• Title/Summary/Keyword: bonding performance

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Effects of Coupling Agents and Clay on the Physical Properties of Wood Flour/Polyethylene Composites (커플링제 및 점토가 목분/폴리에틸렌 복합체의 물성에 미치는 영향)

  • Park, Byung-Sub;Kim, Dae-Su
    • Polymer(Korea)
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    • v.35 no.2
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    • pp.124-129
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    • 2011
  • Wood plastic composites (WPCs) are attracting a lot of interest recently. In this study, wood flour/polyethylene (PE) composites panels comprised of a coupling agent and nanoclay were prepared by melt-blending followed by compression molding. Five maleic anhydride grafted polyethylene (MAPE) coupling agents were tested, and the best choice and its optimum content were determined. The mechanical properties of the WPCs were measured by UTM, and the thermal properties were measured by TGA, DMA, DSC, and TMA. Adding just a small amount (1 phr) of organoclay made the tensile and flexural strength and the crystallinity of the WPC somewhat increase and the storage modulus and dimensional stability of the WPC largely increase. SEM images showed that the coupling agent drastically improved wood flour/PE interfacial bonding. Selecting the best coupling agent optimized content and adding a small amount of organoclay resulted in a high performance wood flour/PE composite.

Nitrogen을 도핑시킨 Ge-Sb-Te 박막의 광전자 및 광흡수 분광학 연구

  • Sin, Hyeon-Jun;Jeong, Min-Cheol;Kim, Min-Gyu;Lee, Yeong-Mi;Kim, Gi-Hong;Jeong, Jae-Gwan;Song, Se-An;Sun, Zhimei
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.02a
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    • pp.186-186
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    • 2013
  • Nitrogen doped Ge-Sb-Te (N-GST) thin films for phase change random access memory (PRAM) applications were investigated by synchrotron-radiation-based x-ray photoelectron spectroscopy and absorption spectroscopy. Nitrogen doping in GST resulted in more favorable N atoms' bonding with Ge atoms rather than with Sb and Te atoms [1,2], which explains the higher phase change transition temperature than that of undoped Ge-Sb-Te thin film. Surprisingly, it was noticed that N atoms also existed in the form of molecular nitrogen, $N_2$, which is detrimental to the stability of the GST performance [3]. N-doped GST experimental features were also supported by ab-initio molecular dynamic calculations [2]. References [1] M.-C. Jung, Y. M. Lee, H.-D. Kim, M. G. Kim, and H. J. Shin, K. H. Kim, S. A. Song, H. S. Jeong, C. H. Ko, and M. Han, "Ge nitride formation in N-doped amorphous Ge2Sb2Te5", Appl. Phys. Lett. 91, 083514 (2007). [2] Zhimei Sun, Jian Zhou, Hyun-Joon Shin, Andreas Blomqvist, and Rajeev Ahuja, "Stable nitride complex and molecular nitrogen in N doped amorphous Ge2Sb2Te5", Appl. Phys. Lett. 93, 241908 (2008). [3] Kihong Kim, Ju-Chul Park, Jae-Gwan Chung, and Se Ahn Song, Min-Cherl Jung, Young Mi Lee, Hyun-Joon Shin, Bongjin Kuh, Yongho Ha, Jin-Seo Noh, "Observation of molecular nitrogen in N-doped Ge2Sb2Te5", Appl. Phys. Lett. 89, 243520 (2006).

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An Experimental Study for Bond Stress between DFRCC and Carbon FRP Plank Used as a Permanent Formwork (영구거푸집으로 활용한 탄소섬유 FRP 판과 DFRCC 사이의 부착응력에 관한 실험적 연구)

  • Park, Chan-Young;Yoo, Seung-Woon
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.34 no.6
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    • pp.1687-1694
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    • 2014
  • Recently FRP of carbon fibers is utilized as a repairing and reinforcing material for concrete structures. In this study, the bond performance between CFRP planks and ductile fiber reinforced cementitious composites was evaluated in order to develop a new system of concrete bridge deck to take advantage of the FRP planks of carbon fiber using as a permanent formwork. In order to strengthen the bonding between the FRP and cast-in-place concrete, an epoxy resin circulated in the market generally was fitted with a silica sand. The bond stress of ordinary concrete appeared in 2.11~5.43MPa and the bond stress of ductile fiber reinforced cementitious composites DC1 (RF4000) and DC2 (PP) respectively were 3.91~5.60MPa, 2.92~5.21MPa and the average bond stress of DC3 (RF4000+RSC15) and DC4 (PP+RSC15) were 4.80~5.58MPa, 5.57~5.89MPa.

Numerical Analysis of ECC Uniaxial Tension Behavior (ECC의 1축 인장 거동 해석)

  • Kim, Yun-Yong;Lee, Bang-Yeon;Kwon, Seung-Hee;Kim, Jeong-Su
    • Proceedings of the Korea Concrete Institute Conference
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    • 2008.04a
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    • pp.917-920
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    • 2008
  • ECC is a special kind of high performance cementititous composite which exhibits typically more than 2% tensile strain capacity by bridging microcracks at a crack section. Therefore, micromechanics should be adopted to obtain multiple cracking and strain hardening behavior. This paper propose a linear elastic analysis method to simulate the multiple cracking and strain hardening behavior of ECC. In an analysis, the stress-crack opening relation modified considering the orientation of fibers and the number of effective fibers is adopted. Furthermore, to account for uncertainty of materials and interface between materials, the randomness is assigned to the tensile strength(${\sigma}_{fci}$), elastic modulus($E_{ci}$), peak bridging stress(${\sigma}_{Bi}$) and crack opening at peak bridging stress(${\delta}_{Bi}$), initial stress at a crack section due to chemical bonding, (${\sigma}_{0i}$), and crack spacing(${\alpha}_cX_d$). Test results shows the number of cracking and stiffness of cracked section are important parameters and strain hardening behavior and maximum strain capacity can be simulated using the proposed method.

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Direct Fabrication of a-Si:H TFT Arrays on Flexible Substrates;Principal Manufacturing Challenges and Solutions

  • O’Rourke, Shawn M.;Loy, Douglas E.;Moyer, Curt;Ageno, Scott K.;O’Brien, Barry P.;Bottesch, Dirk;Marrs, Michael;Dailey, Jeff;Bawolek, Edward J.;Trujillo, Jovan;Kaminski, Jann;Allee, David R.;Venugopal, Sameer M.;Cordova, Rita;Colaneri, Nick;Raupp, Gregory B.
    • 한국정보디스플레이학회:학술대회논문집
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    • 2007.08a
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    • pp.251-254
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    • 2007
  • Principal challenges to $\underline{direct\;fabrication}$ of high performance a-Si:H transistor arrays on flexible substrates include automated handling through bonding-debonding processes, substrate-compatible low temperature fabrication processes, management of dimensional instability of plastic substrates, and planarization and management of CTE mismatch for stainless steel foils. Viable solutions to address these challenges are described.

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Hydrophobic Self-assembled Monolayer(SAM) Coating for Enhanced Demolding Performance in Micromolding (마이크로몰딩의 이형성 향상을 위한 소수성 Self-assembled Monolayer(SAM) 코팅)

  • Park, Sang-Ha;Han, Seung-O;Park, Jong-Yeon;Mun, Seong-Uk;Park, Jeong-Ho
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.51 no.4
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    • pp.175-183
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    • 2002
  • In this paper, the surface modification effect of self-assembled monolayer(SAM) of 1-dodecanethiol [$CH_3$($CH_2$)$_{11}$SH] used as an anti-adhesive film in micromolding process was studied. Monolayers of 1-dodecanethiol[$CH_3$(CH$_2$)$_{11}$SH] were obtained by immersing a metal place in pure 1-dodecanethiol. SAM film on the nickel plate has been examined by using X-ray photoelectron spectroscopy(XPS). The focus has been placed on S-Ni bonding. From the XPS analysis, sulfur atoms were detected from the SAM film as a chemical composition of S-Ni. In order to measure an adhesion force of the SAM-coated nickel surface, atomic force microscopy(AFM) was used in force-distance mode, which whows the micro-adhesive force on solid surface. It was shown that adhesion forces measured from the SAM-coated nickel surface and the Ni surface without SAM coating were 3.52nN and 5.32nN, respectively. In order to investigate the effect of SAM coating on the surface foughness the replica in demolding process, hot embossing experiments were performed using a SAM-coated nickel master and a nickel master without SAM coating. Surface roughness of replica from the SAM-coated master showed 25nm and that of replica from master without SAM coating was 35nm. The smoother surface roughness of the replica from the SAM-coated, master is believed to result from reduction in the adhesion forces.ces.

A Study on the Performance of Mechanical Pressurizing Equipment(MPE) for Improving Bond Strength of Repair Materials for Concrete Box Structures (콘크리트 박스 구조물용 보수재의 부착강도 향상을 위한 기계식 가압장비(MPE) 성능에 관한 연구)

  • Yu, Hyeong-Sik;Jung, Jee-Seung
    • The Journal of the Convergence on Culture Technology
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    • v.6 no.1
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    • pp.477-483
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    • 2020
  • The rehabilitation methods used in existing concrete box structures rely on the method of attaching the repair material to the section of the structure with a spray equipment. In the case of ceiling or wall parts, the adhesion force to the repair material may be reduced by the gravity and dead load after construction. In subway structures, vibration causes a problem that reduces the initial adhesion. Supplementary measures are needed as the quality of repair varies depending on the worker's proficiency and construction environment. In this study, mechanical pressurization equipment was developed that can apply a certain pressure after construction of a repairwork to solve problems such as reduction of adhesion of repair materials by gravity and variation of repair quality by labor work. To find out the effect of the pressurized equipment, a chamber similar to the field conditions was constructed to measure the attachment strength different from the pressurized condition, the section, and the environmental conditions. The pressurization differed from the other parts, but the adhesion strength of up to 70% was increased.

Aging Characteristic of Intermetallic Compounds and Bonding Strength of Flip-Chip Solder Bump (플립 칩 솔더 범프의 접합강도와 금속간 화합물의 시효처리 특성)

  • 김경섭;장의구;선용빈
    • Journal of the Microelectronics and Packaging Society
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    • v.9 no.1
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    • pp.35-41
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    • 2002
  • Flip-chip interconnection that uses solder bump is an essential technology to improve the performance of micro-electronics which require higher working speed, higher density, and smaller size. In this paper, the shear strength of Cr/Cr-Cu/Cu UBM structure of the high-melting solder bump and that of low-melting solder bump after aging is evaluated. Observe intermetallic compound and bump joint condition at the interface between solder and UBM by SEM and TEM. And analyze the shear load concentrated to bump applying finite element analysis. As a result of experiment, the maximum shear strength of Sn-97wt%Pb which was treated 900 hrs aging has been decreased as 25% and Sn-37wt%Pb sample has been decreased as 20%. By the aging process, the growth of $Cu_6/Sn_5$ and $Cu_3Sn$ is ascertained. And the tendency of crack path movement that is interior of a solder to intermetallic compound interface is found.

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A Concise Design for the Irradiation of U-10Zr Metallic Fuel at a Very Low Burnup

  • Guo, Haibing;Zhou, Wei;Sun, Yong;Qian, Dazhi;Ma, Jimin;Leng, Jun;Huo, Heyong;Wang, Shaohua
    • Nuclear Engineering and Technology
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    • v.49 no.4
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    • pp.734-743
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    • 2017
  • In order to investigate the swelling behavior and fuel-cladding interaction mechanism of U-10Zr alloy metallic fuel at very low burnup, an irradiation experiment was concisely designed and conducted on the China Mianyang Research Reactor. Two types of irradiation samples were designed for studying free swelling without restraint and the fuel-cladding interaction mechanism. A new bonding material, namely, pure aluminum powder, was used to fill the gap between the fuel slug and sample shell for reducing thermal resistance and allowing the expansion of the fuel slug. In this paper, the concise irradiation rig design is introduced, and the neutronic and thermal-hydraulic analyses, which were carried out mainly using MCNP (Monte Carlo N-Particle) and FLUENT codes, are presented. Out-of-pile tests were conducted prior to irradiation to verify the manufacturing quality and hydraulic performance of the rig. Nondestructive postirradiation examinations using cold neutron radiography technology were conducted to check fuel cladding integrity and swelling behavior. The results of the preliminary examinations confirmed the safety and effectiveness of the design.

Preparation and Characteristics of Biodegradable Polyurethane/Clay Nanocomposite Films (생분해성 폴리우레탄/클레이 나노복합 필름의 제조 및 특성 연구)

  • Kim, Seong Woo
    • Korean Chemical Engineering Research
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    • v.51 no.3
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    • pp.382-387
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    • 2013
  • Biodegradable polyurethane (PU)/clay nanocomposite films were prepared via extrusion compounding process followed by casting film process. Organically modified montmorillonite (denoted as C30B) with a large amount of hydroxyl groups on its surface was used for the formation of strong bonding with PU resin. From both XRD analysis and TEM observations, the intercalated and exfoliated structure, and dispersion state of silicate platelets in the compounded nanocomposite films were confirmed. In addition, the rheological and tensile properties, optical transparency, oxygen permeability of the prepared nanocomposites were investigated as a function of added nanoclay content, and moreover based on these results, the corelation between the morphology and the resulting properties of the nanocomposites could be presented. The inclusion of nanoclays at appropriate content resulted in remarkable improvement in the nanocomposite performance including tensile modulus, elongation, transparency, and oxygen barrier property, however at excess amount of nanoclays, reduction or very slight increase was observed due to poor dispersion. The biodegradability of the prepared nanocomposite film was evaluated by examining the deterioration in the barrier and tensile properties during degradation period under compost.