• Title/Summary/Keyword: bubble point temperature

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An Experimental Study on Vapor-Liquid Equilibria of HFC and HC Refrigerant Mixtures (탄화수소 및 불화탄화수소 혼합냉매의 기상-액상 평형에 관한 실험적 연구)

  • 강병복;김민수;김영일
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.12 no.11
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    • pp.1031-1037
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    • 2000
  • Isothermal vapor-liquid equilibrium(VLE) data have been obtained for the systems of propane(R290)+1,1,1,2-tetrafluoroethane(R134a) and 1,1,1,2-tetrafluoroethane(R134a)+isobutane(R60A) in the temperature range of 253.15 to 323.15K. Experiments were performed in a circulation type apparatus by injecting vapor through liquid pool using a magnetic pump. Both systems form azeotropes in the temperature range of this study. The experimental results were estimated with the Peng-Robinson equation of state. When the temperature-dependent binary interaction parameter was used in the Peng-Robinson equation of state, the absolute average deviation of the measured bubble point pressures from the values correlated by the Peng-Robinson equation was 0.65% and 0.78% for R290+R134a and R134a+600a, respectively. Azeotropic compositions for both systems were presented.

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Phase Equilibria Measurement of Binary Mixture for the Propoxylated Neopentyl Glycol Diacrylate in Supercritical Carbon Dioxide

  • Byun, Hun-Soo
    • Korean Chemical Engineering Research
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    • v.54 no.2
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    • pp.206-212
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    • 2016
  • Experimental data are reported on the phase equilibrium of propoxylated neopentyl glycol diacrylate in supercritical carbon dioxide. Phase equilibria data were measured in static method at a temperature of (313.2, 333.2, 353.2, 373.2 and 393.2) K and at pressures up to 27.82 MPa. At a constant pressure, the solubility of propoxylated neopentyl glycol diacrylate for the (carbon dioxide + propoxylated neopentyl glycol diacrylate) system increases as temperature increases. The (carbon dioxide + propoxylated neopentyl glycol diacrylate) system exhibits type-I phase behavior. The experimental result for the (carbon dioxide + propoxylated neopentyl glycol diacrylate) system is correlated with Peng-Robinson equation of state using mixing rule. The critical property of propoxylated neopentyl glycol diacrylate is predicted with Joback and Lyderson method.

Investigation of vapor-liquid equilibrium of HFC-32/143a and HFC-143a/134a systems (HFC-32/143a와 HFC-143a/134a계의 기-액상평형 실험에 관한 연구)

  • Kim, C.N.;Park, Y.M.
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.11 no.1
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    • pp.91-99
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    • 1999
  • Vapor-liquid equilibrium apparatus is designed and set up. The equilibrium data of two binary systems, HFC-32/143a and HFC-143a/134a, are measured. Fifteen equilibrium data for HFC-32/143a and HFC-143a/134a systems are measured over the temperature range 263.15~283.15K at 10K interval and the composition range 0.10~0.80, respectively. And vapor-liquid equilibrium data are calculated using equation of state and correlation of activity coefficient and compared with the present data. Equation of state is used CSD and RKS equations and correlation of activity coefficient is used Margules' and Van Ness and Abbott's correlations. Real behavior of HFC-32/143a system has very large deviation with Raoult's rule which is ideal behavior. But real behavior of HFC-143a/134a system is similar to ideal behavior. The calculated data from CSD equation are compared with the data in the open literatures and the calculated data from REFPROP. In the results for REFPROP, the relative deviations of bubble point pressure for HFC-32/143a system are within -2.16~0.84% for CSD equation and within -0.20~1.10% for RKS equation. And the relative deviations of bubble point pressure for HFC-143a/134a system are within -0.45~0.12% and -0.20~2.8% for CSD and RKS equations, respectively.

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Investigation of vapor-liquid equilibrium of HFC32/134a system (HFC32/134a 계의 기-액상평형에 관한 연구)

  • Kim, C.N.;Park, Y.M.;Lee, B.K.;An, B.S.
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.9 no.4
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    • pp.527-535
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    • 1997
  • Vapor-liquid equilibrium apparatus is designed and set up. The vapor-liquid equilibrium data of the binary system HFC32/134a are measured in the range between 258.15 and 283.15K at compositions of 0.2, 0.4, 0.6 and 0.8 mole fraction of HFC32. Twenty-two equilibrium data are obtained. Based upon the present data, the binary interaction parameter for Carnahan-Starling-De Santis equation of state is calculated. Temperature range of data is extended to 313.04K using the data in the open literatures. Interaction parameters are determined at nine isotherms.

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Development and Characterization of High Temperature Filter (내열성여과포의 개발 및 기초성능 규명)

  • 박영옥;구철오;임정환;김홍룡;손재익;이영우
    • Journal of Energy Engineering
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    • v.7 no.1
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    • pp.103-112
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    • 1998
  • A high temperature fabric filter was developed and characterized in order to solve the various problems encountered in the operation of industrial fabric filters. Four kinds of dusts generated in the typical domestic industry were used for its characterization, coke dust from a steel manufacturing process, cement dust from a cement manufacturing process, fly ash from a fluidized-bed combustor, and incinerator ash from a waste plastics incinerator. The physical and chemical properties of the high temperature fabric filter were analyzed in terms of mean flow pore pressure, bubble point pore diameter, mean flow pore diameter, pore size distribution, and the changes in tensile strength and initial elastic modulus under $SO_2$ and $NO_2$ atmospheres. Pressure drop, dust penetration, and figure of merit for the fabric filter were also investigated in a bench-scale filter testing unit. The fabric filter developed in this study had good physical and chemical filter properties and showed a very applicability to typical industrial dusts treatments.

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A Study on the Fluid Mixing Analysis for Proving Shell Wall Thinning of a Feedwater Heater (급수가열기 동체 감육 현상 규명을 위한 유동해석 연구)

  • Shin, Min-Ho;Hwang, Kyeong-Mo;Kim, Kyung-Hoon
    • Proceedings of the KSME Conference
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    • 2004.04a
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    • pp.2017-2022
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    • 2004
  • There are multistage preheaters in the power generation plan to improve the thermal efficiency of the plant and to prevent the components from the thermal shock. The energy source of these heaters comes from the extracted two phase fluid of working system. These two-phase fluid can cause the so-called Flow Accelerated Corrosion(FAC) in the extracting piping and the bubble plate of the heater for example, in case of point Beach Nuclear Power Plant and in the Wolsung Nuclear Power Plant. The FAC is due to the mass transport of the thin oxide layer by the convection. FAC is dependent on many parameters such as the operation temperature, void fraction, the fluid velocity and pH of fluid and so on. Therefore, in this paper velocity was calculated by FLUENT code in order to find out the root cause of the wall thinning of the feedwater heaters. It also includeed in the fluid mixing analysis model are around the number 5A feedwater heater shell including the extraction pipeline. To identify the relation between the local velocities and wall thinning, the local velocities according to the analysis results were compared with distribution of the shell wall thicknes by ultrasonic test.

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End Point Temperature of Rewarming and Afterdrop After Hypothermic Cardiopulmonary Bypass in Pediatric Patients (소아에서의 저체온 심폐바이패스후 재가온 종료온도와 후하강)

  • Kim, Won-Gon;Lee, Hae-Won;Lim, Cheong
    • Journal of Chest Surgery
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    • v.30 no.2
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    • pp.125-130
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    • 1997
  • Separating the patient from hypothermic cardiopulmonary bypass(CPB) before achieving adequate rewarming often results in afterdrop, which can predispose to electrolyte disturbances, arrhythmia, hemodynamic alterations, and shivering-induced increase of oxygen consumption. In an attempt to find an adequate end point temperature of rewarming after hypothermic CPB, 50 pediatric cardiac surgical patients were r ndomly assigned for end point temperature of rewarming of 35.5$^{\circ}C$ (Group 1) or 37t (Group 2), rectal temperature. Thereafter the rectal temperature was measured half, one, four, eight, and 16 hour after arrival to the intensive care unit(ICU), with heart rate and blood pressure. Additionally the rectal temperature was compared with esophageal temperature during CPB, and axillary temperature luring stay in the ICU. Nonpulsatile perfusion with a roller pump was used in all patients and a membrane or bubble oxygenator was used for oxygenation. Both groups were comparable with respect to age, sex, body surface area, total bypass time, and rewarming time. There was no afterdrop in both groups, and there were no statistical differences in the rectal temperatures between two groups. There were also no statistical dilyerences with respect to the heart rate and blood pressure between two groups. At the end of rewarming the esophageal temperature was higher than the rectal temperature. The axil ary temperature measured in ICU was always lower than the rectal temperature. No shivering was noted in all patients. In conclusion, with restoration of rectal temperature above 35.5$^{\circ}C$ at the end of CPB in pediatric patients, we did not observe an afterdrop.

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Humidification Characterization of water-to-gas Membrane Humidifier for Polymer Electrolyte Membrane Fuel Cell (고분자 전해질 연료전지용 water-to-gas 막 가습기의 투과 특성)

  • Chang, Dae-Kwon;Lee, Yong-Taek
    • Membrane Journal
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    • v.20 no.4
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    • pp.326-334
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    • 2010
  • In this study, characterization and performance of membrane humidifier using membrane distillation was evaluated for moisture of fuel gas in the PEMFC. The data were expressed dew point. The best results show $51.19^{\circ}C$ at $60^{\circ}C$ of water temperature, $54.22^{\circ}C$ at 900 mL/min and $60.03^{\circ}C$ at 100 strands. The mass transfer modelling of membrane humidifier were able to predict humidification of fuel gases for operating PEMFC. When the membrane humidifier was applied to the 100 W stack, it showed stable voltage and power. The volume of membrane humidifier was small however, showed better performance than bubble humidifier.

Solubility of Carbon Dioxide in Poly(ethylene glycol) Dimethyl Ether (Poly(ethylene glycol) Dimethyl Ether에 대한 이산화탄소의 용해도)

  • Lee, Eun-Ju;Yoo, Jung-Deok;Lee, Byung-Chul
    • Korean Chemical Engineering Research
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    • v.55 no.2
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    • pp.230-236
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    • 2017
  • Solubility data of carbon dioxide ($CO_2$) in poly(ethylene glycol) dimethyl ether (PEGDME) are presented at pressures up to about 50 bar and at temperatures between 303 K and 343 K. The solubilities of $CO_2$ were determined by measuring the bubble point pressures of the $CO_2+PEGDME$ mixtures with various compositions using a high-pressure equilibrium apparatus equipped with a variable-volume view cell. To observe the effect of the PEGDME molecular weight on the $CO_2$ solubility, the $CO_2$ solubilities in PEGDME with two kinds of molecular weight were compared. As the equilibrium pressure increased, the $CO_2$ solubility in PEGDME increased. On the other hand, the $CO_2$ solubility decreased with increasing temperature. When compared at the same temperature and pressure, the PEGDME with a higher molecular weight gave smaller $CO_2$ solubility on a mass fraction and molality basis, but gave greater $CO_2$ solubilities on a mole fraction basis.

Theoretical Heat Flow Analysis and Vibration Characteristics During Transportation of PCS(Power Conversion System) for Reliability (전력변환장치 캐비넷에서의 내부발열 개선을 위한 열유동 분석 및 유통안전성 향상을 위한 진동특성 분석)

  • Joo, Minjung;Suh, Sang Uk;Oh, Jae Young;Jung, Hyun-Mo;Park, Jong-Min
    • KOREAN JOURNAL OF PACKAGING SCIENCE & TECHNOLOGY
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    • v.28 no.2
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    • pp.143-149
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    • 2022
  • PCS needs to freely switch AC and DC to connect the battery, external AC loads and renewable energy in both directions for energy efficiency. Whenever converting happens, power loss inevitably occurs. Minimization of the power loss to save electricity and convert it for usage is a very critical function in PCS. PCS plays an important role in the ESS(Energy Storage System) but the importance of stabilizing semiconductors on PCB(Printed Circuit Board) should be empathized with a risk of failure such as a fire explosion. In this study, the temperature variation inside PCS was reviewed by cooling fan on top of PCS, and the vibration characteristics of PCS were analyzed during truck transportation for reliability of the product. In most cases, a cooling fan is mounted to control the inner temperature at the upper part of the PCS and components generating the heat placed on the internal aluminum cooling plate to apply the primary cooling and the secondary cooling system with inlet fans for the external air. Results of CFD showed slightly lack of circulating capacity but simulated temperatures were durable for components. The resonance points of PCS were various due to the complexity of components. Although they were less than 40 Hz which mostly occurs breakage, it was analyzed that the vibration displacement in the resonance frequency band was very insufficient. As a result of random-vibration simulation, the lower part was analyzed as the stress-concentrated point but no breakage was shown. The steel sheet could be stable for now, but for long-term domestic transportation, structural coupling may occur due to accumulation of fatigue strength. After the test completed, output voltage of the product had lost so that extra packaging such as bubble wrap should be considered.