• Title/Summary/Keyword: bulk treatment

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The economic benefit of combustible waste into energy: A contingent valuation study (Fe3C12 식각을 이용한 콘덴싱 보일러 잠열 열교환기의 응축 열전달 촉진)

  • Jang, J.H.;Ahn, J.;Shin, D.H.;Chung, T.Y.
    • Journal of Energy Engineering
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    • v.22 no.3
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    • pp.307-311
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    • 2013
  • Heating and hot water has accounted for 68% of Korea's household energy usage. Boiler makes up the bulk of the heating and hot water production. Hence a highly efficient boiler is needed in order to reduce energy consumption. A condensing boiler that recovers latent heat is known to be highly efficient. However, it is expensive and takes more space to necessitate research for improvement. In the present study, we investigated condensation heat transfer of a surface roughened by etching treatment. The etched plate showed 9.2% increase in heat transfer compared to original plate.

Laboratory Study for the Identification of Parameters affecting the Penetration Behavior of Spilled crude oil in a Coastal Sandy Beach (해양에서 유출된 기름의 해변 토양 침투거동에 미치는 영향인자 규명 실험)

  • Cheong Jo, Cheong
    • Journal of Soil and Groundwater Environment
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    • v.8 no.1
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    • pp.81-86
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    • 2003
  • Understanding the penetration behavior of the spilled oil is very important to remove itself and to minimize its impact on intertidal biological communities by earlier treatment of the oil. The purpose of this study is to clarify the effects of wave and tidal actions on the penetration of spilled oil and to evaluate main factors of oil penetration using a sandy-beach model. Infiltration processes into the sediments showed significant difference between seawater and crude oil. Seawater was infiltrated by both wave action and tidal fluctuation into the sediments in sandy beach. However, spilled crude oil penetrated into the sediments only by falling tides and not by wave action, and the first tide is most important for the penetration of stranded oil. Over 70% of bulk fraction in penetrated crude oil was concentrated to the top 2 cm sediment-layer when spilled oil volume was 1 L/$\textrm{m}^2$. Moreover, the penetration of stranded oil into the sandy beach sediments was strongly correlated with the oil viscosity affected by temperature.

Preparation and Characterization of BICND-loaded Multi-Layer PLGA Wafer Containing Glycolide Monomer (글리콜라이드 단량체를 함유한 BICNU 함유 다중층 PLGA웨이퍼의 제조 및 특성결정)

  • 채강수;이진수;정제교;조선행;이해방;강길선
    • Polymer(Korea)
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    • v.28 no.4
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    • pp.335-343
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    • 2004
  • Carmustine (l,3-bis(2-chloroethyI)-1-nitrosourea, BICNU) used as antineoplastic drug for the treatment of brain tumor is not appropriate for the long term delivery, because it has short biological half life. Therefore, poly(D,L-lactide-co-glycolide) (PLGA) is useful as drug carrier for the long term delivery due to bulk erosion property. Glycolide monomer is applied to release of BICNU owing to non-toxic and monomeric components after biodegradation of PLGA. In this study, BICNU-loaded PLGA wafers with or without glycolide monomer were fabricated by conventional direct compression method for the sustained release of BICNU. These wafers were observed for their release profiles of BICNU and degradation rates by SEM, NMR, and GPC. Furthermore, we make multi-layer wafers and compare them with release profiles of conventional wafer. From these results, drug release of BICNU-loaded PLGA wafers was increased with increasing the glycolid monomer contents. We confirmed that glycolide monomer and BICNU contents in barrier-layer influenced the drug release profiles and degradation rate.

The crystallization behaviours of cordierite gel derived from sil-gel method and glass prepared by the conventional melting method. (용융법과 졸겔법으로 제조된 Cordierite 계 유리와 겔의 결정화 거동)

  • Park, Won-Gyu
    • The Journal of Engineering Research
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    • v.1 no.1
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    • pp.15-22
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    • 1997
  • The crystallization behaviours of cordierite gel derived from sol-gel method and glass prepared from conventional melting method with or without $TiO_2$ as nucleants are compared. The densification temperature of gel is $810^{\circ}C$ and its chemical structure identified by IR analysis is same as that of glass melted by conventional method. The beginning crystallization temperature of gel is $965^{\circ}C$ lower than that of melted glass with 10wt% $TiO_2$, which is $978^{\circ}C$. The crystalline phases developed from gel during heat treatment are identified as spinel, $\beta$-quartz solid solution and $\alpha$-cordierite crystal and crystalline phases in case of glass are (Mg,Al)TiOn and $\beta$-quartz solid solution and $\alpha$-cordierite crystal, respectively. The crystallization in melted glass with nucleants occurs through bulk crystallization and in case of that without nucleants surface crystallization occurs, while the crystallization in gel is internal crystallization from interface between particles formed after densification.

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Synthesis and Physical Properties of Sm Doped Pb Free 3 Phase-Glasses (Sm 농도에 따른 무연 3상 유리계의 합성과 물리적 성질)

  • Park, Jong-Ho
    • Korean Journal of Materials Research
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    • v.22 no.7
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    • pp.368-373
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    • 2012
  • Glasses were prepared with compositions of $(13-x)BaO-80B2_O_3-7Li_2O{\cdot}xSm_2O_3$, BBLSx(x=0.5, 0.4, 0.3) by melting the starting materials of boron oxide(99.9%), lithium oxide(99.9%), barium carbon oxide(99.9%), and samarium oxide(99.9%) and then quenching the melt at $1350^{\circ}C$. This led to good-quality BBLSx(x=0.4, 0.3) and poor-quality BBLSx(x=0.5) glasses. The physical and structural properties of the BBLSx glasses were studied by means x-ray diffraction, scanning electron microscopy(SEM), differential scanning calorimetry(DSC), and dielectric spectroscopy. From the x-ray diffraction and SEM results, the quality of the BBLSx glasses significantly depends on the $Sm_2O_3$ concentration. The x-ray diffraction pattern showed that the crystallites in the BBLSx glasses after heat treatment at $700^{\circ}C$ may be $LiBaB_9O_{15}$. From the DSC results, the glass transition temperatures($T_g$), crystallization temperatures($T_c$), and the maximum temperatures of the crystallized($T_p$) BBLSx glasses all changed with the $Sm_2O_3$ concentration. According to the dielectric spectroscopy results, the values of the real dielectric constant and Tan ${\delta}$ of the BBLSx glasses depended on the $Sm_2O_3$ concentration. The values of the real dielectric constant and Tan ${\delta}$ were also shown to depend on the measuring temperature, possibly due to the ion migration in the bulk of the BBLSx glasses.

Effect of Cover Crops on the Soil Properties and Fruit Quality in a Persimmon Orchard (녹비작물이 단감과원의 토양 특성과 과실품질에 미치는 영향)

  • Kim, Byeong-Sam;Cho, Kyung-Chul;Na, Yang-Gi;Yoon, Bong-Ki;Jung, Seok-Kyu;Cho, Kwang-Sik;Lee, Kyung-A;Choi, Hyun-Sug
    • Korean Journal of Organic Agriculture
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    • v.22 no.3
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    • pp.413-421
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    • 2014
  • This study was conducted into the effects of cover crops among the hairy vetch, red clover, rye, and hairy vetch+rye on the soil chemical and physical properties, and fruit yield in mature 'Fuyu' persimmon (Diospyros${\times}$kaki Thunb.) trees. The shallow-rooted red clover had poor dry matter production, resulting in the lowest coverage (66%) on the orchard floor. In contrast, the highest dry matter production observed in rye and hairy vetch+rye. Estimated N, P and K production from the cover crops were the highest on the hairy vetch+rye plots, increasing soil chemicals at a depth of 0-30 cm soil. Rye or hairy vetch+rye treatments decreased the soil bulk density and solid phase. As the hairy vetch+rye treatment increased fruit yield and sugar contents, it could be proposed as an suitable cover crop for improving productivity of persimmon trees.

Isolation of Chitin from Crab Shell Waste (게 가공 폐기물로부터 키틴의 분리)

  • 노홍균;이문이
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.24 no.1
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    • pp.105-113
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    • 1995
  • Procedures for isolatin of chitin have been developed from crab(Chionoecetes opilio) shell waste with 26. 65% chitin on a dry basis. Optimal conditions for demineralization of crab shell were 1N HCl at ambient temperature for 30min with a solids to solbent ratio of 1 : 15(w/v). Optimal deproteinization involved treatment with 5% NaOH at $65^{\circ}C$ for 1 hr with a solids to solvent ratio of 1 : 15(w/v). Effective decoloration was achieved by bleaching with 0.32% sodium hypochlorite solution for 3min with a solids to solvent ratio of 1 : 10(w/v). Particular attentin was given to characterization of the physicochemical properties of the crab chitin. Chitins, from four different mesh sizes of crab shell, did not show significant differences in nitrogen and ash compositions. Bleaching decreased the viscosity of chitin but did not affect its solubility.

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Growth of Spinel CoMn2O4 Thin Films and Post-growth Annealing Effects on Their Physical Properties (CoMn2O4 스피넬 박막의 합성과 후열처리가 박막의 물리적 특성에 미치는 영향)

  • Kim, D.R.;Kim, J.K.;Yoon, S.W.;Song, J.H.
    • Journal of the Korean Magnetics Society
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    • v.25 no.5
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    • pp.144-148
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    • 2015
  • We grew spinel structured $CoMn_2O_4$ thin films and have studied post-growth annealing effects on their physical properties. After post-growth annealing at $700^{\circ}C$ that is lower than the growth temperature ($720^{\circ}C$), crystal structure became cleared accompanying a change of surface structure. In the temperature dependences of magnetization, phase transitions were observed at ~100 K for both before and after post-growth treated samples which were not observed for the bulk. For both samples, ferromagnetic behaviors were observed above 100 K while it turned to ferrimagnetism at low temperature below 100 K. In particular, the ferrimagnetic behavior became strong after the post-growth treatment. These results indicate that the post-growth annealing process plays an important role in determining the physical properties of spinel $CoMn_2O_4$ thin film.

Crystallinity Changes Heat Treatment of Coal Tar Pitch and Phenol Resin used as a Binder for Bulk Graphite Manufacturing (벌크흑연 제조를 위한 결합재로 이용되는 콜타르 핏치 및 페놀수지의 열처리에 의한 결정성 변화)

  • Lee, Sang-Min;Lee, Hyun-yong;Lee, Sang-Hye;Roh, Jae-Seung
    • Applied Chemistry for Engineering
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    • v.32 no.2
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    • pp.174-179
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    • 2021
  • The coal tar pitch and phenol resins are used as binders in artificial graphite manufacture, but there are differences in the initial carbon compound structure. According to the carbonization temperature, it can be expected that there are differences in thermal decomposition behavior, microstructure, and crystallinity change. These properties of the coal tar pitch and phenol resins were compared to each other. As the carbonization temperature of coal tar pitch and phenol resin increases, crystallinity tends to increase. The coal tar pitch went through the carbonization process through the liquid, and it was confirmed that the crystallinity changed rapidly in the temperature range of 500 and 600 ℃, where the microstructure changed quickly. These results confirmed the close correlation between microstructure and crystallinity.

Compacted expansive elastic silt and tyre powder waste

  • Ghadr, Soheil;Mirsalehi, Sajjad;Assadi-Langroudi, Arya
    • Geomechanics and Engineering
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    • v.18 no.5
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    • pp.535-543
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    • 2019
  • Building on/with expansive soils with no treatment brings complications. Compacted expansive soils specifically fall short in satisfying the minimum requirements for transport embankment infrastructures, requiring the adoption of hauled virgin mineral aggregates or a sustainable alternative. Use of hauled aggregates comes at a high carbon and economical cost. On average, every 9m high embankment built with quarried/hauled soils cost $12600MJ.m^{-2}$ Embodied Energy (EE). A prospect of using mixed cutting-arising expansive soils with industrial/domestic wastes can reduce the carbon cost and ease the pressure on landfills. The widespread use of recycled materials has been extensively limited due to concerns over their long-term performance, generally low shear strength and stiffness. In this contribution, hydromechanical properties of a waste tyre sand-sized rubber (a mixture of polybutadiene, polyisoprene, elastomers, and styrene-butadiene) and expansive silt is studied, allowing the short- and long-term behaviour of optimum compacted composites to be better established. The inclusion of tyre shred substantially decreased the swelling potential/pressure and modestly lowered the compression index. Silt-Tyre powder replacement lowered the bulk density, allowing construction of lighter reinforced earth structures. The shear strength and stiffness decreased on addition of tyre powder, yet the contribution of matric suction to the shear strength remained constant for tyre shred contents up to 20%. Reinforced soils adopted a ductile post-peak plastic behaviour with enhanced failure strain, offering the opportunity to build more flexible subgrades as recommended for expansive soils. Residual water content and tyre shred content are directly correlated; tyre-reinforced silt showed a greater capacity of water storage (than natural silts) and hence a sustainable solution to waterlogging and surficial flooding particularly in urban settings. Crushed fine tyre shred mixed with expansive silts/sands at 15 to 20 wt% appear to offer the maximum reduction in swelling-shrinking properties at minimum cracking, strength loss and enhanced compressibility expenses.