchon Supergroup and Choseon Supergroup shows a higher value than $K_2$-$K_6$ samples, probably having an important influence upon thrust faulting. The differential stress reveal again high value at $K_7$ sample, which may suggest the presence of another thrust fault.

• 한국표면공학회지
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• 제51권5호
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• pp.325-331
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• 2018

Calcium carbonate($CaCO_3$) films were formed by an eco-friendly electro-chemical technique on steel substrates in synthesized distilled water solutions containing $NaHCO_3$, $CaCl_2$ and $MgCl_2$ with different ratio respectively. It was investigated to confirm the effect of $Mg^{2+}$ concentration by Scanning Electron Microscopy(SEM), Energy Dispersive x-ray Spectroscopy(EDS) and X-Ray Diffraction(XRD) respectively. From an experimental result, only calcite crystals were found in solution containing no $Mg^{2+}$. By increasing concentration of $Mg^{2+}$, deposition rate decreased and crystal structure was transformed form calcite to aragonite. In case of including $MgCl_2$ 300mM in synthesized solutions containing $NaHCO_3$, $CaCl_2$ 60mM, it was showed over the 90% of aragonite contents which have quite high deposition rate of aragonite. Also, it was confirmed that $Mg^{2+}$ acted as inhibitor on the films which made transforming from calcite to aragonite.

• 지질공학
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• 제24권3호
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• pp.311-322
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• 2014

Limestone bodies under the tectonic environment have experienced various tectonic processes, and also changed the stress state. In this study, calcite twins found in limestones of the Joseon Supergroup and Pyeongan Supergroup in the northeastern part of the Ogcheon Belt, South Korea were measured, then the paleostress (i.e., the maximum shortening axis) was reconstructed using the new calcite strain gauge (NCSG) technique. The average twin thickness and average twin intensity increase as the total twin strain increases. We utilize the appearance of twins, the average twin thickness and average twin intensity, and the total twin strain to estimate that the observed calcite twins were produced at temperatures of < $200^{\circ}C$ in the Joseon Supergroup and $170^{\circ}C$ in the Pyeongan Supergroup. In the Joseon Supergroup, the dominant direction of the maximum shortening axis WNW-ESE to NW-SE; NE-SW shortening is also observed. The maximum shortening axes in the Pyeongan Supergroup are oriented NW-SE and NE-SW. The NE-SW direction of maximum shortening is associated with the occurrence of the Songrim orogeny of the Paleozoic to Early Jurassic, and the NW-SE direction of maximum shortening correlates to the Daebo orogeny of the Early Jurassic to Late Jurassic. It is thus concluded that the paleostress across the study area changed from NE-SW to NW-SE during the Mesozoic.

• 한국산학기술학회논문지
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• 제11권10호
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• pp.4069-4074
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• 2010

침전탄산칼슘 결정화계에서 첨가제인 ethylenediaminetetraacetic acid(EDTA), diethylene triaminepentaacetic acid(DTPA), citric acid(CIT), pyromellitic amid(PMA) 첨가에 의한 탄산칼슘 결정의 형상 변화를 연구하였다. 첨가제를 넣지 않았을 때 낮은 온도 $20^{\circ}C$에서는 calcite 결정이 생성되었고, 높은 온도 $80^{\circ}C$에서는 aragonite 결정이 생성되었으며 EDTA 와 DTPA 첨가에 의한 $40^{\circ}C$, $60^{\circ}C$ 중간온도에서는 aragonite 결정이 생성됨을 알 수 있었다. CIT와 PMA 첨가에 의해 aragonite의 성장이 지연 되었으며 calcite 단일상이 나타났다. 첨가제가 단일상의 탄산칼슘을 만드는데 중요한 요소임을 발견되었다.

• 한국지하수토양환경학회지:지하수토양환경
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• 제7권2호
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• pp.45-52
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• 2002

문경지역 온천은 칼슘-중탄산 온천으로 원수의 온도는 약 $28.5^{\circ}C$이다 원수는 EC(1,857 $\mu\textrm{s}$/cm), $HCO_3$ (1,250 mg/l), $SO_4$(147.60 mg/l), Mg(43.05 mg/l) . 그리고 Ca(279.43 mg/l)로 상당히 높은 값을 나타낸다. 원수에는 소량의 침전물이 형성되지만 보일러로 가열할 경우 많은 양의 침전물이 형성된다. 원수에서 침전되는 광물은 대부분 방해석이지만 보일러실에는 아라고나이트와 방해석이 동시에 정출된다. 온천수 내의 화학종은 $CO_3$는 대부분 $HCO_3^{-}$ 이지만 상당 부분이 $H_2$$CO_3$로, $SO_4$는 $SO_4^{2-}$ , Mg는 $Mg^{2+}$ Ca는$ Ca^{2+}$ 로 존재한다. 전체적으로 볼 때 대부분의 성분에서 $CO_3$를 포함한 화학종이 존재하는 것을 볼 수 있다. 포화지수를 근거로 침전 가능한 광물은 다이아스포어, 보에마이트, 깁사이트, 아라고나이트, 방해석, 능철석 등이지만 X-선회절 분석결과 침전물은 아라고나이트, 방해석, 철수산화물로 구성되어 있다.

• 한국지반공학회지:지반
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• 제6권1호
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• pp.15-24
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• 1990

This paper describes the results of study on major factors influencing time-dependent deformation behaviour of swelling shales. The study was carried out by analyzing all the swell test results available for shales from southern Ontario. Major factors studied are (1) the presence of ambient water, (2) calcite content and (3) the applied stress. The results of the study on seven shales show that the swelling of shale is associated with the formation of cracks and the absorption of water in these cracks. The magnitude of swelling potential is related linearly to the amount of absorbed water. The presence of calcite inhibits the swelling of shales studied, reducing the swelling to zero at about 30% of calcite content. All the shales studied exhibit the stress-dependent swelling behaviour, though there Is a difference in the degree of dependency.

• 동굴
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• 제75호
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• pp.21-33
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• 2006

Yangdan Cave displays as a Vadose Cave rathre than a Phreatic Cave due to its fluvial activated ramnants of the cave beds and walls. Geochemistry experiments of the speleothem (stalactite and stalagmite)were generated in order to find out the cave material characteristics using XRD. The results present that the composition of the cave materials consists of Calcite, Dolomite, Quartz, K, K-Feldspar. Plagioclasc, Illite, and Kaolinite. These materials commonly exhibited less mineral composition than other caves. In terms of calcite compostion of the cave the upper cave materials (d=3.049) contain less than lower cave materials (d=3.055). Finally the calcite compostion of the cave materials between stalactite (d=3.055) and stalagmite (d=3.054) displays simillar values.

• Journal of Microbiology and Biotechnology
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• 제20권11호
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• pp.1571-1576
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• 2010

Two bacterial strains designated as CT2 and CT5 were isolated from highly alkaline cement samples using the enrichment culture technique. On the basis of various physiological tests and 16S rRNA sequence analysis, the bacteria were identified as Bacillus species. The urease production was 575.87 U/ml and 670.71 U/ml for CT2 and CT5, respectively. Calcite constituted 27.6% and 31% of the total weight of sand samples plugged by CT2 and CT5, respectively. Scanning electron micrography analysis revealed the direct involvement of these isolates in calcite precipitation. This is the first report of the isolation and identification of Bacillus species from cement. Based on the ability of these bacteria to tolerate the extreme environment of cement, they have potential to be used in remediating the cracks and fissures in various building or concrete structures.

• 한국건축시공학회:학술대회논문집
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• 한국건축시공학회 2019년도 추계 학술논문 발표대회
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• pp.73-74
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• 2019

In order to examine the chemical stabilization through DCG curing of cement paste exposed to high temperature environment, we produced a sample of 40% W/C cement paste and heated it for 180 minutes under the heating temperature of $800^{\circ}C$. The DCG curing time was 6, Three time conditions were divided into 12 and 18 hours. As a result of XRD analysis, Calcite ($CaCO_3$) was found in Theta 29.4, 40, and 46.5o. As the curing time increased, the peak of Calcite also increased, which is due to the increased reaction time with DCG. Therefore, Calcite produced through DCG curing seems to have stabilized chemically by filling the pores generated by heating.