• 제목/요약/키워드: boron analysis

검색결과 264건 처리시간 0.035초

붕산농도 거동분석을 위한 종합적 붕산주입 및 희석모델 개발 (Development of Integrated Boration and Dilution Model for Boron Concentration Behavior Analysis)

  • Chi, Sung-Goo;Park, Han-Kwon;Kuh, Jung-Eui
    • Nuclear Engineering and Technology
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    • 제24권1호
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    • pp.30-39
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    • 1992
  • 본 연구에서는 붕산주입 및 회석운전동안에 노심의 붕산농도를 변화시키기 위한 보충수 유량을 예측하고 화학 및 체적제어계통을 포함한 원자로 냉각재계통내에 있는 각종 계통에서 붕산농도 거동분석을 위한 종합적 붕산주입 및 희석모델(INBAD)이 제안되었다. 이 모델은 기존의 노심코드와 새로 개발된 붕산주입 및 희석모델로 구성되어 있으며 붕산주입 및 희석모델은 단일 cell 모델 및 다중 cell모델을 이용하여 본 연구목적에 맞게 개발되었다. 또한, 본 모델에서는 보다 실제적인 붕산농도 거동분석을 위하여 가변적 가압기 가열기 출력 및 선택적인 보충수 운전형태 (직접주입 또는 간접주입)가 모사되었다. 이 모델의 유용성을 증명하기 위하여 영광 3,4호기 설계자료를 이용하여 각종 계통에서 직접주입 및 간접주입운전에 대한 붕산농도 거동분석을 수행하였고, 노심의 붕산농도에 대한 가압기 가열기의 영향을 검토하였다. 그 결과 본 모델은 붕산주입 및 희석운전시에 각종 계통에서 붕산농도 변화를 정확히 예측할 수 있음을 보여 주었다.

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Determination of Boron Isotopic Ratio by Using an Alpha Track Technique

  • Park, Yong-Joon;Pyo, Hyung-Yeal;Song, Kyu-Seok;Song, Byoung-Chul;Jee, Kwang-Yong;Kim, Won-Ho
    • Bulletin of the Korean Chemical Society
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    • 제27권10호
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    • pp.1609-1612
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    • 2006
  • The determination of the boron isotopic ratio in solutions was achieved by means of a solid state track detector by using an alpha track. The neutron flux was optimized by using a Cd-foil to find the optimum conditions for counting the number of alpha tracks on the selected solid detector caused by the (n, $\alpha$) nuclear reaction of boron. The home-made multi-dot detector plate was utilized in this study to increase the reproducibility of the measurement by uniformly drying the boron solution within the marked circle area on the detector plate. The experimental results of this study verified that the $^{11}B/^{10}B $ isotopic ratio can be measured by observing the number of alpha tracks for different concentrated standard solutions with various isotopic compositions. This technique was applied to the determination of $^{10}B$ enrichment factor in a biological sample for a boron neutron capture therapy.

Boron Powder 적용 연료과농 추진제 및 연소 후 생성물의 특성 연구 (Characteristics of Fuel-rich Solid Propellants with Boron Powder and the Combustion Products)

  • 김미리;김정은;길태옥
    • 한국추진공학회지
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    • 제26권1호
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    • pp.12-19
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    • 2022
  • 덕티드 로켓의 가스발생기에 사용되는 추진제는 연료과농 추진제로서, 일반적인 고체 로켓 추진제에 비하여 과량의 금속연료와 소량의 산화제를 포함한다. 본 논문에서는 연료과농 추진제를 제조하기 위하여 보론 분말과 MgAl(Magnesium-Aluminium Alloy)를 적용하였다. 이 금속연료를 적용한 추진제의 특성을 분석하였고, 이를 통하여 최적의 조성을 연구하였다. 추진제의 연소생성물 분석을 통하여 보론 비드가 아닌 미립의 보론 분말로도 가스발생기용 연료과농 추진제가 가능함을 확인하였다.

전기방사 후 탄소화된 폴리아크릴로니트릴(PAN) 나노섬유의 수용액 중 붕소 흡착 (Aqueous Boron Adsorption on Carbonized Nanofibers Prepared from Electrospun Polyacrylonitrile(PAN) Mats)

  • 홍소희;한선기;김수영;원용선
    • 청정기술
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    • 제28권3호
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    • pp.210-217
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    • 2022
  • 붕소(Boron)은 희소자원으로 유리, 반도체 재료, 화약 등 다양한 용도로 사용되고 있는데, 우리나라의 경우 붕소를 전량 수입에 의존하고 있으며 전 세계 붕소 매장량과 현재 추세의 생산량을 고려하면 50년 이후 지상의 붕소는 고갈될 확률이 높다. 따라서 안정적 붕소의 공급을 위해 해수 내의 붕소를 회수할 수 있는 소재 및 공정의 개발이 요구된다. 이에 본 연구에서는 수용액 중 붕소를 회수하기 위한 소재로 전기방사 후 탄소화된 폴리아크릴로니트릴(polyacrylonitrile, PAN) 나노섬유를 도입하였다. 먼저 탄소섬유 표면의 붕소 흡착 기작을 이론적으로 구현하기 위해 범밀도함수이론(density functional method) 기반의 분자모델링 작업을 수행하였는데, 계산된 에너지도(energetics)에 따르면 붕소가 탄소섬유 표면에 흡착되는 화학반응이 가능한(viable) 것으로 판단되었다. 한편 전기방사로 제작된 PAN 나노섬유를 대기 중에서 안정화를 진행한 후 아르곤(Ar) 분위기에서 탄소화하였고 붕산 수용액에 담지시켰다. SEM과 Raman 분석을 통해 각각 전기방사와 탄소화가 잘 진행되었는지 확인하였고, XPS 분석을 통해 탄소섬유 표면에 질소가 잘 도핑되었는지 여부와 붕소의 흡착 여부를 확인하였다. 결과적으로 전기방사된 PAN으로부터 제작된 탄소섬유는 해수 내 붕소 회수에 사용될 수 있는 소재로 판단된다.

Analysis of the Boron Concentration Behavior Using LTC code During Power Maneuvering

  • Kwon, Jong-Soo;Chi, Sung-Goo;Park, Hae-Yun;Park, Seong-Hoon;Lee, Gi-Won
    • 한국원자력학회:학술대회논문집
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    • 한국원자력학회 1996년도 춘계학술발표회논문집(1)
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    • pp.413-418
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    • 1996
  • The main purpose of this paper is to develop the modified LTC code for accurate analysis of the boron concentration behavior of all components in the Nuclear Steam Supply System (NSSS). This is achieved by adapting a multi-cell mad to the existing Long Term Cooling (LTC) code. To verify the modified LTC, the simulated results were compared with the actual test results measured during YGN 4 initial criticality test. It was shown that the simulated results of this modified LTC were in good agreement with the actual test results. Also, the boron concentration behavior analysis were performed using the modified LTC code for both direct and indirect dilution/boration nude using YGN 3,4 design data. This modified LTC code can provide a valuable information in predicting boron concentration behavior during power maneuvering such as startup operation, shutdown operation and load follow operation. It is expected that the modified LTC can be applied to both on-line and off-line mode using Plant Computer System(PCS).

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저탄소.저합금 보론 첨가강의 냉각속도에 따른 미세조직과 기계적 성질의 영향 (The Effect of Microstructure and Mechanical Property with Cooling Rapid in Boron-Treated Low Carbon Low Alloy Steel)

  • 손제영;이기동;김성구;김영석
    • 한국소성가공학회:학술대회논문집
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    • 한국소성가공학회 2008년도 추계학술대회 논문집
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    • pp.207-210
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    • 2008
  • The effects of boron additions in steels have long been recognized as very important, mainly with respect to hardnability of heat treatable steels. we investigated the effect of the microstructure and mechanical properties with cooling condition after heat treatment of the boron-treated(${\fallingdotseq}8{\sim}18ppm$) low carbon(${\fallingdotseq}0.2%C$) low alloy steel. The specimens were austenitised for 10 min at $910^{\circ}C$, cooled for the various periods of time from 10 sec to 30 sec or with water after forming for 15 sec. After cooling, mechanical properties were measured by tensile test and hardness test. For analysis of microstructure, Optical were carried out.

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핫스탬핑용 보론강의 고온 성형한계선도 평가 연구 (Formability Test of Boron Steel Sheet at Elevated Temperature for Hot Stamping)

  • 한수식
    • 소성∙가공
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    • 제26권2호
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    • pp.121-126
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    • 2017
  • The hot stamping process is an innovative forming method that could prevent the cracking of high strength steel sheets. The formability test of boron steel sheet using forming limit diagrams at elevated temperature is very complicated and time consuming job. In this paper, an alternative test method to evaluate the formability of boron steel in hot stamping has proposed. It measured the FLD0 instead of whole strain combinations of FLD with the tensile test machine and specially designed test rig. Test results shows that the proposed test method can simulate the plain strain condition fracture and can make the FLD of boron steel sheet at elevated temperature with less effort.

Benzothiazole fluorine-boron core complex: quantum luminescence controls

  • 손영아;김형주;이효천
    • 한국염색가공학회:학술대회논문집
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    • 한국염색가공학회 2012년도 제46차 학술발표회
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    • pp.71-71
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    • 2012
  • To control luminescence emission property, a novel series of strong fluorescent fluorin-boron complexes were synthesized in higher yield. The resulting structural analysis was completed. Small molecules with a built-in fluorine-boron core structural architecture has been attracted considered attention as the key emissive elements due to the their good properties such as bipolar charge transport and high photo efficiency. Thus, new type of fluorine-boron(F-B) complexes are designed and prepared. Changing the substituent position on fluorophore ring provided a deep understanding on the relationship between structure and optical properties.

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Buckling temperature of a single-walled boron nitride nanotubes using a novel nonlocal beam model

  • Elmerabet, Abderrahmane Hadj;Heireche, Houari;Tounsi, Abdelouahed;Semmah, Abdelwahed
    • Advances in nano research
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    • 제5권1호
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    • pp.1-12
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    • 2017
  • In this paper, the critical buckling temperature of single-walled Boron Nitride nanotube (SWBNNT) is estimated using a new nonlocal first-order shear deformation beam theory. The present model is capable of capturing both small scale effect and transverse shear deformation effects of SWBNNT and is based on assumption that the inplane and transverse displacements consist of bending and shear components, in which the bending components do not contribute toward shear forces and, likewise, the shear components do not contribute toward bending moments. Results indicate the importance of the small scale effects in the thermal buckling analysis of Boron Nitride nanotube.

Determination of Hot Leg Recirculation Switchover Time to Prevent Boron Precipitation during Post-LOCA LTC for ULCHIN l&2

  • Park, Han-Rim;Ban, Chang-Hwan;Jeong, Jae-Hoon;Hwang, Sun-Tack;Chang, Byong-Hoon
    • 한국원자력학회:학술대회논문집
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    • 한국원자력학회 1996년도 추계학술발표회논문집(1)
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    • pp.328-333
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    • 1996
  • Boric acid concentrations of the refueling water storage tank (RWST) and the accumulators for Ulchin 1&2 (UCN 1&2) are increased to meet the post loss of coolant accident (post-LOCA) shutdown requirement for the extended fuel cycles from 12 months to 18 months. To maintain long term cooling (LTC) capability following a LOCA, the switchover tine is examined using BORON code to prevent the boron precipitation in the reactor core with the increased boron concentrations. The analysis results show that, at 8 hours after the initiation of LOCA. the emergency core noting system (ECCS) should be manually realigned to the simultaneous recirculation mode from the cold leg recirculation mode.

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