• Journal of the Korea Concrete Institute
• /
• v.27 no.2
• /
• pp.127-136
• /
• 2015

To evaluate the effects of limestone powder and silica fume on the properties of high-strength high-volume ground granulated blast-furnace slag (GGBFS) blended cement concrete, this study investigated the rheology, strength development, hydration and pozzolanic reaction characteristics, porosity and pore size distribution of high-strength mortars with the water-to-binder ratio of 20, 50 to 80% GGBFS, up to 20% limestone powder, and up to 10% silica fume. According to test results, compared with the Portland cement mixture, the high-volume GGBFS mixture had much higher flow due to the low surface friction of GGBFS particles and higher strength in the early age due to the accelerated cement hydration by increase of free water; however, because of too low water-to-binder ratio and cement content, and lack of calcium hydroxide content, the pozzolanic reactio cannot be activated and the long-term strength development was limited. Limestone powder did not affect the flowability, and also accelerate the early cement hydration. However, because its effect on the acceleration of cement hydration is not greater than that of GGBFS, and it does not have hydraulic reactivity unlikely to GGBFS, compressive strength was reduced proportional to the replacement ratio of limestone powder. Also, silica fume and very fine GGBFS lowered flow and strength by absorbing more free water required for cement hydration. Capillary porosities of GGBFS blended mortars were smaller than that of OPC mortar, but the effect of limestone powder on porosity was not noticeable, and silica fume increased porosity due to low degree of hydration. Nevertheless, it is confirmed that the addition of GGBFS and silica fume increases fine pores.

• Journal of the Korea Concrete Institute
• /
• v.26 no.3
• /
• pp.277-285
• /
• 2014

The purpose of this study is to investigate experimentally the variation factors range having influence on the rheological properties of the combined self-compacting concrete according to materials quality, weighting error and site conditions. Two types cement (blast-furnace slag cement and belite cement), lime stone powder as binder and the optimum mix proportions in the preceded study are selected for this study. Also, variations for sensitivity test are as followings; (1) Concrete temperature 3 cases (2) Surface moisture of sand 5cases (3) Fineness modulus of sand 5cases (4) Specific surface of lime stone powder 3cases (5) Dosage of chemical admixture 5cases. Slump flow ($650{\pm}50mm$), 500 mm reaching time (($7{\pm}3sec$), V-type flowing time ($15{\pm}5sec$) and U-box height (min. 300 mm) are tested for sensitivity. As test results, the variations range for quality control are as followings. (1) Concrete temperature; $10{\sim}20^{\circ}C$(below $30^{\circ}C$) (2) Surface moisture of sand; $base{\pm}0.6%$ (3) Fineness modulus of sand; $2.6{\pm}0.2$ (4) Dosage of chemical admixture; $base{\pm}0.2%$ (5) Specific surface of lime stone powder $6000cm^2/g$. Compared with two types cement including based belite cement (binary type) and based slag cement (ternary type), the combined self-compacting concrete used belite cement type is most stable in the quality control because of high contents for lime stone powder and $C_2S$. It is to propose a control scheme of the combined self-compacting concrete in the actual construction work.

• Journal of the Korea Concrete Institute
• /
• v.15 no.6
• /
• pp.785-793
• /
• 2003

This study is intended to analyze the effectiveness of expansive additive, shrinkage reducing agent and combination of the two to reduce the autogenous and drying shrinkage of high performance concrete using mineral admixture such as fly ash, blast furnace slag powder and silica fume. According to results, when expansive additive and shrinkage reducing agent are mixed within an appropriate mixing ratio, fluidity and air content are not influenced, and the enhancement of compressive strength is favorable at the age of 91 and 180days. At the mixing ratio of expansive additive of 5% and 10%, the autogenous and drying shrinkage is reduced by 32∼68% and 25∼49% respectively in comparison with plain concrete. And they are reduced by 18∼34% and 16∼26% respectively at the mixing ratio of shrinkage reducing agent of 0.5% and 1.0%, compared with plain concrete. The mixture of EA-SR combined with expansive additive and shrinkage reducing agent is most effective for reduction of shrinkage. Therefore, it is considered that the using method in combination with expansive additive and shrinkage reducing agent is effective to reduce the shrinkage of high performance concrete using mineral admixture such as fly ash, blast slag powder and silica fume.

• Journal of the Korea institute for structural maintenance and inspection
• /
• v.21 no.5
• /
• pp.141-147
• /
• 2017

Recently, lots of researches on concrete with high volume mineral admixtures such as ground granulated blast-furnace slag(GGBS) have been carried out to reduce greenhouse gas. The high volume GGBS concrete has advantages such as low heat, high durability, but it has a limitation in practical field application, especially low strength development in early ages. This study investigated the compressive strength and hydration characteristics of high performanc and volume GGBS cement pastes with low water to binder ratio. The effects of fineness($4,330cm^2/g$, $5,320cm^2/g$, $6,450cm^2/g$, $7650cm^2/g$) and replacement(35%, 50%, 65%, 80%) of GGBS on the compressive strength, setting and heat of hydration were analyzed. Experimental results show that the combination of high volume slag cement paste with low water to binder ratio and high fineness GGBS powder can improve the compressive strength at early ages.

• Journal of the Korea Concrete Institute
• /
• v.20 no.3
• /
• pp.405-412
• /
• 2008

Six alkali-activated (AA) concrete mixes were tested to explore the significance and limitations of developing an environmental friendly concrete. Ground granulated blast-furnace slag and powder typed sodium silicate were selected as source material and an alkaline activator, respectively. The main parameter investigated was the replacement level of lightweight fine aggregate to the natural sand. Workability and mechanical properties of lightweight AA concrete were measured: the variation of slump with time, the rate of compressive strength development, the splitting tensile strength, the moduli of rupture and elasticity, the stress-strain relationship, the bond resistance and shrinkage strain. Test results showed that the compressive strength of lightweight AA concrete sharply decreased when the replacement level of lightweight fine aggregate exceeded 30%. In particular, the increase in the discontinuous grading of lightweight aggregate resulted in the deterioration of the mechanical properties of concrete tested. The measured properties of lightweight AA concrete were also compared, wherever possible, with the results obtained from the design equations specified in ACI 318-05 or EC 2, depending on the relevance, and the results predicted from the empirical equations proposed by Slate et al. for lightweight ordinary Portland cement concrete. The stress-strain curves of different concrete were compared with predictions obtained from the mathematical model proposed by Tasnimi. The measured mechanical properties of lightweight AA concrete generally showed little agreement with the predictions obtained from these equations.

• Corrosion Science and Technology
• /
• v.8 no.5
• /
• pp.171-176
• /
• 2009

The chloride threshold level (CTL) in mixed concrete containing, ordinary Portland cement (OPC), pulverized fuel ash (PFA) ground granulated blast furnace slag (GGBS), and silica fume (SF) is important for study on corrosion of reinforced concrete structures. The CTL is defined as a critical content of chloride at the steel depth of the steel which causes the breakdown of the passive film. The criterion of the CTL represented by total chloride content has been used due to convenience and practicality. In order to demonstrate a relationship between the CTL by total chloride content and the CTL by free chloride content, corrosion test and chloride binding capacity test were carried out. In corrosion test, Mortar specimens were cast using OPC, PFA, GGBS and SF, chlorides were admixed ranging 0.0, 0.2, 0.4, 0.8, 1.0, 1.5, 2.0, 2.5 and 3.0% by weight of binder. All specimens were cured 28 days, and then the corrosion rate was measured by the Tafel's extrapolation method. In chloride binding capacity, paste specimens were casting using OPC, PFA, GGBS and SF, chlorides were admixed ranging 0.1, 0.2, 0.3, 0.5, 1.0, 1.5, 2.0, 2.5 and 3.0% by weight of binders. At 28days, solution mixed with the powder of ground specimens was used to measure binding capacity. All specimens of both experiments were wrapped in polythene film to avoid leaching out of chloride and hydroxyl ions. As a result, the CTL by total chloride content ranged from 0.36-1.44% by weight of binders and the CTL by free chloride content ranged from 0.14-0.96%. Accordingly, the difference was ranging, from 0.22 to 0.48% by weight of binder. The order of difference for binder is OPC > 10% SF > 30% PFA > 60% GGBS.

• Journal of the Korea Convergence Society
• /
• v.8 no.2
• /
• pp.157-162
• /
• 2017

Inorganic stiffening agents were prepared by mixing paper sludge incineration ash, blast furnace slag fine powder quicklime, anhydrous gypsum and fly ash. The main components of the solidifying agent developed for sludge treatment were SiO, $Al_2O_3$, $TiO_2$, $Fe_2O_3$, $Mn_2O_3$, CaO, MgO, $Na_2O$, $K_2O$, $P_2O$, and $SO_3$. Unlike cement, the developed solidifying agent did not contain $Cr^{6+}$, which is known as a carcinogen. Heavy metals and oil contaminated soil were mixed with solidifying agent and cured for 7 days and the heavy metal content was below the environmental standard. Sewage sludge cake, food waste and solidifying agent were mixed with each other, and after 7 days curing, soil component test showed that the heavy metal content was below the environmental standard. After mixing the sludge, solidifying agent and additive mixture into the beaker, the ammonia concentration was measured to be 0 after 3 days.

• Journal of Convergence for Information Technology
• /
• v.7 no.1
• /
• pp.67-73
• /
• 2017

Paper sludge ash, blast furnace slag, fine powder quicklime, anhydrous gypsum, and fly ash as the main ingredients were prepared to suit the salty soils of marine soils. The solidification component is a kind of recycled ceramic, and CaO plays an important role in solidification. The neutralization time after solidification was about 2 weeks, and the compressive strength was about 12N/mm2 in the mortar test after one week incubation with standard yarn. This is about 14 times stronger than the solidifying agent used in the metropolitan area. As a result of applying plate load test to saltous marine soils, we obtained the yield load that can pass the large scale even after 5 days. In the uniaxial compressive strength test, shear strength of about 300 kPa was obtained after 5 days. It will be useful for supplementing the soft ground in the area where marine reclamation is much like the Incheon area.

• Corrosion Science and Technology
• /
• v.8 no.3
• /
• pp.110-115
• /
• 2009

At the onset of corrosion of steel in concrete, hydrogen ions usually evolve in the process of electrochemical reaction, thereby decreasing the pH of the pore solution, which can be buffered by cement hydration products, as being representatively illustrated by calcium hydroxide. Hence, a fall in the pH is dependent on properties of cement hydration (i.e. hydration products and degree of hydration). The present study tested acid neutralization capacity (ANC) of cementitious binders of OPC(Ordinary Portland Cement), 30% PFA(Pulverized Fuel Ash), 60% GGBS(Ground Granulated Blast Furnace Slag), 10% SF(Silica Fume) to quantify the resistance of cement matrix to a pH fall. Cement pastes were cast at 0.4 of a free W/C ratio with 1.5% chlorides by weight of binder in cast. Powder samples obtained crushed and ground specimen after 200 days of curing were diluted in still water combined with different levels of 1M nitric acid solution, ranging from 0.5 to 20 mol/kg. Then, the pH of diluted solution was monitored until any further change in the pH did not take place. It was seen that the pH of the diluted solution gradually decreased as the molar amount of nitric acid increased. At some particular values of the pH, however, a decrease in the pH was marginal, which can be expressed in the peak resistances to a pH fall in the ANC curve. The peaks occurred at the variations in the pH, depending on binder type, but commonly at about 12.5 in the pH, indicate a resistance of precipitated calcium hydroxide. The measurement of water soluble chloride at the end of test showed that the amount of free chloride was significantly increased at the pH corresponding to the peaks in the ANC curve, which may reflect the adsorption of hydration products to chlorides.

• Proceedings of the Korea Concrete Institute Conference
• /
• 2008.11a
• /
• pp.717-720
• /
• 2008

This study analyzed the basic characteristics and the characteristic of drying shrinkage and creep of high performance concrete complexly metathesized by BS and FA and the results are summarized as the followings. Regarding to the compressive strengths according to the passage of aging, OPC was appeared to be larger than B2F1 at the initial aging but B2F1 was appeared to be higher than OPC at aging 28days. Regarding to the changing rate of drying shrinkage according to the passage of aging, both OPC and B2F1 were appeared to be increased and, at aging 60days, B2F1 was appeared to be largely increased by about 42% as -21${\times}$10-6 및 -51${\times}$10-6 as compared to OPC. The transforming rate of creep was appeared to have been largely increased at the initial aging and then be smoothly increased somewhat as the aging was passed. And regardign to the transforming rate of creep after 60 days had been passed, B2F1 was appeared to be largely increased by about 13% as compared to OPC.