• Title/Summary/Keyword: boron behavior

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A STUDY ON THE BEHAVIOR OF BORON DISTRIBUTION IN LOW CARBON STEEL BY PARTICLE TRACKING AUTORADIOGRAPHY

  • Mun, Dong-Jun;Shin, Eun-Joo;Koo, Yang-Mo
    • Nuclear Engineering and Technology
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    • v.43 no.1
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    • pp.1-6
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    • 2011
  • The behavior of the non-equilibrium grain boundary segregation of boron in low carbon steel was studied through a particle tracking autoradiography. The behavior of the non-equilibrium grain boundary segregation of boron during continuous cooling was compared with the isothermal kinetics of the non-equilibrium grain boundary segregation of boron at the holding temperature using an effective time method. On the basis of the experiments, the cooling rate dependence of the non-equilibrium segregation of boron was explained using the time dependence of the non-equilibrium segregation of boron in low carbon steel. The experimental observations for the cooling rate dependence of the grain boundary segregation of boron are in good agreement with the time dependence of the grain boundary segregation of boron. The mechanisms of the non-equilibrium segregation of boron during cooling in low carbon steel are also discussed.

Development of Integrated Boration and Dilution Model for Boron Concentration Behavior Analysis (붕산농도 거동분석을 위한 종합적 붕산주입 및 희석모델 개발)

  • Chi, Sung-Goo;Park, Han-Kwon;Kuh, Jung-Eui
    • Nuclear Engineering and Technology
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    • v.24 no.1
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    • pp.30-39
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    • 1992
  • In this study, an integrated boration and dilution (INBAD) model is proposed to predict the required makeup flowrate for RCS boron concentration change and to analyze the boron concentration behavior at each subsystem within the RCS including CVCS during boration and dilution operation. The INBAD model is constructed by integrating an existing neutronic code and a boration and dilution model. The boration and dilution model has been developed for our specific purpose using the one-cell model and multi-cell model. In addition, in order to assess the boron concentration behavior more realistically, two important features such as variable pressurizer heater output and optional makeup mode (either direct or indirect injection) are implemented in this model. In order to demonstrate the usefulness of this model, the boron concentration behavior analysis at each subsystem were performed for both direct and indirect injection mode using YGN 3 and 4 design data. Also, the effect of pressurizer heater output on the primary loop boron concentration was investigated. The results showed that the boron concentration changes can be predicted accurately at each subsystem during boration and dilution operation.

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Analysis of the Boron Concentration Behavior Using LTC code During Power Maneuvering

  • Kwon, Jong-Soo;Chi, Sung-Goo;Park, Hae-Yun;Park, Seong-Hoon;Lee, Gi-Won
    • Proceedings of the Korean Nuclear Society Conference
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    • 1996.05a
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    • pp.413-418
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    • 1996
  • The main purpose of this paper is to develop the modified LTC code for accurate analysis of the boron concentration behavior of all components in the Nuclear Steam Supply System (NSSS). This is achieved by adapting a multi-cell mad to the existing Long Term Cooling (LTC) code. To verify the modified LTC, the simulated results were compared with the actual test results measured during YGN 4 initial criticality test. It was shown that the simulated results of this modified LTC were in good agreement with the actual test results. Also, the boron concentration behavior analysis were performed using the modified LTC code for both direct and indirect dilution/boration nude using YGN 3,4 design data. This modified LTC code can provide a valuable information in predicting boron concentration behavior during power maneuvering such as startup operation, shutdown operation and load follow operation. It is expected that the modified LTC can be applied to both on-line and off-line mode using Plant Computer System(PCS).

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Reverse annealing of boron doped polycrystalline silicon

  • Hong, Won-Eui;Ro, Jae-Sang
    • Proceedings of the Korean Vacuum Society Conference
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    • 2010.02a
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    • pp.140-140
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    • 2010
  • Non-mass analyzed ion shower doping (ISD) technique with a bucket-type ion source or mass-analyzed ion implantation with a ribbon beam-type has been used for source/drain doping, for LDD (lightly-doped-drain) formation, and for channel doping in fabrication of low-temperature poly-Si thin-film transistors (LTPS-TFT's). We reported an abnormal activation behavior in boron doped poly-Si where reverse annealing, the loss of electrically active boron concentration, was found in the temperature ranges between $400^{\circ}C$ and $650^{\circ}C$ using isochronal furnace annealing. We also reported reverse annealing behavior of sequential lateral solidification (SLS) poly-Si using isothermal rapid thermal annealing (RTA). We report here the importance of implantation conditions on the dopant activation. Through-doping conditions with higher energies and doses were intentionally chosen to understand reverse annealing behavior. We observed that the implantation condition plays a critical role on dopant activation. We found a certain implantation condition with which the sheet resistance is not changed at all upon activation annealing.

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Effect of Austenitizing Temperature on the Hardenability and Tensile Properties of Boron Steels (오스테나이트화 온도에 따른 보론강의 경화능과 인장 특성)

  • Hwang, Byoungchul
    • Korean Journal of Materials Research
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    • v.25 no.9
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    • pp.497-502
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    • 2015
  • The hardenability of boron steel specimens with different molybdenum and chromium contents was investigated using dilatometry and microstructural observations, and then was quantitatively measured at a critical cooling rate corresponding to 90 % martensite hardness obtained from a hardness distribution plotted as a function of cooling rate. Based on the results, the effect of an austenitizing temperature on the hardenability and tensile properties was discussed in terms of segregation and precipitation behavior of boron atoms at austenite grain boundaries. The molybdenum addition completely suppressed the formation of pro-eutectoid ferrite even at the slowest cooling rate of $0.2^{\circ}C/s$, while the chromium addition did at the cooling rates above $3^{\circ}C/s$. On the other hand, the hardenability of the molybdenum-added boron steel specimens decreased with an increasing austenitizing temperature. This is associated with the preferred precipitation of boron atoms since a considerable number of boron atoms could be concentrated along austenite grain boundaries by a non-equilibrium segregation mechanism. The secondary ion mass spectroscopy results showed that boron atoms were mostly segregated at austenite grain boundaries without noticeable precipitation at higher austenitization temperatures, while they formed as precipitates at lower austenitization temperatures, particularly in the molybdenum-added boron steel specimens.

Enhanced Field Emission Behavior from Boron-Doped Double-walled Carbon Nanotubes Synthesized by Catalytic Chemical Vapor Deposition

  • Kang, J.H.;Jang, H.C.;Choi, J.M.;Lyu, S.C.;Sok, J.H.
    • Journal of Magnetics
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    • v.17 no.1
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    • pp.9-12
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    • 2012
  • Attempts to dope carbon nanotube (CNT) with impurities in order to control the electronic properties of the CNT is a natural course of action. Boron is known to improve both the structural and electronic properties. In this report, we study the field emission properties of Boron-doped double-walled CNT (DWCNT). Boron-doped DWCNT films were fabricated by catalytic decomposition of tetrahydrofuran and triisopropyl borate over a Fe-Mo/MgO catalyst at $900^{\circ}C$. We measured the field emission current by varying the doping amount of Boron from 0.8 to 1.8 wt%. As the amount of doped boron in the DWCNT increases, the turn-on-field of the DWCNT decreases drastically from 6 V/${\mu}m$ to 2 V/${\mu}m$. The current density of undoped CNT is 0.6 mA/$cm^2$ at 9 V, but a doped-DWCNT sample with 1.8 wt% achieved the same current density only at only 3.8 V. This shows that boron doped DWCNTs are potentially useful in low voltage operative field emitting device such as large area flat panel displays.

Plastic Behavior of $\textrm{L1}_{2}\textrm{Ni}$-20Al-10Fe Intermetallic Compounds with Microalloying Additions of B, Hf and Zr (B, Hf, Zr첨가에 따른 $\textrm{L1}_{2}\textrm{Ni}$-20Al-10Fe 금속간화합물의 소성거동)

  • Kim, Min-Cheol;Hwang, Seung;O, Myeong-Hun;Wi, Dang-Mun
    • Korean Journal of Materials Research
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    • v.7 no.7
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    • pp.592-596
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    • 1997
  • LI$_{2}$형 결정구조를 갖는 Ni-20at.%AI-10at%Fe 금속간화합물에 boron, zirconium 과 hafnium을 최고 0.5at.% 까지 첨가하여 항복강도, 연성, 파괴 등 기계적 성질의 변화를 인장시험과 X선분석 및 XPS분석 등을 통하여 관찰하였다. Ni-20at.% AI-10at.% Fe금속간화합물에 boron을 첨가하였을 때는 연신율의 현저한 증가가 나타났으나 zirconium이나 hafnium첨가의 경우에는 별다른 효과가 나타나지 않았다. Ni-20at.%AI-10at%Fe 금속간화합물의 경우, boron의 양이 증가할수록 인장연신율이 증가하였으며 0.1at.%의 boron을 첨가한 경우 최고 48.5%의 상온인장연신율을 나타내었다. 첨가물을 넣지 않은 경우와 zirconium과 hafnium을 첨가한 경우, 파괴모드는 입계파괴의 형태를 나타내었으나 boron을 첨가한 경우에는 파괴모드가 입계파괴에서 입내파괴로 변화되었다. XPS분석을 통하여 boron이 입계에 편석된 것을 관찰할 수 있었으며 이는 이미 제시된 여러가지 해석들과 일치하는 결과이다. 이로부터 boron의 첨가에 따른 인장연신율의 증가는 boron의 입계편석거동과 관련이 있음을 알 수 있다.

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A Study on the Behavior of Boron Extraction from Brine by Diol-type Extractant (Diol계(系) 추출제(抽出劑)에 의한 염수(鹽水) 중(中) 보론의 추출거동(抽出擧動) 연구(硏究))

  • Yoon, Mi-Hee;Kang, Dong-Jun;An, Jeon-Woong;Min, Dong-Joon
    • Resources Recycling
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    • v.21 no.1
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    • pp.41-48
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    • 2012
  • A study on the behavior of boron extraction by TMPD(2,2,4-trimethyl-1,3-pentanediol) was carried out to find the optimum conditions for the boron extraction from brine. In case of boron extraction from 0.736 g/L boron-containing brine, typical optimum extractive conditions would be confirmed to be 0.75 mol/L of extractant concentration at 3.0 pH of brine with 1 of phase ratio and 20 min. of shaking time at 298 K respectively. And 1 mol/L sodium hydroxide of stripping agent was shown above 99 % of boron extraction and stripping efficiencies. Also, extraction equilibrium equation were obtained through experiments as follows : log D = 1.7 log $[TMPD]_O$ + constant at pH < 6.

A study on a Boron-Nitride Nanotube as a Gigahertz Oscillator (기가헤르츠 오실레이터를 위한 BN 나노튜브 연구)

  • Lee, Jun-Ha
    • Journal of the Semiconductor & Display Technology
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    • v.6 no.1 s.18
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    • pp.27-30
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    • 2007
  • The gigahertz oscillator behavior of double-walled boron-nitride nanotube (BNNT) was investigated by using classical molecular dynamics simulations. The BNNT oscillator characteristics were compared to carbon-nanotube (CNT) and hybrid-C@BNNT oscillators. The results show that the BNNT oscillators are higher than the van der Waals force of the CNT oscillator. Since the frictional effects of BNNT oscillators are higher than that of a CNT oscillator, the damping factors of BNNT and hybrid oscillators are higher than that of a CNT oscillator.

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Toughening of Boron Carbide Ceramics by Addition of $TiB_2$ ($TiB_2$ 첨가에 의한 탄화붕소 소결체의 파괴인성 증진)

  • 이채현;박원규;김종희
    • Journal of the Korean Ceramic Society
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    • v.33 no.4
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    • pp.464-470
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    • 1996
  • Toughening mechanism of boron carbide ceramics by the addition of titanium boride was investigated. Speci-men was prepared by hot pressing of boron carbide with upto 30vol% of titanium boride particulates. Toughness of boron carbide ceramics was increased from 4.7 MPa m1/2 to 6.3 MPa m1/2 with 15 vol% TiB2 addition. But further increase of TiB2 content results in slow decrease of toughness. From microstructure evaluation and crack propagation behavior it is concluded that the major toughening mechanism is crack deflection pheno-mena.

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