• Analytical Science and Technology
• /
• v.9 no.2
• /
• pp.168-178
• /
• 1996

Molecular structures of petroleum fractions(diesel fuel, bunker-C oil, lubricant base stocks) have been analyzed and compared in terms of the compositions (aromatics, naphtherucs, paraffinics), aromatics(benzene-nuclear and bonded alkyl groups), C2(methylene) carbon atoms % $C_{\alpha}$ and $C_{\beta}$ carbon stom % in alkyl groups and paraffins(branched and normal) by near-infrared and $^{13}C$-NMR spectroscopy.

• Proceedings of the KSME Conference
• /
• 2001.06d
• /
• pp.60-65
• /
• 2001

Bomb calorimeter was developed for measuring the calorific value of combustible matter such as wastes. The calorimeter consist of bomb, stirred-water type bucket, thermometer and ignition circuit. Operation and performance of the calorimeter have been tested experimentally. In the present study, calorific values of light oil, lamp oil and bunker C oil is measured using the bomb calorimeter. Mass of the sample is fixed at lg, and oxygen pressure in the bomb is used as an experimental parameter. Sample in the oxygen bomb is burned with electrically heated Ni-Cr wire of 100mm in length, and temperature of water in the bucket become increased by $5^{\circ}C$ during about 30min. Calorific value of the sample is calculated with the temperature difference of water. Combustion tests, such as the record of temperature history and the inspection of remnants, are performed at 4, 6, 8 and 10 atm of the oxygen pressure. From the test results, oxygen pressure in the bomb must be over 10atm for complete combustion.

• 한국생물공학회:학술대회논문집
• /
• 2001.11a
• /
• pp.556-557
• /
• 2001

This study was performed to improve the efficency of production of biosudactant which were produced by newly screened MNNGCN-Methyl-N-Nitro- Nitrosoguanidine) mutagenized P. aeruginosa EMS1. A culture grown exponentially for $30^{\circ}C$ in trypic soy brotb is adjusted to pH. MNNG is added and incubated in water bath shaker at about 250 ${\sim}$300rpm. After 20 min, is dilutecl into colded trypic soy broth and centrifugation. The cell pellet is resuspended in 50$m{\ell}$ of trypic soy broth. Cultures are grown at $30^{\circ}C$ overnight. cetyltrimethylammonium bromide-metbylene blue agar plate selected dark blue halo colony. Peanut oil, Castor oil, Olive oil, and so on were compared as carbon source of surface tension and emulsifying activity.

• Korean Journal of Microbiology
• /
• v.33 no.3
• /
• pp.193-198
• /
• 1997

Microorganisms capable of producing biosurfactant were isolated from oil-contaminated soils and seawater. Among them, the selected strain SW1 was identified as Pseudomonas sp. by taxonomical characteristic tests, and so tentatively named Pseudomonas sp. SWI. The optimal temperature and initial pH for biosurfactant production were TEX>30^{\circ}C.$ and 7.0, respectively. The optimal medium composilion for the production of biosurfactant by Pseudomonas sp. SW1 were hexadecane of 2.0%, yeast extract of 0.04%, $K_{2}HPO_4$ of 0.02%, $KH_2PO_4$ of 0.03% and $MgSO_4$ center dot $7H_2O$ of 0.04%, respectively. Under the above conditions, minimum wrface tension was 32 mN/m after incubation of 2 days. The biosurfactant was produced during initial stationary phase in the optimal medium. Pseudotnonas sp. SWl utilized various hydrocarbons such as Bunker oils, n-alkanes and branched alkanes as a sole carbon source.

• Journal of Advanced Marine Engineering and Technology
• /
• v.32 no.7
• /
• pp.1080-1088
• /
• 2008

This paper addresses some concerns faced by the shipping industry nowadays. Initially, the environmental issues were resolved and stricter regulations are now being implemented with regards to the exhaust gas, specifically nitrogen oxides (NOx) and sulfur oxides (SOx), emitted from ships. Secondly, with the increasing and unstable cost of fuel oils in the world market, it has become almost a necessity to explore on a new alternative fuel. Hence, this study was conducted. An experiment was carried-out on a fishing survey vessel with the main engine (M/E) and generator engine (G/E) operated on expensive marine gas oil (MGO). During the experiment, two pre-refinery systems were installed and different fuel oil samples were employed for the M/E and the G/E. Furthermore, the NOx emission and soot concentration were monitored and verified. The results confirmed the compatibility of some fuel oil types to the engines and meeting the emission standards. MDO, MF15 and Bunker A can be used in place of MGO for the engines(M/E, G/E).

• Tribology and Lubricants
• /
• v.28 no.5
• /
• pp.233-239
• /
• 2012

The engine of a large ship operates under wet conditions using a fuel such as bunker C oil, which includes sulfur and many impurities. A cylinder liner made of cast iron is very susceptible to damage such as scuffing on the surface. This scuffing can reliably be attributed to the destruction of the oil film and the corrosion wear caused by water and sulfur included in the fuel, along with abrasion impurities and poor lubricants. In this study, a reciprocating friction and wear test was carried out with a cast iron specimen, which was used to simulate an engine cylinder in a corrosive environment. Base-oil and stirred oil containing distilled water, NaCl solution, and dilute sulfuric acid were used as lubricants. The friction surface was analyzed using a microscope and EDAX, and the friction coefficient was measured using a load-cell under each experimental condition. We then attempted to investigate the damage to the cylinder liner using the results.

• Transactions of the Korean Society of Mechanical Engineers B
• /
• v.21 no.5
• /
• pp.679-690
• /
• 1997

Oil spill over the sea and the river become a serious problem in these days. Two different approaches are used to clean up the spilled oil by means of chemical dispersion and mechanical devices. If it is possible, removing spilled oil using mechanical devices are highly desirable in order not to worry about the secondary contamination from chemical treatment. One of the major unsolved problems using mechanical devices has been the recovery of highly viscous oil spill. So, the systematic experimental data for treating very viscous oil are still wanting. In the present study a series of experiments were carried out to study the effect of the rotational direction of the belt skimmer on the rate of oil recovery using Bunker C oil. Three different situations, namely, upward, downward and up-and-downward pickup rate have been investigated for variable belt speed. The results showed that the rate of oil recovery for downward pickup was much higher than that for upward pickup. The major mechanism to recover the oil using a belt skimmer has been confirmed that oil sticks to the belt surface while moving to the water rather than moving upward. For the removal of spilled oil the optimal belt speed under the present experimental conditions was found to be about 200 ~ 270 mm/s just before the starvation started. The present experimental results would provide the basis for understanding the performance characteristics and physics of various types of skimmers.

• Journal of Preventive Medicine and Public Health
• /
• v.42 no.2
• /
• pp.73-81
• /
• 2009

Objectives : This study presents a scientific basis for the establishment of an environmental health contingency plan for dealing with accidental coastal oil spills and suggests some strategies for use in an environmental health emergency. Methods : We reviewed the existing literature, and analyzed the various fundamental factors involved in response strategies for oil spill. Our analysis included data derived from Hebei Spirit oil spill and used air dispersion modeling. Results : Spill amounts of more than 1,000 kl can affect the health of residents along the coast, especially those who belong to vulnerable groups. Almost 30% of South Korean population lives in the vicinity of the coast. The area that is at the highest risk for a spill and that has the greatest number of people at risk is the stretch of coastline from Busan to Tongyeong. The most prevalent types of oil spilt in Korean waters have been crude oil and bunker-C oil, both of which have relatively high specific gravity and contain volatile organic compounds, polycyclic aromatic hydrocarbons, and metals. In the case of a spill of more than 1,000 kl, it may be necessary to evacuate vulnerable and sensitive groups. Conclusions : The government should establish environmental health planning that considers the spill amount, the types of oil, and the distance between the spot of the accident and the coast, and should assemble a response team that includes environmental health specialists to prepare for the future oil spill.

• Journal of Environmental Impact Assessment
• /
• v.29 no.3
• /
• pp.219-229
• /
• 2020

This study evaluated the applicability of the convergence technology by deriving the optimum conditions about operating factors of electrical resistance heating to enhance the soil flushing effect on soil contaminated with bunker C oil in the coastal landfill area. As a result of the batch scale experiment, the flushing efficiency of the VG-2020 was higherthan that of the Tween-80, and the flushing efficiency increased by about 1.4 times at 60℃ compared to room temperature. As a result of the electrical resistance heating box experiment, soil temperature rose to 100℃ in about 40~80 minutes in soil with water content of 20~40%, and it was found that the heat transfer efficiency is excellent when the pipe-shaped electrode rod with STS 316 material is located in a triangular arrangement in saturated soil. In addition, it was confirmed that the interval between the electrode rods to maintain the soil temperature above 60℃ under the optimum conditions was 1.5 m, and the soil flushing box experiment accompanying electrical resistance heating showed TPH reduction efficiency of about 55% at 5 Pore Volume, and satisfied the Korean standard for the conservation of soil (less than TPH 2,000 mg/kg) at 10 Pore Volume.

• Journal of the Korean Society for Marine Environment & Energy
• /
• v.16 no.4
• /
• pp.263-267
• /
• 2013

In this research, a novel optical measuring methodology for the measurement of oil thickness in seawater is suggested by evaluating the light absorption which is occurred in the process of penetrating through oil layer on seawater. Laser having monochromatic wave is used as a light source and photodiode which can convert the intensity of the light into an electrical signal is applied to measure the intensity of the penetrating light through the oil-water mixtures. In the experiment, bunker C and lubricating oil are used, and three different lasers having different wavelengths are applied and compared for the selection of an optimal light source. As a result, it is observed that in the case of blue laser, the intensity of the light on the optical sensor decreases with an increase in the oil thickness. Through this relation, both the presence of oil and the thickness of oil can be determined.