• Title/Summary/Keyword: bubble charge

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A High Efficiency Electrolytic Cell by Superposing Pulsed Corona Discharge in Water (수중 펄스코로나 방전을 중첩한 고효율 강전해수 발생장치)

  • 이재용;김진규;정성진;박승록;문재덕
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.50 no.2
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    • pp.79-85
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    • 2001
  • A conventional electrolyzing cell has been made by an ion exchange membrane inbetween parallel plate electrodes. A low dc voltage is applied to the electrodes for electrolyzing and the efficiency is remained in low. in this study, a novel electrolyzing cell with a pair of slit-type third electrodes installed inbetween parallel plate electrodes has been proposed and investigated experimentally. And pulse power wa supplied to between each electrodes. This slit type of third electrodes can concentrate the strong electric fields at the every its edges to accelerate the electrolyzing powers, and to generate oxygen bubble discharges for generating oxidants. And moreover the slits eliminate the space charge limiting action and the temperature of the water by leaking out through the slits from electrolyzing region to outside of the main electrode region. As a result, it was found that a strong electorzed water of pH 2.8 and pH 10.5 and oxidants dissolved water of 1 [ppm] in acidic water were obtained with a tap water fed at the electric current of 2 [A], which however were several times higher oxidant and ion concentration quantity compared with the conventional cell.

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Photovoltaic effect in $\beta$-carotene glass ($\beta$-carotene glass의 광기전력효과)

  • 김의훈
    • 전기의세계
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    • v.20 no.4
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    • pp.23-30
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    • 1971
  • The photovoltaic behaviors ahve been observed with a sandwich-type cell, consisting of a junction between .betha.-carotene and stannic oxide conducting layer to provide a junction electrode. In the stannic oxide and .betha.-carotene junction it was found that its electromotive forse decreased to a value smaller than the original one. This is due to a space charge formation. Photovoltage reached approximately 40mV with an irradiation energy of 250Kcal/M$^{2}$hr. It appeared that a magnitude of the photovoltaic response was proportional to the logarithm of irradiance. The time constant of the photovoltaic effect was shown to be approximately 0.7 sec. The wavelength dependence of the photovoltaic behavior was very anomalous. It is assumed that such an anomalous photoresponse depends on a internal capacitance due to some bubble during process to make a cell.

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Fundamental Structure in Simultaneous Removal for Phytoplankton and Nutrient Salt in Lakes

  • SEKI, Tatsuhiro;ISHII, Yuuichi;ISHII, Toshio;TAKI, Kazuo
    • Environmental Engineering Research
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    • v.14 no.4
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    • pp.220-225
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    • 2009
  • The water quality in eutrophic lakes is affected by serious problems, such as abnormal increasing of Cyanobacteria. The purpose of this study was to investigate the possibility of a modified flotation system using a hybrid technique formed by chemical compounds and an electrostatic bridge. Therefore, experiments using the hybrid technique were performed to measure the zeta potential value on the phytoplankton surface and the removal efficiencies of phytoplankton, ammonia nitrogen, nitrate nitrogen and phosphoric acid. The results were as follows: Firstly, the zeta potential of M.aeruginosa was observed to approach charge neutralization due to adhesion of magnesium hydroxide precipitate on the phytoplankton surface in the pH range 10.5 to 11. Secondly, the concentration of chlorophyll-a decreased from about 150 to 20${\mu}g$g/L, with a maximum removal efficiency of 84% due to coagulation with pH values higher than 10. Thirdly, the N$H_4$-N concentration was observed to decrease from 0.62 to 0.54mg-N/L (13%), and the P$O_4$-P concentration, which is a limiting factor to the formation of algae blooms, decreased from 0.27 to 0.02mg-P/L (92%). These findings suggest that the modified flotation system can be applied for the purification of the raw water of numerous lakes containing high phytoplankton populations and elevated pH.

Test and Evaluation for Time Delay Function of Point Detonating Fuze by Underwater Sound Analysis (수중음향 분석을 통한 충격신관 지연기능 시험평가)

  • Na, Taeheum;Jang, Yohan;Jeong, Jihoon;Kim, Kwanju
    • Journal of the Korea Institute of Military Science and Technology
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    • v.20 no.2
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    • pp.217-224
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    • 2017
  • This study proposes an evaluation method for time delay function(TDF) of Point Detonation(PD) fuse using underwater explosion and water entry phenomena. Until now, nothing but the naked eyes of an observer or video images have been used to determine whether the TDF of PD fuze is operated or not. The observer has verified the performance of TDF by analysing the shape of the plume formed by underwater explosion. However, it is very difficult to evaluate the TDF of PD fuse by these conventional methods. In order to overcome this issue, we propose a method using underwater sound signal emitted from the underwater explosion of high explosive charge. The result shows that the measured sound signal is in accord with the physical phenomena of water entry of warhead as well as underwater explosion. Also, from the hypothesis test of bubble period, difference on underwater sound analysis between dud event and delay one is proved.

Suppressing Effect of Hydrogen Evolution by Oxygen Functional Groups on CNT/ Graphite Felt Electrode for Vanadium Redox Flow Battery (탄소나노튜브/흑연펠트 전극의 산소작용기를 활용한 바나듐 레독스 흐름 전지의 수소발생 억제 효과)

  • Kim, Minseong;Ko, Minseong
    • Journal of the Korean institute of surface engineering
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    • v.54 no.4
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    • pp.164-170
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    • 2021
  • Vanadium redox flow batteries (VRFB) have emerged as large-scale energy storage systems (ESS) due to their advantages such as low cross-contamination, long life, and flexible design. However, Hydrogen evolution reaction (HER) in the negative half-cell causes a harmful influence on the performance of the VRFB by consuming current. Moreover, HER hinders V2+/V3+ redox reaction between electrode and electrolyte by forming a bubble. To address the HER problem, carbon nanotube/graphite felt electrode (CNT/GF) with oxygen functional groups was synthesized through the hydrothermal method in the H2SO4 + HNO3 (3:1) mixed acid solution. These oxygen functional groups on the CNT/GF succeed in suppressing the HER and improving charge transfer for V2+/V3+ redox reaction. As a result, the oxygen functional group applied electrode exhibited a low overpotential of 0.395 V for V2+/V3+ redox reaction. Hence, this work could offer a new strategy to design and synthesize effective electrodes for HER suppression and improving the energy density of VRFB.

Effect of Ultrasonic Irradiation on Ozone Nanobubble Process for Phenol Degradation (페놀 분해를 위한 오존 나노기포 공정에서 초음파 조사의 영향)

  • Lee, Sangbin;Park, Jae-Woo
    • Journal of the Korean GEO-environmental Society
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    • v.23 no.3
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    • pp.23-29
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    • 2022
  • In this study, we investigated the ozone nanobubble process in which nanobubble and ultrasonic cavitation were applied simultaneously to improve the dissolution and self-decomposition of ozone. To confirm the organic decomposition efficiency of the process, a 200 mm × 200 mm × 300 mm scale reactor was designed and phenol decomposition experiments were conducted. The use of nanobubble was 2.07 times higher than the conventional ozone aeration in the 60 minutes reaction and effectively improved the dissolution efficiency of ozone. Ultrasonic irradiation increased phenol degradation by 36% with nanobubbles, and dissolved ozone concentration was lowered due to the promotion of ozone self-decomposition. The higher the ultrasonic power was, the higher the phenol degradation efficiency. The decomposition efficiency of phenol was the highest at 132 kHz. The ozone nanobubble process showed better decomposition efficiency at high pH like conventional ozone processes but achieved 100% decomposition of phenol after 60 minutes reaction even at neutral conditions. The effect by pH was less than that of the conventional ozone process because of self-decomposition promotion. To confirm the change in bubble properties by ultrasonic irradiation, a Zetasizer was used to measure the bubbles' size and zeta potential analysis. Ultrasonic irradiation reduced the average size of the bubbles by 11% and strengthened the negative charge of the bubble surface, positively affecting the gas transfer of the ozone nanobubble and the efficiency of the radical production.

Experimental Study on Behavior of Green Water for Rectangular Structure (사각형 해양구조물의 청수현상 발생과정에 대한 실험적 연구)

  • Chae, Young Jun;Lee, Kang Nam;Jung, Kwang Hyo;Suh, Sung Bu;Lee, Jae Yong
    • Journal of Ocean Engineering and Technology
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    • v.30 no.1
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    • pp.44-50
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    • 2016
  • An experimental study was performed to investigate the behavior of green water on a structure with a rectangular cross section under wave conditions, along with the flow characteristics in bubbly water flow. An experiment was conducted in a two-dimensional wave flume using an acrylic model (1/125) of FPSO BW Pioneer operating in the Gulf of Mexico under its design wave condition. The occurrence of green water, including its development, in front of the model was captured using a high-speed Charge Coupled Device (CCD) camera with the shadowgraph technique. Using consecutive images, the generation procedure for green water on the model was divided into five phases: flip through, air entrapment, wave run-up, wave overturning, and water shipping. In addition, the distinct water elevations of the green water were defined as the height of flip through, height of splashing jet, and height of freeboard exceedance, and showed a linear relationship with the incoming wave height.