• Title/Summary/Keyword: bulk density

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Electronic structure and magnetism of catalytic material Pt3Ni surfaces: Density-functional study

  • Sharma, Bharat Kumar;Kwon, Oryong;Odkhuu, Dorj;Hong, Soon Cheol
    • Proceedings of the Korean Magnestics Society Conference
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    • 2012.11a
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    • pp.172-172
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    • 2012
  • A Pt-skin $Pt_3Ni$(111) surface was reported to show high catalytic activity. In this study, we investigated the magnetic properties and electronic structures of the various oriented surfaces of bulk-terminated and Pt-segregated $Pt_3Ni$ by using a first-principles calculation method. The magnetic moments of Pt and Ni are appreciably enhanced at the bulk-terminated surfaces compared to the corresponding bulk values, whereas the magnetic moment of Pt on the Pt-segregated $Pt_3Ni$(111) surface is just slightly enhanced because of the reduced number of Ni neighboring atoms. Spin-decomposed density of states shows that the dz2 orbital plays a dominant role in determining the magnetic moments of Pt atoms in the different orientations. The lowering of the d-band center energy (-2.22 eV to -2.46 eV to -2.51 eV to -2.65 eV) in the sequence of bulk-terminated (100), (110), (111), and Pt-segregated (111) may explain the observed dependence of catalytic activity on surface orientation. Our d-band center calculation suggests that an observed enhanced catalytic activity of a $Pt_3Ni$(111) surface originates from the Pt-segregation.

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Influence of Soil Texture and Bulk Density on Root Growth Characteristics and Nutrient Influx Rate of Soybean Plant (토성(土性)과 용적밀도(容積密度)가 대두(大豆)의 뿌리 생장특성(生長特性)과 양분흡수기능(養分吸收機能)에 미치는 영향(影響))

  • Jung, Yeong-Sang;Lim, Hyung-Sik
    • Korean Journal of Soil Science and Fertilizer
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    • v.22 no.3
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    • pp.221-227
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    • 1989
  • This study was conducted to understand the influence of soil compaction on root growth and nutrient uptake characteristics of the soybean roots grown in two soils with different texture. Tap root elongation was measured on young seedling grown in cores compacted to different bulk densities of 1.2, 1.4 and $1.6/cm^3$ with different soil water retention in laboratory. The soil used were Samgag sandy loam and Baegsan loam soils. The wet and dry weight, total length, average radius and total surface area of roots were measured on soybean plants grown in 1/5000 a Wagner pots compacted to different bulk density of 1.2 and $1.4g/cm^3$. The nutrient uptake of soybean shoot was measured and evaluated with the unit surface area of roots at the 7th, 17th and 27th days after germination. The results were as follows: 1. The tap root elongation rate was faster in the loam soil with low bulk density than in the sandy loam soil with high bulk density. The elongation rates were remarkedly decreased when soil water was lower than the retention of 4 bars in loam soil and that of 1 bars in sandy loam soil. 2. Tap root elongation rate sharply decreased as increased soil strength higher than $2kgf/cm^2$ measured by ELE penetrometer showing curvillinear regression. However, it was low regardless of soil strength when soil water retention was 10 bars in sandy loam soil. 3. From the pot experiment, the total length of roots were longer in loam soil than in sandy loam soil and was longer in the soils with lower bulk density. The average radius of fine roots grown in sandy loam soil was larger than that grown in loam soil. The total surface area of roots was greater in the loam soil with low bulk density than in the sandy loam soil with high bulk density as the total length of roots. 4. The amounts of nutrient uptake by soybean shoots were greater in loam soil primarily due to more production of dry matter than in sandy loam soil. The nitrogen influx rates through the unit surface area were 597 to $753nmoles/day-cm^2$ in loam soil and 222 to $365nmoles/day\;cm^2$ in sandy loam soilshowing higher value in higher bulk density. The potasium influx rates were 99 to $175nmoles/day-cm^2$, and those of phosphate were 26 to $46nmoles/day\;cm^2$. Those of Ca and Mg were 175 to 246 and 163 to $205nmoles/day\;cm^2$. The difference in nutrient influx rates between bulk densities of these elements were lower than that of nitrogen.

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Development of Ceramic Superconductor Bulk for Electric Energy resonance (초전도 화합물 세라믹 벌크 개발)

  • Lee, Sang-Heon;Choi, Yong
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.11a
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    • pp.42-43
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    • 2008
  • The numerous application of ceramic superconducting bulk such as magnetic levitation train flywheel energy, levitation transpormation, magnetic bulk magnet etc. To obtain YBaCuO materials in the form of large single crystals are necessary. A refreshment and uniform distributon of the superconducting particle in the sample. The enhancement of the critical density was ascribe to a fine dispersion of the superconducting particle.

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The Effects of Soil Physical Properties on Root Distribution of Barley (토양의 물리적(物理的) 특성(特性)이 대맥의 뿌리 분포(分布)에 미치는 영향(影響))

  • Jo, In-Sang;Kim, Lee-Yul;Choi, Dae-Ung;Im, Jeong-Nam;Um, Ki-Tae
    • Korean Journal of Soil Science and Fertilizer
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    • v.16 no.2
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    • pp.126-130
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    • 1983
  • This study was desinged to find out the effects of soil physical properties on root development of barley. Barley fields were selected in consideration of drainage class and texture. Soil hardness were measured at the field. Soil bulk density, air ratio and root distribution were obtained from the core samples. 1. The amount of roots were increased and the root were distributed deeper layers with better drainage class and finer soil texture. 2. Soil hardness was related to soil bulk density, and the regression coefficient was increased with clay content (Clay ; $r=0.837^{**}$, Clay loam ; $r=0.678^*$, and Sandy loam ; $r=0.654^*$). 3. There was a highly negative correlation ($r=-0,846^{**}$) between bulk density of subsoils and amount of roots and the root developments were markedly reduced in soil bulk density of $1.4g/cm^3$. 4. Bulk density of subsoils was decreased with worse soil drainage and finer texture. Especially, in case of clayey soil at imperfectly or moderately drained soils, the air phase was less than 20% and the barley growth was worse. 5. Root development were related to hardness in surface, bulk density and ok phase in 10-30cm layer, and air phase in 30-50cm layer.

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Fabrication of the Bulk Superconductor by Thermal Diffusion Process (열확산 프로세스에 의한 초전도 벌크 합성)

  • Lee, Sang Heon
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.34 no.6
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    • pp.461-465
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    • 2021
  • A diffusion heat treatment process for YBa2Cu3O7-y bulk superconductor in a Gd2O3 powder was attempted. As a result of measuring the critical temperature of the superconducting bulk, there was no change in the superconducting transition temperature as the Gd particles diffused into the YBa2Cu3O7-y lattice, resulting in dense microstructure. As a result of measuring the critical current, the critical current density (Jc) of the superconducting bulk having treated by the Gd thermal diffusion treatment at 0 T increased to 3×104 A/cm2 at 0 T, which was higher than that of the superconducting bulk without thermal diffusion treatment. The surface magnetic force of the superconducting bulk with Gd thermal diffusion treatment was observed at the center of the superconducting bulk with the maximum trapped magnetic force (Hmax) of 1.51 kG. This result means that the Gd thermal diffusion treatment contributes to improving the critical current density Jc of YBa2Cu3O7-y, and it is believed that Gd particles migrating into the superconducting bulk through thermal diffusion either fill the surface pores of YBa2Cu3O7-y superconductors or act as a flux pinning center.

Effects of a compaction method for powder compacts on the critical current density of MgB2 bulk superconductors

  • Kang, M.O.;Joo, J.;Jun, B.H.;Choo, K.N.;Kim, C.J.
    • Progress in Superconductivity and Cryogenics
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    • v.21 no.2
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    • pp.40-44
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    • 2019
  • In this study, the effects of the compaction method for (Mg+2B) powders on the apparent density and superconducting properties of $MgB_2$ bulk superconductor were investigated. The raw powders used in this study were nano-sized boron (B) and spherical magnesium (Mg). A batch of a powder mixture of (Mg+2B) was put in a steel mold and uniaxially pressed at 1 ton or 3 tons into pellets. Another batch of the powder mixture was uniaxially pressed at 1 ton and then pressed isostatically at $1800kg/cm^2$ in the water chamber. All pellets were heat-treated at $650^{\circ}C$ for 1 h in flowing argon gas for the formation of $MgB_2$. The apparent density of powder compacts pressed at 3 ton was higher than that at 1 ton. The cold isostatic pressing (CIP) in a water chamber allowed further increase of the apparent density of powder compacts, which influenced the pellet density of the final products ($MgB_2$). The compaction methods (uniaxial pressing and CIP) did not affect the formation of $MgB_2$ and superconducting critical temperature ($T_c$) of $MgB_2$, but affected the critical current density ($J_c$) of $MgB_2$ significantly. The sample with the high apparent density showed high $J_c$ at 5 K and 20 K at applied magnetic fields (0-5 T).

Soil Physical Properties of Arable Land by Land Use Across the Country (토지이용별 전국 농경지 토양물리적 특성)

  • Cho, H.R.;Zhang, Y.S.;Han, K.H.;Cho, H.J.;Ryu, J.H.;Jung, K.Y.;Cho, K.R.;Ro, A.S.;Lim, S.J.;Choi, S.C.;Lee, J.I.;Lee, W.K.;Ahn, B.K.;Kim, B.H.;Kim, C.Y.;Park, J.H.;Hyun, S.H.
    • Korean Journal of Soil Science and Fertilizer
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    • v.45 no.3
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    • pp.344-352
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    • 2012
  • Soil physical properties determine soil quality in aspect of root growth, infiltration, water and nutrient holding capacity. Although the monitoring of soil physical properties is important for sustainable agricultural production, there were few studies. This study was conducted to investigate the condition of soil physical properties of arable land according to land use across the country. The work was investigated on plastic film house soils, upland soils, orchard soils, and paddy soils from 2008 to 2011, including depth of topsoil, bulk density, hardness, soil texture, and organic matter. The average physical properties were following; In plastic film house soils, the depth of topsoil was 16.2 cm. For the topsoils, hardness was 9.0 mm, bulk density was 1.09 Mg $m^{-3}$, and organic matter content was 29.0 g $kg^{-1}$. For the subsoils, hardness was 19.8 mm, bulk density was 1.32 Mg $m^{-3}$, and organic matter content was 29.5 g $kg^{-1}$; In upland soils, depth of topsoil was 13.3 cm. For the topsoils, hardness was 11.3 mm, bulk density was 1.33 Mg $m^{-3}$, and organic matter content was 20.6 g $kg^{-1}$. For the subsoils, hardness was 18.8 mm, bulk density was 1.52 Mg $m^{-3}$, and organic matter content was 13.0 g $kg^{-1}$. Classified by the types of crop, soil physical properties were high value in a group of deep-rooted vegetables and a group of short-rooted vegetables soil, but low value in a group of leafy vegetables soil; In orchard soils, the depth of topsoil was 15.4 cm. For the topsoils, hardness was 16.1 mm, bulk density was 1.25 Mg $m^{-3}$, and organic matter content was 28.5 g $kg^{-1}$. For the subsoils, hardness was 19.8 mm, bulk density was 1.41 Mg $m^{-3}$, and organic matter content was 15.9 g $kg^{-1}$; In paddy soils, the depth of topsoil was 17.5 cm. For the topsoils, hardness was 15.3 mm, bulk density was 1.22 Mg $m^{-3}$, and organic matter content was 23.5 g $kg^{-1}$. For the subsoils, hardness was 20.3 mm, bulk density was 1.47 Mg $m^{-3}$, and organic matter content was 17.5 g $kg^{-1}$. The average of bulk density was plastic film house soils < paddy soils < orchard soils < upland soils in order, according to land use. The bulk density value of topsoils is mainly distributed in 1.0~1.25 Mg $m^{-3}$. The bulk density value of subsoils is mostly distributed in more than 1.50, 1.35~1.50, and 1.0~1.50 Mg $m^{-3}$ for upland and paddy soils, orchard soils, and plastic film house soils, respectively. Classified by soil textural family, there was lower bulk density in clayey soil, and higher bulk density in fine silty and sandy soil. Soil physical properties and distribution of topography were different classified by the types of land use and growing crops. Therefore, we need to consider the types of land use and crop for appropriate soil management.

Measurement of Dielectric Properties of Cereal Grains by Nondestructive Microwave Measurement Technique (마이크로파 비파괴 계측기술을 이용한 곡류의 유전율 측정)

  • Kim, Ki-Bok
    • Journal of the Korean Society for Nondestructive Testing
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    • v.22 no.4
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    • pp.369-376
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    • 2002
  • The dielectric properties of cereal grains such as short-grain rough rice, brown rice and barley with various moisture contents were determined by measuring the attenuation and phase shift of the microwave signal trough the grain samples at 9.5GHz. The microwave free-space transmission measurement system consisted of sample holder, horn antenna and network analyzer. Dielectric constant and loss factor of grain samples increased with moisture content and bulk density and agreed well with previous research results. Moisture density, which is defined as the product of moisture content and bulk density, was proposed as a bulk density and variety compensation factor. The technique for measurement of dielectric properties based on free-space transmission may be useful for other particulate materials.

Effect on the Forming Property of Ceramic Powder by Dynamic CIP (동적 정수압 가압 성형에 의한 분말의 성형특성)

  • 김병익;최상흘
    • Journal of the Korean Ceramic Society
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    • v.29 no.5
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    • pp.391-395
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    • 1992
  • In order to improve the compactness and uniformity in ceramic green body, we have developed dynamic CIP(Cold Isostatic Pressing) as a new forming method in which the CIP and the vibratory pressing were combined. In dynamic CIP, bulk density on alumina compacts was linearly increased with higher │Pmax-Pbias│and maximum pressure of dynamic-CIP was decreased over one-third of that of conventional CIP to obtain the same bulk density.

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Effect of Dry Granulation Process on Flowability of Erdosteine

  • Wang, Hun-Sik;Kwon, Min-Chang;Shim, Ji-Yeon;Park, Jun-Sang
    • Proceedings of the PSK Conference
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    • 2003.10b
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    • pp.230.2-230.2
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    • 2003
  • Erdosteine, an expectorant, has been known to show a very poor flowability. Furthermore, high dosing amount (300mg/cap) and bulk density make it more difficult to fill in a capsule less than No. 0 size as bulk state. We have studied the possibility of dry granulation process in purpose of getting a better flowability and manufacturing efficiency. A roller compactor was introduced for this purpose and the applicability of laboratory result into commercial scale instrument was also experimented.Roller compacting process was very favorable to obtain the granules with good flowability and improved density profiles. (omitted)

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