• Title/Summary/Keyword: butyl rubber

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Modification of EPDM Rubbers for Enhancement of Environmental Durability of Aerator Membrane (산기관용 멤브레인 고무판의 환경내구성 향상을 위한 EPDM 고무의 개질)

  • Ahn, Won-Sool
    • Journal of Environmental Science International
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    • v.17 no.1
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    • pp.107-112
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    • 2008
  • A study on the enhancement of environmental durability of EPDM rubber materials for the aerator membrane was performed using a butyl rubber as a modifier. A conventional EPDM rubber formulation was evaluated as having about 26.0 wt% or more oil content from the chloroform immersion test. These oils would be gradually and continuously deleted from the aerator membrane when directly exposed to a waste-water or chemically corrosive fluids, making the membrane less flexible and the performance worse. To improve this, a butyl rubber (IIR) was utilized as the modifier for a low-ENB type of EPDM rubber formulation with low-oil content. The environmental durability of the IIR-modified EPDM rubber material was expected to be greatly enhanced compared to the conventional one. However, the mechanical and performance properties such as elongation, tensile strength, and air bubble size, etc. were still maintained as good as in the conventional one. Furthermore, TGA analysis of the IIR-modified EPDM material showed that there would be partially compatible between IIR and EPDM. It also showed that the initial degradation temperature of the IIR-modified EPDM could be somewhat increased, exhibiting the enhanced compatibility among the components and, thereby, more enhanced environmental durability.

A Study on the Adhesion Performance of Acrylate Using Tack Rolling Ball Test (Tack Rolling Ball Test를 활용한 아크릴레이트의 점착 성능에 대한 연구)

  • Yoon, Jun-No;Park, Wan-Goo;Park, Jin-Sang;Choi, Su-Young;Kim, Byoung-Il;Oh, Sang-Keun
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2018.11a
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    • pp.173-174
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    • 2018
  • In this study, the objective of this study was to evaluate the adhesive characteristics of existing self-adhesive rubber asphalt sheet, butyl sheet and acrylate sheet in a low temperature environment through Tack Rolling Ball Test to obtain basic data on acrylate. As a result of this experiment, in the case of the self-molding rubber asphalt sheet and the butyl rubber sheet, the compound of the sheet was frozen in the low temperature environment and the iron bead was separated. On the other hand, the acrylate sheet did not freeze the acrylate even at 0 ℃, It is confirmed that the measured value is shown by Ball Test.

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Acoustic Properties of Rubber Compound for Anechoic Coating

  • Bae, Jong Woo;Kim, Won Ho;Ahn, Byung Hyun
    • Elastomers and Composites
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    • v.53 no.4
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    • pp.195-201
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    • 2018
  • Three kinds of rubber compounds were prepared, and their underwater acoustical properties were investigated for anechoic coating. Dynamic mechanical properties of the rubber compounds were measured using a dynamic mechanical analyzer and extended to 100 kHz using time-temperature superposition. The sound speed, reflection coefficient, and attenuation constant were calculated. Silicone rubber showed the lowest reflection coefficient, and nitrile rubber showed the highest attenuation constant. The acoustic properties of nitrile rubber compounds with various compositions were investigated. The sound speed, reflection coefficient, and transmission coefficient of the nitrile rubber in the frequency range of 200-1000 kHz were measured in a water-filled tank.

High Performance Barrier Technologies for Tire Innerliner (타이어 인너라이너용 고차단화 기술)

  • Kang, Yong-Gu;Lee, Seong-Peal;Han, Min-Hyun
    • Elastomers and Composites
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    • v.46 no.2
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    • pp.102-111
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    • 2011
  • The innerliner for a tire has excellent impermeability, air retention and good flex properties. The innerliner offers a role to improve performance parameter, such as air retention and tire durability that is of praricular importance for commercial tires. In order to improve the gas barrier properties of a innerliner, most of the innerliner rubbers, such as a halogenated butyl rubber(HIIR), brominated poly(isobutylene-co-isoprene)(BIIR), brominated polyisobutylene-co-paramethylstyrene(BIMS) are used as nanocomposites with nano fillers such as silicates, graphite etc. Innerliners based on nanocomposites may allow gauge adjustments and permeability reductions with potential improvement in tire durability. This article discusses potential innerliner permeablity reduction and compounding parameters on the properties of nanocomposite based innerliners.

Wax Barrier Effect on Migration Behaviors of Antiozonants in NR Vulcanizates (천연고무 가류물에서 왁스막이 오존노화방지제의 이동에 미치는 영향)

  • Choi, Sung-Seen
    • Elastomers and Composites
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    • v.34 no.2
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    • pp.147-155
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    • 1999
  • Waxes compounded into rubber migrate to the surface and form a protection film on the rubber surface. In general, antiozonants were used with wax to protect ozonation of rubber. Influence of wax barrier formed on the surface of a rubber vulcanizate on migration of antiozonants was studied using natural rubber (NR) vulcanizates containing various type waxes. IPPD (N-isopropyl-N'-phenyl-p-phenylenediamine), HPPD (N-l,3-dimethylbutyl-N'-phenyl-p-phenylenediamine), SBPPD (N,N'-di(sec-butyl)-p-phenylenediamine), and DMPPD (N,N'-di(1,4-dimethylpentyl)-p-phenylenediamine) were employed as antiozonants. Migration experiments were performed at constant temperatures of 60 and $80^{\circ}C$ for 10, 20, 30 days using a convection oven. The migration rates of the antiozonants in the vulcanizate without wax are faster than those in the vulcanizates containing waxes. The antiozonants migrate slower in the vulcanizate containing wax with a high molecular weight distribution than in the vulcanizate with a low one. The migration rates of DMPPD and SBPPD are faster than those of HPPD and IPPD.

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The Transmissibility of Rubber Damper in the Compact Disc Player (컴팩트 디스크 플레이어 고무댐퍼의 전달율)

  • Lee, Tae-Keun;Kim, Byoung-Sam
    • Transactions of the Korean Society of Machine Tool Engineers
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    • v.17 no.4
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    • pp.126-132
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    • 2008
  • The vibration and disturbances from operating the compact disk layer have an effect on the play ability. As the excitation sources of the compact disk player, there are the vibration of the motors and gears, impact by mechanical parts and the external excitations. So, most of the compact disk player have a anti-vibrational system, which is included some rubber or oil dampers. In this study, the vibration characteristics of rubber damper which is used home compact disk player are investigated. The materials and shape of rubber damper are changed, and the transmissibility is measured. As a conclusion, the natural frequency is moved to higher frequency and the transmissibility is reduced by the increasing rubber stiffness. In comparison to butyl rubber damper, the transmissibility of silicon damper was increased by larger restitution elasticity. The hollow damper was effective to reduced the transmissibility.

Studies on the Quality Reinforcement for Pneumatic Tire and Tube (Part 5) Physical Properties for Tire Cord and Butyl Tube (Tire 및 Tube의 품질보강(品質補强)에 관(關)한 연구(硏究) (제5보(第5報)) Tire Cord 및 Butyl Tube의 물성(物性)에 대(對)하여)

  • Kim, Joon-Soo;Lee, Myung-Whan;Yum, Hong-Chan;Lee, Chin-Bum;Park, Chang-Ho;Hong, Chong-Myung;Im, Dong-Ho
    • Elastomers and Composites
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    • v.4 no.1
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    • pp.89-93
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    • 1969
  • 1. Physical properties of various nylon cords in a tire, both of home and foreign products are studied. The experimental data for home nylon cords appeared to be quite satisfactory for use in a tire compared with foreign nylon cords with respect to its tenacity, elongation, shrinkage and contraction. 2. Excellent results have been obtained with 50 phr carbon in butyl-carbon compounding.

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Graft Copolymerization of Poly(Methyl Methacrylate) onto Natural Rubber Latex (천연고무 Latex에 Poly(Methyl Methacrylate)의 그라프트 공중합)

  • Kim, K.S.;Shin, M.H.;Choi, S.K.;Keum, K.M.
    • Elastomers and Composites
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    • v.28 no.3
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    • pp.191-197
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    • 1993
  • The graft copolymerization of methyl methacrylate(MMA) onto natural rubber latex(NRL) initiated by t-butyl hydroperoxide(t-BHPO) was investigated in aquous medium. The grafting percentage, grafting efficiency and total conversion were observed in various reaction conditions such as monomer, initiator and emulsifier concentration, reaction temperature, reaction time and agitation speed. The optimum conditions for the graft copolymerization onto natural rubber latex were as follows ; At given monomer concentration of $3{\times}10^{-2}mole/l$, the maximum grafting percentage was appeared in the case of grading in initiator concentration of $4{\times}10^{-2}mo1e/l$ and emulsifier concentration of 0.2wt.% at $40^{\circ}C$ for 5hrs.

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Effect of Liquid Isoprene Rubber on the Adhesion Property of UV Curable Acrylic Pressure-Sensitive Adhesive (액상 이소프렌 고무가 자외선 경화형 아크릴 점착제의 점착 특성에 미치는 영향)

  • Lee, Jiye;Chung, Kyungho
    • Elastomers and Composites
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    • v.49 no.3
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    • pp.210-219
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    • 2014
  • In this study, the acrylic pressure sensitive adhesive (PSA) for the optical functionality sheet was prepared by blending liquid isoprene rubber. The acrylic PSA was synthesized with butyl acrylate, acrylic acid, 2-ethylhexyl acrylate and 2-hydroxyethyl methacrylate. Toluene was used to a solvent for polymerization. Liquid isoprene rubber (LIR-50) was blended with the acrylic PSA and blend ratio was 0 ~ 50 wt%. According to the results, the adhesive transfer, which was the big problem of acrylic adhesive, was reduced with the addition of LIR-50. The secondary bonding of LIR-50 with substrate did not occurred due to absence of polar group in LIR-50. The peel strength and adhesive transfer were decreased by UV curing and the degreed of decrease depended on the amounts of photoinitiator and UV irradiation time. On the other hand holding power increased drastically by increasing amounts of photoinitiator and UV irradiation time.