• 복식문화연구
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• 제11권6호
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• pp.967-971
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• 2003

As the concerns over health increased in 1990's, research and development on the health material were also activated. The development of UV-cut textile became the hot issue, because the damage of W irradiation due to ozone depletion has become widely known. UV-cut effect is determined by the material, the color, the organization and the density of UV-cut fibers. UV-cut effect is very different according to the fibers. Polyester is known to have a better effect. Even in the same textile material, staple fiber has more effect than filament fiber. Different colors have different offsets. Although textiles have the same color, the effects can be different according to the depth of color. PET, PET/cotton blend, nylon and cotton fabrics were ultraviolet cutting finished with padding method using several absorbers. These UV-cut effect can be improved through the processing. Safety of UV-cut textile for the body must be considered future, Until now the figure of the UV-cut effects has been emphasized. There has been no experiment on the human body, although the textiles are directly on the human body. Futhermore there os no safety standard of UV-cut textiles. Therefore every effort will be made to set the standard UV-cut processing is established. The need of UV-cut products will be known to the consumers.

• Korean Chemical Engineering Research
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• 제50권6호
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• pp.1068-1075
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• 2012

압출성형을 통한 core/shell 구조를 갖는 폴리부틸렌테레프탈레이트(PBT)/Nylon6,12 미세모를 제조함에 있어 최적의 압출조건을 규명하기 위하여, 압출온도와 배합비를 다르게 하여 제조한 블렌드 미세모의 상용성을 SEM 모폴로지와 DSC 분석을 통해 확인하고 UTM을 통해 압출속도에 따른 기계적 물성의 변화를 측정하였다. SEM 모폴로지 분석결과 압출온도가 증가할수록 분산상인 Nylon6,12 비드의 크기가 감소하였으며, Nylon6,12의 함량이 증가할수록 PBT 매트릭스 내 Nylon6,12의 상분리 현상이 감소하였다. DSC 분석 결과도 같은 경향을 나타냈는데, 압출온도가 상승함에 따라 녹는점에 해당하는 피크들의 경계가 사라지고, Nylon6,12의 비율이 증가할수록 두 피크의 간격이 좁아지는 것을 확인할 수 있었다. 한편 PBT/Nylon6,12 블렌드 미세모의 인장강도와 연신율 및 굴곡강도와 굴곡탄성률 모두 압출온도가 $260^{\circ}C$ 일 때까지 증가하였으나 그 이상의 온도에서는 오히려 감소하였다. $260^{\circ}C$에서의 인장강도와 연신율, 굴곡강도, 굴곡탄성률은 각각 560 $kg_f/cm^2$와 220%, 807 $kg_f/cm^2$, 22,146 $kg_f/cm^2$였는데 이는 PBT와 Nylon6,12의 중간 값을 상회하는 수치로 두 물질이 압출성형에 의한 블렌드 효과가 있다는 것을 확인할 수 있었다. 이처럼 우수한 상용성을 보일 때의 블렌드 압출 조건들을 토대로 하여 core/shell 구조의 이중구조 미세모를 제조하였다.

• 공업화학
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• 제25권1호
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• pp.14-19
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• 2014

본 연구에서는 탄소섬유(carbon fiber, CF)와 탄소나노튜브(carbon nanotube, CNT)를 포함하는 PMMA/PVDF 및 PET/PVDF 블렌드 나노복합재료를 이축성형 압출기를 이용하여 용융삽입법으로 제조하였다. SEM을 이용하여 PMMA/PVDF/CF/CNT 나노복합재료의 모폴로지를 관찰한 결과, CNT가 matrix에서 효과적으로 분산되지 못한 반면 PET/PVDF/CF/CNT 나노복합재료에서는 CNT가 잘 분산된 것으로 관찰되었다. 상분리된 PET/PVDF 블렌드에서 CNT가 PET 상에 효과적으로 분산된 것으로 보였는데 이는 PET의 페닐렌기와 CNT 표면의 그라파이트 시트가 ${\pi}-{\pi}$ interaction에 의한 것으로 판단되었다. 또한 CF도 PET와의 계면 접착성이 우수한 것으로 나타났다. PET/PVDF/CF 나노복합재료의 전기전도도는 CNT를 첨가함으로써 증가하였으나 PMMA/PVDF/CF 나노복합재료에 CNT를 첨가한 경우 전기전도도가 향상되지 않았다. 모폴로지 관찰결과에서 CNT의 분산 정도는 전기전도도 물성 결과와 일치하였다. DSC 분석 결과, PET/PVDF/CF/CNT 나노복합재료에서는 결정화 온도가 증가하였는데, 이는 CF 및 CNT가 PET의 결정화를 촉진 시키는 조핵제 역할을 하기 때문인 것으로 보였다. 굴곡물성 결과, PET/PVDF/CF/CNT 나노복합재료에서 PET와 CF의 친화성이 우수하여 굴곡탄성률이 크게 증가하였다.

• 한국의상디자인학회지
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• 제12권2호
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• pp.67-73
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• 2010

Whole process of textile printing is made by computer and it remarkably improves environment problem. This digital textile printing is becoming next step environment friendly textile printing method. But, still now range of textile possible for digital textile printing is limited, and also color analysis according to fiber types is not completed. The ink printed on the fabrics through DTP printer can be absorbed and fixed into textile without any blots by pre-treatment using suitable media solution for fabrics types. The chemical formulation of media solution used in the pre-treatment process varies according to the types of textiles and inks for DTP products. First, I studied reference books or articles about color analysis of digital textile printing. Second, I recorded pre-process, printing, post-process and coloring of silk, wool, nylon at same condition. After that, I analyzed $L^*\;a^*\;b^*$, Total K/S, ${\Delta}E$ and studied color intensity and coloring. According to this study, I suggested particular textile special for coloring and manual for affective coloring control. It showed that the performance of the digital printing on the Silk, Wool and Nylon blend fabrics treated by the media solution developed in this study was better than the one treated by the previous media solution for each single inks.

• Bulletin of the Korean Chemical Society
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• 제30권9호
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• pp.1967-1972
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• 2009

The electrospinnability of pitch was improved by blending in a solution of polyacrylonitrile (PAN) resulting in the reduction of the average fiber diameter from 2000 to 750 nm. Activated carbon fibers (ACFs) derived by stabilization, carbonization and steam activation at 700, 800, and 900 ${^{\circ}C}$ of the PAN/pitch electrospun fibers for 60 min were investigated as electrodes for supercapacitors. The Brunauer, Emmett, Teller (BET) specific surface area ranged from 732 to 1877 $m^2g^{-1}$ and the specific capacitance from 75.5 to 143.5 $Fg^{-1}$, depending on the activation conditions. Electrodes from the electrospun web activated at 900 ${^{\circ}C}$ exhibited a particularly quick response showing a high frequency of 5.5 Hz at a phase angle of ‒$45^o$ of the impedance spectroscopy.

• 한국염색가공학회지
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• 제19권1호
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• pp.1-11
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• 2007

Dyeing of polyester/cotton blends is usually carried out through the two-bath or one-bath two-step dyeing method using proper disperse dyes and reactive dyes for each fiber. However, the dyeing requires relatively long and complicated procedure as well as there are some problems such as lower dyeability. In the present study, new one-bath one-step dyeing process was investigated using disperse dyes having amino groups and hetero-bifunctional bridge compound(DBDCBS) including dichloro-s-triazinyl groups and ${\alpha},{\beta}$-dibromopropionylamido groups to improve the dyeability of cotton component in polyester/cotton blends. And the one-bath dyeing properties of polyester/cotton blends was evaluated by various dyeing conditions such as pH, temperature and dye concentration, The optimum dyeing condition was pH 4 and $110-120^{\circ}C$. Color fastness were relatively good because of the colvalent bond formation between DBDCBS-reacted cotton fiber and disperse dye.

• 복식문화연구
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• 제12권6호
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• pp.945-952
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• 2004

Shrink-resist effects and properties of the knitted fabrics from wool/acrylic(W/A) fiber blends were determined to find out an optimal blending ratio keeping the quality properties of wool products. The test fabrics were knitted by a weft knitting machine with all needle knitting structure ($0{\times}0$ rib) under the same knitting conditions with five different types of yarns: $W100\%,\;A100\%$, and W/A blended yarns(70/30, 50/50, 30/70). Shrinkage during repeated washing, electrostatic propensity, thermal resistance and pilling propensity of W/A knits. The shrink resistance was significantly enhanced on repeated washing of W/A knits, especially, over $50\%$ acrylic blended knits. Addition of strong physical force and alkali detergent applied in this washing experiment brought about superior effects with the low shrinkage rate although it was very severe washing conditions for wool fabrics. The results from the washing experiment implies that W/A blend knits can be machine washed at individual households with other ordinary laundry. There was some changes and variation found in thermal resistance, electrostatic propensity, and pilling. W/A 50/50 blended knits did not bring serious changes to other physical properties comparing with original wool, which helps consumers care wool knitted clothes more conveniently.

• 한국의류학회지
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• 제31권7호
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• pp.1119-1127
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• 2007

Nonwovens have been widely used in various regions from the households to the industrial, agricultural and medical goods. Synthetic fibers have been used for source of nonwovens commonly because of their useful and economic properties. They are not only main factor causing environmental problems but also spend huge cost to renew the environmental disruption by them. Nonwovens must have both cost-competitiveness and environment-friendly property to be the desirable sources in 21th centuries. For meet these needs, it is suitable for the times that economical and environmentally-safe kenaf fibers would be used as raw materials of nonwovens. Kenaf and polyester fibers were blended in 4 types of ratio : 0/100, 20/80, 40/60, 60/40 were needle-punched. The nonwovens properties such as color values, surface appearance, strength, elongations, stiffness, moisture regain, water and oil absorbency, and electrification were tested. As the results, tensile and tear strengths, water and oil absorbency were maximum at 20/80 kenaf/polyester blend nonwoven, because of effecting by nonwoven structure and fiber properties. The moisture regain were increased according to kenaf were blended and the eletrification reduced in proportion to the kenaf fibers by chemical property of fiber composed nonwovens.

• Biotechnology and Bioprocess Engineering:BBE
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• 제6권6호
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• pp.426-432
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• 2001

Perstractive fermentation is a good way to increase the productivity of bioreactors. Us-ing Propionibacteria as the model system, the feasibility of using supported emulsion liquid mem-brane(SELM) fro perstractive fermentation is assessed in this study. Five industrial solvents were considered as the solvent for perparing the SELM. The more polar a solvent, is the higher the par-tition coefficeint However, toxicity of a solvent also increases with its polarity. CO-1055(indus-trial decanol/octanol blend)has the highest partition coefficient toward propionic acid among the solvents that has no molecular toxicity toward Propionibacteria, A preliminary extraction study was conducted using tetradecane as solvent in a hydrophobic hollow fiber contactor. The results confirmed that SELM eliminates the equilibrium limitation of conventional liquid-liquid extrac-tion and allows the use of a non-toxic solvent with low partition coefficient.

• Composites Research
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• 제20권1호
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• pp.23-31
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• 2007

Jute fiber Green Composite의 기계적 향상을 위한 계면특성을 향상시키기 위하여 커플링제를 도입하여 첨가량에 따른 특성변화를 실험적으로 규명하였다. Maleic anhydride grafted popolypropylene(MAPP)는 자연섬유와의 계면특성의 향상에서 물리화학적 역할을 하는 것으로 판단된다. MAPP에 의한 용융상태에서의 낮아진 수지의 점도는 흐름성이 향상되어 섬유의 계면과의 접촉 면적을 확대시킨다. 약 80mm의 jute 장섬유 mat에 maleated coupler가 혼합된 PP 복합재의 물성 향상과 열가소성수지의 물리적 변화와의 관계를 고찰하였다. 이 물리적 현상을 유동지수(MI: Melting flow index) 및 점도, contact angle, 복합재료 두께, 계면전단강도, morphology 분석 등의 인자들을 이용하여 기계적 물성 향상에 기여하는 정도를 확인하였다. 특히 유동지수(MI)와 점도, MAPP의 혼합량은, 전당강도(IFSS), 인장 및 굴곡 강도와 인장탄성률의 향상과 매우 관계가 있음을 실험 결과를 통하여 확인하였다.