• 제목/요약/키워드: bulk structure

검색결과 852건 처리시간 0.033초

벌크 비정질 Zr-Ti-Cu-Ni-Be 합금의 고온 압축 변형 특성 (High Temperature Compressive Deformation Behavior of the Bulk Metallic Glass Zr-Ti-Cu-Ni-Be Alloy)

  • 이광석;하태권;안상호;장영원
    • 소성∙가공
    • /
    • 제10권7호
    • /
    • pp.565-572
    • /
    • 2001
  • It is well known that a multicomponent $Zr_{4l.2}Ti_{13.8}Cu_{12.5}Ni_{10}Be_{22.5}$ bulk metallic glass alloy shows good bulk glass forming ability due to its high resistance to crystallization in the undercooled liquid state. DSC and XRD have been performed to confirm the amorphous structure of the master alloy. To investigate the mechanical properties and deformation behavior of the bulk metallic $Zr_{4l.2}Ti_{13.8}Cu_{12.5}Ni_{10}Be_{22.5}$ alloy, a series of compression tests has been carried out at the temperatures ranging from $351^{\circ}C$ to $461^{\circ}C$at the various initial strain rates from $2{\times}10^4s^1$ to $2{\times}10^2s^1$. Three types of nominal stress-strain curves have been identified such as linear stress-strain relationship meaning fracture at maximum stress, plastic deformation including stress overshoot and steady-state flow, plastic deformation without stress overshoot depending on the strain rate and test temperature. Also DSC analysis for the compressed specimens was carried out to investigate the change of structure, thermal stability and crystallization behavior for the various test conditions.

  • PDF

제지 원료의 특성 및 물리적 처리가 종이의 기공 구조 및 물성에 미치는 영향 (Effects of Raw Materials for Papermaking and Physical Treatment on the Pore Structure and Paper Properties)

  • 원종명;남기영;정순기
    • 펄프종이기술
    • /
    • 제39권4호
    • /
    • pp.7-13
    • /
    • 2007
  • Effects of pulp type, refining and filler type on the pore characteristics and physical properties of paper were investigated. HwBKP, SwBKP and BCTMP are used to study the effect of pulp type in this study. The effects of each filler (PCC, GCC and talc) and the combination of PCC/GCC were also studied. Highest bulk, pore volume and light scattering are obtained from BCTMP and PCC. It was found that the pore size and pore volume are important in light scattering in paper structure. It was found that PCC was the most effective filler for the improvement of the bulk and light scattering because of the increase in pore volume which can scatter light, but the increase of PCC content was not so effective in the improvement of bulk.

Wire-woven Bulk Kagome의 압축 특성 분석 (Analysis of Compressive Characteristics of Wire-woven Bulk Kagome)

  • 이병곤;최지은;강기주;전인수
    • 대한기계학회논문집A
    • /
    • 제32권1호
    • /
    • pp.70-76
    • /
    • 2008
  • Periodic cellular metals (PCMs) are actively being investigated because of their excellent specific strength and stiffness, and multi-functionality such as a heat disperse structure bearing external loading. The Kagome truss PCM has been proved that it has higher resistance to plastic buckling and lower anisotropy than other truss PCMs. In this paper, the out-of-plane compressive responses of the WBK specimens have been measured, theoretically predicted and numerically analyzed. Three specimens of two-layered WBK are fabricated and tested for measuring the responses. The peak stress of compressive behavior and effective elastic modulus are predicted based on the equilibrium equation and elastic energy conservation. Moreover, the structure of the specimen is modeled using the commercial mesh generation code, PATRAN and the finite element analysis for the model under the compression is carried out using the commercial FE code, ABAQUS. Finally, the obtained results are compared with each other to analyze the compressive characteristics of Wire-woven Bulk Kagome (WBK).

벌크 시멘트 트레일러의 정동적 유한요소해석 (Static and Dynamic Finite Element Analyses of a Bulk-Cement Trailer)

  • 김진곤;이재곤
    • 대한기계학회논문집A
    • /
    • 제36권8호
    • /
    • pp.945-951
    • /
    • 2012
  • 본 논문에서는 하부 프레임 구조가 보다 단순해진 분말류 운송차량인 벌크시멘트 트레일러의 정동적 특성을 유한요소해석을 통하여 분석하였다. 이를 위하여 벌크시멘트 트레일러가 받는 하중의 대부분을 지지하는 섀시 프레임과 탱크부분을 상용 유한요소해석 소프트웨어인 ANSYS를 이용하여 삼차원 상세 유한요소모델링을 수행하였다. 자유진동해석을 통하여 차체의 동적특성을 이해하는데 필수적인 벌크시멘트 트레일러 몸통의 고유진동수와 진동모드를 분석하였다. 또한, 정적인 응력해석을 통하여 트레일러의 취약부위를 찾은 후 다구찌 실험계획법을 적용하여 경량화를 시키면서도 취약부위의 강도를 높일 수 있는 방안을 제시하였다.

Electronic structure and magnetism of catalytic material Pt3Ni surfaces: Density-functional study

  • Sharma, Bharat Kumar;Kwon, Oryong;Odkhuu, Dorj;Hong, Soon Cheol
    • 한국자기학회:학술대회 개요집
    • /
    • 한국자기학회 2012년도 자성 및 자성재료 국제학술대회
    • /
    • pp.172-172
    • /
    • 2012
  • A Pt-skin $Pt_3Ni$(111) surface was reported to show high catalytic activity. In this study, we investigated the magnetic properties and electronic structures of the various oriented surfaces of bulk-terminated and Pt-segregated $Pt_3Ni$ by using a first-principles calculation method. The magnetic moments of Pt and Ni are appreciably enhanced at the bulk-terminated surfaces compared to the corresponding bulk values, whereas the magnetic moment of Pt on the Pt-segregated $Pt_3Ni$(111) surface is just slightly enhanced because of the reduced number of Ni neighboring atoms. Spin-decomposed density of states shows that the dz2 orbital plays a dominant role in determining the magnetic moments of Pt atoms in the different orientations. The lowering of the d-band center energy (-2.22 eV to -2.46 eV to -2.51 eV to -2.65 eV) in the sequence of bulk-terminated (100), (110), (111), and Pt-segregated (111) may explain the observed dependence of catalytic activity on surface orientation. Our d-band center calculation suggests that an observed enhanced catalytic activity of a $Pt_3Ni$(111) surface originates from the Pt-segregation.

  • PDF

Characteristics of Fe-Ni Nanopowders Prepared by Electrical Explosion of Wire in Water and Ethanol

  • Bac, L.H.;Kim, B.K.;Kim, J.S.;Kim, J.C.
    • Journal of Magnetics
    • /
    • 제16권4호
    • /
    • pp.435-439
    • /
    • 2011
  • In this work, we prepared Fe-Ni alloy nanopowders by wire electrical explosion in deionized water and ethanol. Particles size and morphology of the as-synthesized nanoparticles prepared in water and ethanol were observed by transmission electron microscopy. In both cases, the as-synthesized nanoparticles were in nearly spherical shape and their size distribution was broad. The particles prepared in the water were in core-shell structure due to the oxidation of Fe element. X-ray diffraction was used to analyze the phase of the nanopowders. It showed that the nanopowders prepared in water had ${\gamma}$-Fe-Ni solid solution and FeO phase. The samples obtained in ethanol were in two phases of Fe-Ni solid solution, ${\gamma}$-Fe-Ni and ${\alpha}$-Fe-Ni. Bulk samples were made from the as-synthesized nanopowders by spark plasma sintering at $1000^{\circ}C$ for 10 min. Structure of the bulk sample was observed by scanning electron microscope. Magnetic properties of the as-synthesized nanopowders and the bulk samples were investigated by vibrating sample magnetometer. The hysteresis loop of the assynthesized nanopowders and the sintered bulk samples revealed a ferromagnetic characteristic.

탈수소자에 의한 종이 미세구조 및 물성 변화 평가 (Evaluation of the Changes in Local Paper Structure and Paper Properties Depending on the Forming Elements Types)

  • 성용주
    • 펄프종이기술
    • /
    • 제41권1호
    • /
    • pp.17-23
    • /
    • 2009
  • The influence of different forming elements on the local paper structure and the related paper properties was investigated in this study. Specifically, a conventional papermaking foil system and a velocity induced drainage (VID) system were compared. The study involved the analysis of the product samples obtained from the commercial machine trials. The paper samples produced with VID forming systems showed better formation. The deterministic patter in the local structural profile map of the Foil samples indicated the structure of foil samples was more supple after forming process and then easier to be marked by various fabrics such as wet pressing fabric. The higher bulk was observed in the VID samples, which resulted in higher scattering coefficient, lower ZDT strength, and higher bending stiffness.

Variation of the Si-induced Gap State by the N defect at the Si/SiO2 Interface

  • 김규형;정석민
    • 한국진공학회:학술대회논문집
    • /
    • 한국진공학회 2016년도 제50회 동계 정기학술대회 초록집
    • /
    • pp.128.1-128.1
    • /
    • 2016
  • Nitrided-metal gates on the high-${\kappa}$ dielectric material are widely studied because of their use for sub-20nm semiconductor devices and the academic interest for the evanescent states at the Si/insulator interface. Issues in these systems with the Si substrate are the electron mobility degradation and the reliability problems caused from N defects that permeates between the Si and the $SiO_2$ buffer layer interface from the nitrided-gate during the gate deposition process. Previous studies proposed the N defect structures with the gap states at the Si band gap region. However, recent experimental data shows the possibility of the most stable structure without any N defect state between the bulk Si valence band maximum (VBM) and conduction band minimum (CBM). In this talk, we present a new type of the N defect structure and the electronic structure of the proposed structure by using the first-principles calculation. We find that the pair structure of N atoms at the $Si/SiO_2$ interface has the lowest energy among the structures considered. In the electronic structure, the N pair changes the eigenvalue of the silicon-induced gap state (SIGS) that is spatially localized at the interface and energetically located just above the bulk VBM. With increase of the number of N defects, the SIGS gradually disappears in the bulk Si gap region, as a result, the system gap is increased by the N defect. We find that the SIGS shift with the N defect mainly originates from the change of the kinetic energy part of the eigenstate by the reduction of the SIGS modulation for the incorporated N defect.

  • PDF

Zr-V-Mn-Ni계 라브스상 합금의 미세 구조와 전기 화학적 특성 (The Microstructure and the Electrochemical Characteristics of Zr based Zr-V-Mn-Ni Laves Phase Alloy)

  • 정치규;한동수;정원섭;김인곤;김원백
    • 한국수소및신에너지학회논문집
    • /
    • 제8권3호
    • /
    • pp.121-129
    • /
    • 1997
  • 아크 용해법으로 제작한 $ZrV_{0.1}Mn_{0.7}Ni_{1.2}$ 합금(bulk 합금) 잉고트는 $ZrV_{0.2}Mn_{0.98}Ni_{1.04}$의 조성식을 가지는 fcc 구조의 C15형 Laves상이 주류를 이루는 matrix와 $ZrV_{0.01}Mn_{0.13}Ni_{1.2}$의 조성으로 $Z_9Ni_{11}$의 금속간 화합물 구조를 가지는 2nd phase가 균일하게 분포된 2개의 상으로 구성되어 있었다. $ZrV_{0.1}Mn_{0.7}Ni_{1.2}$ 합금의 방전 특성에 이 두 가지 상들이 미치는 영향을 알아보기 위해서 matrix와 2'nd phase합금을 분리 제작하였고, 이들 전극에 대한 전기 화학적인 충방천 특성들을 조사하였다. 그 결과 방전용량은 2nd phase가 가장 낮은 $160mAh/g$, 그 다음으로 matrix가 200mAh/g으로 bulk의 250mAh/g보다 낮았다. Matrix조성의 합금은 bulk합금과 거의 유사한 활성화, 고율 방전율, 자기방전 특성을 가졌고, 또한 활성화 후에 충방전에 따른 용량감소의 경향이 현저히 관찰되었다. 그러나 2nd phase 조성의 합금은 이들과는 확연한 차이를 보였다. 즉 활성화되기 어렵지만 활성화된 후에 용량감소의 경향은 거의 없었고 또한 자기방전 특성도 우수하였다.

  • PDF

수소용 다이어프램 압축기의 작동유 특성에 따른 수치해석 (Numerical Analysis on a Dependence of Hydrogen Diaphragm Compressor Performance on Oil Characteristics)

  • 박현우;신영일;이영준;송주헌;장영준;전충환
    • 한국신재생에너지학회:학술대회논문집
    • /
    • 한국신재생에너지학회 2009년도 춘계학술대회 논문집
    • /
    • pp.787-790
    • /
    • 2009
  • There are several types of compressors which are appropriate for hydrogen gas station. Metal diaphragm type of hydrogen compressor is the one of them, a use in which satisfies the requirements of maintaining gas purity and producing high pressure over 700 bar. The objective of this study is to investigate an characteristics of compression as bulk modulus of oil varies. Three cases of bulk modulus ranging from $2{\times}10^9$, $4.52{\times}10^9$ and $7{\times}10^9$ were studied through FSI (Fluid Structure Interaction) analysis. Gas pressure, oil pressure and deflection degree of diaphragm were analysed during a certain period of compression process. Highest pressure and deflection were found in the condition of high bulk modulus of $7{\times}10^9$.

  • PDF