• Title/Summary/Keyword: boric acid

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Safety margin and fuel cycle period enhancements of VVER-1000 nuclear reactor using water/silver nanofluid

  • Saadati, Hassan;Hadad, Kamal;Rabiee, Ataollah
    • Nuclear Engineering and Technology
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    • v.50 no.5
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    • pp.639-647
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    • 2018
  • In this study, the effects of selecting water/silver nanofluid as both a coolant and a reactivity controller during the first operating cycle of a light water nuclear reactor are investigated. To achieve this, coupled neutronic-thermo-hydraulic analysis is employed to simulate the reactor core. A detailed VVER1000/446 reactor core is modeled in monte carlo code (MCNP), and the model is verified using the porous media approach. Results show that the maximum required level of silver nanoparticles is 1.3 Vol.% at the beginning of the cycle; this value drops to zero at the end of cycle. Due to substitution of water/boric acid with water/Ag nanofluid, reactor operation time at maximum power extends to 357.3 days, and the energy generation increases by about 27.3%. The higher negative coolant temperature coefficient of reactivity in the presence of nanofluid in comparison with the water/boric acid indicates that the reactor is inherently safer. Considering the safety margins in the presence of the nanofluid, minimum departure from nucleate boiling ratio is calculated to be 2.16 (recommendation is 1.75).

Decay Resistance of Fire-Retardant Treated Wood

  • Lee, Hyun-Mi;Yang, Jae-Kyung;Kim, Jong-Man
    • Journal of the Korean Wood Science and Technology
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    • v.32 no.6
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    • pp.7-13
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    • 2004
  • In this study, the Korean pine wood (Pinus densiflora Sieb. et Zucc) and Italian poplar wood (Populus euramericana Guinier) was treated with a mixture of monoammonium phosphate (MAP) and boric acid. Their usability as fire retardant and as decay-resistant construction and interior materials were evaluated by testing of chemicals, corrosion rate and absorption rate, weight loss and chemical contents. An experiment was performed to compare treated pine wood and Italian poplar wood. According to the results, Italian poplar wood had higher specific gravity and retention of chemicals than pine wood, and treated wood showed higher decay-resistance than untreated one. Weight loss was less in treated wood than untreated one because the degree of decay was lower in the former than the latter. Corrosion rate and absorption rate met the KS standard for wood preservative performance. The chemical contents analysis was carried out to determine the degree of decay and it was found that the preservative effect of chemical treatment was lower in Italian poplar wood than in pine wood.

Solidify Properties of Radioactive Waste using Paraffin Wax (파라핀 왁스를 이용한 방사성 폐기물의 고화 특성)

  • Lee, Han Chul;Chang, Yoon Ho
    • Applied Chemistry for Engineering
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    • v.17 no.4
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    • pp.391-396
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    • 2006
  • When radioactive wastewater was solidified treatment by cement, the drying rate of cement and the volume reduction ratio was decreased because of boric acid component in the wastewater. In order to supplement the demerit, effects of paraffin wax investigated in this study. Paraffin wax has a hydrophobic properties and a low affinity with inorganic materials. When the radioactive wastewater was tested by a small of wax, the compressive strength of solidified waste are decreased Therefore boric acid in radioactive wastewater are first treated by alkali salt and coated by the stearic acid. During the solidification step, The amount of paraffin wax addition get the result that the compressive strength of solidification with cement was the same as that with paraffin wax. The leaching properties of radioactive waste solidified was the same CFL (cumulative fraction leached), PR (penetration rate), effective diffusivity if paraffin wax content in solidified waste was 20% or 25%.

Effect of Fluoride Ion in the Analysis of Tin by HG-ICP-AES (HG-ICP-AES법에 의한 Tin 분석시 플루오르화 이온의 영향에 대한 연구)

  • Lim, Heon-Sung;Cho, Sung-Il;Lee, Sueg-Geun
    • Analytical Science and Technology
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    • v.14 no.5
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    • pp.416-421
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    • 2001
  • The optimization of the reductant and acid concentration for stannane($SnH_4$) generation was investigated by using a continuous flow hydride generator combined with an inductively coupled plasma-atomic emission spectrometer. Several different prereductants were studied to remove the interfering effect of fluoride ion on the hydride generating of tin. The optimum acid concentration was 0.5-1.0 M for the 1-2% $NaBH_4$ and 1.0 M NaOH and the interfering effect of fluoride ion was minimized using boric acid and L-cysteine mixed solution as a prereductant. The reconveries of tin at 20 ng/mL level in the solution containing fluoride ion were 100~108 %.

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The X-Ray Fluorescent Spectrographic Analysis of Silicate Minerals (X線螢光分析에 依한 珪酸鹽鑛物의 分析)

  • Chan Kuk Kim;Ki Nam Sang;Hwang Am Kim
    • Journal of the Korean Chemical Society
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    • v.13 no.1
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    • pp.49-55
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    • 1969
  • X-ray Fluorescence Spectrographic method has been applied for the rapid determination of main components, such as $SiO_2$, $Al_2O_3$, $Fe_2O_3$, CaO, MgO and $K_2O$ in Silicate Minerals. In this method, Boric Acid was used as a binder after fusion with Lithium Tetraborate in the briquet-making process. The Lithium Flubride, Ammonium di-Hydrogen Phosphate and Ethylene Diamine d-Tartrate crystals were used with Scintillation counter and Gas Flow counter as the detectors. Several influences on this method were discussed, including the particle size of samples and reducing of the matrix effects by dilution with Boric Acid and addition of Lanthanum Oxide with the diluent. In order to test the reproducibility of this method described above, the determination of the same kind of samples were carried out repeatedly, and the results obtained were presented in the table. Calibration curves for each element were presented, and the application of the method was tested with International Rock Standard T-Ⅰ. All the results obtained by X-Ray Fluorescence Spectrographic method were compared with the results by conventional chemical method.

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Combustion Characteristics of Hinoki Cypress Louver after Pressure Impregnation with Boric Acid, Borax and Ammonium Phosphate (붕사, 붕산 및 인산암모늄을 가압 함침한 편백 루버의 연소특성)

  • Park, Hyung-Ju
    • Fire Science and Engineering
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    • v.29 no.6
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    • pp.1-5
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    • 2015
  • In this study, the combustion characteristics of Hinoki Cypress Louver were measured after performing pressure impregnation with aqueous solution of boric acid, borax, and ammonium phosphate. The characteristics measured include ignition time, critical heat flux, and mass loss rate by incident hear flux (25, 30 and $50kW/m^2$). The samples used for the test were $100{\times}100{\times}10mm$, and the 5 min variation for each incident heat flux was measured 3 times. The results show that the ignition time for incident heat flux of $25kW/m^2$ showed a delay effect of 17.4 to 21.3% except for Type C-H. There was no significant difference at 35 and $50kW/m^2$ in the average mass loss rate in Types A-H and D-H, which had lower rates than Type N-H, which was predicted to be higher than that of Type N-H ($10.7kW/m^2$) by 38.22 to 60.46%. It is thus expected that at the time of initial primary fire, there would be a delay effect against fire spread.

Optimization of boric acid production process from boron ore (붕소원광으로부터 붕산제조 공정의 최적화)

  • 임형미;이옥란;이승호;최병현
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2003.03a
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    • pp.32-32
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    • 2003
  • Calcuim borate 화합물의 하나인 Colemanite 천연원광을 출발물질로 붕산을 제조하는 공정에 대한 연구로 황산 첨가량과 처리온도, 건조온도와 시간에 따라 생성되는 붕산의 결정상과 수득률, 순도 및 입자의 형상을 관찰하였다. 황산 첨가로 붕소 성분은 용해되어 액상에 남고, SO$_4$$^{2-}$ 와 결합하여 불용성 고체로 분리되고, 붕소의 온도에 따른 용해도 차를 이용하여 재결정화하는 방법으로 99% 이상의 순도를 갖는 붕산(H$_3$BO$_3$)을 얻었다. 공정의 각 단계에서 생성되는 화합물을 TG, NMR, IR, XRD, ICP 등의 방법으로 분석하여 최적 제조 조건을 찾았다.

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Effect of Induction Heat Bending Process on the Properties of ASME SA106 Gr. C Carbon Steel Pipes

  • Kim, Ki Tae;Kim, Young Sik;Chang, Hyun Young;Oh, Young Jin;Sung, Gi Ho
    • Corrosion Science and Technology
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    • v.14 no.2
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    • pp.47-53
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    • 2015
  • Recently, the bending process is greatly applied to fabricate the pipe line. Bending process can reduce welding joints and then decrease the number of inspection. Thus, the maintenance cost will be reduced. Induction heat bending process is composed of bending deformation by repeated local heat and cooling. By this thermal process, corrosion properties and microstructure can be affected. This work focused on the effect of induction heating bending process on the properties of ASME SA106 Gr. C low carbon steel pipes. Microstructure analysis, hardness measurements, and immersion corrosion test were performed for base metal and bended area including extrados, intrados, crown up, and down parts. Microstructure was analyzed using an optical microscope and SEM. Hardness was measured using a Rockwell B scale. Induction heat bending process has influenced upon the size and distribution of ferrite and pearlite phases which were transformed into finer structure than those of base metal. Even though the fine microstructure, every bent area showed a little lower hardness than that of base metal. It is considered that softening by the bending process may be arisen. Except of I2, intrados area, the others showed a similar corrosion rate to that of base metal. But even relatively high rate of intrados area was very low and acceptable. Therefore, it is judged that induction heat bending process didn't affect boric acid corrosion behaviour of carbon steel.

A Feasibility Study on the Polymer Solidification of Evaporator Concentrated Wastes (폐액증발기 농축폐액 폴리머고화 타당성 연구)

  • Yang, Ho-Yeon;Kim, Ju-Youl
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.5 no.4
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    • pp.297-308
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    • 2007
  • The granulation equipment of concentrated wastes is manufactured for the polymer solidification of concentrated wastes. It uses liquid sodium silicate as a granulating agent for the granulating of dried powder containing boric acid. The granulating agent is sprayed in the form of droplet and mean size of dried granules is $2{\sim}4mm$. The new technology which has been used for the polymer solidification of spent resin in U.S. and certified by Nuclear Regulatory Commission (NRC) is successfully applied to concentrated wastes. This uses in-situ solidification process within drum without mechanical mixing. Maximum loading of waste can be achieved without increasing of waste volume. Polymer waste forms were evaluated with several test such as fire test, compressive strength test, leaching test, immersion test, irradiation test, and thermal cycling test according to standard test procedures.

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Susceptibilities of German Cockroach, Blattella germanica to Insecticides According to Application Methods (바퀴에 대한 처리방법에 따른 살충제 감수성)

  • Han Jongbeen;Kim Gil-Hah
    • Korean journal of applied entomology
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    • v.43 no.3 s.136
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    • pp.241-247
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    • 2004
  • Susceptibility of Blattella germanica male adults to 61 commercial insecticides was evaluated by diet dipping method. Among them three insecticides of dichlorvos, fenitrothion, and fipronil showed over $90\%$ mortality. The insect was more susceptible to dichlorvos and fenitrothion in filter paper contact method than in diet dipping one, but fipronil was vice versa. Toxicities of the three chemicals were evaluated by application parts of the such as head, thorax, abdomen, and legs. Dichlorvos and fenitrothion were more toxic when applied to head, and flpronil was thorax. $LT_{50}$ values by diet dipping method showed that fenitrothion and fipronil acted more rapidly than boric acid and hydramethylnon. The values of the former two were 1.05 and 0.98 days, and those of the latter two were 3.92 and 2.26 days, respectively.