• Title/Summary/Keyword: bulk structure

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Effects of Alkaline Treatment on the Characteristics of Chemical Pulps for Papermaking (알칼리 처리가 제지용 화학펄프의 특성에 미치는 영향)

  • Won, Jong-Myoung;Kim, Min-Hyun
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.43 no.3
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    • pp.106-112
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    • 2011
  • The effects of alkaline treatment on the WRV, crystalline structure and sheet structure of softwood and hardwood bleached kraft pulp were investigated. Sodium hydroxide and sodium carbonate were used as chemicals for alkaline treatment and two levels of alkali dosage (5%, 10%) were applied respectively. Alkali treated and untreated pulp were refined to three levels (550, 450 and 350 mL CSF). WRV of the alkali treated pulps depended on the alkaline type and concentration. It was found that the crystalline structures of softwood and hardwood pulp were not changed by refining. Sodium carbonate and lower concentration of sodium hydroxide treatment did not caused any modification of cellulose crystalline structure, while higher concentration of sodium hydroxide treatment caused the partial modification of cellulose crystalline structure. Alkaline treatment of hardwood bleached kraft pulp led to the shrinkage of fiber diameter and bulky structure of sheet. Alkaline treatment of softwood bleached kraft pulp did not cause the significant change in fiber shrinkage and bulk of sheet.

Na Borosilicate Glass Surface Structures: A Classical Molecular Dynamics Simulations Study (소듐붕규산염 유리의 표면 구조에 대한 분자 동역학 시뮬레이션 연구)

  • Kwon, Kideok D.;Criscenti, Louise J.
    • Journal of the Mineralogical Society of Korea
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    • v.26 no.2
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    • pp.119-127
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    • 2013
  • Borosilicate glass dissolution is an important chemical process that impacts the glass durability as nuclear waste form that may be used for high-level radioactive waste disposal. Experiments reported that the glass dissolution rates are strongly dependent on the bulk composition. Because some relationship exists between glass composition and molecular-structure distribution (e.g., non-bridging oxygen content of $SiO_4$ unit and averaged coordination number of B), the composition-dependent dissolution rates are attributed to the bulk structural changes corresponding to the compositional variation. We examined Na borosilicate glass structures by performing classical molecular dynamics (MD) simulations for four different chemical compositions ($xNa_2O{\cdot}B_2O_3{\cdot}ySiO_2$). Our MD simulations demonstrate that glass surfaces have significantly different chemical compositions and structures from the bulk glasses. Because glass surfaces forming an interface with solution are most likely the first dissolution-reaction occurring areas, the current MD result simply that composition-dependent glass dissolution behaviors should be understood by surface structural change upon the chemical composition change.

High Temperature Plastic Deformation Behaviors of the Bulk Metallic Glass Zr-Ti-Cu-Ni-Be Alloy (벌크 비정질 Zr-Ti-Cu-Ni-Be 합금의 고온 소성 변형 특성)

  • Lee K. S.;Ha T. K.;Ahn S. H.;Chang Y. W.
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2001.10a
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    • pp.272-276
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    • 2001
  • Multicomponent $Zr_{41.2}Ti_{13.8}Cu_{12.5}Ni_{10}Be_{22.5}$ bulk matallic glass alloy shows good bulk glass forming ability due to its high resistance to crystallization in the undercooled liquid state.1) In this study, DSC and X-ray diffractometry have been performed to confirm the amorphous structure of the master $Zr_{41.2}Ti_{13.8}Cu_{12.5}Ni_{10}Be_{22.5}$ alloy. To investigate the mechanical properties and deformation behaviors of the bulk metallic $Zr_{41.2}Ti_{13.8}Cu_{12.5}Ni_{10}Be_{22.5}$ alloy, a series of compression tests has been carried out at the temperatures ranging from $351^{\circ}C$ to $461^{\circ}C$ and at the various initial strain rates from $2{\times}10^{-4}s^{-1}\;to\;2{\times}10^{-2}s^{-1}$. There are two types of nominal stress-strain curves. The one shows linear stress-strain relationship meaning fracture at maximum stress, the other shows plastic deformation including steady-state flow. Also DSC analysis for the compressed specimens has been performed to investigate the change of thermal stability and crystallization behavior for the various test conditions.

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The study of 181,000 DWT BULK CARRIER global vibration characteristic by global vibration analysis (181,000 DWT BULK CARRIER 전선 진동해석을 통한 전선진동특성 고찰)

  • Lim, Gu-Sub;Jeong, Tea-Seok;Choi, Youndal-Dal;Seok, Ho-Il
    • Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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    • 2008.11a
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    • pp.329-330
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    • 2008
  • The 181,000 DWT Bulk Carrier has a different deck house type, which is not typical for previous bulk carriers, to meet the new international rules for bulk carriers. This new deck house has much smaller transverse breadth than the hull's transverse breath, resulting in large levels of the transverse response of the deck house. In addition, the longitudinal response of the funnel showed rather a large magnitude of vibration, which are excited by the ship's main excitations such as the main engine H-moment and the propeller surface forte when the ship operates at the NCR and the MCR speeds In the ballast condition. To solve these issues, the global forced vibration analysis has been performed for the ship and the ship structure has been modified to reduce the vibration level by increasing the girder depth and adjusting the engine room tank arrangement.

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Prediction of Bow Flare Impact Pressure and Its Application to Ship Structure Design - Tanker and Bulk Carrier - (선수 플레어 충격압력 추정과 구조설계에의 응용 - 탱커와 산적화물선 -)

  • 김용직;신기석;신찬호;강점문;김만수;김성찬;오수관;임채환;김대헌
    • Journal of the Society of Naval Architects of Korea
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    • v.40 no.3
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    • pp.22-28
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    • 2003
  • In rough seas, bow-flare regions of the full ships (tanker and bulk carrier) are subiect to high impact pressures due to the on-coming breaking waves. And many ships suffer structural damages in that region, even though they were built under the bow structure strengthening rules of the ship classes. So, a new design method for bow-flare structure is highly required. In this paper, a new prediction method of the bow-flare impact pressure (in terms of equivalent static pressure) acting on the full ships' bow is presented. This method is based on the 6 full ships' damage analysis and the breaking wave impact mechanism. Calculation results of the bow-flare impact pressure and the shell plate thickness are shown and discussed. Through the example calculations, it was found that the present method is useful for the structure design of the full ships' bow.

Structural Properties of $Al_2O_3$Ceramics with impurities (불순물 첨가에 따른 $Al_2O_3$세라믹스의 구조적 특성)

  • 우원석;김지헌;임성수;박인길;이영희
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2000.07a
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    • pp.387-390
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    • 2000
  • The $Al_2$O$_3$specimens were prepared by the conventional mixed oxide method with addition La$_2$O$_3$, Bi$_2$O$_3$. The specimens were sintered at 15$25^{\circ}C$, 5hr., in air. The structural properties of the specimens were investigated by XRD and SEM. The $Al_2$O$_3$ceramics with dopants had hexagonal structure and didn't show secondary phases. In the case of specimens with 0.25wt% La$_2$O$_3$and 0.25wt% Bi$_2$O$_3$bulk densities and lattice parameter of c/a were 3.818g/cm$^3$, 3.783g/cm$^3$and ca=2.725, c/a=2.723, respectively. The bulk densities of $Al_2$O$_3$ceramics were decreased with dopants.

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Characterization of uranium species in molten salt : An application of synchrotron-based XAFS spectroscopy

  • Cho, Young-Hwan;Choi, In-Kyu;Kim, Won-Ho
    • Proceedings of the Korean Nuclear Society Conference
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    • 2002.10a
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    • pp.319.2-319
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    • 2002
  • Synchrotron-based X-ray absorption spectroscopy has been applied to determine the changes in bulk oxidation state of uranium oxides in molten salt. From an analysis of XANES data, one can determine the cahnges in bulk oxidation-state of U compounds in salts(LiCl/KCl). XAFS spectroscpy is a powerful tool for probing the changes in valence state and structure of uranium compounds in colten salt as well as in noncrystalline form and doped in other matrices.

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Simplified fabrication method of Functional materials (기능성 재료의 간소화된 합성법)

  • Lee, Sang-Heon
    • Proceedings of the KIEE Conference
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    • 2008.07a
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    • pp.1240-1241
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    • 2008
  • Superconducting ceramics of YBaCuO was fabricated on SrTiO substrate by chemical fabrication method using fine powder of YBaCuO having diameter less than 1um. The pattern of the fabricated superconducting bulk was linear and the thickness of it can be controlled in the range of 50um. The structure of the surface of film by diffraction pattern and composition. The tape like YBaCuO bulk with width of 10mm was formed on substrate using similar method. Tape like film is expected to utilize as material of superconducting tape.

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Crystal Growth and Characterization of Compound Semiconductor Materials (화합물 반도체 재료의 결정성장과 특성평가)

  • 민석기
    • Korean Journal of Crystallography
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    • v.1 no.2
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    • pp.115-125
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    • 1990
  • We have investigated bulk and hetero-epitaxial growth of GaAs single crystal. Various growth techniques such as HB, HZM, and VGF for high quality bulk GaAs were successfully developed by appling the specially designed DM(direct monitoring) furnace. Al GaAs/GaAs superlattice structure and In(x)Ga(1-x) As/GaAs epilayers were also grown by MOCVD and VPE, respectively. The characterization of GaAs single crystals and epilayers was made by X-ray diffraction, Hall effect, PL, chemical etching and angle lapping technique.

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Solar Energy Utilization in a Greenhouse Bulk Curing and Drying System(I) (Greenhouse Bulk건조기에 의한 태양열이용에 관한 연구 (제I보))

  • 진정의;이승철;이상하
    • Journal of the Korean Society of Tobacco Science
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    • v.2 no.1
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    • pp.61-67
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    • 1980
  • The greenhouse hulk curing and drying system utilizing the direct solar energy was tested to see how much fuel could be saved for curing flue-cured tobacco at the Daegu Experiment Station, Korea Tobacco Research Institute (North latitute: 35$^{\circ}$49'), in 1979. The structure consists of transparent fiberglass exterior, polyurethan boards covered with galvanized iron as the heat absorbers and insulation boards, air duct in which the air is introduced to the furnace room of bulk curing barn, and gravel heat storage system. All exterior surface of heat absorbers, air duct, and gravels were coated with black paint. The air temperature and total radiation were 20.5 to 35.5$^{\circ}C$ and 1004.2 to 1436.2 cal/$\textrm{cm}^2$ during the 3 replicated curing tests, respectively. The greenhouse bulk curing and drying system was able to cut fuel consumption by 25 percent compared with the conventional bulk curing barn. The maximum temperatures for the top absorber and the inlet air of the system were 89$^{\circ}C$ and 64$^{\circ}C$, respectively, and the average temperature of inlet air was higher than that of conventional one by 18$^{\circ}C$.

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