• 제목/요약/키워드: bond characteristics

검색결과 707건 처리시간 0.027초

방청시멘트 도막철근의 내부식 성능 및 부착강도 성능연구 (Corrosion and Bond Strength Characteristics of Anti-Corrosive Cement Coated Reinforcements)

  • 오병환;이종렬;조윤구
    • 콘크리트학회지
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    • 제11권2호
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    • pp.251-259
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    • 1999
  • 최근 다양한 침해환경에 건설되는 구조물이 증가함에 따라 철근 및 강재의 부식위험성이 높아지면서, 철근 콘크리트 구조물의 내구성 저하문제가 큰 관심으로 떠오르고 있다. 특히 해양 환경하에 건설된 철근 콘크리트 구조물의 경우 구조물 외부로부터 침투되는 염분의 영향으로 인한 철근부식이 발생 및 진행되어 콘크리트 구조물에 균열, 박리 등의 손상을 받게된다. 그러므로 해양콘크리트 구조물은 염해에 대해 내구성 및 신뢰성 확보가 중요시되고 있다. 따라서, 본 연구에서는 철근의 부착강도를 크게 감소시키지 않게 하는 방법으로서 시멘트 계통의 방청시멘트를 철근에 도막한 후 내부식성능과 부착강도특성을 실험적으로 연구하였다. 본 연구결과, 방청시멘트 도막철근은 소요의 내부식성능을 갖고 있으면서도 부착강도특성도 일반철근과 유사하였으며, 앞으로 실구조물의 내구성증진을 위해 효율적으로 사용될 수 있는 토대가 될 것으로 사료된다.

Effects of Hybrid Coat on shear bond strength of five cements: an in-vitro study

  • Guo, Yue;Zhou, Hou-De;Feng, Yun-Zhi
    • The Journal of Advanced Prosthodontics
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    • 제9권6호
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    • pp.447-452
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    • 2017
  • PURPOSE. To evaluate the sealing performance of Hybrid Coat and its influence on the shear bond strength of five dentin surface cements. MATERIALS AND METHODS. Six premolars were pretreated to expose the dentin surface prior to the application of Hybrid Coat. The microscopic characteristics of the dentinal surfaces were examined with scanning electron microscopy (SEM). Then, 40 premolars were sectioned longitudinally, and 80 semi-sections were divided into a control group (untreated) and a study group (treated by Hybrid Coat). Alloy restoration was bonded to the teeth specimen using five different cements. Shear bond strength was measured by the universal testing machine. The fracture patterns and the adhesive interface were observed using a stereomicroscope. RESULTS. SEM revealed that the lumens of dentinal tubules were completely occluded by Hybrid Coat. The Hybrid Coat significantly improved the shear bond strength of resin-modified glass ionomer cement (RMGIC) and resin cement (RC) but weakened the performance of zinc phosphate cement (ZPC), zinc polycarboxylate cement (ZPCC) and glass ionomer cement (GIC). CONCLUSION. Hybrid Coat is an effective dentinal tubule sealant, and therefore its combined use with resin or resin-modified glass ionomer cements can be applied for the prostheses attachment purpose.

FRP 판과 현장타설 콘크리트 사이의 단순 부착모델 제안 (A Proposal of Simplified Bond Stress-Slip Model between FRP Plank and Cast-In-Place Concrete)

  • 유승운
    • 한국구조물진단유지관리공학회 논문집
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    • 제12권1호
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    • pp.65-72
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    • 2008
  • 최근에 상용 FRP 판(plank)을 콘크리트 구조물의 영구 거푸집 및 보강재로 이용하기 위한 연구가 진행되고 있다. FRP 판과 타설 콘크리트가 합성효과를 발휘하기 위해서는 두 재료간의 부착이 중요한 요인 중의 하나이다. 이러한 부착을 확보하기 위하여 FRP 판에 모래를 일반적으로 건설현장에서 많이 사용하는 에폭시를 이용하여 부착하였다. FRP 판과 콘크리트 합성구조의 구조적 거동을 이해하기 위해서는 FRP판과 타설 콘크리트 사이의 정량적인 국부 부착모델이 필요하다. 본 연구에서는 이와 같은 합성구조 시스템에 간단히 적용할 수 있는 단순 부착모델을 제안한다.

Effect of waste aluminium shavings on the bond characteristics of laterized concrete

  • Ofuyatan, Olatokunbo M.;Ivoke, Anthony A.;Olowofoyeku, Adeoye M.;Adesina, Adeyemi;Oluwafemi, John
    • Advances in materials Research
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    • 제8권1호
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    • pp.25-36
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    • 2019
  • The utilization of fibre in concrete production not only solves the problem of disposing this solid waste but helps conserve natural resources. This study investigated the effect of waste aluminum shavings on bond strength of laterized concrete. Laterized concrete spliced beams of $150{\times}250{\times}2150mm$ and $175{\times}275{\times}2300mm$ were prepared. Fifteen specimens with 16 mm and 20 mm were cast with the addition of aluminium shavings at varying percentages of 1vol%, 1.5vol% and 2vol%; another ten specimens with 16 mm and 20 mm diameter bars at 0% of aluminium shavings were cast as control. Concrete cubes of number were prepared, three taken for each set of various percentages of aluminium shavings were used to determine the concrete strength. It was observed from the analysis that the compressive strength decreased as the percentage of aluminium shavings increased, while the aluminium shavings increased the bond between concrete and steel. However, for normal concrete there was an increase in bond resistance with increase in aluminium shavings. The bond resistance of 16 mm was found to be higher than that of 20 mm in all the specimens tested.

프랜차이즈 모기업 핵심역량 자원이 가맹점 관계결속과 재계약의도에 미치는 영향 (Effects of Core Competence and Resource Sharing on the Relational Bond among Franchisees and on Re-contract Intention in the Franchising Parent Companies)

  • 허영욱;주말찬
    • 유통과학연구
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    • 제12권4호
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    • pp.11-22
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    • 2014
  • Purpose - The domestic franchise industry has made significant contributions to industry such as investment, employment, and community economy development, facilitating growth potential. The franchise industry provides management knowhow transfer between parent companies and franchisees as per contracts addressing use of business signs, franchisees' independent position, franchisor support, and royalties to be paid to the franchisors. However, many franchisors lack management knowhow and provide insufficient support because of poor control of franchisees and not having a systematic approach to support. This results in dissatisfied franchisees and failure to establish long-term relationships. Few studies have examined relational commitment and/or re-contract intention by support resources between franchisors and franchisees, despite a considerable output of theories and studies of the growth of the franchise industry. The purpose of this study, therefore, was to examine the effects of the ability to provide resources on relational commitments and re-contract intention, and to suggest causal relationships and implications. Research design, data, and methodology - The subject was domestic franchisors registered with the Association of Franchise with more than 50 franchisees. Franchisees under contract for 2 years and considering re-contract of their franchise 2 years later were used. The subjects totaled 300 franchisees in Seoul. A questionnaire survey was used to investigate the subject of franchisees' concessions during the 10 days from November 21, 2013 to November 30, 2013. After excluding 16 surveys with poor answers, 284 responses were finally used. Four areas and 44 questions were used. A nominal scale was used for four common characteristics questions including gender, ages, educational background, and franchise managing time. Questions regarding ability, relational commitment, and re-contract intention made use of a Likert 5-point scale. Data coding and data cleaning were used. SPSS 18.0 was used as follows. First, frequency analysis was done to investigate demographic characteristics. Second, exploratory factor analysis was done to verify validity of testing tools, and Cronbach's α coefficient was used to verify reliability. Third, correlation analysis and multiple regression analysis were done. An exploratory factor analysis was done to verify validity of concepts. A correlation analysis was done to test relationships between the variables, and multiple regression analysis was done to verify franchisor's ability, franchisees' relational commitment, and re-contract intention. Results - The following were the outcomes. First, store operation management, finance operation management, and human resource management affected the calculated bond. Second, store operation management and finance operation management affected the emotional bond. Third, store operation management, finance operation management, human resource management, and marketing management affected the prescriptive bond. Fourth, calculated bond and prescriptive bond had an effect on re-contract intention. Conclusions - As stated above, in franchise management, parent companies' offer and instruction of core competence to their franchisees as an information resource could improve the relational bond by helping them grow together through the resource sharing. Consequently, core competence factors were promoting factors that could improve franchisees' re-contract intention for a long time.

결합재와 베니어세라믹이 금속-세라믹 보철물의 전단결합강도와 계면특성에 미치는 영향 (The Influence of Bonding Strength and Interface Characteristics to Bonding Agent and Veneer Ceramics on Metal-Ceramic Prosthetics)

  • 김민정;최성민;정인성
    • 대한치과기공학회지
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    • 제33권4호
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    • pp.349-357
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    • 2011
  • Purpose: In this study, for the reasons of observing the changes when using bonding agent with Ni-Cr alloy and Co-Cr alloy and using VM13 and Vintage MP ceramic which have the disparity in coefficient of thermal expansion, it is carried out to evaluate the characteristics of the bonding agent through the analysis of the interface between metal and ceramic and the analysis of bond strength by variable. Methods: The surface treatment was performed on the two kinds of alloy(Ni-Cr alloy and Co-Cr alloy) specimens, which were sandblasted and were treated with bonder application. The metal-ceramic interfaces were analyzed with EPMA in order to ionic diffusion, and the shear test was performed. Results: As a result of observation of metal-ceramic interfacial properties, it was observed that Cr atoms were spread from the alloy body to the ceramic floor in the specimen of Group B. It was also seen that Cr, W atoms were spread from the alloy body to the ceramic floor in the specimen of Group S. In consequence of observing Shear bond strength, it was calculated that the specimen of BSV was 27.75(${\pm}11.21$)MPa, BSM was 27.02(${\pm}5.23$)MPa, BCV was 30.20(${\pm}5.99$)MPa, BCM was 27.94(${\pm}10.76$)MPa, SSV was 20.83(${\pm}2.58$)MPa, SSM was 23.98(${\pm}3.94$)MPa, SCV was 32.32(${\pm}4.68$)MPa, and SCM was 34.54(${\pm}10.63$)MPa. Conclusion: In the metal-ceramic interface of Bellabond plus sample group, diffusion of Cr atoms was incurred and diffusion of C Cr atoms and W atoms in the sample group of $Starloy{(R)}\;C$ was observed. Using bonding agent showed the higher bond strength than using the sand blasting treatment. In the Bellabond plus alloys, the specimen group with the use of binding materials showed higher shear bond strength, but didn't show statistically significant differences (p>0.05). In the $Starloy{(R)}\;C$ alloys, the specimen group with the use of binding materials showed higher shear bond strength and statistically significant differences(p<0.05). In terms of VM13 ceramic, it was in the Bellabond plus alloys that the high shear bond strength was showed, but there's no statistically significant differences(p>0.05). In terms of Vintage MP ceramic, it was in the $Starloy{(R)}\;C$ alloys that the high shear bond strength was showed and statistically significant differences(p<0.05). Metal-ceramic to fracture of the shear strength measurements and an analysis of all aspects of military usage fracture of the composite, respectively.

의치용 레진치와 수복용 복합레진 간의 결합강도에 관한 연구 (SHEAR BOND STRENGTHS BETWEEN ABRASION-RESISTANT DENTURE TEETH AND COMPOSITE RESINS)

  • 김미리;정창모;전영찬;임장섭
    • 대한치과보철학회지
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    • 제40권2호
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    • pp.201-212
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    • 2002
  • This study investigated the shear bond strengths between abrasion-resistant denture teeth and composite resins according to surface treatments. Denture teeth for this study were Trubyte IPN teeth(Dentsply Inc., USA) with interpenetrating polymer network and Endura Posterio (Shofu Inc. Japan) of composite resin teeth, and restorative composite resins were Clearfil FII (Kuraray, Japan) of the self-cured composite resin and Z100(3M Dental Product, USA) of the light-cured composite resin. Five different surface treatments were evaluated: (1) $50{\mu}m\;A1_2O_3$ sandblasting: (2) #100 carbide paper; (3) chloroform; (4) retentive holes; and (5) no treatment. After surface treatments, denture teeth were examined by scanning electron microscopy(SEM), and the maximum shear bond strengths between abrasion-resistant denture teeth and composite resins were measured using Instron. The results were as follows; 1. IPN teeth treated with sandblasting had the highest shear bond strength, and Endura treated with sandblasting and carbide paper had significantly greater shear bond strength than with any other surface treatment. 2. Regardless or composite resins, the shear bond strength on Endura was greater than on IPN teeth. 3. Regardless of denture teeth, the shear bond strength of Clearfil FII was greater han of Z100. 4. In appearance of SEM, IPN teeth treated with sandblasting showed generalized roughness on the all of surface, however, carbide paper treatment resulted in partly rough. Endura treated with sandblasting and carbide paper showed similar surface characteristics. Wetting denture teeth surface with chloroform removed the debris and created a particle-free and smooth surface.

Full Geometry Optimizations of Bond-Stretch Isomers of C202+ Fullerene Dication by the Hybrid Density Functional B3LYP Methods

  • Lee, Ji-Hyun;Lee, Chang-Hoon;Park, Sung-S.;Lee, Kee-Hag
    • Bulletin of the Korean Chemical Society
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    • 제32권1호
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    • pp.277-280
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    • 2011
  • We studied the relative stability and atomic structure of five $C_{20}^{2+}$ isomers obtained by two-electron ionization of a $C_{20}$ cage (the smallest fullerene). All the isomers are bond-stretch isomers, i.e., they differ in bond length. In particular, in one of the isomers with Ih symmetry, all the bond lengths are equal. Full geometry optimizations of the dipositive ion $C_{20}^{2+}$ were performed using the hybrid density functional (B3LYP/6-31G(d)) methods. All isomers were found to be true minima by frequency analysis at the level of B3LYP/6-31G(d) under the reinforced tight convergence criterion and a pruned (99,590) grid. The zero-point correction energy for the cage bond-stretch isomers was in the increasing order $D_{2h}<C_{2h}<C_2<T_h<I_h$ of $C_{20}^{2+}$. The energy difference among the isomers of cage dipositive ions was less than that among neutral cage isomers. Our results suggest that these isomers show bond-stretch isomerism and that they have an identical spin state and an identical potential energy curve. Although the predominant electronic configurations of the isomers are similar, the frontier orbital characteristics are different, implying that we could anticipate an entirely different set of characteristic chemical reactions for each type of HOMO and LUMO.

Effect of antioxidants on push-out bond strength of hydrogen peroxide treated glass fiber posts bonded with two types of resin cement

  • Khoroushi, Maryam;Mazaheri, Hamid;Tarighi, Pardis;Samimi, Pouran;Khalighinejad, Navid
    • Restorative Dentistry and Endodontics
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    • 제39권4호
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    • pp.303-309
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    • 2014
  • Objectives: Hydrogen peroxide ($H_2O_2$) surface treatment of fiber posts has been reported to increase bond strength of fiber posts to resin cements. However, residual oxygen radicals might jeopardize the bonding procedure. This study examined the effect of three antioxidant agents on the bond strength of fiber posts to conventional and self-adhesive resin cements. Materials and Methods: Post spaces were prepared in forty human maxillary second premolars. Posts were divided into five groups of 8 each: G1 (control), no pre-treatment; G2, 10% $H_2O_2$ pre-treatment; G3, G4 and G5. After $H_2O_2$ application, Hesperidin (HES), Sodium Ascorbate (SA) or Rosmarinic acid (RA) was applied on each group respectively. In each group four posts were cemented with Duo-Link conventional resin cement and the others with self-adhesive BisCem cement. Push-out test was performed and data were analyzed using 2-way ANOVA and tukey's post-hoc test (${\alpha}=0.05$). Results: There was a statistically significant interaction between the cement type and post surface treatment on push-out bond strength of fiber posts (p < 0.001, F = 16). Also it was shown that different posts' surface treatments significantly affect the push-out bond strength of fiber posts (p = 0.001). $H_2O_2$ treated posts (G2) and control posts (G1) cemented with Duo-link showed the highest ($15.96{\pm}5.07MPa$) and lowest bond strengths ($6.79{\pm}3.94$) respectively. Conclusions: It was concluded that $H_2O_2$ surface treatment might enhance the bond strength of fiber posts cemented with conventional resin cements. The effect of antioxidants as post's surface treatment agents depends on the characteristics of resin cements used for bonding procedure.

2,2-Bis[4-(2-methoxy-3-methacryloyloxy propoxy) phenyl] propane을 함유한 상아질 접착레진의 물성이 접착강도에 미치는 영향 (The effect of the strength and wetting characteristics of Bis-GMA/TEGDMA-based adhesives on the bond strength to dentin)

  • 박은숙;김창근;배지현;조병훈
    • Restorative Dentistry and Endodontics
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    • 제36권2호
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    • pp.139-148
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    • 2011
  • 연구목적: 치과용 접착제에서 기저단량체로 사용되는 Bis-GMA를 Bis-M-GMA로 대체한 접착레진이, Bis-GMA/TEGDMA 를 사용한 접착제와 비교할 만한 물성과 접착강도를 가지는지 알아보고자 하였다. 연구 재료 및 방법: 다양한 구성비의 Bis-GMA, Bis-M-GMA 및 TEGDMA 를 함유한 접착레진을 제작하여, 점도(${\eta}$), 중합률(DC) 및 굴곡강도(FS)를 측정하고, 상아질에 대한 미세인장접착강도(MTBS)를 측정하였다. 해석을 위해 각 단량체들의 용해도 상수(${\delta}_t$)를 비교하였고, 접착계면을 주사전자현미경으로 관찰하였다. 결과: Bis-M-GMA의 점도는 3.65 Pa s로 크게 감소하였다. Bis-GMA를 함유하지 않는 접착레진은 Bis-GMA를 함유한 접착레진에 비해 낮은 굴곡강도를 보였다(p < 0.05). TEGDMA 함량이 낮은 접착레진은 TEGDMA 함량이 높은 접착레진에 비해 낮은 미세인장접착강도를 보였으며(p < 0.05), 주사전자현미경 사진에서 균열이나 틈이 관찰되었다. 결론: 높은 접착강도를 얻기 위해서는 접착레진의 높은 굴곡강도와 초기 중합률 뿐 아니라, 접착레진과 primer 처리 된 상아질 사이의 용해도 상수의 적합성도 요구되었다.